Exotic Quantum Research Articles

Emerging new phases in correlated Mott insulatorCa2RuO4

Abstract The Mott insulator Ca2RuO4 is a paradigmatic example among transition
metal oxides, where the interplay of charge, spin, orbital, and lattice degrees of freedom leads to competing quantum phases. In this paper, we focus on and review some key aspects, from the underlying physical framework and its basic properties, to recent theoretical efforts that aim to trigger unconventional quantum ground states, using several external parameters and stimuli. Using first-principle calculations, we demonstrate that Ca2RuO4 shows a spin splitting in the reciprocal space, and identify it as an altermagnetic candidate material. The non relativistic spin-splitting has an orbital selective nature, dictated by the local crystallographic symmetry. Next, we consider two routes that may trigger exotic quantum states. The first one corresponds to transition metal substitution of the 4d4 Ru with isovalent 3d3 ions. This substitutional doping may alter the spin-orbital correlations favoring the emergence of negative thermal expansion. The second route explores fledgling states arising in a nonequilibrium steady state under the influence of an applied electric field. We show that the electric field can directly affect the orbital density, eventually leading to strong orbital fluctuations and the suppression of orbital imbalance, which may, in turn, reduce antiferromagnetism. These aspects suggest possible practical applications, as its unique properties may open up possibilities for augmenting existing technologies, surpassing the limitations of conventional materials.

Observation of vortices in a dipolar supersolid.

Supersolids are states of matter that spontaneously break two continuous symmetries: translational invariance owing to the appearance of a crystal structure and phase invariance owing to phase locking of single-particle wavefunctions, responsible for superfluid phenomena. Although originally predicted to be present in solid helium1-5, ultracold quantum gases provided a first platform to observe supersolids6-10, with particular success coming from dipolar atoms8-12. Phase locking in dipolar supersolids has been investigated through, for example, measurements of the phase coherence8-10 and gapless Goldstone modes13, but quantized vortices, a hydrodynamic fingerprint of superfluidity, have not yet been observed. Here, with the prerequisite pieces at our disposal, namely a method to generate vortices in dipolar gases14,15 and supersolids with two-dimensional crystalline order11,16,17, we report on the theoretical investigation and experimental observation of vortices in the supersolid phase (SSP). Our work reveals a fundamental difference in vortex seeding dynamics between unmodulated and modulated quantum fluids. This opens the door to study the hydrodynamic properties of exotic quantum systems with numerous spontaneously broken symmetries, in disparate domains such as quantum crystals and neutron stars18.

Spin-valley locked topological phase transitions in reversible strain-tailoring honeycomb motifs

Using an effective low-energy k·p model on the frontier px,y orbitals, we establish a general phase diagram of spin-valley locked band inversion by introducing a mechanical strain field into nonmagnetic honeycomb motifs with robust spin–orbit coupling and intrinsically broken inversion symmetry. Using first-principles calculations, we realize such multiple topological phase transitions in a strained InTe monolayer within experimental reach with the Weyl semimetal as the nontrivial boundary state at two critical strains. The massless Weyl fermions endow the spin and valley Hall effects with ultrafast and dissipationless transport over a broad low-energy window. The valley selective circular dichroism can be regulated by strain-induced band inversion. A crossover between the topologically trivial and nontrivial regimes with sizable bandgaps makes InTe suitable for room-temperature (RT) topological strain-effect transistors. Our work not only demonstrates a fundamental mechanism for exploring tunable topological states and valley physics but also provides a potential platform for realizing many exotic phenomena and RT quantum devices.

Diverse electronic landscape of the kagome metal YbTi3Bi4

Kagome lattices have emerged as an ideal platform for exploring exotic quantum phenomena in materials. Here, we report the discovery of Ti-based kagome metal YbTi3Bi4 which we characterize using angle-resolved photoemission spectroscopy (ARPES) and magneto-transport, in combination with density functional theory calculations. Our ARPES results reveal the complex fermiology of YbTi3Bi4 and provide spectroscopic evidence of four flat bands. Our measurements also show the presence of multiple van Hove singularities originating from Ti 3d orbitals and a linearly-dispersing gapped Dirac-like bulk state at the K¯\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\overline{\\,{\\mbox{K}}\\,}$$\\end{document} point in accord with our theoretical calculations. Our study establishes YbTi3Bi4 as a platform for exploring exotic phases in the wider LnTi3Bi4 (Ln = lanthanide) family of materials.

