Dominant Exchange Research Articles

Investigation of the electronic, optical and magnetic properties of a novel two-dimensional lead-free perovskite: High visible-light absorption and long-range magnetic ordering.

Recently, big issues that need to be solved in photovoltaic solar cells area are the toxicity and instability of lead halide perovskites which have shown exceptional photoelectric performances. Herein, we report the synthesis and physico-chemical characterization of a novel two-dimensional (2D) lead-free perovskite. The 2D Cu(II)-based perovskite (C4N3H16)[CuCl4]∙Cl was successfully stabilized by the slow evaporation method under room temperature. The X-ray diffraction shows a layered structure with an inorganic network formed by four corners sharing CuCl6 octahedra. The UV-Vis absorption analysis confirms the manifestation of the cooperative Jahn-Teller effect around the Cu(II) ions. In addition to the ligand-to-metal charge transfer transitions, crystal field transitions (d-d) enhance the visible-light absorbance and make the material suitable for green solar cell applications with a band gap energy of 2.17 eV. The thermal analysis revealed the thermal stability of (C4N3H16)[CuCl4]∙Cl. Magnetic measurements revealed the presence of dominant ferromagnetic exchange interactions with J/kB = 22.85 K within the 2d planes, with a weak antiferromagnetic exchange interaction yielding a long-range magnetic ordering at 12 K.

Syntheses, structures, and magnetic properties of new [Co9] cluster

A new spin-cluster compound K6BaCo9(PO4H)3(PO4)6Cl2 was synthesized by the traditional solid-phase method. The fundamental magnetic unit of the compound is a coupled [Co9] cluster, which is composed of three non-coplanar triangles. These [Co9] clusters are interconnected by phosphate groups, constructing a two-dimensional framework in the ab plane. The crystal shows the clear easy-axis anisotropy. No long-range magnetic ordering was observed down to 2 K, but there is short-range spin correlation below T = 2.45 K. The Curie-Weiss temperature is about θCW = −19.38 K for the powder sample, which indicates that the dominant exchange interaction is antiferromagnetic with strong frustration (f = |θCW|/T ≈ 10). The magnetization curve presents a likely magnetic field induced transition at μ0Hc = 1.85 T.

Algebraic ER=EPR and complexity transfer

We propose an algebraic definition of ER=EPR in the GN → 0 limit, which associates bulk spacetime connectivity/disconnectivity to the operator algebraic structure of a quantum gravity system. The new formulation not only includes information on the amount of entanglement, but also more importantly the structure of entanglement. We give an independent definition of a quantum wormhole as part of the proposal. This algebraic version of ER=EPR sheds light on a recent puzzle regarding spacetime disconnectivity in holographic systems with O\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\mathcal{O} $$\\end{document}(1/GN) entanglement. We discuss the emergence of quantum connectivity in the context of black hole evaporation and further argue that at the Page time, the black hole-radiation system undergoes a transition involving the transfer of an emergent type III1 subalgebra of high complexity operators from the black hole to radiation. We argue this is a general phenomenon that occurs whenever there is an exchange of dominance between two competing quantum extremal surfaces.

Energy Transport and Conversion Within Earth's Supercritical Bow Shock: The Role of Intense Lower‐Hybrid Whistler Waves

AbstractDetailed analysis of a high Mach number quasiperpendicular Earth bow shock crossing by the Magnetospheric Multiscale (MMS) spacecraft fleet reveal that lower‐hybrid (LH) whistler waves generated in the shock foot region transport energy predominately along the shock surface and slightly toward the shock ramp in the shock normal incidence frame, where wave energy accumulates and is dissipated into the plasma. This suggests the LH whistlers play an integral role in energy reconfiguration at high Mach number collisionless shocks with ramifications to plasma heating. The multipoint observations are used to quantify the wave characteristic parameters (via interferometry), Poynting fluxes, and energy conversion rates D, and to assess their scale dependencies and spatial and temporal properties. The whistler associated energy transport and conversion are found to depend on scale and location within the layer. High‐frequency electrostatic waves yield largest values of D. However, the dominant net energy exchange contribution is from the LH whistlers. In the foot spatially temporally coherent net energy exchange from the plasma to whistlers is observed, whereas deeper in the ramp net wave energy dissipation to the plasma is observed exhibiting significant space‐time variability. These results are consistent with the modified two stream instability driven by the relative drift between reflected ions and electrons as the mechanism for wave growth in the foot. Owing to strong electron heating, whistler energy dissipation in the ramp is attributed to Landau damping, which out‐competes the destabilizing effect of the reflected ion and electron drift.

