Hydrogen Safety Research Articles

Effect of burst pressure and vented area on vented hydrogen explosions

Effect of burst pressure and vented area on vented hydrogen explosions

The Impact of the Configuration of a Hydrogen Refueling Station on Risk Level

The paper discusses potential hazards at hydrogen refueling stations for transportation vehicles: cars and trucks. The main hazard analyzed here is an uncontrolled gas release due to a failure in one of the structures in the station: storage tanks of different pressure levels or a dispenser. This may lead to a hydrogen cloud occurring near the source of the release or at a given distance. The range of the cloud was analyzed in connection to the amount of the released gas and the wind velocity. The results of the calculations were compared for chosen structures in the station. Then potential fires and explosions were investigated. The hazard zones were calculated with respect to heat fluxes generated in the fires and the overpressure generated in explosions. The maximum ranges of these zones vary from about 14 to 30 m and from about 9 to 14 m for a fires and an explosions of hydrogen, respectively. Finally, human death probabilities are presented as functions of the distance from the sources of the uncontrolled hydrogen releases. These are shown for different amounts and pressures of the released gas. In addition, the risk of human death is determined along with the area, where it reaches the highest value in the whole station. The risk of human death in this area is 1.63 × 10−5 [1/year]. The area is approximately 8 square meters.

Large Eddy Simulation of large-scale hydrogen deflagrations using the Thickened Flame Model with stretch sensitivity adaptation and thermo-diffusive instability modeling

Due to the high costs associated to experimental testing of hydrogen (H2) explosions, numerical simulations play an essential role in the design of safe industrial systems. In this work, we investigate the use of the Thickened Flame Model (TFM) to perform simulations of H2 deflagrations. Specific issues arise when considering hydrogen: (i) due to differential diffusion, the flame is very sensitive to stretch; (ii) instabilities of the flame front are generated and lead to an increased flame propagation speed. Both of these phenomena are affected by flame thickening. First, the flame sensitivity to stretch is artificially increased by the thickening. The recently developed Ma-TFM model proposes a correction of diffusive fluxes to reach the correct Markstein length and is selected in this work. Secondly, thermo-diffusive and hydrodynamic flame instabilities are also altered by thickening. By computing the dispersion relationship for a hydrogen/air mixture, we show that the instability scales are proportional to the thickening factor F. A simple subgrid scale (SGS) model, based on the computations of laminar unstable 2-D and 3-D flames, is then considered to take into account the effect of instabilities. The Ma-TFM and SGS instability models are applied together for the first time on a semi-industrial vented lean hydrogen deflagration, leading to promising results. In particular, it is found that considering 3-D unstable flames is necessary to accurately predict the experimental pressure peaks.

The Adsorption and Sensing Characteristics of Metal‐Calix[4]Arenes Toward Hydrogen Molecule: Density Functional Theory, Perturbation Theory and Molecular Dynamics Approaches

AbstractCalixarenes, which can be functionalized in a wide range of derivatives, are one of the chemicals that should be considered for safe energy storage. This research focused on utilization Density Functional Theory (DFT) method to investigate the hydrogen sensing and adsorption characteristics of two distinct calix[4]arene compounds and their corresponding metal complexes. In the study, electronic sensor properties were investigated by using different approaches. In addition, the dynamic stability was determined by Molecular dynamics (MD) calculations. Perturbation theory analysis has revealed the importance of the relationship between Fe and S atoms. The adsorption energy on the C1 structure with the best adsorption ability was calculated as −10.3 kJ/mol. According to RDG analysis, weak van der Waals interactions play a role in adsorption. The C2‐Fe complex with a substantial decrease in the HOMO–LUMO gap has been identified and explained as an applicant material for electronic sensor against hydrogen molecule. Moreover, it was also determined that the C2‐Fe complex has work function type gas sensor property against hydrogen molecule. According to the results, metal‐calixarene complexes can play an important role in hydrogen safety in the future.

