Excess Surfactant Research Articles

Surfactant-Free Preparation of Conjugated Polymer Nanoparticles in Aqueous Dispersions Using Sulfate Functionalized Fluorene Monomers.

Conjugated polymer nanoparticles (CPNs) can be synthesized by a Suzuki-Miyaura cross-coupling miniemulsion polymerization to give stable dispersions with a high concentration of uniform nanoparticles. However, large amounts of added surfactants are required to stabilize the miniemulsion and prevent the aggregation of the nanoparticles. Removal of the excess surfactant is challenging, and residual surfactant in thin films deposited from these dispersions can reduce the performance of optoelectronic devices. We report a novel approach to prepare stable dispersions with no added surfactant using a fluorene monomer, 2,7-dibromo-9,9-bis(undecanesulfate)-9H-fluorene, with alkyl side chains terminated by negatively charged sulfate groups. This functionality mimics the structure of one of the most commonly used surfactants, sodium dodecyl sulfate (SDS). This charged monomer effectively stabilizes the miniemulsion through electrostatic repulsion without the use of any additional surfactant in molar ratios ranging from 2.0 to 20.0 mol % of total monomer content for the preparation of poly(9,9-dioctylfluorene) (PFO) and poly(9,9-dioctylfluorene-alt-bithiophene) (PF8T2). Incorporation of 5.0 mol % of the amphiphilic monomer gave stable dispersions with a surface potential below -40 mV and, and polymers with molar mass (Mn) above 10 kg mol-1. This method should be generally applicable to the preparation of dispersions of polyfluorenes for application in organic electronic and optoelectronic devices without the requirement for time-consuming processes to remove residual surfactant.

Insertion of anionic synthetic clay in lamellar surfactant phases.

We describe the different mixed colloidal solutions that can be obtained when mixing equivalent quantities of a synthetic anionic clay to surfactants forming lamellar phases in the absence of added salt. The important quantity driving toward insertion or depletion is the osmotic pressure, of the lamellar phase and of the clay alone. Competition for water is the main driving force toward dispersion, inclusion or exclusion (phase separation). In the case of a nonionic surfactant ( ) mixed with Laponite, undulations quenched by the surfactant-decorated clay lead to swelling; inclusion is not observed due to differences in rigidity. Long-range order is weakened leading eventually to the exclusion of surfactant in excess. In the case of a double anionic system (AOT-Laponite), electrostatic is dominant and the three regimes are encountered. In the catanionic case, admixing the double chain cationic lipid DDAB to the clay (in large charge excess), the platelets are coated by a positively charged bilayer. Long-range order is very efficiently dampened. From a low threshold (2% by weight), there is exclusion of a clay-poor collapsed lamellar phase, detected by the swelling of the main phase. The cationized clay does not interfere with the molecular force balance: the location of the critical point is unchanged. At high Laponite concentration, a very puzzling microstructure is observed. Some phase diagrams as well as representative SANS and SAXS data are extracted from the complete results concerning the lyotropic lamellar phase mixing problem available with all measures and evaluations of osmotic pressures in the PhD of the late Isabelle Grillo.

Endogenous LXR signaling controls pulmonary surfactant homeostasis and prevents lung inflammation

Lung type 2 pneumocytes (T2Ps) and alveolar macrophages (AMs) play crucial roles in the synthesis, recycling and catabolism of surfactant material, a lipid/protein fluid essential for respiratory function. The liver X receptors (LXR), LXRα and LXRβ, are transcription factors important for lipid metabolism and inflammation. While LXR activation exerts anti-inflammatory actions in lung injury caused by lipopolysaccharide (LPS) and other inflammatory stimuli, the full extent of the endogenous LXR transcriptional activity in pulmonary homeostasis is incompletely understood. Here, using mice lacking LXRα and LXRβ as experimental models, we describe how the loss of LXRs causes pulmonary lipidosis, pulmonary congestion, fibrosis and chronic inflammation due to defective de novo synthesis and recycling of surfactant material by T2Ps and defective phagocytosis and degradation of excess surfactant by AMs. LXR-deficient T2Ps display aberrant lamellar bodies and decreased expression of genes encoding for surfactant proteins and enzymes involved in cholesterol, fatty acids, and phospholipid metabolism. Moreover, LXR-deficient lungs accumulate foamy AMs with aberrant expression of cholesterol and phospholipid metabolism genes. Using a house dust mite aeroallergen-induced mouse model of asthma, we show that LXR-deficient mice exhibit a more pronounced airway reactivity to a methacholine challenge and greater pulmonary infiltration, indicating an altered physiology of LXR-deficient lungs. Moreover, pretreatment with LXR agonists ameliorated the airway reactivity in WT mice sensitized to house dust mite extracts, confirming that LXR plays an important role in lung physiology and suggesting that agonist pharmacology could be used to treat inflammatory lung diseases.Graphical