Impact of wall-slip on the soluto-marangoni instability in a two-fluid system in a channel–Creeping flow scenario

The role of wall-slip on the soluto-Marangoni instability that emerges in a two-fluid creeping two-dimensional Poiseuille flow is assessed within the framework of Orr-Sommerfeld analysis and species-transport system. Different wall-slip scenarios, namely S1 (slip at the upper wall), S2 (slip at the lower wall), S1S2 (symmetric slip at the upper and lower walls) are considered. The system instability is characterized by identifying unstable and stable zones in the m-n (viscosity ratio - depth ratio) plane for each of the slip conditions at the wall using asymptotic analysis for long-wave disturbances. Numerical simulations based on Chebyshev spectral collocation method reveals the emergence of two modes (M1 and M2) and corresponding stability features are displayed for typical values of Marangoni numbers, n, m and slip lengths. The occurrence of short-wave modes and the features of exchanging dominance between the short-wave modes in the presence of wall-slip for different slip condition are elucidated and the physical mechanism responsible for triggering the instability in the system are revealed through energy budget analysis. The channel system hosting less viscous fluid adjacent to the upper wall demonstrates interesting characteristics such as (among other things): stabilizing/destabilizing the emerging M1/M2 modes in system with no-slip by imposing S1/S2/S1S2 wall conditions and increasing the slip length; exchange of dominance of unstable modes beyond a threshold slip length for S1 slip type. The study thus presents possible means of stabilizing/destabilizing a creeping channel flow system by designing the walls of the channel with appropriate slip type relevant to the application.

Interlayer Magnetic Exchange Mechanism of Bilayer Transition‐Metal Trihalides

AbstractLayer‐ and stacking‐dependent interlayer magnetism observed in bilayer has attracted a lot of attention recently. Although considerable efforts have been made, the interlayer exchange mechanism still lacks a clear physical picture. In this paper, orbital overlap‐dependent super‐super‐exchange (SSE) interactions are proposed to understand the interlayer magnetism of bilayer (M = Cr, Fe, and Mo; X = Cl, Br, and I) with different stacking orders. The detailed atom‐ and orbital‐resolved magnetic exchange couplings are evaluated to reveal the underlying mechanism. The results suggest that the interlayer magnetic ground state of all bilayers are antiferromagnetism (AFM) due to the electronic configuration of cation. While and are found to possess stacking‐dependent interlayer magnetism due to the competition between AFM and ferromagnetism (FM), the dominant interlayer AFM exchange couplings are the and for and , respectively, indicating different underlying mechanisms. These distinct interlayer magnetism can be consistently understood by the number and strength of SSE paths, which can be determined by the rule based on the orbital overlap of mediating anions. Moreover, the atom‐ and orbital‐resolved magnetic exchange couplings are also evaluated in detail, which are in good agreement with the above qualitative mechanism. This work provides detailed information and insight for understanding the stacking‐dependent interlayer magnetism, which is beneficial for the application of 2D magnetic materials.

Negativity and its capacity in JT gravity

We study the refined Rényi negativity in the matrix model of Jackiw-Teitelboim (JT) gravity. We first consider the JT gravity with dynamical branes, which serves as a toy model of the evaporating black hole. By including the backreaction of branes, we find that the refined Rényi negativity monotonically decreases at late time of the evaporation. Next we define a novel quantity, which we call “capacity of negativity,” as a derivative of the refined Rényi negativity with respect to the replica number. We find that the capacity of negativity has two peaks as a function of time, which comes from the exchange of dominance of the different types of replica wormholes.