Risk assessment of hydrogen leakage and explosion in a liquid hydrogen facility using computational analysis

In this study, the dispersion and explosion of liquid hydrogen (LH2) in leakage accidents are investigated using the Flame Accelerator Simulator (FLACS) code. The study focus was a liquid hydrogen research facility in Gimhae, South Korea. Simulations were conducted under various conditions by varying the mass flow rates (0.61 and 0.3 kg/s), directions (lateral in areas with minimal structures, lateral towards a tube trailer truck, and downward), and durations (90 and 180 s) of leakage. The results indicated that higher leakage mass flow rates produce a larger flammable cloud volume (FCV), resulting in higher maximum overpressures than that caused by lower flow rates. Downward leakage generally resulted in a larger FCV and higher overpressure than lateral leakage. The explosion characteristics were also influenced by geometry of LH2 facility, including the presence of structures in the leakage path. Contrastingly, leakage duration had a minimal effect on the maximum overpressure because an increased duration causes a greater dilution of hydrogen, only slightly expanding the FCV. According to the overpressure–impulse diagram, higher leakage flow rates cause severe health risks, approaching thresholds for lung rupture and 100% fatality. Contrary to the minor damages caused by lower leakage flow rates. High flow rates, particularly with downward leaks, can cause significant structural damage in brick buildings, potentially leading to partial demolition.

The impact of fuel cell vehicle exhaust grille shape under natural ventilation on hydrogen leakage and diffusion

The rapid progression of hydrogen fuel cell vehicles has brought forth various challenges, primarily the frequent occurrence of hazardous incidents stemming from hydrogen leakage and diffusion. Consequently, there is a growing emphasis on hydrogen safety, leading to the development of stricter standards and regulations to mitigate the associated safety risks. Research on the design of exhaust port structures to facilitate the safe diffusion of hydrogen after leakage in diverse scenarios has become increasingly significant. This study examines the impact of exhaust grille shapes on hydrogen leakage and diffusion phenomena within the hydrogen storage compartment of fuel cell vehicles under natural ventilation conditions. Five distinct porous grille shapes were examined: rectangular, circular, square, rhombic, and hexagonal grilles. Numerical simulations of hydrogen leakage and diffusion within the compartment were conducted using Cradle scFLOW software. The effectiveness of the different grille shapes was assessed using several criteria, including average hydrogen molar fraction, pressure drop (indicative of negative pressure regions), density, and Richardson number. Overall, the rectangular grille exhibited superior performance in facilitating hydrogen venting.

Advancements in Flexible and Stretchable Electronics for Resistive Hydrogen Sensing: A Comprehensive Review.

Flexible and stretchable electronics have emerged as a groundbreaking technology with wide-ranging applications, including wearable devices, medical implants, and environmental monitoring systems. Among their numerous applications, hydrogen sensing represents a critical area of research, particularly due to hydrogen's role as a clean energy carrier and its explosive nature at high concentrations. This review paper provides a comprehensive overview of the recent advancements in flexible and stretchable electronics tailored for resistive hydrogen sensing applications. It begins by introducing the fundamental principles underlying the operation of flexible and stretchable resistive sensors, highlighting the innovative materials and fabrication techniques that enable their exceptional mechanical resilience and adaptability. Following this, the paper delves into the specific strategies employed in the integration of these resistive sensors into hydrogen detection systems, discussing the merits and limitations of various sensor designs, from nanoscale transducers to fully integrated wearable devices. Special attention is paid to the sensitivity, selectivity, and operational stability of these resistive sensors, as well as their performance under real-world conditions. Furthermore, the review explores the challenges and opportunities in this rapidly evolving field, including the scalability of manufacturing processes, the integration of resistive sensor networks, and the development of standards for safety and performance. Finally, the review concludes with a forward-looking perspective on the potential impacts of flexible and stretchable resistive electronics in hydrogen energy systems and safety applications, underscoring the need for interdisciplinary collaboration to realize the full potential of this innovative technology.

