Exergetic Efficiency Research Articles

Impact of collector aspect ratio on the energy and exergy efficiency of a louvered fin solar air heater

Solar air heaters have huge applications in renewable energy utilization segments concerning the issues of space heating, drying, and ventilation systems. Performance prediction of such systems largely depends upon the design of the collector itself. The present study has highlighted the influence of various aspect ratios of the collector on the thermal and exergy performance of louvered finned solar or air heaters. In this context, an experimental analysis has been carried out to compare the performance of LFSAH with conventional PSAH. These results show that an increase in aspect ratios enhances thermal efficiencies of heat transfer and the systems. An aspect ratio of 4:1 showed the maximum thermal efficiencies as 81.63 % for LFSAH and 68.13 % for PSAH. On the other hand, at larger mass flow rates, the exergetic efficiency of LFSAH becomes lower owing to the larger friction and exergy losses and sometimes even lower than that of PSAH. The novelties of the present study are in emphasizing the importance of aspect ratio in optimizing solar air heater design and providing relevant insight for better energy use.

Advanced Exergy-Based Optimization of a Polygeneration System with CO2 as Working Fluid.

Using polygeneration systems is one of the most cost-effective ways for energy efficiency improvement, which secures sustainable energy development and reduces environmental impacts. This paper investigates a polygeneration system powered by low- to medium-grade waste heat and using CO2 as a working fluid to simultaneously produce electric power, refrigeration, and heating capacities. The system is simulated in Aspen HYSYS® and evaluated by applying advanced exergy-based methods. With the split of exergy destruction and investment cost into avoidable and unavoidable parts, the avoidable part reveals the real improvement potential and priority of each component. Subsequently, an exergoeconomic graphical optimization is implemented at the component level to improve the system performance further. Optimization results and an engineering solution considering technical limitations are proposed. Compared to the base case, the system exergetic efficiency was improved by 15.4% and the average product cost was reduced by 7.1%; while the engineering solution shows an increase of 11.3% in system exergetic efficiency and a decrease of 8.5% in the average product cost.

Analysis and Optimization of a s-CO2 Cycle Coupled to Solar, Biomass, and Geothermal Energy Technologies

This paper presents an analysis and optimization of a polygeneration power-production system that integrates a concentrating solar tower, a supercritical CO2 Brayton cycle, a double-flash geothermal Rankine cycle, and an internal combustion engine. The concentrating solar tower is analyzed under the weather conditions of the Mexicali Valley, Mexico, optimizing the incident radiation on the receiver and its size, the tower height, and the number of heliostats and their distribution. The integrated polygeneration system is studied by first and second law analyses, and its optimization is also developed. Results show that the optimal parameters for the solar field are a solar flux of 549.2 kW/m2, a height tower of 73.71 m, an external receiver of 1.86 m height with a 6.91 m diameter, and a total of 1116 heliostats of 6 m × 6 m. For the integrated polygeneration system, the optimal values of the variables considered are 1437 kPa and 351.2 kPa for the separation pressures of both flash chambers, 753 °C for the gasification temperature, 741.1 °C for the inlet temperature to the turbine, 2.5 and 1.503 for the turbine pressure ratios, 0.5964 for the air–biomass equivalence ratio, and 0.5881 for the CO2 mass flow splitting fraction. Finally, for the optimal system, the thermal efficiency is 38.8%, and the exergetic efficiency is 30.9%.

A geothermal-based freshwater/cooling system assisted by heat recovery sections: 3E analysis and techno-economic optimization using genetic algorithm

The proposed system uses a dual-loop organic Rankine cycle, a reverse osmosis desalination unit, an absorption cooling unit, and a thermoelectric generator to produce electricity and freshwater for urban areas. A thorough assessment of the system's thermodynamic and economic performance has been conducted, with a parameter-based investigation to assess the effect of key variables on the system performance. The parametric study indicates that rising the geothermal mass flow rate enhances the energy efficiency, but lowers the energy efficiency and affects the cooling requirements. Moreover, the optimum inlet temperature in turbine 1 increases the desalination efficiency up to 105.02 kg/s at 115 °C, and higher temperatures reduce the performance and system efficiency. Adjusting the temperature difference at the pinch point at Evaporator1 is crucial for system efficiency, with trade-offs between freshwater output, expenses, and exergy efficiency. The capability of the system to produce up to 6,048,000 L of potable water daily signifies a monumental leap towards meeting the water demands of nearly 42,000 individuals, based on European consumption standards. Lastly, the application of genetic algorithms in the optimization process results in an exergetic efficiency of 32.79 % and a cost rate of 58.05 $/h, demonstrating the system's enhanced operational effectiveness.

