Experimental modal analysis techniques are designed to exploit a property of linear vibration theory in order to construct a mathematical model of a structure from the minimum amount of measured mobility data. This property, derived from the orthogonality of normal modes, is that, in principle, all the elements of the full N × N mobility matrix can be derived from measurement of the elements in just one row or column of that matrix. The property is also used in procedural quality “checks”, in which one measures some of the derived mobilities as well as predicting them. The derivation process itself, however, gives rise to an inherent error when the frequency range covered does not include all the natural frequencies of the structure. The source of this error is discussed and some illustrations of its significance are quoted, demonstrating the need for caution when applying modal analysis methods to practical structures.