Incident investigation of hydrogen explosion and fire in a residue desulfurization process

A large hydrogen explosion and fire occurred on October 27, 2022 in a residue desulfurization (RDS) process in a refinery in Kaohsiung, Taiwan. RDS is an important process that use hydrogen to convert the sulfur in the fuel into hydrogen sulfide for producing low sulfur fuel. The incident occurred during pressurization of the RDS reactors and downstream coolers by hydrogen. The incident led to significant damages to the downstream coolers and some part of the RDS reactors. Detailed incident investigation was carried out. A reactor effluent air cooler (REAC) in the downstream of RDS reactors was found to be ruptured in the rectangular header box. With security videos, process DCS data, leak and dispersion modelling, and actual damage on the process, it is possible to reproduce the leak rate, size of the initial fireball and damages done to the process. It is also found that the hydrogen leak was accompanied by prompt ignition which is commonly encountered in high-pressure hydrogen services. Recommendations are made to prevent and mitigate any future incident from the RDS process.

Breaking the Pt Electron Symmetry and OH Spillover towards PtIr Active Center for Performance Modulation in Direct Ammonia Fuel Cell.

The growing interest in low-temperature direct ammonia fuel cells (DAFCs) arises from the utilization of a carbon-neutral ammonia source; however, DAFCs encounter significant electrode overpotentials due to the substantial energy barrier of the *NH2 to *NH dehydrogenation, compounded by the facile deactivation by *N on the Pt surface. In this work, a unique catalyst, Pt4Ir@AlOOH/NGr i.e., Pt4Ir/ANGr, is introduced composed of PtIr alloy nanoparticles controllably decorated on the pseudo-boehmite phase of AlOOH-supported nitrogen-doped reduced graphene (AlOOH/NGr) composite, synthesized via the polyol reduction method. The detailed studies on the structural and electronic properties of the catalyst by XAS and VB-XPS reveal the possible electronic modulations. The optimized Pt4Ir/ANGr composition exhibits a significantly improved onset potential and mass activity for AOR. The DFT study confirms the OHad species spillover by AlOOH and Pt4Ir (100) facilitates the conversion of the *NH2 to *NH with minimal energy barriers. Finally, testing of DAFC at the system level using a membrane electrode assembly (MEA) with Pt4Ir/ANGr as the anode catalyst, demonstrating the suitability of the catalyst for its practical applications. This study thus uncovers the potential of the Pt4Ir catalyst in synergy with ANGr, largely addressing the challenges in hydrogen transportation, storage, and safety within DAFCs.

Effect of mesh aluminum alloy on hydrogen and propane explosion characteristics

In order to explore the effect of mesh aluminum alloy (MAA) on the explosion characteristics of different types of gases, experiments were conducted by filling MAA in hydrogen and propane explosion pipes. The explosion characteristic parameters of hydrogen and propane with different volume fractions under the action of MAA were obtained. The chain reaction process and thermodynamic reaction mechanism of hydrogen and propane explosions were studied using the numerical simulation software CHEMKIN-PRO and Materials Studio. The experimental results show that MAA significantly promotes hydrogen explosions but inhibits propane explosions. Simulation results show that ·H, ·O, and ·OH are key radicals in the hydrogen explosion process. As the hydrogen volume fraction increases, the number of radicals in the reaction system also increases. When MAA is filled in the hydrogen explosion test pipe, the turbulence of the flame structure inside the pipe increases the collision probability between key radicals such as ·H, ·O, and ·OH, sharply increasing the temperature of the explosion reaction system, resulting in a promoting effect of MAA on hydrogen explosions. When MAA is introduced into the propane explosion test pipe, it creates a barrier and wall effect. This reduces the number of key radicals in the reaction system and lowers the likelihood of radical collisions, which slows down the rates of multiple chain reactions and inhibits the propane explosion. Thermodynamically, it can be seen that propane requires more energy than hydrogen for key elementary reactions to explode, making it more difficult to react.