Nonequilibrium control of kagome metals

Abstract Exotic quantum order in kagome metals, i.e., quantum materials with a Fermi liquid parent state of electrons on a kagome lattice, has appeared as a vibrant emerging field of condensed matter physics. Already in a small kagome material subclass such as vanadium-based compounds AV$$_3$$ 3 Sb$$_5$$ 5 ($$A=$$ A = K, Rb, Cs), the first wave of experimental exploration has brought about manifold evidence for hitherto largely elusive phenomena such as high-temperature charge ordering with orbital currents, nematic order, cascades of charge ordering transitions with hierarchies of ordering vectors, and unconventional superconductivity. We argue that kagome metals promise to be a prototypical ground for the nonequilibrium analysis of quantum order through time-dependent parameter control and manipulation. In particular, we propose to investigate the nematic character of kagome quantum order through light and strain pulses, as well as the nature of time-reversal symmetry breaking and chirality through properly polarized laser pulses. Graphical abstract

Dirac-Like Fermions Anomalous Magneto-Transport in a Spin-Polarized Oxide 2D Electron System.

In a 2D electron system (2DES) the breaking of the inversion, time-reversal and bulk crystal-field symmetries is interlaced with the effects of spin-orbit coupling (SOC) triggering exotic quantum phenomena. Here, epitaxial engineering is used to design and realize a 2DES characterized simultaneously by ferromagnetic order, large Rashba SOC and hexagonal band warping at the (111) interfaces between LaAlO3, EuTiO3, and SrTiO3 insulators. The 2DES displays anomalous quantum corrections to the magneto-conductance driven by the time-reversal-symmetry breaking occurring below the magnetic transition temperature. The results are explained by the emergence of a non-trivial Berry phase and competing weak anti-localization/weak localization back-scattering of Dirac-like fermions, mimicking the phenomenology of gapped topological insulators. These findings open perspectives for the engineering of novel spin-polarized functional 2DES holding promises in spin-orbitronics and topologicalelectronics.

Emerging Chirality and Moiré Dynamics in Twisted Layered Material Heterostructures.

Moiré superstructures arising at twisted 2D interfaces have recently attracted the attention of the scientific community due to exotic quantum states and unique mechanical and tribological behaviors that they exhibit. Here, we predict the emergence of chiral distortions in twisted layered interfaces of finite dimensions. This phenomenon originates in intricate interplay between interfacial interactions and contact boundary constraints. A metric termed the fractional chiral area is introduced to quantify the overall chirality of the moiré superstructure and to characterize its spatial distribution. Despite the equilibrium nature of the discovered energetic and structural chirality effects, they are shown to be manifested in the twisting dynamics of layered interfaces, which demonstrates a continuous transition from stick-slip to smooth rotation with no external trigger.

Dirac fermions and spin transport in the SrVO3/SrTiO3 quantum well

The type-II Dirac fermions are characterized by a tilted Dirac cone and sustain exotic quantum transport phenomena. Here, we show the emergence of a type-II Dirac nodal loop in the SrVO3/SrTiO3 quantum well structure by density functional theory calculations and symmetry arguments. When the spin–orbit coupling (SOC) is neglected, the unavoidable crossing between two t2g bands gives rise to a nodal loop in the Brillouin zone, which is protected by the mirror symmetry. Such a nodal loop is fully gapped by including SOC, which results in a large spin Hall effect due to large spin Berry curvatures. Our findings add the unexplored functionality to oxide quantum wells and offer a practical platform to explore the interplay between topological fermions and spin transport phenomena.