Exergetic characterization of flat plate solar collector using genetic algorithm

With the rapid advancement of technology, the global demand for energy is increasing exponentially. It is crucial to focus on energy conservation and conversion across all sectors. This study conducted a second law or exergy analysis on a solar water heating system to uncover hidden losses during the process. To optimize exergetic efficiency, a genetic algorithm was employed to control the overall loss coefficient of a solar flat plate collector. Four decision variables were used in the genetic algorithm—heat flux rate, glass cover temperatures at the inlet and exit, and collector plate temperature to minimize the overall loss coefficient. Energy efficiency, entropy generation, and exergy destruction were estimated for various mass flow rates using thermodynamic equilibrium equations. Exergy correlations were developed concerning mass flow rate (0.001–0.009 kg/s), inlet temperature (300 K–360 K), collector plate area (1–10 m²), incident solar energy (400–900 W/m²), optical efficiency (0.4%–1%), and ambient temperature (300–315 K) under a range of initial conditions. It was found that exergy efficiency slightly increased (0.01%–0.08%) over a 12-h period. Although this increase is small, it can significantly contribute to energy conservation over the long term. The genetic algorithm predicted the minimum loss coefficient occurring during peak hours (12–14 p.m.) with respect to four decision variables. The results of this study were compared with existing literature and showed good agreement. In addition to the exergy analysis, an uncertainty error analysis was performed to assess the reliability and accuracy of the experimental measurements and computational predictions. By quantifying these uncertainties, the study ensured that the reported enhancements in exergy efficiency and the optimization results obtained through the genetic algorithm are robust and credible. This rigorous error analysis adds confidence to the findings, highlighting the potential for improved energy conservation in solar water heating systems.

Energy performance and wind exposure of windward, lateral, and leeward high-rise photovoltaic facades

The growing demand for sustainable energy solutions leads to the integration of photovoltaic/thermal (PV/T) modules into building facades. This study evaluates and compares the energy potential, wind load, and environmental benefits of PV/T modules installed on different facades of high-rise buildings. Using advanced computational techniques, including Computational Fluid Dynamics (CFD), the wind interaction with PV/T modules on windward, lateral, and leeward facades is modeled and analyzed. Each computational process requires over two weeks to complete due to the complexity of the simulations. The results demonstrate that the leeward facade is more effective for electricity generation, while the windward and sideward facades perform better for thermal energy storage. Maximum energy outputs of 217 kW for thermal energy and 73 kW for electrical energy are recorded, depending on wind conditions. Additionally, energetic and exergetic efficiencies reach 55.2 % and 17.7 %, respectively. The study also finds that the leeward facade has the greatest impact on reducing CO2 emissions. These findings provide valuable insights into designing optimal PV/T facades for high-rise structures, expanding the range of structural designs and offering opportunities for implementing mitigation measures to enhance system durability and efficiency. The novelty of this research lies in the detailed comparative analysis of PV/T performance across multiple facades, offering a practical framework for future sustainable building designs.