Investigation on the inhibition effect and mechanism of hydrogen explosion by 2-bromo-3,3,3-trifluoropropene

This study investigated the effect of 2-bromo-3,3,3-trifluoropropene (2-BTP, C3H2BrF3) on hydrogen explosion behavior through a combination of experiments and simulations. The maximum explosion pressure (pmax), maximum pressure rise rate ((dp/dt)max), and critical inhibition concentration (CIC), across different equivalence ratios (Φ) and inhibitor concentrations (V), were obtained via experiments. The changes in adiabatic flame temperature, mole fraction of active radicals and sensitivity coefficient throughout the reaction were analyzed using CHEMKIN. The fuel-like properties of 2-BTP and the carbon monoxide (CO) produced by decomposition led to a promoting effect on the lean hydrogen explosion, primarily due to the elementary reactions R31, R806 and R882. When Φ≥1.0, the capture of active radicals via elementary reactions such as R908, R1507, and R88 was enhanced, resulting in the dominance of inhibition and a corresponding inhibitory effect. Notably, 2-BTP exhibited an inhibitory effect for (dp/dt)max at any equivalence ratio. The CIC decreased from 10% to 4% when increasing equivalence ratios from 0.6 to 2.0. This work provides crucial data and a theoretical foundation for the prevention and control of hydrogen explosions.

Applying membrane techniques to separate hydrogen from natural gas for hydrogen technologies

Today, the world's energy industry is grappling with several issues arising from restrictions on harmful greenhouse gas emissions, related to climate and environmental protection. Methods of storing energy in various types of carriers are becoming increasingly important, the most promising of which is hydrogen. Various methods of storing it are being considered, where an interesting option is to store it temporarily, under certain conditions, in existing natural gas networks. The challenge, however, is its subsequent recovery. Membrane technology is receiving special attention among recovery methods because of its potential efficiency in hydrogen separation, safety and ease of operation, low energy requirements and environmental friendliness. The paper presents a literature study of the issue, preliminary analyses of membrane gas separation and the advisability of the direction of the new research that has been undertaken. The possibility of applying membrane techniques to the process of separating hydrogen from natural gas in transmission and distribution networks for hydrogen storage technology is presented. Preliminary research is geared toward exploring the scope of applicability of this method of membrane separation, in which the primary goal is to determine the possibility of separating hydrogen from methane. In this paper, within the framework of the adopted simplified structure of the polymeric membrane module, the basic parameters of the process (share of hydrogen in the feed, membrane surface area) were determined, as well as the influence and dependence of transmembrane pressure (permeate) on the values of membrane selectivity, recovery rate and purity of the obtained hydrogen.

Phase change materials as hydrogen explosion suppressants: An experimental and kinetic investigation

To investigate the potential application of phase change materials as H2 explosion suppressants, in the present work, the inhibition effect of Na2HPO4·12H2O, K2HPO4·3H2O, and Na2CO3·10H2O on H2 explosion were experimentally studied. The corresponding explosion suppression mechanism was calculated by using a comprehensive combustion model. Results showed that the selected phase change materials inhibited the H2 explosion, and Na2CO3·10H2O has the most significant effect for fuel-lean H2-air mixtures when 12 g was added. Of which the maximum explosion pressure (Pmax) and maximum rate of pressure rise (dp/dt)max were reduced by 26.6 % and 28.1 %, and maximum pressure increase time (tb) and peak pressure time(tc) were increased by 112.2 % and 120.3 %. The inhibition mechanism of Na2CO3·10H2O on H2 was revealed by numerical simulation. The adiabatic flame temperature (AFT) and laminar burning velocity (LBV) of H2-air mixture decrease with increasing hydrated salt addition, the free radicals H, O and OH have a decisive influence on the explosion process during which H decreases by 86.4 % at most. The chain initial reaction O + H2 ⇌ H + OH and the sodium-containing primitive reaction NaO + H + M ⇌ NaOH + M have the most significant influence on the combustion processes. The results of present work give a theoretical foundation for application the phase change materials in H2 explosion safety industry.

