In this paper, the experimental study of heat transfer during condensation of freons R22 and R407С in a plain smooth tube with 17 mm inner diameter was carried out at saturated condensing temperature 40 °C, while mass velocity ranged between 6 and 57 kg/(m2s) and vapour quality changed from 0.23 to 0.95. The unique measurements of circumferential heat fluxes and heat transfer coefficients were performed with the thick wall method during the stratified flow of the phases. The authors performed numerical simulation of heat transfer from condensing vapour to cooling water through the thick-walled cylindrical wall. The CFD model was validated by conducting the physical experiment, which indicated the results coincidence with an error from 7 to 20%. The obtained results allowed improving prediction of effective heat transfer coefficients for vapour condensation, which takes into account the influence of condensate flow in the bottom part of the tube on the heat transfer. This method generalizes with sufficient accuracy (error ± 30%) the experimental data on condensation of freons R22, R134a, R123, R125, R32, R410a, propane, isobutene, propylene, dimethyl ether, carbon dioxide and methane under the stratified flow conditions. Using this method for designing heat exchangers, which utilize such types of fluids, will increase the efficiency of thermal energy systems.