Optimization and exergoeconomic analysis of a biomass-driven cogeneration system for power and cooling applications

Due to the increasing population and the expansion of industry in daily life, a significant depletion of fossil fuel resources is observed, accompanied by escalating environmental concerns. In response to these challenges, this study presents an optimized cogeneration system powered by renewable biomass, designed for simultaneous power and cooling generation. The system integrates a biomass gasification unit, a steam Rankine cycle, a helium-driven gas turbine cycle, and an ammonia-water-based two-stage absorption refrigeration cycle with a bleed line. Thermodynamic and exergoeconomic analyses reveal a net power output of 5356 kW, a cooling load of 360.9 kW, and an exergetic efficiency of 29.52 %. Financially, the system shows a net present value of 11.76 $M and a payback period of 6.51 years. A multi-objective optimization utilizing the gray wolf algorithm improves system performance through the employment of three diverse scenarios, which raises power output to 5864 kW, cooling load to 372 kW, and optimize net present to 14.28 $M with a reduced payback period of 5.96 years. The studied system is well-suited for industrial applications, rural electrification, and district energy systems, and offers a sustainable and economically viable energy solution.

Energy, Exergy, environmental and economic based experimental investigation of solar air heater using a novel arc rib geometry

To enhance the thermal efficacy of solar air heaters, the most efficient method is to disturb the viscous layer by roughening the surface using the artificial rib. In this research, a discrete apex-down arc-shape rib geometry on a roughened plate is used to examine the energy-exergo and economic- environmental based performance of solar air heater. By changing the Reynolds number from 3000 to 14,000 and maintaining a gap width to rib height ratio of 4, a relative height rib ratio of 0.045, and a pitch to rib height ratio of 10, the effects of arc rib angles of 30, 45, and 60 degrees are studied. The environmental exergy loss was determined to be substantial, between 70 % and 80 %. Maximum system to air exergy loss occurs at Reynolds number of 3000 with 5.64 W. At a temperature parameter of 0.0377 m2K/W, both the thermal and exergetic efficiencies are at their highest, at 77.60 % and 3.81 %, respectively. In comparison to a plate having a plain surface, the suggested apex-down discrete arc rib performs better based on energy payback time, usable yearly energy, and enviro-economic criteria. Finally, at rib angle of 30°, the conditions that optimize the heat transfer and energy payback time, energy cost, exergo-economic, and enviro-economic characteristic of the current artificially roughened geometry of solar air heater.

Discharging Performance Analysis of MXene Nano‐Enhanced Phase Change Material for Double and Triplex Tube Thermal Energy Storage

ABSTRACTThe present study numerically investigates the energy and exergy analysis of solidification of phase change materials within a double tube and triple tube latent heat storage unit using ANSYS Fluent. Double tube and triple tube thermal energy storage system's thermal characteristics are examined using MXene nano‐enhanced phase change material to determine system efficiency, discharged energy, heat transfer rate, exergy destruction, entropy generation number, exergetic efficiency, liquid fraction, solidification temperature contours. The result revealed that the double tube thermal energy storage with pure cetyl alcohol PCM has 14.76% lower discharge exergy than MXene‐based nano‐enhanced phase change material in pure solidification. In a triple tube thermal energy storage system, the solidification time for MXene‐based nano‐enhanced phase change material is impressively reduced by 54.76% compared to a double tube system using pure phase change material. At a Fourier number of 0.00672, MXene nano‐enhanced phase change material exhibits an 11.69% higher Stefan number (St) than cetyl alcohol phase change material in a double tube thermal energy storage system. At 2400 s, pure phase change material and MXene nano‐enhanced phase change material generated 3.14% and 4.88% less entropy than pure cetyl alcohol in the triple tube thermal energy storage system. During the pure solidification process in a double tube thermal energy storage system, pure cetyl alcohol experiences 7.60% higher exergy destruction compared to MXene nano‐enhanced phase change material at a solidification time of 2400 s. In a triple tube thermal energy storage system, the discharging temperature for pure cetyl alcohol phase change material is 2.92% lower than that in a double tube system. Double tube thermal energy storage with pure cetyl alcohol discharged more efficiently over 2400 s. The triple tube thermal energy storage system solidified cetyl alcohol PCM 20.83% faster than pure phase change material due to MXene nanoparticles' better thermophysical properties. Thus, MXene‐based nano‐enhanced cetyl alcohol phase change material solidifies faster per volume in a triple tube thermal energy storage latent heat system.