High-pressure core meltdown and hydrogen generation during In-vessel and Ex-vessel phases of VVER-1000 nuclear reactor and effect of heat structures

Following unprecedented Fukushima Daiichi severe accident, which significantly amplify the production of hydrogen and the associated risk of explosions, particularly in accidents like station blackout (SBO) that jeopardize containment integrity and reactor safety, a thorough investigation and comprehension of the phenomenon known as high-pressure melt ejection (HPME) are necessary. This study examines how the SBO accident develops without operator intervention or access to emergency diesel generators through full nuclear power plant simulation, including containment, core, primary, and secondary circuits. Accurate time step selection is crucial for the simulation to produce reliable results for high-pressure melt ejection processes. While the process is faster and easier under Low Pressure Melt Ejection (LPME) conditions, time step tuning can significantly lengthen the (HPME) simulation (approximately one month for each scenario). After thorough examinations and analysis of various simulation findings, three cases were evaluated for the ex-vessel phase, illustrating the most likely scenarios of high-pressure molten material splashing into the cavity. The findings demonstrate that during the in-vessel phase, 578 kg of hydrogen is created. Additionally, during the ex-vessel phase, there is a significant increase in the containment’s temperature and pressure due to the high-temperature hydrogen and significant water and steam leakage. The temperature and pressure inside the containment rise well above the safety criteria due to the leakage of 1529 kg of hydrogen from the cavity and lead to hydrogen explosion due to MELCOR message. The calculated amount of hydrogen gas is within the explosion limit range of 18.3% to 59% of the containment atmospheric pressure volume. Moreover, the height and diameter of the cavity alter due to the direct heating and corrosion of the cavity walls, ultimately compromising the integrity of the plant in the alpha mode. Based on the results obtained, it can be seen that if a large portion of the molten material is deposited on the concrete surface (case III) instead of dispersed in the cavity atmosphere (case I), the rate of hydrogen production and therefore the total amount of hydrogen (and its related energy) produced will be increased and could lead to deflagration to detonation situation.

Investigating the Key Drivers in the Transition to Sustainable Hydrogen Transportation Fuel

Introduction. Hydrogen is a promising energy carrier that can achieve net-zero carbon emissions and decrease fossil fuel dependency. However, the importance of the driving forces in hydrogen adaptation and acceptance during the transition to this technology should be emphasised. When assessing hydrogen as a sustainable transportation fuel, defining the success criteria is vital to comprehend the benefits of hydrogen in the transition process. The transport sector is a priority area for the transition to zero emissions, which requires an understanding of the links between the key drivers of hydrogen adoption in transportation. Aim and tasks. This study aims to identify the key drivers of the hydrogen transition and explore the relationship between the transition drivers to hydrogen as a sustainable transport fuel based on a comprehensive literature review and an interpretative structural modelling approach to determine the relationship between the above-mentioned key drivers. Results. This study identified key drivers for the transition to hydrogen as a sustainable transport fuel using the Interpretive Structural Modelling (ISM) approach. This study examines the potential of hydrogen transition, analyses the driving forces, and examines their interrelationships in terms of driving force and dependent force. The role of technological development and transition awareness in achieving the SDGs is revealed. Robust regulatory agendas and supportive strategies, Workforce development and training based on hydrogen deployment, and Industry partnerships and collaboration are the most fundamental drivers for achieving the transition to hydrogen as a sustainable transport fuel. In addition, the advancement of hydrogen technologies in production, storage, and transportation, as well as hydrogen production and use, aligns with environmental aims, which are key factors that depend mainly on the actions of other driving forces. However, the limitations of this study include subjectivity and potential differences in the driving forces across countries and sectors. Conclusions. The deployment of green hydrogen transition for a clean energy source is critical in carbon-intensive sectors of the economy, which are characterised by key drivers and their interlinkages, such as regulatory strategies, workforce development, and industry partnerships. This has increased the flexibility of energy systems with the collaboration of the stakeholders for developing hydrogen technologies and infrastructure, considering the environmental safety, economic efficiency, and social acceptability of hydrogen.

