Excitation Region Research Articles

Additive and subtractive hybrid manufacturing assisted by femtosecond adaptive optics

Advanced micro–nano devices commonly require precise three-dimensional (3D) fabrication solutions for pre-designing and integrating 0D to 3D configurations. The additive–subtractive hybrid manufacturing strategy dominated by femtosecond laser direct writing has become an increasingly interesting technical route for material processing. In this study, a novel approach termed femtosecond adaptive optics-assisted hybrid manufacturing was proposed, which integrates subtractive (femtosecond laser ablation) and additive (two-photon polymerization) fabrication. In this hybrid manufacturing method, the introduction of adaptive optics offers parallel direct writing and wide-area material processing capabilities. To demonstrate the validity of the hybrid approach, on-chip surface plasmon polariton waveguides with strong sub-wavelength field confinement and enhanced functionality were successfully fabricated. In comparison with the terahertz-wave devices fabricated based on the focused ion beam technique, the functional tests in terahertz near-field microscopy show a rival performance fabricated with our hybrid approach. Besides, our cost-effective solution also dramatically reduces the fabricating time of excitation regions by a factor >16. Our work provides a new inspiration in integrated photonics.

Overtone Excitation of Nitrogen Molecules via Stimulated Raman Pumping.

Nitrogen bond activation is a pivotal process in chemistry, with bond excitation being fundamental to understanding the underlying mechanisms, making the preparation of molecules in specific quantum states crucial. Here we report the first overtone excitation of the N2 molecule from X1Σg+(v = 0, j = 0, 1, and 2) to X1Σg+(v = 2, j = 0, 1, 2, and 3) using the stimulated Raman pumping (SRP) method in a pulsed molecular beam. N2 was detected using 2+1 resonance-enhanced multiphoton ionization through the a″1Σg+ state. An excitation efficiency of 4% was achieved within the excitation region in which the SRP laser intensity was saturated, indicating the low cross-sectional nature of the process. The SRP detuning spectra for different branches were measured, and the excited N2 [X1Σg+(v = 2)] was further used to access various vibrational states of a″1Σg+, enabling the determination of its vibrational constants. This research opens up new opportunities for studying the specific high vibrational excitation of nitrogen in reactions and scattering experiments and contributes additional precise spectral data for the N2 molecule.

High-efficiency terahertz surface plasmon metacoupler empowered by bilayer bright–dark mode coupling

Conversion from free-space waves to surface plasmons has been well studied as a key aspect of plasmonics. In particular, efficient coupling and propagation of surface plasmons via phase gradient metasurfaces are of great current research interest. Hereby, we demonstrate a terahertz metacoupler based on a bilayer bright–dark mode coupling structure attaining near-perfect conversion efficiency (exceeding 95%) without considering absorption loss of the materials and maintaining a high conversion level even when the area of the excitation region changes. To validate our design, a fabricated metacoupler was assessed by scanning near-field terahertz microscopy. Our findings could pave the way for developing high-performance plasmonic devices encompassing ultra-thin and compact functional devices for a diverse range of applications, especially within the realm of high-speed terahertz communications.

Dissipative nonlinear dynamics of ferromagnetic bilayer

Within the framework of the classical Landau–Lifshitz equations with damping in the Landau form, the relaxation of highly excited magnetic multilayers, consisting of two ferromagnetic layers with magnetic anisotropy of the easy plane type and ferromagnetic exchange interaction between the layers, is analytically and numerically studied. It is shown that the relaxation of the energy and magnetization of the system is of a non-trivial behavior. In the region of strong excitation of the system, the time dependence of the magnetization is non-monotonic, and the smooth time dependencies of energy and magnetization are superimposed by oscillations associated with the essentially nonlinear dynamics of the magnetization vectors in the layers.

Ultrafast dynamics and internal processing mechanism of silica glass under double-pulse femtosecond laser irradiation