Binary surfactant-optimized silica aerogel slurries for building materials: Effects of formulation and content

Developing silica aerogel slurries is a strategic approach for incorporating silica aerogels into matrix materials to enhance the efficiency of aerogel composites. This study introduces a novel binary surfactant mixture, using a 1:4 ratio of polyether L62 and CTAC, optimized for the performance of aerogel slurries. Our extensive testing reveals that this formulation significantly reduces the surface tension to 24.25 mN/m and achieves a remarkable thermal conductivity of 26.7 mW/m/K, while maintaining high hydrophobicity with a contact angle exceeding 125°. The slurries exhibit a wet density of 0.48 g/cm³ and a dry density of 0.098 g/cm³, emphasizing the lightweight nature of the aerogel composites. Additionally, the study illustrates that while increasing the surfactant concentration optimally raises the aerogel content, excess surfactant adversely affects the thermal insulation properties. Microstructural analysis confirms that the binary surfactant mixture effectively modifies the aerogel surface, overcoming the dispersal limitations associated with aerogel's hydrophobic groups. This breakthrough in slurry formulation greatly enhances both the insulating and water-repellent capabilities of silica aerogels, offering a viable engineering solution for developing high-performance aerogel composites for thermal insulation applications.

Maize‐derived zein/acrylic hybrid emulsion for superior skin adhesion and water resistance in cosmetic adhesives

AbstractWaterborne acrylic emulsions are considered suitable materials for cosmetic skin adhesives because of their positive attributes, such as their safe water‐based polymerization process and low volatile‐organic‐compound emissions. The significant challenge of inadequate water resistance in emulsion adhesives, which is primarily caused by the excess surfactants retained at the interface of emulsion particles upon film formation, necessitates urgent resolution for their viable application as cosmetic adhesives. Zein, a corn‐derived protein, possesses hydrophobic amino acids that provide exceptional water‐repellent characteristics. Therefore, zein is expected to exhibit a remarkable skin‐adhesion attribute. This paper presents the introduction of a pioneering zein/acrylic hybrid emulsion exhibiting remarkable skin adhesion and water resistance, which was achieved through the use of zein, a corn‐derived protein. After formation, the zein/ sodium dodecyl sulfate (SDS) complex can unfold the zein chain, thereby enhancing skin adhesion, while concurrently inhibiting surfactant migration to enhance water resistance. The zein/SDS complex was introduced into the Pre‐emulsion (PE) manufacturing process during emulsion polymerization. As expected, the zein/acrylic hybrid emulsion demonstrated favorable skin adhesion and a notable improvement in water resistance. This approach presents a promising avenue for the practical application of emulsion nanoparticles as eco‐friendly cosmetic adhesives, offering excellent durability and skin adhesion through the utilization of naturally derived proteins.

Charge Regulation at the Nanoscale as Evidenced from Light-Responsive Nanoemulsions.