Investigation into the hydrogen inhibition mechanism of Platycladus orientalis leaf extract as a biodegradation inhibitor for waste aluminum-silicon alloy dust in wet dust collectors

This study investigates the risk of hydrogen explosion caused by waste metal dust encountering water in wet dust collectors. It proposes using renewable plant extracts to suppress hydrogen evolution from aluminum-silicon (Al-Si) alloy dust, aiming to achieve intrinsically safer production. Platycladus orientalis leaf extract (POLE) was prepared using water as a solvent. Hydrogen inhibition experiments, material characterization, and theoretical calculations were conducted to evaluate the effect of POLE on waste Al-Si dust. The inhibition experiments demonstrated that POLE exhibits excellent inhibitory performance. At a POLE concentration of 2.0 g/L, the hydrogen inhibition efficiency reaches 97.71 % after 22 h, with a reaction rate constant of 8.9708 × 10−5, approaching zero. This efficiency remained stable over 5 days. POLE formed a uniform, dense protective film on the Al-Si dust surface, with a contact angle of 99.23°. FTIR spectra revealed absorption peaks corresponding to POLE functional groups and Al-O bonds, indicating that successfully adsorption of POLE through both physical and chemical interactions. Finally, theoretical calculations were performed to further explain the hydrogen inhibition mechanism of POLE, supplementing and confirming the characterization data. This study inhibited hydrogen production from waste dust, offering a new approach to enhancing the hydrogen production rate from recycled Al scraps.

In-situ hydrogen-generating injectable short fibers for osteoarthritis treatment by alleviating oxidative stress

Hydrogen (H₂) has great potential in the treatment of osteoarthritis, but its rapid diffusion and short retention time make it difficult to exert stable therapeutic effects. This study developed a short-fiber injectable material that can continuously generate hydrogen in situ to eliminate reactive oxygen species (ROS), alleviate oxidative stress and inflammation, and promote tissue repair. We prepared H–Si nanosheets with high hydrogen generation efficiency using a wet chemical exfoliation method and combined them with GelMA short fibers via electrospinning technology, achieving the in situ delivery of H–Si nanosheets and regulated hydrogen generation rate through the encapsulation and degradation of GelMA, ultimately achieving continuous and controlled hydrogen supply and stable therapeutic effects for osteoarthritis. In vitro and in vivo experiments confirmed the safety and efficacy of this material. The results showed that the material could continuously and efficiently generate hydrogen in simulated physiological environments (100 mg of material could generate 8.6 % hydrogen), effectively eliminate cellular reactive oxygen species (ROS positive rate reduced by 85.89 %), reduce cellular senescence and apoptosis (cell death rate decreased by 52 %, SA-βgal expression decreased by 78.3 %), promote normal chondrocyte function (Col II expression increased by 67.4 %, Ki67 expression increased by 87.5 %), and improve osteoarthritis in rats (OARSI score increased by 216 %). The in situ hydrogen generation and control system designed in this study provides a new method for the hydrogen's local and stable treatment of osteoarthritis. Statement of significanceHydrogen (H₂) has great potential in the treatment of osteoarthritis by alleviating oxidative stress, but its rapid diffusion and short retention time make it difficult to exert stable therapeutic effects. This study introduces an innovative injectable material combining H–Si nanosheets and GelMA short fibers to address this issue. By enabling continuous in situ hydrogen generation, this material effectively eliminates reactive oxygen species, reduces oxidative stress and inflammation, and promotes tissue repair. In vitro and in vivo experiments demonstrate its high hydrogen generation efficiency, safety, and therapeutic efficacy, offering a promising new approach for osteoarthritis management.