Femtosecond laser-induced plasma filaments have potential for various applications including attosecond physics, spectroscopy, and microprocessing. However, the use of plasma filaments to generate high-aspect-ratio internal modifications remains low-efficiency. Here, we experimentally demonstrated high-efficiency internal processing using plasma filaments induced by a double-pulse femtosecond laser. The processing mechanism was revealed through an investigation of the ultrafast dynamics of plasma filaments in experiments and simulations. We found that the excitation region of the first pulse (P1) exerted a temporal effect on the propagation and absorption of the second pulse (P2) due to the evolution of excited electrons, thus resulting in different processing characterizations. At a smaller inter-pulse delay (IPD), electrons and self-trapped excitons induced by P1 improved the absorption of P2 in the shallow region. Consequently, the main excitation regions of P1 and P2 were separated, resulting in a lower density of energy deposition and weak modifications. Whereas, at a larger IPD, P2 penetrated a deeper region with the relaxation of electrons and excitons induced by P1, leading to a better overlap of excitation regions between P2 and P1, thus improving the density of energy deposition and achieving efficient microprocessing. Besides, at an infinite IPD, P2 behaved like P1, but no modification was obtained owing to the complete energy diffusion of P1. Therefore, controlling the electron dynamic and energy diffusion contributes to the improvement of modification efficiency. Furthermore, the distribution of electron densities on the cross section was estimated to precisely analyze the microprocessing. These results are expected to aid in a better understanding of the interaction mechanism between dielectrics and intense ultrafast lasers and be useful for microprocessing applications.

Ultrashort-pulse-laser ablation of freestanding dielectric thin films

Ultrashort-pulse-laser ablation of dielectric thin films is strongly affected by the interference of the exciting laser pulse with itself, which causes the deposited energy to be confined to narrow regions equidistantly spaced along the propagation direction of the laser. We investigate how this affects the ablation mechanism of freestanding Al2O3\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\hbox {Al}_2\\hbox {O}_3$$\\end{document} thin films by analyzing the laser-generated structures with several post-mortem imaging and spectroscopic techniques. Close to the ablation threshold, the laser-irradiated region exhibits surface blistering. Higher intensities cause layers of material to be removed corresponding to ejection of material initiated from the regions of high excitation. Significantly above the ablation threshold, the laser-generated structure is remarkably stable and consists of a membrane of thickness corresponding to the distance between neighboring interference maxima, which is uniquely determined by the central wavelength of the laser pulse and the refractive index of the film. The electronic excitation as a function of depth is simulated using a multiple-rate-equation model in combination with finite-difference-time-domain propagation of the laser field. The simulations confirm the strongly localized excitation and thus correlate well with the observed laser-generated structures.

Virtual stimulation of the interictal EEG network localizes the EZ as a measure of cortical excitability.

Introduction: For patients with drug-resistant epilepsy, successful localization and surgical treatment of the epileptogenic zone (EZ) can bring seizure freedom. However, surgical success rates vary widely because there are currently no clinically validated biomarkers of the EZ. Highly epileptogenic regions often display increased levels of cortical excitability, which can be probed using single-pulse electrical stimulation (SPES), where brief pulses of electrical current are delivered to brain tissue. It has been shown that high-amplitude responses to SPES can localize EZ regions, indicating a decreased threshold of excitability. However, performing extensive SPES in the epilepsy monitoring unit (EMU) is time-consuming. Thus, we built patient-specific in silico dynamical network models from interictal intracranial EEG (iEEG) to test whether virtual stimulation could reveal information about the underlying network to identify highly excitable brain regions similar to physical stimulation of the brain. Methods: We performed virtual stimulation in 69 patients that were evaluated at five centers and assessed for clinical outcome 1year post surgery. We further investigated differences in observed SPES iEEG responses of 14 patients stratified by surgical outcome. Results: Clinically-labeled EZ cortical regions exhibited higher excitability from virtual stimulation than non-EZ regions with most significant differences in successful patients and little difference in failure patients. These trends were also observed in responses to extensive SPES performed in the EMU. Finally, when excitability was used to predict whether a channel is in the EZ or not, the classifier achieved an accuracy of 91%. Discussion: This study demonstrates how excitability determined via virtual stimulation can capture valuable information about the EZ from interictal intracranial EEG.

Near-field induced local excitation dynamics of Na10 and Na10-N2 from real-time TDDFT.

Electron dynamics of the Na10 chain and the Na10-N2 complex locally excited by an atomistic optical near-field are investigated using real-time time-dependent density functional theory calculations on real-space grids. Ultrafast laser pulses were used to simulate the near-field excitation under on- and off-resonance conditions. Off-resonance excitation did not lead to the propagation of the excitation through the Na10 chain. In contrast, under the resonance conditions, the excited state is delocalized over the entire Na chain. Analysis of the local dipole moment of each atom in Na10 indicates that this behavior is consistent with the transition density. Adding an N2 molecule to the opposite end of the local excitation region results in energy transfer via the Na10 chain. The energy transfer efficiency of the N2 molecule is well correlated with the absorption spectrum of Na10. The present study paves the way for realizing remote excitation and photonic devices at the atomic scale.