Emulsions are indispensable in everyday life, and the demand for emulsions' diversity and control of properties is therefore substantial. As emulsions possess a high internal surface area, an understanding of the oil/water (o/w) interfaces at the molecular level is fundamental but often impaired by experimental limitations to probe emulsion interfaces in situ. Here, we have used light-responsive surfactants (butyl-AAP) that can photoisomerize between E and Z isomers by visible and UV light irradiation to tune the emulsion interfaces. This causes massive changes in the interface tension at the extended o/w interfaces in macroemulsions and a drastic shift in the surfactants' critical micelle concentration, which we show can be used to control both the stability and phase separation. Strikingly different from macroemulsions are nanoemulsions (RH ∼90 nm) as these are not susceptible to E/Z photoisomerization of the surfactants in terms of changes in their droplet size or ζ-potential. However, in situ second-harmonic scattering and pulsed-field gradient nuclear magnetic resonance (NMR) experiments show dramatic and reversible changes in the surface excess of surfactants at the nanoscopic interfaces. The apparent differences in ζ-potentials and surface excess provide evidence for a fixed charge to particle size ratio and the need for counterion condensation to renormalize the particle charge to a critical charge, which is markedly different compared to the behavior of very large particles in macroemulsions. Thus, our findings may have broader implications as the electrostatic stabilization of nanoparticles requires much lower surfactant concentrations, allowing for a more sustainable use of surfactants.

Polymeric surfactants at liquid–liquid interfaces: Dependence of structural and thermodynamic properties on copolymer architecture

Polymeric surfactants are amphiphilic molecules with two or more different types of monomers. If one type of monomer interacts favorably with a liquid, and another type of monomer interacts favorably with another, immiscible liquid, then polymeric surfactants adsorb at the interface between the two liquids and reduce the interfacial tension. The effects of polymer architecture on the structural and thermodynamic properties of the liquid–liquid interface are studied using molecular simulations. The interface is modeled with a non-additive binary Lennard-Jones fluid in the two-phase region of the phase diagram. Block and gradient copolymer surfactants are represented with coarse-grained, bead-spring models, where each component of the polymer favors one or the other liquid. Gradient copolymers have a greater concentration at the interface than do block copolymers because the gradient copolymers adopt conformations partially aligned with the interface. The interfacial tension is determined as a function of the surface excess of polymeric surfactant. Gradient copolymers are more potent surfactants than block copolymers because the gradient copolymers cross the dividing surface multiple times, effectively acting as multiple individual surfactants. For a given surface excess, the interfacial tension decreases monotonically when changing from a block to a gradient architecture. The coarse-grained simulations are complemented by all-atom simulations of acrylic-acid/styrene copolymers at the chloroform-water interface, which have been studied in experiments. The agreement between the simulations (both coarse-grained and atomistic) and experiments is shown to be excellent, and the molecular-scale structures identified in the simulations help explain the variation of surfactancy with copolymer architecture.

Electrical and thermal conductivity in graphene-enhanced carbon-fibre/PEEK: The effect of interlayer loading

Combining graphene at different loadings with composites offers the possibility of tailored electrical and thermal properties for the aerospace sector, including electrostatic dissipation, thermal management and lightning strike protection applications. The effects of interlaminar graphene loadings to impart property enhancement in fibre reinforced thermoplastic composites remains unknown. Spray deposition offers a highly scalable, and rapid method to embed graphene. This study investigates the application of spray-deposited graphene suspension synthesised via liquid phase exfoliation (LPE) to functionalise carbon fibre/polyether ether ketone (CF/PEEK) composites. LPE graphene suspensions were spray deposited onto CF/PEEK prepreg ply substrates to create smooth thin films. With increased deposition time the graphene thin film root mean squared roughness decreased from 3.51 μm to 2.52 μm. The addition of 0.25 wt%, 0.7 wt% and 1.1 wt% graphene to the interlaminar regions in consolidated CF/PEEK imparted enhanced electrical and thermal conductivity. Electrical conductivity enhancement of up to ∼252% transverse to the fibre direction and up to ∼204% through thickness was measured after the addition of 0.25 wt% graphene. Thermal diffusivity increased up to ∼183% through-thickness, while 61% in the transverse to the fibre direction with 0.7 wt% additions. However, increased graphene loading also increased the void content in the composite resulting in reduced shear strength. Excess surfactant vapourisation during high temperature processing likely created voids up to 2.8 vol% often located within the interply and interlaminar region hindering anisotropic conductivity enhancement. Nevertheless, graphene loadings within the interlaminar region show promise in imparting bulk property enhancement.