Methods of Thermal Energy Storage by Using Smart Heat Pumps

Abstract To address energy problems in thermodynamic installations, the authors of the paper propose a working methodology in which the determining role of the exergetic aspects of the processes is especially emphasized. One of these energy problems, addressed in many papers in recent years, is of particular importance in the fight to reduce chemical and thermal pollution of the environment: the problem of storing excess energy and energy from renewable or residual sources. Approaching this issue as well from this point of view, the authors propose a series of solutions by which they seek to use the most of the exergy extracted from the available energy sources. The solutions proposed here are based on the use of an own invention, the isothermalizer, a particularly powerful tool, able to bring highly effective solutions to many of the problems that concern researchers determined to create a cleaner planet. Designers and users of thermodynamic systems now have the possibility of an initial choice and subsequent changes (with the change of external conditions), of their energy and exergetic efficiency, as well as the possibility of calculating the material and energy costs necessary to achieve the proposed objective. In any gas compression/expansion problem, the energy efficiency is established precisely, by choosing the isothermal speed of the process (so of the isothermal temperature), and the power density, by choosing the total surface of the thermal sponge, the flow rate and the mode of distribution of the cooling agent. As the isothermalizer is equipped with a processor that controls and modifies the isothermal speed in such a way that the exergy consumption is optimized, the energy storage processes become processes of extracting thermal energy from a tank and transferring it to another tank, a process accompanied by consumption/supply of mechanical energy.

Energy, Exergy, Exergo-economic and Exergo-environmental analysis of Waste Heat-based Convective Dryer

Food drying is a widely used method of food preservation worldwide, and the utilization of waste heat from exhaust flue gas presents a significant opportunity to reduce the energy consumption of industrial drying processes. This study thoroughly examines the energy and exergy efficiency, sustainability indicators, and various exergo-environmental and exergo-economic parameters to assess the performance of a waste heat-based convective dryer (WHCD). The study found that drying at 70°C performed the best (among 50°C, 60°C and 70°C) for the overall drying process, with a maximum overall exergetic efficiency of 4.89%. The results of exergo-economic analysis revealed that the drying chamber exhibited the highest exergy destruction cost at US$0.01193 per hour, and it was determined that improving the drying chamber was of paramount importance. An exergo-environmental assessment indicates that the proposed dryer effectively mitigates 14.15 tons of over a 20-year lifespan. Sensitivity analysis of the proposed system reveals that the energy efficiency is more sensitive to the food drying temperature than the exergy efficiency. A 33% increase in drying temperature increases the exergy efficiency by 19.37% while reducing the energy efficiency by 37.54%. Hence, adopting the proposed system in industrial settings could significantly enhance energy-efficient and sustainable food drying processes.

Comprehensive assessment and energetic-exergetic performance optimization of a new solar thermal electricity system based on Scheffler-type receivers combined with screw-type volumetric machines

This study explores the potential of a novel solar-powered cascade Rankine cycle system based on Scheffler-type receivers combined with screw expanders. Specifically, in this solar power system, steam is generated in the Scheffler-type receiver, which proves to be well performing compared with other technological solutions to exploit solar energy, due to satisfactory efficiency of the focal receiver that is able to curtail heat losses, even at high evaporation temperatures. Subsequently, steam expands in the screw machines which, unlike conventional steam turbines, are specially fitting in energy conversion with vapor-liquid mixes in the field from tens to hundreds of kW. In the present study, comprehensive assessment of this renewable energy power system is thoroughly conducted in a large range of operating states. For this purpose, specific numerical models and basic criteria fixed for the screw expanders and Scheffler receivers part-load behavior are combined with thermodynamic formulations established for energetic-exergetic performance optimization of the entire solar thermal electricity plant. Hence, parametric optimization of the major thermodynamic factors involved at part-load operating situations is conducted to enhance the energetic and exergetic efficiencies of the designed solar thermal power system.