Study on the radiation directivity of a ring-excited thin circular plate with a fixed boundary

Air-coupled transducer with a flat plate structure have many applications in the fields of ground weather observation, ultrasonic defoaming, and directional strong acoustic radiation. In this paper, an analytical equation of the far-field radiation directivity of a fixed boundary ring-excited thin circular plate (RTCP) is deduced using Rayleigh integration method. A finite element model of the RTCP is established, and the relationship between the far-field radiation directivity and the excitation position, excitation area and working frequency is studied by considering the third-order axisymmetric flexural vibration of the RTCP. Computation results show that, for a RTCP, the excitation position has more effect on its radiation directivity. When the plate is excited at the positions between first two nodes, the directivity can be enhanced. When the excitation position is in the trough of the normal displacement curve along radius direction, the side lobes of the radiation directivity of the RTCP are minimized. The area of excitation region has smaller influence on the frequency and radiation directivity of the RTCP. However, working frequency has a great influence on the radiation directivity of the RTCP. When the working frequency is close to the vibration frequency of the circular plate, the sound radiation directivity is the best. A prototype fixed boundary circular plate excited by a longitudinal sandwich transducer was designed and manufactured. For comparison, its finite element model was also setup to simulate its acoustic radiation directivity. Experimental results were found to be in agreement with the theoretical calculations and finite element simulation results.

Voltage manipulation of magnetic rogue waves for controllable electromagnetic interference

In this paper, we investigated the excitation of magnetic rogue waves and their voltage control in ferromagnetic nanowires. Starting from the Maxwell equations coupled with the Landau–Lifshitz–Gilbert equation, we derived the generalized derivative nonlinear Schrödinger equation under the long-wave approximation, which describes the nonlinear wave evolution in anisotropic ferromagnetic nanowires. By constructing the corresponding Lax pair, we obtained the exact solutions of first-order and second-order magnetic rogue waves via a generalized Darboux transformation. After spectral analysis and modulation instability analysis, we present the excitation regions of magnetic rogue waves. Furthermore, we tested and achieved precise control over the occurrence positions of first-order and second-order magnetic rogue waves by applying bias voltage. We further discussed the physical implications of these results, highlighting their potential applications in controlled electromagnetic interference for data destruction.

Polymer-dispersed liquid-crystal coatings for ultrasound visualization: Experiment and theory.

Polymer dispersed liquid crystal (PDLC) films are formed of droplets of liquid crystal (LC) held in a polymer matrix. Similar to aligned LC films, PDLCs exhibit the acousto-optic (AO) effect when excited by acoustic waves of sufficient amplitude, whereby the PDLC film becomes transparent in the excited regions (acoustic clearing). Despite decades of research there is still debate over the mechanisms of the AO effect for the case of LC films, with several competing theories, and AO effects in PDLC have not been studied theoretically. This paper explores the AO effect in PDLC both experimentally and theoretically, and attempts a theoretical description of the observed phenomena based on the theoretical approach by Selinger etal. for aligned LC films. The acousto-optic effect in PDLC is shown to be due to direct interaction of acoustic waves with LC droplets, rather than due to compression of the droplet itself. Polarizing microscopy revealed changes in droplet shape at excited points. This is consistent with reorientation as a contributing factor, possibly coexisting with flows at higher excitation powers. In previous experimental studies PDLC films were prepared with cover slides, in the same way as LC AO cells, significantly limiting applications by adding complexity to the design. Also, to exhibit AO clearing it was considered that the PDLC needed to be prepared with high LC concentrations (over 75% by weight). We demonstrate that no cover slide is necessary, and that PDLC coatings without a cover have improved sensitivity to acoustic waves. We demonstrate the AO effect for LC concentrations as low as 40% by weight. The ability to use standard composition PDLC, with no top cover, is paving the way to paint-on visual ultrasound sensors.

High sensitive detection of Cd, Hg, Pb and Cr in rice based on LA-MPT-OES with optimized excitation regions by two-dimensional characterization of plasma plume

Direct, rapid and highly sensitive detection of heavy metals in rice is essential to ensure food safety. In this research, a combination of laser ablation and microwave plasma torch optical emission spectrometry (LA-MPT-OES) was proposed. Based on the optimal observation positions, a high sensitivity and direct determination of Cd, Hg, Pb and Cr in rice were realized. The limits of detection (LOD) were 0.97, 0.12, 0.61 and 0.15 μg/kg, respectively, which were reduced by one order of magnitude compared to the optimal observation height. In addition, the LOD was reduced by one to two orders of magnitude compared with the techniques that require sample pre-treatment. Moreover, the results of the Certified Reference Materials and real samples were in agreement with the reference values with a relative error in the range of 0.28% ∼ 14.16%. The results demonstrated that LA-MPT-OES could be a promising tool to detect heavy metals in rice.