Simple model for self-propulsion of microdroplets in surfactant solution.

We propose a simple active hydrodynamic model for the self-propulsion of a liquid droplet suspended in micellar solutions. The self-propulsion of the droplet occurs by spontaneous breaking of isotropic symmetry and is studied using both analytical and numerical methods. The emergence of self-propulsion arises from the slow dissolution of the inner fluid into the outer micellar solution as filled micelles. We propose that the surface generation of filled micelles is the dominant reason for the self-propulsion of the droplet. The flow instability is due to the Marangoni stress generated by the nonuniform distribution of the surfactant molecules on the droplet interface. In our model, the driving parameter of the instability is the excess surfactant concentration above the critical micellar concentration, which directly correlates with the experimental observations. We consider various low-order modes of flow instability and show that the first mode becomes unstable through a supercritical bifurcation and is the only mode contributing to the swimming of the droplet. The flow fields around the droplet for these modes and their combined effects are also discussed.

Heat treated graphene thin films for reduced void content of interlaminar enhanced CF/PEEK composites

Graphene enhanced thermoplastic composites offer the possibility of conductive aerospace structures suitable for applications from electrostatic dissipation, to lightning strike protection and heat dissipation. Spray deposition of liquid phase exfoliated (LPE) aqueous graphene suspensions are highly scalable rapid manufacturing methods suitable to automated manufacturing processes. The effects of residual surfactant and water from LPE on thin films for interlaminar prepreg composite enhancement remain unknown. This work investigates the effect of heat treatment on graphene thin films spray deposited onto carbon fibre/polyether ether ketone (CF/PEEK) composites for reduced void content. Graphene thin films deposited onto CF/PEEK prepreg tapes had an RMS roughness of 1.99 μm and an average contact angle of 11°. After heat treatment the roughness increased to 2.52 μm with an average contact angle of 82°. The SEM images, contact angle, and surface roughness measurements correlated suggesting successful removal of excess surfactant and moisture with heat treatment. Raman spectroscopy was used to characterise the chemical quality of the consolidated graphene interlayer. Spectral data concluded the graphene was 3–4 layered with predominantly edge defects suggesting high quality graphene suitable for electrical enhancement. Conductive-AFM measurements observed an increase in conductive network density in the interlaminar region after the removal of surfactant from the thin film. Heat treatment of the Control sample successfully reduced void content from 4.2 vol% to 0.4 vol%, resulting in a 149% increase in compressive shear strength. Comparatively, heat treatment of graphene enhanced samples (~ 1 wt%) reduced void content from 5.1 vol% to 2.8 vol%. Although a 25% reduction in shear strength was measured, the improved electrical conductivity of the interlaminar region extends the potential applications of fibre reinforced thermoplastic composites. The heat treatment process proves effective in reducing surfactant and thus void content while improving electrical conductivity of the interlayer in a scalable manner. Further investigations into graphene loading effects on conductive enhancement, and void formation is needed.

Glassy and compressed nanoemulsions stabilized with sodium dodecyl sulfate in the presence of poly(ethylene glycol)-diacrylate.

The rheology of concentrated nanoemulsions is critical for their formulation in various applications, such as pharmaceuticals, foods, cosmetics, and templating advanced materials. The rheological properties of nanoemulsions depend on interdroplet interactions, Laplace pressure, dispersed phase volume fraction, and continuous phase properties. The interdroplet forces can be tuned by background electrolytes (i.e., charge screening), surfactant type, the excess surfactant micelle concentration, and depletant molecules such as polymer chains. In the current research, we study the effect of varying the content of poly(ethylene glycol)-diacrylate (PEGDA) on the interfacial tension of the water-oil phase and rheological properties of concentrated nanoemulsions with 50% and 60% volume fractions. Sodium dodecyl sulfate (SDS) is used as the ionic surfactant. The final concentrated nanoemulsions are repulsive according to overall interaction potentials and are in the glass and compressed states based on the effective volume fraction estimation. They contain nearly same SDS concentration on the droplet surface and also in the bulk, but a different amount of PEGDA. The scaled rheological properties of the glassy nanoemulsions show a higher dependency on the PEGDA content and the possible effect of polymer-surfactant complexations compared to those of the compressed ones. This dependency is more pronounced in small strain amplitudes but not in large strains in the non-linear regime. These results provide insights into formulating concentrated nanoemulsions with controlled rheology for expanded application areas.