Economic Analyses of a New Power and Cooling System at Low Temperature Applications

Recent research suggests that the implementation of more efficient combined cooling and power systems, which enable the cogeneration of electricity and cooling, can enhance the efficiency of hybrid plants. The present investigation is motivated by finding that, in the literature review on combined power and cooling systems, there is very limited information on the coupling of the organic Rankine cycle (ORC) and the ejector refrigeration cycle (ERC) with low sink temperatures. A suggested approach to do this involves using hot exhaust gas and waste heat engines to power an ORC hybrid system. To enhance the ORC–ERC system's performance, three heater configurations use waste heat from the ORC turbine exhaust, ejector, and engine waste heat to heat the working fluid. Renewable energy sources are the primary focus of most current research initiatives. The present research focuses on unique ORC and ERC systems, considered as combined power and cooling systems, with the goal of improving exergy performance at low temperatures. The suggested ORC–ERC can generate energy destruction of 69.85 kW at a source temperature of 155 °C, with an exergetic efficiency of 76.9% at the turbine. Setting the entrainment ratio at 0.5 results in a total sum unit cost of products (SUCP) of 465 $/kW‐h for the ORC–ERC. Furthermore, the 37.83% exergy destruction ratio introduces heat exchanger 2 (HE2) as the primary cause of the suggested ORC–ERC's irreversibility. A detailed parametric study reveals that altering the hot source temperature and entrainment ratio improves the system's SUCP. The current examination at high sink temperatures may be expanded to an advanced exergoenvironmental investigation.

Development and modeling of power, hydrogen and freshwater production based on a novel double-flash geothermal power plant

In this article, a novel geothermal energy-assisted multigeneration plant is proposed and analyzed from the thermodynamic, economic, and environmental perspectives. In the design of the geothermal power system, a transcritical Rankine cycle, which employs CO2 as the working fluid (tCO2-RC), a Kalina cycle (KC), a hydrogen generation sub-plant, and a desalination unit are considered. The reverse osmosis (RO) desalination process is used for freshwater production, while the proton exchanger membrane (PEM) electrolyzer is utilized for hydrogen generation. In addition, parametric analyses are conducted to ascertain the impacts of the temperature of the geothermal source, mass flow rate, and flash chamber pressure on system performance. According to the results, the plant's overall energetic and exergetic efficiencies are determined to be 8.6 % and 34.9 %, respectively where the net power production is calculated as 3317.94 kW, and the system's total irreversibility is found to be 5852.88 kW. Furthermore, the hourly H2, O2, and freshwater generation amounts are 8.5 kg, 49.1 kg, and 9.3 m3, respectively. Finally, the levelized energy cost (LEC) and sustainability index of the system are found to be 0.128 USD/kWh and 0.215.

Assessing the thermoeconomic performance of a solar-powered trigeneration system with an upgraded transcritical carbon dioxide unit

With the intervention of the industry in every aspect of human lifestyle on the one hand, and the prompt reduction in fossil fuel and their harms to the environment, including global warming, on the flip side, the importance of renewable sources of energy has been revealed more than ever. The presented study attempted to investigate a new configuration for a trigeneration configuration based on a solar renewable source. The proposed system comprises a parabolic trough solar collector segment to drive a transcritical carbon dioxide power and refrigeration subsystem, a dual-pressure organic Rankine cycle, and a thermal vapor compression process combined with a multi-effect desalination unit. The suggested configuration is carefully inspected from thermodynamic and economic perspectives, encompassing an analysis of a certain condition and a detailed parametric evaluation. Four decision parameters are employed for the parametric evaluation, in conjunction with two scenarios from a multi-objective particle swarm optimization combined with a linear programming method for multidimensional preference analysis as a decision-maker. The examination outputs bring out a net output power of 12.147 MW, a 7.707 MW cooling load, a 4.448 kg/s freshwater, and energetic and exergetic efficiencies of 15.286 % and 10.192 %, respectively. Moreover, examining the system's performance from an economic perspective reveals a total product cost rate of 954.249 $/h, leading to a 4.694-year payback period. This study optimizes energy usage and minimizes waste, offering industrial applications such as reducing fossil fuel dependence and lowering greenhouse gas emissions. It supports sustainable development and facilitates the global transition to cleaner energy sources.