Mixed‐Valence Manganese Carboxylate Clusters, {MnIII6MnII4}, {MnIII7MnII5Na}, and {MnIII7MnII5}, Derived from the Combined Use of Di‐2‐pyridyl Ketone with Selected Aliphatic Diols

AbstractThree new polynuclear clusters with the formulae [Mn10O4(OH)(OMe){(py)2C(O)2}2{(py)2C(OMe)(O)}4(MeCO2)6](ClO4)2 (1), Na[Mn12O2(OH)3(OMe){(py)2C(O)2}6{(py)2C(OH)(O)}2(MeCO2)2(H2O)10](ClO4)8 (2) and [Mn12O4(OH)2{(py)2C(O)2}6{(py)2C(OMe)(O)}(MeCO2)3(NO3)3(H2O)(DMF)2](NO3)2 (3) were prepared from the combination of di‐2‐pyridyl ketone, (py)2CO, with the aliphatic diols (1,3‐propanediol (pdH2) or 1,4‐butanediol (1,4‐bdH2)) in Mn carboxylate chemistry. The reported compounds do not include the aliphatic diols employed in this reaction scheme; however, their use is essential for the formation of 1–3. The crystal structures of 1–3 are based on multilayer cores which, to our knowledge, are reported for the first time in Mn cluster chemistry. Direct current (dc) magnetic susceptibility studies showed the presence of dominant antiferromagnetic exchange interactions within 1–3. Alternating current (ac) magnetic susceptibility studies revealed the presence of out‐of‐phase signals below 3.0 K for 2 and 3 indicating the slow relaxation of the magnetization vector, characteristic of single‐molecule magnets; the Ueff value of 2 was found to be 23 K and the preexponential factor τ0 ~7.6×10−9 s.

Enabling cross-country learning andexchange to support universal health coverage implementation.

As countries transition from external assistance while pursuing ambitious plans to achieve universal health coverage (UHC), there is increasing need to facilitate knowledge sharing and learning among them. Country-led and country-owned knowledge management is foundational to sustainable, more equitable external assistance for health and is a useful complement to more conventional capacity-building modalities provided under external assistance. In the context of external assistance, few initiatives use country-to-country sharing of practitioner experiences, and link learning to receiving guidance on how to adapt, apply and sustain policy changes. Dominant knowledge exchange processes are didactic, implicitly assuming static technical needs, and that practitioners in low- and middle-income countries require problem-specific, time-bound solutions. In reality, the technical challenges of achieving UHC and the group of policymakers involved continuously evolve. This paper aims to explore factors which are supportive of experience-based knowledge exchange between practitioners from diverse settings, drawing from the experience of the Joint Learning Network (JLN) for UHC-a global network of practitioners and policymakers sharing experiences about common challenges to develop and implement knowledge products supporting reforms for UHC-as an illustration of a peer-to-peer learning approach. This paper considers: (1) an analysis of JLN monitoring and evaluation data between 2020 and 2023 and (2) a qualitative inquiry to explore policymakers' engagement with the JLN using semi-structured interviews (n = 14) with stakeholders from 10 countries. The JLN's experience provides insights to factors that contribute to successful peer-to-peer learning approaches. JLN relies on engaging a network of practitioners with diverse experiences who organically identify and pursue a common learning agenda. Meaningful peer-to-peer learning requires dynamic, structured interactions, and alignment with windows of opportunity for implementation that enable rapid response to emerging and timely issues. Peer-to-peer learning can facilitate in-country knowledge sharing, learning and catalyse action at the institutional and health system levels.

A new family of heterometallic [Cu6M4] (M = Gd, Tb, Dy and Y) clusters derived from the combined use of selected pyridyl poly-alcohol ligands.

The combined use of 2-(2-pyridyl)-1,3-propane-diol (pypdH2) and 2-hydroxymethyl-2-(2-pyridyl)-1,3-propane-diol (pyptH3) in Cu2+/4f chemistry has afforded a new family of isostructural [Cu6M4(pypt)4(pypdH)4(NO3)8] [M = Gd (1), Tb (2), Dy (3), and Y (4)] complexes. These compounds are based on an unprecedented three-layered symmetric [Cu6M4(μ-OR)16]8+ structural core, formed from the connection of the metal ions by bridging alkoxide arms of the organic ligands. Direct current magnetic susceptibility studies for complexes 1-3 revealed the presence of dominant ferromagnetic exchange interactions, suggesting the existence of large spin ground state values. Alternating current magnetic studies indicate the presence of slow-magnetic relaxation in 1-3.