Universal Character of Breaking of Wormlike Surfactant Micelles by Additives of Different Hydrophobicity.

Wormlike surfactant micelles are widely used in various applications including fracturing technology in oil industry, template synthesis of different nanoobjects, micellar copolymerization of hydrophilic and hydrophobic monomers, and so forth. Most of those applications suggest the solubilization of different additives in the micelles. The present paper is aimed at the comparative study of the effect of the solubilization of hydrophobic (n-decane and 1-phenylhexane) and hydrophilic (N-isopropylacrylamide and acrylamide) substances on the rheological properties and structure of the micelles using several complementary techniques including rheometry, small angle neutron scattering, dynamic light scattering, and diffusion ordered NMR spectroscopy. For these studies, mixed micelles of potassium oleate and n-octyltrimethylammonium bromide containing the excess of either anionic or cationic surfactants were used. It was shown that hydrophobic additives are completely solubilized inside the micelles being localized deep in the core (n-decane, 1-phenylhexane) or near the core/corona interface (1-phenylhexane). At the same time, only a small fraction of hydrophilic additives (14% of N-isopropylacrylamide and 4% of acrylamide) penetrate the micelles being localized at the corona area. Despite different localization of the additives inside the micelles, all of them induce the breaking of wormlike micelles with the formation of either ellipsoidal microemulsion droplets (in the case of hydrophobic additives) or ellipsoidal surfactant micelles (in the case of hydrophilic additives). The breaking of micelles results in the drop of viscosity of the solution up to water value. The main result of this paper consists in the observation of the fact that for all the additives under study, the dependences of the viscosity on the volume fraction of additive lie on the same master curve being shifted along the volume fraction axis by a certain factor depending on the hydrophobicity of the added species. Those data are quite useful for various applications of wormlike surfactant micelles suggesting the solubilization of different additives inside them.

Water-Processed Organic Solar Cell with Efficiency Exceeding 11.

Water processing is an ideal strategy for the ecofriendly fabrication of organic photovoltaics (OPVs) and exhibits a strong market−driven demand. Here, we report a state−of−the−art active material, namely PM6:BTP−eC9, for the synthesis of water−borne nanoparticle (NP) dispersion towards ecofriendly OPV fabrication. The surfactant−stripping technique, combined with a poloxamer, facilitates purification and eliminates excess surfactant in water−dispersed organic semiconducting NPs. The introduction of 1,8−diiodooctane (DIO) for the synthesis of surfactant−stripped NP (ssNP) further promotes a percolated microstructure of the polymer and NFA in each ssNP, yielding water−processed OPVs with a record efficiency of over 11%. The use of an additive during water−borne ssNP synthesis is a promising strategy for morphology optimization in NP OPVs. It is believed that the findings in this work will engender more research interest and effort relating to water−processing in preparation of the industrial production of OPVs.

Solid lipid nanoparticles and nanostructured lipid carriers of dual functionality at emulsion interfaces. Part I: Pickering stabilisation functionality