Experimental analysis of a pilot plant in Organic Rankine Cycle configuration with regenerator and thermal energy storage (TES-RORC)

Applying thermal energy storage in a Regenerative Organic Rankine Cycle system is a possible combination of energy storage for renewable and waste energy sources. This research presents an experimental analysis of a regenerative organic Rankine cycle pilot plant, incorporating a thermal energy storage chamber based on a phase change materials to obtain thermal inertia in the system. The primary heat source is the residual heat of combustion gases at a temperature of approximately 320 °C coming from a generating set that operates within a thermal power generation plant. The prototype uses a twin-screw expander modified to work as a turbine. Novec 649 was used as the working fluid which is an organic compound. The experimental evaluation of the regenerative organic Rankine cycle with thermal energy storage has been carried out through energy and exergetic efficiency analysis to verify the operation of the pilot plant. Values of 13.2 % were obtained for the exergetic efficiency and 2.67 % for the global efficiency of the cycle, with a maximum expander work of 11.8 kW. It was demonstrated that the thermal energy storage system provides energy in response to the plant's operating inertia for 17.5 min, sufficient time for the gradual shutdown of the plant equipment, maintaining the working power of the regenerative organic Rankine cycle.

Enhancing solar thermoelectric power generation with supercritical CO2 cooling: Hydraulic, thermal, and exergy analysis

This research investigates the dynamic behavior and impact of various factors on the hydraulic, thermal, and exergetic characteristics of a solar-based thermoelectric device using a pin–fin heatsink cooled by supercritical CO2. A comprehensive numerical model analyzes the heat dissipation and performance of the power generator, integrating a thermoelectric generator and a pin–fin heatsink with various pin shapes. Key geometric and operational parameters, such as the height of PN (P-type and N-type semiconductor) legs of the TEG, the number of thermocouples, operating pressure, Reynolds number, and CO2 temperature, are examined for a comprehensive performance assessment. The study highlights the superior performance of CO2 coolant over traditional water-cooling system. Near the critical temperature of CO2, enhanced heat transfer significantly boosts power output, conversion efficiency, and exergetic efficiency. For example, at 8 MPa, the TEG’s (thermoelectric generator) power output increases from 1.31 mW at 295 K to 2.35 mW at 310 K. Comparisons reveal that while water coolant lowers the cold side temperature more effectively, it results in reduced power output due to decreased temperature differentials and increased pressure loss. Conversely, CO2 coolant maintains higher cold side temperatures while having advantages in power output. At 315 K, the cold side temperature with water is 315.7 K compared to 346.7 K with CO2. Increasing the number of thermocouples from 18 to 32 for a leg height of 1 mm leads to an approximate 102.3 % increase in voltage. Raising the PN leg height from 1 mm to 2 mm for an NTC of 50 results in a nearly 99.8 % increase in voltage. Lozenge-shaped fin produces a peak power output of 2.73 mW, while square fin generates 2.62 mW. This research underscores CO2’s potential as a high-performance coolant in solar thermoelectric applications, offering insights into optimizing system design for maximum efficiency.

Novel solar-based cogeneration system: Parabolic trough integrating supercritical Brayton and organic Rankine cycles with membrane distillation