Effects of Dzyaloshinskii–Moriya interactions on dipole-exchange spin waves in finite-length ferromagnetic chains

A spin-wave theory that includes the antisymmetric Dzyaloshinskii–Moriya exchange interactions and long-range dipole–dipole interactions, in addition to the Heisenberg bilinear exchange and the applied magnetic field, is presented for finite-length ferromagnetic spin chains. It is found that three different physical situations arise, depending on the direction chosen in this geometry for the axial vector of the Dzyaloshinskii–Moriya interactions. In some cases this leads to a tilting of the equilibrium orientations near the ends of the chain due to interfacial effects and with consequential effects on the spectrum of discrete dipole-exchange spin waves. When variations are introduced for the dominant bilinear exchange interactions at the ends of the spin chain, it is shown that localized spin waves with spatial decay characteristics may occur.

Rare Nuclearities and Unprecedented Structural Motifs in Manganese Cluster Chemistry from the Combined Use of Di-2-Pyridyl Ketone with Selected Diols

The combined use of di-2-pyridyl ketone ((py)2CO) with various diols in Mn cluster chemistry has afforded five new compounds, namely, [Mn11O2(OH)2{(py)2CO2}5(pd)(MeCO2)3(N3)3(NO3)2(DMF)4](NO3)∙2DMF∙H2O (1∙2DMF∙H2O), [Mn11O2(OH)2{(py)2CO2}5(mpd)(MeCO2)3(N3)3(NO3)2(DMF)4](NO3) (2), [Mn12O4(OH)2{(py)2CO2}4(mpd)2(Me3CCO2)4(NO3)4(H2O)6](NO3)2∙2MeCN (3∙2MeCN), [Mn4(OMe)2{(py)2C(OMe)O}2(2-hp)2(NO3)2(DMF)2] (4), and [Mn7{(py)2CO2}4(2-hp)4(NO3)2(DMF)2](ClO4)∙DMF (5∙DMF) ((py)2CO22− and (py)2C(OMe)O− = gem-diol and hemiketal derivatives of di-2-pyridyl ketone, pdH2 = 1,3-propanediol, mpdH2 = 2-metly-1,3-propanediol, 2-hpH2 = 2-(hydroxymethyl)phenol). Complexes 1 and 2 are isostructural, possessing an asymmetric [MnIII5MnII6(μ4-O)(μ3-O)(μ3-OH)(μ-OH)(μ3-OR)2(μ-OR)10(μ-N3)]8+ core. Compound 3 is based on a multilayer [MnIII8MnII4(μ4-O)2(μ3-O)2(μ3-OH)2(μ-OR)12]10+ core, while complex 4 comprises a defective dicubane core. The crystal structure of 5 reveals that it is based on an unusual non-planar [MnIII5MnII2(μ-OR)12]7+ core with a serpentine-like topology. Direct current (dc) magnetic susceptibility studies revealed the presence of dominant antiferromagnetic exchange interactions in complex 3, while ferromagnetic coupling between the Mn ions was detected in the case of compound 5. Fitting of the magnetic data for complex 4 revealed weak antiferromagnetic interactions along the peripheral MnII∙∙∙MnIII ions (Jwb = −0.33 (1) cm−1) and ferromagnetic interactions between the central MnIII∙∙∙MnIII ions (Jbb = 6.28 (1) cm−1).

Arbitrageurs in the Bitcoin ecosystem: Evidence from user-level trading patterns in the Mt. Gox exchange platform

We mine the leaked history of trades on Mt. Gox, the dominant Bitcoin exchange from 2011 to early 2014, in order to detect the triangular arbitrage conducted on the platform. To this end, we exploit user identifiers per trade to identify and describe the individual trading patterns of 440 arbitrageurs. Moreover, we introduce proxies for expertise and document that the expert users' distribution of profits first-order stochastically dominates that of non-expert users. Most importantly, by including user fixed effects, we show that expert users make profits on arbitrage by reacting quickly to plausible exogenous variations on the official exchange rates. A small number of expert arbitrageurs are able to conduct the vast majority of the arbitrage actions and systematically yield higher profits: our results provide empirical evidence that arbitrageurs are few and sophisticated users, characterized by the ability to incorporate information and to quickly react to exogenous shocks within short time scale intervals.