Solid lipid nanoparticles and nanostructured lipid carriers are two types of lipid nanoparticulate systems, that have been primarily studied for their capability to function as active carriers, and only more recently utilised in Pickering emulsion stabilisation. Unveiling the factors that impact upon the lipid particle characteristics related to their Pickering functionality could enable the development of a liquid formulation with tailored microstructure and potentially the capacity to display a two-fold performance. In part I, this work investigates how certain formulation characteristics, namely solid-to-liquid lipid mass ratio and presence of unadsorbed surfactant in the aqueous carrier phase, affect the structural properties of the lipid particles, and in turn how these influence their Pickering stabilisation capacity. The effect of the formulation parameters was assessed in terms of the wettability and physicochemical properties of the lipid particles, including particle size, crystallinity and interfacial behaviour. Lipid particles fabricated with higher liquid lipid content (70% w/w) were shown to be more hydrophilic and have lower surfactant decoration at their surface compared to particles containing lower or no liquid lipid in their crystalline matrix. The emulsion stabilisation ability through a Pickering mechanism was confirmed for all types of lipid particles using polarised microscopy. Increasing liquid lipid content and removal of excess surfactant did not compromise the particle stabilisation capacity, though emulsion droplets of larger sizes were initially acquired in the latter case. The particle-stabilised emulsions maintained their physical integrity, with particles retaining close association with the emulsion interface over a storage period of 12 weeks.

Using Polymer-Surfactant Charge Ratio to Control Synergistic Flocculation of Anionic Particulate Dispersions.

This study investigates the flocculation induced destabilization of particulate dispersions by oppositely charged polymer–surfactant complexes, with a particular focus on controlling interactions by modulating the charge ratio Z, (where Z = [+polymer]/[−surfactant]) via [−surfactant] at fixed Cpolymer. Cationic hydroxyethyl cellulose (cat-HEC) polymer-sodium dodecylsulfate (SDS) complexes were prepared with either excess polymer (Z > 1) or surfactant (Z < 1) charges. Anionic particulate dispersions (Ludox and polystyrene-butadiene Latex) were then exposed to the complexes, and solvent relaxation NMR was used to characterize the particle surfaces before and after exposure. In both particulate dispersions, flocculation induced destabilization was enhanced after exposure to cat-HEC-SDS complexes with Z > 1, leaving any excess particle surfaces uncoated after gentle centrifugation. However, complexes with Z < 1 showed no adsorption and destabilization in the Ludox dispersions and only slight destabilization in the Latex dispersions due to possible hydrophobic interactions. Substituting SDS for non-ionic surfactant (C12E6) showed no additional destabilization of the dispersions, but post-centrifugation relaxation rates indicated preferential adsorption of C12E6 onto the particle surfaces. Since the dominant forces are electrostatic, this study highlights the possibility of controlling the interactions between oppositely charged polymer–surfactant complexes and particle surfaces by modulating Z through [−surfactant].

Effect of an excess of surfactant on thermophoresis, mass diffusion and viscosity in an oily surfactant-stabilized ferrofluid.

The effect of an excess of surfactant on the thermophoresis of a sterically stabilized ferrofluid is investigated experimentally by forced Rayleigh scattering (FRS). The experiments are performed with a stable magnetic fluid sample to which controlled amounts of surfactant are added. A decrease in the thermally induced transport of magnetic nanoparticles is observed while increasing the temperature T. The positive Soret coefficient [Formula: see text] decreases by adding 2vol% of surfactant at room temperature. As shown by FRS relaxation, this decreasing is mainly associated with a reduction of the interaction between the carrier fluid and individual nanoparticles. No significant effect of extra surfactant on the sign of [Formula: see text] is observed at higher T's (up to [Formula: see text]C). Dynamic light scattering at room temperature reveals the presence of a small amount of clusters/aggregates in the samples, which are hardly detectable by FRS relaxation. The presence of these small clusters/aggregates is confirmed by a rheological probing of the fluid properties. Whatever T, a small amount of added surfactant first causes a decrease of the ferrofluid viscosity, associated with a 10% decreasing of the flow activation energy. Further on, viscosity and activation energy both recover at higher excess surfactant concentrations. These results are analyzed in terms of saturation of the surfactant layer, concentration of free surfactant chains and heat of transport of the nanoparticles.