This research addresses advancements towards third-generation concentrated solar power (CSP) systems, highlighting the critical need for improved system efficiency through advanced power cycles and optimized waste heat utilisation. By integrating a direct parabolic trough solar collector (PTSC) with a supercritical CO₂ (sCO₂) Brayton cycle and direct contact membrane distillation (DCMD), coupled with a bottoming organic Rankine cycle (ORC), this study proposed a novel solution for the co-generation of power and clean water. Innovative design and optimisation methodologies for the integrated system were introduced, and a comprehensive mathematical model was developed and validated, facilitating a comparative analysis of various ORC fluids' techno-economic performance. The investigation revealed that under baseline conditions, neopentane and isobutane demonstrated slightly better cycle's net-work, whereas toluene showed significantly higher water production due to the higher mass flow rate of seawater needed, resulting from the lower condenser inlet temperature. Furthermore, parametric analysis revealed that varying ambient temperatures resulted in different optimal fluids, with cyclohexane, n-octane, n-nonane, and n-heptane achieving the highest thermal efficiency of around 36.52% at 10°C. Additionally, this study highlighted substantial exergy destruction in the DCMD desalination process, accounting for 63.12% of the exergy destruction in the bottoming cycle, predominantly at the membrane where approximately 67% occurred. Moreover, the second compression and expansion stages, especially at higher Direct Normal Irradiance (DNI) levels, contributed the most to exergetic destruction in the topping cycle. Significantly, the double cycle showed exergetic efficiency improvements between 0.12% and 0.35% across different DNI levels while in contrast, single cycles demonstrated marginally superior water production capacity. Economic analyses using bare module costing to assess the levelized cost of electricity and water, along with net present value calculations, revealed that varying ambient temperatures resulted in different optimised fluids. Notably, n-octane achieved the highest net present value, approximately 4.53% above baseline conditions, at an ambient temperature of 10°C. Finally, recommendations for organic fluids for each ambient temperature based on techno-economic optimisation were detailed.

Exergetic efficiency and CO2 intensity of hydrogen supply chain including underground storage

Hydrogen plays a crucial role in the transition to low-carbon energy systems, especially when integrated into energy storage applications. In this study, the concept of exergy-return on exergy-investment (ERoEI) is applied to investigate the exergetic efficiency (defined as the ratio of useful exergy output to invested exergy input) and CO2 equivalent intensity of the hydrogen supply chain, with a specific focus on the underground hydrogen storage process. Our findings reveal that the overall exergetic efficiency of the electricity-to-hydrogen-to-electricity conversion process can reach up to 25 %. Among the hydrogen production methods, green hydrogen, produced via electrolysis powered by renewable energy, exhibits the lowest CO2 equivalent intensity. Blue hydrogen, produced from natural gas with carbon capture, can significantly reduce the carbon footprint of electricity generation, though this advantage comes at the expense of decreased exergetic efficiency. Analysis further indicates that the exergetic efficiency of underground storage components ranges from 72 % to 92 %. A substantial fraction of the exergy is lost during compression and injection of the stored hydrogen. Nevertheless, the subsurface operations contribute a minimal CO2 emission, between 1.46–4.56 grams of equivalent CO2 per megajoule (gr-CO2eq/MJ) when powered by low-carbon energy sources. Furthermore, it is found that hydrogen loss in the reservoir, along with methane and hydrogen leak during surface operations, notably affects the overall efficiency of the storage process.

Optimizing compressed air energy storage with organic Rankine cycle and ejector refrigeration for sustainable power and cooling provision

In the pursuit of sustainable energy systems, integrating storage technologies is crucial. Compressed air energy storage (CAES) emerges as a significant option for ensuring reliable power supply during peak hours. This study focuses on a configuration combining a CAES unit with two integrated organic Rankine cycle and ejector refrigeration units (ORCERC). The primary objective is to ensure adequate power supply during peak hours in the discharge period, while also providing cooling capacity to enhance system flexibility and efficiency. The proposed system is evaluated from thermodynamic, exergoeconomic, and exergoenvironmental perspectives to determine optimal operating conditions for the CAES unit. A fluid selection process identified a suitable zeotropic mixture, R141b/Hexane, as the working fluid for both ORCERCs. The results demonstrate a net power production of 20,749.91 kW and a cooling load of 1448.23 kW, with cost and exergoenvironmental impact rates of $1193.59/h and 143.42 Pt/h, respectively. Additionally, the configuration achieves an exergy round-trip efficiency of 65.85 % and a payback period of 2.88 years. Increasing the HTES temperature from 1150 to 1250 K improved both the round-trip efficiency (RTE) and exergetic round-trip efficiency (ERTE) from 52.22 % to 53.39 % and 62.98 %–63.71 %, respectively, while reducing the product cost and exergoenvironmental impact rate from $1128 to $1117/h and 134.35 to 127.93 Pt/h, respectively. Three triple-objective optimization scenarios were considered, yielding diverse outcomes, each contributing unique insights into the system's performance and potential improvements.