Gone with the fire: Market reaction to cryptocurrency exchange shutdown

Disruption and shutdown of exchanges frequently happen in the cryptocurrency market, though its potential impacts are relatively under-investigated due to several empirical challenges. This study employs 20-h of service interruption on October 15th at Upbit, the dominant cryptocurrency exchange in Korea, as an exogenous shock to examine the effect of unexpected service interruption at the exchange on cryptocurrency market. Event study estimation using price data from Binance, the largest cryptocurrency exchange globally, shows the sharp and negative reactions to cryptocurrencies mostly traded at Upbit. Major currencies such as Bitcoin and Ethereum also presented limited reactions, implying that service interruption could be interpreted as vulnerability of overall cryptocurrencies.

The role of Zn and Ru substitution on the structural, magnetic and dielectric properties of ferrite cuprospinels

A comprehensive study on the structural, magnetic and dielectric behavior of ferrite cuprospinels with site specific substitution of non-magnetic Zn and weakly magnetic Ru ions has been presented. Such substitution leads to two classes of stable crystal symmetries, (i) tetragonal (I41/amd): CuFe1.95Ru0.05O4 and Cu0.95Zn0.05Fe1.95Ru0.05O4 and (ii) cubic (Fd-3m):Cu0.60Zn0.40Fe1.95Ru0.05O4 and Cu0.05Zn0.95Fe1.95Ru0.05O4 bulk polycrystals. The former set of compounds undergo significant Jahn-Teller (JT) distortion due to high Cu content and such distortion gets lifted with the substitution of non-magnetic Zn ions. Ferrimagnetic (FiM) behavior is predominant in all these compounds except the highest Zn (95 at.%) content cubic system with diluted substitution of Ru (2.5 at.%) which exhibits antiferromagnetic ordering below the Néel temperature (T N ∼ 10.9 K). We employed Néel’s expression for FiM systems applicable for the two sublattice model to extract the dominant exchange interactions (J AA , J AB and J BB ) between the A-site and B-site cations. Subsequently the high temperature (300 K T 900 K) inverse paramagnetic susceptibility data has been fitted to the above expression which yields dominant ∼ 391 K with very high asymptotic Curie temperature for the tetragonally distorted dilute Zn substituted cuprospinel, while the Zn-rich cubic system exhibits ∼ 300 K. On the other hand, the tetragonally distorted spinel devoid of Zn exhibits dominant ∼ 229 K with negligible and moderate (65 K) signifying that the JT active ions cause the onset of magnetic frustration and enhanced ordering temperatures. All the investigated systems exhibit significant magneto-crystalline anisotropy with a maximum anisotropy field H K ∼ 6 kOe and maximum anisotropy constant (K 1 ∼ 10.88×105 erg cm−3). The broadband dielectric spectroscopy studies reveal significant enhancement of mid-frequency dielectric constant ε R (f, T) with plateau-like feature over a wide temperature and frequency window, together with low-loss as a result of the incorporation of Ru ions into the tetragonally distorted spinel lattice. The ac resistivity ρ(f, T) studies reveal that the mode of conduction follows Mott’s variable-range hopping (VRH) model with a linear logarithmic variation of ρ ac versus T −0.25. The temperature dependence of the VRH activation energy of charge carriers follows a linear behavior which indicates the presence of localized polaron in all the investigated systems.

Magnetic excitations in the topological semimetal YbMnSb2

We report neutron scattering measurements on YbMnSb$_2$ which shed new light on the nature of the magnetic moments and their interaction with Dirac fermions. Using half-polarized neutron diffraction we measured the field-induced magnetization distribution in the paramagnetic phase and found that the magnetic moments are well localised on the Mn atoms. Using triple-axis neutron scattering we measured the magnon spectrum throughout the Brillouin zone in the antiferromagnetically ordered phase, and we determined the dominant exchange interactions from linear spin-wave theory. The analysis shows that the interlayer exchange is five times larger than in several related compounds containing Bi instead of Sb. We argue that the coupling between the Mn local magnetic moments and the topological band states is more important in YbMnSb$_2$ than in the Bi compounds.

Pharmacological strategies to manage hyperkalaemia: out with the old, in with the new? Not so fast….