The Clock and Wavefront Self-Organizing model recreates the dynamics of mouse somitogenesis in vivo and in vitro.

During mouse development, presomitic mesoderm cells synchronize Wnt and Notch oscillations, creating sequential phase waves that pattern somites. Traditional somitogenesis models attribute phase waves to a global modulation of the oscillation frequency. However, increasing evidence suggests that they could arise in a self-organizing manner. Here, we introduce the Sevilletor, a novel reaction-diffusion system that serves as a framework to compare different somitogenesis patterning hypotheses. Using this framework, we propose the Clock and Wavefront Self-Organizing model that considers an excitable self-organizing region where phase waves form independent of global frequency gradients. The model recapitulates the change in relative phase of Wnt and Notch observed during mouse somitogenesis and provides a theoretical basis for understanding the excitability of mouse presomitic mesoderm cells in vitro.

Photochemistry of Photoinduced-Reaction Generated Bubbles.

UV light can create and grow bubbles (herein referred to as PIRGBs for photoinduced-reaction generated bubbles) at liquid/solid interfaces through photoinduced reactions that produce gases. Unlike the simple experience of blowing water bubbles through a straw, in which the bubbles quickly move away from their nucleation sites, not only can a deep UV laser beam create PIRGBs in liquid acetone, but also can hold and grow them. Free bubbles could be attracted to the excitation region from millimeters away, indicating that the reactions cause radial inward flow on the liquid surface. The radial flow can be due to imbalanced surface tensions at the interfaces. Raman measurements reveal that the gases in the PIRGBs include C2H6, CO, and H2, and in liquid acetone, sp2-carbon species are detected upon the UV excitation. Time series Raman measurement discloses a photocarbonization process in which small acyclic carbon species gradually form small clusters with carbon rings and eventually produce a large piece of amorphous carbon at the top of a PIRGB in pure liquid acetone. The photocarbonization may open new avenues for development of carbonaceous materials. Using PIRGB, miniature or microscale gas production reactors can be developed for producing gases.

Demystification of luminescence properties and the near imperceptible thermal quenching of Sm3+-doped tungstate phosphors.

Ultra-high thermally stable Ca2MgWO6:xSm3+ (x = 0.5, 0.75, 1, 1.25, and 1.5mol%) double perovskite phosphors were synthesized through solid-state reaction method. Product formation was confirmed by comparing the X-ray diffraction (XRD) patterns of the phosphors with the standard reference file. The structural, morphological, thermal, and optical properties of the prepared phosphor were examined in detail using XRD, Fourier transform infrared spectra, scanning electron microscopy, diffused reflectance spectra, thermogravimetric analysis (TGA), photoluminescence emission, and temperature-dependent PLE (TDPL). It was seen that the phosphor exhibited emission in the reddish region for the near-ultraviolet excitation with moderate Colour Rendering Index values and high colour purity. The optimized phosphor (x = 1.25mol%) was found to possess a direct optical band gap of 3.31 eV. TGA studies showed the astonishing thermal stability of the optimized phosphor. Additionally, near-zero thermal quenching was seen in TDPL due to elevated phonon-assisted radiative transition. Furthermore, the anti-Stokes and Stokes emission peaks were found to be sensitive toward the temperature change and followed a Boltzmann-type distribution. All these marked properties will make the prepared phosphors a suitable candidate for multifield applications and a fascinating material for further development.

Ultrafast processing of zirconia ceramics by transient and selective laser absorption

Ultrashort-pulse lasers (USPLs) are used in the machining of zirconia ceramics (ZrO2) because of their extremely high peak intensities. However, highly efficient and high precision microprocessing of ZrO2 remains challenging. In this study, we applied a transient and selective laser (TSL) processing technique by combining a USPL and a continuous-wave (CW) laser to realize ultrafast drilling of opaque ZrO2. Ultra-high-efficiency TSL drilling of ZrO2 was achieved with a processing efficiency 1800 times higher than that of USPL drilling. The material removal mechanism, hole formation process, and parameter dependence of TSL drilling were revealed by direct observation of the internal processing phenomenon on a timescale of microseconds. The variations in the processed surface characteristics, including surface morphology, elemental composition, and phase composition, are also presented. Subsequently, the effect of different excited electron regions occurring in the picosecond timescale induced by the USPL on the TSL drilling performance is discussed. Finally, the repeatability and stability of the TSL processing were verified by fabricating microarrays of different sizes. This study will contribute to revealing the ultrafast processing mechanisms of TSL processing in ZrO2 microfabrication. Furthermore, this technique can significantly broaden the applications of ZrO2 in the advanced electronic industry by greatly improving the microprocessing efficiency.