Numerical study of external explosion in vented hydrogen explosions

In the current study, numerical study of vented hydrogen explosions was performed utilizing computational fluid dynamics (CFD) software GASFLOW-MPI. A turbulent combustion model based on Schmidt correlation was formulated. Within this model, flame instabilities resulted from two intrinsic effects, Hydrodynamic instability, and Landau-Darrieus and Thermal-Diffusive instabilities were incorporated. The numerical simulation results revealed the mechanism of overpressure evolution inside and outside the vessel. Notably, the mechanism of the overpressure peak induced by the external explosion was revealed. The effects of turbulence models on overpressure time profiles were investigated. Moreover, it was determined that heat transfer, arising from thermal radiation and convection, exerts only a negligible influence on the maximum internal overpressure. Subsequently, the performance of GASFLOW-MPI in simulating vented hydrogen explosions for different ignition locations (center and rear ignitions) and varying hydrogen concentrations (22 %-38 %) was assessed against experimental data. Comparative analysis revealed a close agreement between the predicted results and experimental data. Furthermore, the competency of GASFLOW in simulating medium-scale vented hydrogen explosions was validated against experimental data.

Thermal energy propagation characteristics and hazard effects of hydrogen cloud explosion

Hydrogen has advantages such as high energy density and zero carbon emissions, but it poses a risk of generating explosion fireballs in the air. The gas explosion process not only involves thermal radiation from the fireball but also heat conduction and convection caused by the diffusion of high-temperature products. In this work, the thermal parameters of hydrogen cloud explosion with different equivalence ratios and gas cloud radius in an unconfined space were investigated. The results show that the flame temperature-distance curve of a hydrogen explosion exhibited a ’Z’ type. The maximum distance of flame propagation is positively correlated with the peak thermal radiation flux and cloud radius and increases first and then remains steady with the equivalence ratio. When only considering thermal convection, the minimum injury distance of flame temperature is achieved, and the thermal radiation effect can promote the flame propagation speed. Under the q-t criterion, the effective thermal radiation radius of first-level damage at a gas cloud size of 1 m was 6.11 m at φ = 1.2, which was 1.89 times that of φ = 0.6. Compared with the thermal dose criterion, the thermal flux-time criterion results in a larger thermal injury radius. The propulsion effect of hydrogen explosion products can cause the hydrogen cloud in the premixed zone to diffuse outward. The critical distance of hydrogen diffusion within the lower explosion limit was also analyzed. This study provides significant guiding implications for preventing hazards in people and buildings.

Effects of Vent Size and Pressure on Hydrogen Explosion Dynamic Characteristics.

Explosion venting is an effective method to reduce the explosion damage; in order to study the mechanism of an explosion venting process in internal and external space, this paper investigates the influence of vent parameters on hydrogen-air explosion in a rectangular duct through numerical simulation. The model including the internal and external space is first constructed, and then the explosion dynamic behaviors of the full flow field are analyzed under different vent pressures and sizes. The study aims to reveal the coupling effect of the flame, pressure, and flow field on hydrogen explosion venting. The results indicate that the explosion intensity increases with the growth of the vent pressure and the reduction of the vent size. The maximum external overpressure increases to 2.6 and 2.3 times as the vent pressure increased to 10 times or vent size reduced by 90%. The flame and combustible gas mixture evolve from a mushroom cloud into a jet form as the vent size decreases, and vortexes formed at the flame front suppress flame propagation. However, the flame speed increases significantly as the flame passes the vent under the impact of larger pressure gradient, which results in a more violent turbulence intensity and secondary external explosion.