Simultaneous addition of surfactant and oxidant to remediate a polluted soil with chlorinated organic compounds: Slurry and column experiments

The inadequate management of wastes associated with chlorinated organic compounds (COCs) has become a huge environmental problem. Surfactant Enhanced In-Situ Chemical Oxidation (S-ISCO) was studied as a successful technique to remediate polluted sites. This work investigated the reaction between an aqueous solution of nonionic surfactant (Emulse-3®) and an oxidant (sodium persulfate activated with NaOH) with a real polluted soil with a complex mixture of COCs from lindane liquid wastes. Two experimental setups were used. In the first one, the reactions were carried out in batch mode under slurry conditions using different surfactant concentrations (0–10 g·L−1), 210 mM of persulfate and 420 mM of NaOH with an aqueous to soil ratio VL/W = 10 L·kg−1. The runs were carried using a column loaded with the soil in the second experimental setup. The solution of surfactant, oxidant and activator was put in contact with soil in four pore volumes with a ratio aqueous to soil ratio VL/W = 0.2 L·kg−1. Under these experimental conditions, the surfactant addition improved the reduction of COCs compared with the application carried out without surfactant, from 40.1% to values of conversion of 64.8 – 90.4%. However, an excess of surfactant hindered the COCs oxidation and increased the unproductive consumption of the oxidant, resulting in an optimal value of surfactant in the aqueous phase (1–2 g·L−1). A remarkable drop in the surfactant concentration in the aqueous phase and COCs solubilized was noticed in column runs due to the surfactant adsorption.

Surfactant-free starch-graphene composite films as simultaneous oxygen and water vapour barriers

A single coating formulation for multifunctional composites, such as a gas barrier against both oxygen and water vapour, is the holy grail for the packaging industry. Since the last decade, graphene has been touted as the ideal barrier material in composites due to its morphology and impermeability to all gases. However, this prospect is limited by either poor dispersion of graphene or excess surfactants to aid the dispersion, both leading to shortcuts that allow gas permeation through the composite. Here, we demonstrate a combined gas barrier with starch-graphene composite films made from a single formulation of surfactant-free starch nanoparticle-stabilized graphene dispersion (2.97 mg mL−1). Hence, the incorporated graphene reduces the permeability of both the oxygen and the water vapour by over 70% under all the relative humidity conditions tested. Moreover, these films are foldable and electrically conductive (9.5 S m−1). Our surfactant-free approach of incorporating graphene into an industrially important biopolymer is highly relevant to the packaging industry, thus offering cost-effective and water-based solution depositions of multifunctional composite films for wide-ranging applications, such as gas barriers in food packaging.

Improving membrane protein structural study in electron cryo-microscopy: impact of surfactant excess

Over the past decade, the number of membrane protein (MP) structures solved at the atomic resolution level by electron cryo-microscopy (cryo-EM) has increased dramatically [1]. Despite the impact of cryo-EM in MP structural biology, further technological developments are still required. A major limitation lies in the preparation of high-quality grids: general advices might be shared [2], but grid properties remain poorly reproducible and system-dependent.

Unraveling the Kinetics and Mechanism of Surfactant-Induced Wetting in Membrane Distillation: An In Situ Observation with Optical Coherence Tomography.

In this study, we performed a direct contact membrane distillation and successfully demonstrated the non-invasive imaging of surfactant-induced wetting using optical coherence tomography. This method enabled us to investigate the wetting kinetics, which was found to follow a "three-region" relationship between the wetting rate and surfactant concentration: the (i) nonwetted region, (ii) concentration-dependent region, and (iii) concentration-independent region at low, intermediate, and high surfactant concentrations, respectively. This wetting behavior was explained by the "autophilic effect", i.e., the wetting was caused by the transfer of surfactants from the water-vapor interface to the unwetted membrane and rendered this membrane hydrophilic, and then the wetting frontier moved forward under capillary forces. At region-(i), the surfactant concentration in the water-vapor interface (Clv) was too low to make the unwetted membrane sufficiently hydrophilic; thereby, the membrane could not be wetted. At region-(ii), due to the fast adsorption of the surfactant on the newly wetted membrane, the wetting rate was determined by the advection/diffusion of surfactants from the feed stream. Consequently, the wetting rate increased with the increases in the water flux and surfactant concentration. At region-(iii), the advection/diffusion provided excess surfactants for adsorption, and thus Clv reached its upper limit (maximum surface excess) and the wetting rate leveled off.