Aqueous phosphate detection in real samples using NIR-triggered Diamino Bis-Benzimidazoquinoline fluorescence sensor: An experimental and theoretical approach

The present work reports the design, synthesis, and sensing applications of Diamino bis-benzimidazoquinoline (DA-BISQ) derivatives. These compounds were synthesized in appreciable yield and characterized by FT-IR, 1H, and 13C NMR spectral and mass spectrometry. Optical studies revealed intriguing dual excitation properties: single excitations at λex 330-386 nm and double excitations at λex 660-772 nm in 10 % ethanol-water medium. The near-infrared excitation region λex 660-772 nm was particularly focused on the detection of F¯, Cl¯, Br¯, I¯, AcO ̄, ClO4¯, NO3¯, and HPO4¯ anions. Notably, selective fluorescence quenching "OFF" responses were observed for geometric anions like AcO¯, ClO4¯, NO3¯, and HPO4¯. Interestingly, the pyridine spacer-containing derivative 1c exhibited a unique fluorescence "OFF-ON'' response for the phosphate ion. Cyclic voltammetry titration further corroborated the binding affinity towards phosphate. To demonstrate practical applicability, a thin-film strip of receptor 1c was fabricated and tested for effective phosphate sensing in human blood serum samples. Density functional theory calculations were performed to elucidate the sensing mechanism with the phosphate anion. The combined experimental and theoretical results suggest an internal charge transfer process between the receptor and the anion.

Direct observation of the transition from spin waves to the magnon Bose condensate

Bose-Einstein condensation occurs at an appropriate density of bosonic particles, depending on their mass and temperature. The transition from the semiclassical paradigm of spin waves to the magnon Bose-Einstein condensed state (mBEC) was obtained experimentally with increasing magnon density. We used the Faraday rotation effect to study the spatial distribution of the magnon density and phase far from their excitation region. A coherent magnetization precession was observed throughout the sample, which indicates the formation of a magnon BEC. It is shown that this result under experimental conditions goes beyond the applicability of the Landau-Lifshitz-Gilbert semiclassical theory.

Maser polarization through anisotropic pumping

Context. Polarized emission from masers is an excellent tool to study magnetic fields in maser sources. The linear polarization of the majority of masers is understood as an interplay of maser saturation and anisotropic pumping. However, for the latter mechanism, no quantitative modeling has been presented yet. Aims. We aim to construct a comprehensive model of maser polarization, including quantitative modeling of both anisotropic pumping and the effects of maser saturation on the polarization of masers. Methods. We extended regular (isotropic) maser excitation modeling with a dimension that describes the molecular population alignments, as well as including the linear polarization dimension to the radiative transfer. The results of the excitation analysis yielded the anisotropic pumping and decay parameters, which were subsequently used in one-dimensional proper maser polarization radiative transfer modeling. Results. We present the anisotropic pumping parameters for a variety of transitions from class I CH3OH masers, H2O masers, and SiO masers. SiO masers are highly anisotropically pumped due to them occurring in the vicinity of a late-type star, which irradiates the maser region with a strong directional radiation field. Class I CH3OH masers and H2O masers occur in association with shocks, and they are modestly anisotropically pumped due to the anisotropy of the excitation region. Conclusions. Our modeling constitutes the first quantitative constraints on the anisotropic pumping of masers. We find that anisotropic pumping can explain the high polarization yields of SiO masers, as well as the modest polarization of unsaturated class I CH3OH masers. The common 22 GHz H2O maser has a relatively weak anisotropic pumping; in contrast, we predict that the 183 GHz H2O maser is strongly anisotropically pumped. Finally, we outline a mechanism through which non-Zeeman circular polarization is produced, when the magnetic field changes direction along the propagation through an anisotropically pumped maser.

Problems of Analogies and Neuroimaging in the Study of Animal Psychology

Possibilities of understanding of animal psychology are considered. In results of performed analysis hypothesis about possibility of approximate understanding of animal with the brain psychology (not in full) is formulated. It is shown that understanding the sensations of animals based on similarity of excited brain regions in them and in humans, i.e. extrapolations, and visualization data is very problematic. For the purposes of understanding the psychology of animals, the author proposed and established using complex hierarchical approach based on multilevel simulation with experimental methods.