Abstract Shales and mudstones are fine-grained rocks formed in sedimentary basins throughout Earth’s history. These lithologies are increasingly important targets for mineral deposit exploration since they can have economic resources of critical minerals including vanadium (V), an essential component of redox-flux batteries in solar cells. However, many Paleozoic shale-hosted V deposits are metamorphosed and deformed. This commonly obscures primary features including V-bearing host phases and the original composition of organic material. In this study, we present geochemical and mineralogical data from the Paleozoic Van Property deposit, Northwest Territories, Canada, to show that V can be released from organic matter during metamorphism and incorporated in clay phases such as illite. The siliceous argillites at the Van Property hosts up to 0.69% V2O5 and were metamorphosed to (sub-)greenschist facies. Their mineralogy is dominated by quartz with minor graphite, illite, muscovite, pyrite, sphalerite, rutile, and carbonates. Although, some illite (i.e., high-V illite) can have up to 13 wt% V2O3 and rutile can have up to 4.4 wt% V2O3, mass balance calculations are insufficient to explain V enrichment at the Van Property utilizing only illite and rutile. The third V host is inferred to be carbonaceous matter in which V accumulated syn-deposition on the seafloor. Subsequent metamorphism led to the demetallation of V-bearing geoporphyrins and the release of vanadyl ions (VO2+), some of which were then incorporated into high-V illite and rutile. This process of V enrichment highlights the role of organic matter in scavenging V from superficial reservoirs and the importance of metamorphism on subsequent V release and its incorporation into inorganic phases. The geochemistry of siliceous, V-rich argillites at the Van Property is also compared to other V-enriched shale and mudstone deposits, highlighting the diversity of shale-hosted V deposits, and emphasizing the need for further research to close the knowledge gaps related to variations in composition, mineralogy and V enrichment processes.
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