Creating and controlling global Greenberger-Horne-Zeilinger entanglement on quantum processors

Greenberger-Horne-Zeilinger (GHZ) states, also known as two-component Schrödinger cats, play vital roles in the foundation of quantum physics and the potential quantum applications. Enlargement in size and coherent control of GHZ states are both crucial for harnessing entanglement in advanced computational tasks with practical advantages, which unfortunately pose tremendous challenges as GHZ states are vulnerable to noise. Here we propose a general strategy for creating, preserving, and manipulating large-scale GHZ entanglement, and demonstrate a series of experiments underlined by high-fidelity digital quantum circuits. For initialization, we employ a scalable protocol to create genuinely entangled GHZ states with up to 60 qubits, almost doubling the previous size record. For protection, we take a different perspective on discrete time crystals (DTCs), originally for exploring exotic nonequilibrium quantum matters, and embed a GHZ state into the eigenstates of a tailor-made cat scar DTC to extend its lifetime. For manipulation, we switch the DTC eigenstates with in-situ quantum gates to modify the effectiveness of the GHZ protection. Our findings establish a viable path towards coherent operations on large-scale entanglement, and further highlight superconducting processors as a promising platform to explore nonequilibrium quantum matters and emerging applications.

Dynamic Jahn-Teller effect in the strong spin-orbit coupling regime

Exotic quantum phases, arising from a complex interplay of charge, spin, lattice and orbital degrees of freedom, are of immense interest to a wide research community. A well-known example of such an entangled behavior is the Jahn-Teller effect, where the lifting of orbital degeneracy proceeds through lattice distortions. Here we demonstrate that a highly-symmetrical 5d1 double perovskite Ba2MgReO6, comprising a 3D array of isolated ReO6 octahedra, represents a rare example of a dynamic Jahn-Teller system in the strong spin-orbit coupling regime. Thermodynamic and resonant inelastic x-ray scattering experiments, supported by quantum chemistry calculations, undoubtedly show that the Jahn-Teller instability leads to a ground-state doublet, resolving a long-standing puzzle in this family of compounds. The dynamic state of ReO6 octahedra persists down to the lowest temperatures, where a multipolar order sets in, allowing for investigations of the interplay between a dynamic JT effect and strongly correlated electron behavior.

Towards heavy double-gluon hybrid mesons with exotic quantum numbers in QCD sum rules

The double-gluon hybrid meson configuration was recently proposed and investigated within QCD sum rules. In this talk, we discuss the color structures of the double-gluon hybrid meson and construct current operators with exotic quantum numbers JPC=1−+ and 2+− for two of the structures. In the framework of QCD sum rules, we consider the condensates up to dimension-8 at the leading order of αs for both charmonium and the bottomonium systems. The results indicate that the masses of the 1−+ and 2+− charmonium double-gluon hybrid mesons are approximately 6.1−7.2 GeV and 6.3−6.4 GeV, respectively. As for the bottomonium systems, their masses fall within the range of 13.7−14.3 GeV and 12.6−13.3 GeV for the 1−+ and 2+− channels, respectively. Additionally, the charmonium hybrids could be produced in the radiative decays of bottomonium mesons in BelleII experiment.

On the feasibility of detecting quantum delocalization effects on relativistic time dilation in optical clocks

Abstract We derive the predicted time dilation of delocalized atomic clocks in an optical lattice setup in the presence of a gravitational field to leading order in quantum relativistic corrections. We investigate exotic quantum states of motion whose relativistic time dilation is outside of the realm of classical general relativity, finding a regime where 24 Mg optical lattice clocks currently in development would comfortably be able to detect the special-relativistic contribution to the quantum effect (if the technical challenge of generating the necessary states can be met and the expected accuracy of such clocks can be attained). We find that the gravitational contribution, on the other hand, is negligible in this setup. We provide a detailed experimental protocol and analyse the effects of noise on our predictions. We also show that the magnitude of our predicted quantum time dilation effect remains just out of detectable reach for the current generation of 87 Sr optical lattice clocks. Our calculations agree with the predicted time dilation of classical general relativity when restricting to Gaussian states.

Generic Approach to Intrinsic Magnetic Second-Order Topological Insulators via Inverted p-d Orbitals.