Since the 1950s, sodium polystyrene sulphonate (SPS) has been the dominant cation exchange agent prescribed for hyperkalaemia. Clinicians have had plenty of time to learn of SPS's advantages and limitations. The demands of drug regulatory agencies regarding the incorporation of medications into the market were not so stringent then as they are today, and the efficacy and safety of SPS have been questioned. In recent years, two novel cation exchangers, patiromer and sodium zirconium cyclosilicate, have received (or are in the process of receiving) regulatory approval in multiple jurisdictions globally, after scrutiny of carefully conducted trials regarding their short-term and mid-term efficacy. In this debate, we defend the view that all three agents are likely to have similar efficacy. Harms are much better understood for SPS than for newer agents, but currently there are no data to suggest that novel agents are safer than SPS. Drug choices need to consider costs, access and numbers-needed-to-treat to prevent clinically important events; for potassium exchangers, we need trials directly examining clinically important events.

Multiplicity of Zn coordination sites at cubic spinel ferrites: magnetism and influence of the Zn d band

Zinc substituted nickel ferrite (ZnxNi1 − xFe2O4) is investigated under density functional theory (DFT) within the DFT + U approximation for x ≤ 0.50, with particular interest in understanding the effect of Zn on the net magnetization. Using as a reference ZnFe2O4, the localization of the Zn d band is proved to have a large impact on the preference for Zn to occupy either tetrahedral (ZnA) or octahedral (ZnB) coordination sites, which in ZnFe2O4 is equivalent to the relative stability of the direct and inverse spinel forms. This affects the lattice volume, with ZnA favoring larger lattice expansions. Additional important consequences emerge on the magnetism of the system, as ZnA and ZnB alter the balance of atoms at the magnetic sublattices in a different way: while ZnA enhances the global magnetization by reducing the minority spin contribution, the opposite occurs for ZnB. On the other hand, the dominant magnetic exchange interactions are not significantly altered by Zn independently of its distribution, while the magnetic anisotropy of soft NiFe2O4 is further weakened. Our simulations support the presence of a significant ratio of Zn atoms at octahedral positions at ZnxNi1 − xFe2O4, mainly as the Zn concentration increases, putting limits to the ability to increase the magnetization of NiFe2O4 by Zn substitution.

Magnetic and electrical properties of high-entropy rare-earth manganites

Detailed investigations of structural, magnetic and electronic transport properties of hole-doped high-entropy rare-earth manganites are presented. The high-entropy samples (La0.2Nd0.2Pr0.2Sm0.2Eu0.2)1−xSrxMnO3 (0 ≤ x ≤ 0.5), synthesized using the solid-state technique, show a change in the crystal structure from Pbnm to R-3c with increasing Sr substitution, attributed to the change in the tolerance factor. Prominent ferromagnetic ordering is observed in the sample with a rhombohedral structure (x ≥ 0.3), originating from the dominant double exchange mechanism mediated by itinerant electrons. Further, the Curie temperature is smaller for the high-entropy sample with x=0.3, as compared to La0.7Sr0.3MnO3, suggesting a strong relation between the Curie temperature and the Mn–O–Mn bond angle associated with the reduced ionic radii at the rare-earth site. The electrical resistivity of the high-entropy samples is larger than those of La1−xSrxMnO3, which can be ascribed to the reduced bandwidth due to the enhanced structural distortion. A concomitant rise in magnetoresistance is observed for high-entropy samples with the increase in Sr concentration. These findings considering the configurational complexity of different rare-earths advance the understanding of high-entropy rare-earth manganites.

The Russian E-commerce Market During COVID-19: Legal Regulation and Trends

The subject of this paper’s research is the peculiarities of legal regulation and development of the e-commerce market during the COVID-19 pandemic. The author examines in detail the concept of "e-commerce," which is understood as an economic sphere that combines trade and financial transactions that are carried out through contactless interaction of the parties involved. The article also analyzes the system of legal regulation of the e-commerce market and identifies trends for further improvement. Particular attention is paid to the impact of the pandemic on civil law turnover, resulting in the e-commerce market becoming the dominant commodity exchange in the Russian Federation. The study provides statistics on commodity exchange on online platforms for 2021–2022, which has grown significantly compared to previous years. The author’s main conclusions are that the COVID-19 pandemic accelerated the processes of digitalization in all spheres of public life, as a result of which trade and financial transactions, for the most part, began to be carried out via the Internet and laid the foundation of the digital economy; to date, electronic commerce has become predominant, but is not devoid of shortcomings of legal regulation; trends of strengthening digital transformation are aimed at delineating the legal status and responsibility of participants in trade ("marketplace," "online store," etc.), expanding the list of types of digital assets and determining their legal regime (account, etc.).