The integration of intrinsically magnetic and topologically nontrivial two-dimensional materials holds tantalizing prospects for exotic quantum anomalous Hall insulators and magnetic second-order topological insulators (SOTIs). Compared with their well-studied nonmagnetic counterparts, the pursuit of intrinsic magnetic SOTIs remains limited. In this work, we address this gap by focusing on p-d orbitals inversion, a fundamental but often overlooked phenomena in the construction of topological materials. We begin by developing a theoretical framework to elucidate p-d orbital inversion through a combined density-functional theory calculation and Wannier downfolding. Subsequently we showcase the generality of this concept in realizing ferromagnetism SOTIs by identifying two real materials with distinct lattices: 1T-VS2 monolayer in a hexagonal lattice and CrAs monolayer in a square lattice. We further compare it with other mechanisms requiring spin-orbit coupling and explore the similarities to topological Kondo insulators. Our findings establish a generic pathway toward intrinsic magnetic SOTIs.

On-Surface Synthesis of Triaza[5]triangulene through Cyclodehydrogenation and its Magnetism.

Triangulenes as neutral radicals are becoming promising candidates for future applications such as spintronics and quantum technologies. To extend the potential of the advanced materials, it is of importance to control their electronic and magnetic properties by multiple graphitic nitrogen doping. Here, we synthesize triaza[5]triangulene on Au(111) by cyclodehydrogenation, and its derivatives by cleaving C-N bonds. Bond-resolved scanning tunneling microscopy and scanning tunneling spectroscopy provided detailed structural information and evidence for open-shell singlet ground state. The antiferromagnetic arrangement of the spins in positively doped triaza[5]triangulene was further confirmed by density function theory calculations. The key aspect of triangulenes with multiple graphitic nitrogen is the extra pz electrons composing the π orbitals, favoring charge transfer to the substrate and changing their low-energy excitations. Our findings pave the way for the exploration of exotic low-dimensional quantum phases of matter in heteroatom doped organic systems.

Realization of Two-Dimensional Intrinsic Polar Metal in a Buckled Honeycomb Binary Lattice.

Structural topology and symmetry of a two-dimensional (2D) network play pivotal roles in defining its electrical properties and functionalities. Here, a binary buckled honeycomb lattice with C3v symmetry, which naturally hosts topological Dirac fermions and out-of-plane polarity, is proposed. It is successfully achieved in a group IV-V compound, namely monolayer SiP epitaxially grown on Ag(111) surface. Combining first-principles calculations with angle-resolved photoemission spectroscopy, the degeneration of the Dirac nodal lines to points due to the broken horizonal mirror symmetry is elucidated. More interesting, the SiP monolayer manifests metallic nature, which is mutually exclusive with polarity in conventional materials. It is further found that the out-of-plane polarity is strongly suppressed by the metallic substrate. This study not only represents a breakthrough of realizing intrinsic polarity in 2D metallic material via ingenious design but also provides a comprehensive understanding of the intricate interplay of many exotic low-dimensional quantum phenomena.

Nematic Ising superconductivity with hidden magnetism in few-layer 6R-TaS2

In van der Waals heterostructures (vdWHs), the manipulation of interlayer stacking/coupling allows for the construction of customizable quantum systems exhibiting exotic physics. An illustrative example is the diverse range of states of matter achieved through varying the proximity coupling between two-dimensional (2D) quantum spin liquid (QSL) and superconductors within the TaS2 family. This study presents a demonstration of the intertwined physics of spontaneous rotational symmetry breaking, hidden magnetism, and Ising superconductivity (SC) in the three-fold rotationally symmetric, non-magnetic natural vdWHs 6R-TaS2. A distinctive phase emerges in 6R-TaS2 below a characteristic temperature (T*) of approximately 30 K, which is characterized by a remarkable set of features, including a giant extrinsic anomalous Hall effect (AHE), Kondo screening, magnetic field-tunable thermal hysteresis, and nematic magneto-resistance. At lower temperatures, a coexistence of nematicity and Kondo screening with Ising superconductivity is observed, providing compelling evidence of hidden magnetism within a superconductor. This research not only sheds light on unexpected emergent physics resulting from the coupling of itinerant electrons and localized/correlated electrons in natural vdWHs but also emphasizes the potential for tailoring exotic quantum states through the manipulation of interlayer interactions.

Construction of topological quantum magnets from atomic spins on surfaces.

Artificial quantum systems have emerged as platforms to realize topological matter in a well-controlled manner. So far, experiments have mostly explored non-interacting topological states, and the realization of many-body topological phases in solid-state platforms with atomic resolution has remained challenging. Here we construct topological quantum Heisenberg spin lattices by assembling spin chains and two-dimensional spin arrays from spin-1/2 Ti atoms on an insulating MgO film in a scanning tunnelling microscope. We engineer both topological and trivial phases of the quantum spin model and thereby realize first- and second-order topological quantum magnets. We probe the many-body excitations of the quantum magnets by single-atom electron spin resonance with an energy resolution better than 100 neV. Making use of the atomically localized magnetic field of the scanning tunnelling microscope tip, we visualize various many-body topological bound modes including topological edge states, topological defects and higher-order corner modes. Our results provide a bottom-up approach for the simulation of exotic quantum many-body phases of interacting spins.

Superconductivity and topological quantum states in two-dimensional moiré superlattices

Moiré superlattices have emerged as an excellent platform for investigating a plethora of exotic quantum states in condensed matter physics. Recent advancements have unveiled abundant discoveries in two-dimensional moiré superlattices. In this paper, we will present a review of the recent progresses in superconductivity and topological physics within graphene and transition metal dichalcogenides-based moiré superlattices. Additionally, we outline future potential challenges and desirable efforts for discovering, understanding, and controlling these novel states in two-dimensional moiré superlattices.

Crystal Growth, Structure, and Diverse Magnetic Behaviors in Frustrated Triangular Lattice REBO3 (RE = Tb-Yb).

Triangular lattice (TL) materials are a rich playground for investigating exotic quantum spin states and related applications in quantum computing and quantum information. Millimeter-level single crystals of REBO3 (RE = Tb-Yb) with a nearly perfect RE-based TL have been successfully grown via a high-temperature flux method and structurally characterized via single-crystal X-ray diffraction. These 113-type materials crystallize in a monoclinic crystal system with a C2/c space group. Anisotropic magnetism and dominant antiferromagnetic interactions are found for the above materials based on DC magnetic susceptibility measurements. The comprehensive low-temperature specific heat data of REBO3 (RE = Tb-Tm) are characterized on single crystals for the first time, which exhibit diverse magnetic behaviors. Specifically, two weak-field-induced transitions could be found in the case of DyBO3 based on the specific heat measurements. Our results suggest that REBO3 (RE = Tb-Yb) is a TL magnetic system for investigating potential quantum magnetism.

Light single-gluon hybrid states with various exotic quantum numbers

We apply the QCD sum rule method to study the light single-gluon hybrid states with various (exotic) quantum numbers. We construct 24 single-gluon hybrid currents and use 18 of them to calculate the masses of 44 single-gluon hybrid states with the quark-gluon contents q¯qg (q=u/d) and s¯sg. We concentrate on the hybrid states with the exotic quantum number JPC=1−+, whose masses and widths are calculated to be M|q¯qg;1−1−+⟩=1.67−0.17+0.15 GeV, Γ|q¯qg;1−1−+⟩=530−330+540 MeV, M|q¯qg;0+1−+⟩=1.67−0.17+0.15 GeV, Γ|q¯qg;0+1−+⟩=120−110+160 MeV, M|s¯sg;0+1−+⟩=1.84−0.15+0.14 GeV, and Γ|s¯sg;0+1−+⟩=100−80+110 MeV. Our results support the interpretations of the π1(1600) and η1(1855) as the hybrid states |q¯qg;1−1−+⟩ and |s¯sg;0+1−+⟩, respectively. Considering the uncertainties, our results suggest that the π1(1600) and η1(1855) may also be interpreted as the hybrid states |q¯qg;1−1−+⟩ and |q¯qg;0+1−+⟩, respectively. To differentiate these two assignments and to verify whether they are hybrid states or not, we propose to examine the a1(1260)π decay channel in future experiments. Published by the American Physical Society 2024