Exceptional Behavior Research Articles

Precipitation drives western Patagonian glacier variability and may curb future ice mass loss.

Two-thirds of all glaciers worldwide are projected to disappear by 2100 CE. Large uncertainties however remain in maritime settings, where some glaciers have recently gained mass in response to increased snowfall. One of these regions is southern Patagonia, where increased precipitation since the 1980s seems to have attenuated glacier retreat. Whether this exceptional behavior will continue in a warmer future is unclear. Here, we use a numerical ice-flow model constrained by paleoglaciological data to simulate how climate variability influenced the evolution of three maritime outlet glaciers of the Southern Patagonian Icefield during the last 6000 years. Our experiments suggest that precipitation drove 67% of the centennial-scale fluctuations in the volume of the modeled glaciers. When applied to the temperature projected by 2100 CE, our simulations show that precipitation needs to increase by 10-50% to maintain present-day glacier volumes, depending on the climate scenario (SSP1-2.6 to SSP5-8.5). This implies that if greenhouse-gas emission cuts fail, these glaciers will enter a warmer regime unseen over the last 6000 years, where precipitation cannot offset glacier mass loss. Conversely, if emissions are curtailed, increased precipitation could halt mass loss of some of Patagonia's largest glaciers, and potentially of other maritime glaciers worldwide.

Evidence for Nanostructures of at Least 20 nm in a Phosphonium Ionic Liquid at Room Temperature Using Fluorescence Correlation Spectroscopy.

Fluorescence correlation spectroscopy (FCS) measurements are performed on the ionic liquid (IL), tetradecyl(trihexyl) phosphonium chloride, [P66614+][Cl-], using fluorescent probes of varying sizes: ATTO 532, ∼2 nm; and 20- and 40 nm fluorescent beads. The fluorescence correlation function, G(t), is analyzed in terms of a distribution of diffusion coefficients using a maximum entropy method (MEM). For ATTO 532 and the 20 nm beads, the fit to G(t) yields two well-defined distributions; for the 40 nm beads, however, only one is obtained. These results are consistent with the existence of two nanodomains whose size is greater than or equal to 20 nm and less than 40 nm. The origin of such nanodomains is attributed to a liquid-liquid phase transition. Other groups have observed liquid-liquid phase transitions experimentally in a number of systems, including [P66614+][Cl-]. We suggest that because large regions (i.e., greater than 1-2 nm) resulting from the liquid-liquid phase transition would be expected to have different properties, such as viscosity, and because their presence would necessarily increase the number of interfaces in the IL, these regions may provide an explanation for the exceptional behavior of ILs in various separation systems.

Synthesis and Fabrication of Metal Cation Intercalation in Multilayered Ti3C2Tx Composite CNF Electrode for Asymmetric Coin Cell Supercapacitors.

Ti3C2Tx has attracted considerable attention from researchers in energy storage due to its unique structure and beneficial surface functional group characteristics. Recent studies have focused extensively on developing Ti3C2Tx composites to create potential electrode materials for energy storage applications. Carbon nanofiber is often combined with Ti3C2Tx to produce high-performance functional nanocomposites, effectively harnessing the unique properties of Ti3C2Tx nanosheets while ensuring exceptional electrochemical behavior. This work employs an ultrasonication method to prepare a Na-Ti3C2Tx/CNF electrode. Establishing a stable interlayer structure between Ti3C2Tx nanosheets and cationic metal intercalation materials is crucial for expanding the interlayer spacing of Ti3C2Tx and creating multidirectional stable ion transport channels. Consequently, this process exposes more active sites that are accessible to ions. At a current density of 1 A g-1, the resulting Na-Ti3C2Tx/CNF demonstrates an impressive specific capacitance of 680.2 F g-1. Notably, the asymmetric supercapacitor assembled with Na-Ti3C2Tx/CNF as the positive electrode and activated carbon as the negative electrode exhibits remarkable cyclic retention of 83.1% and the Coulombic efficiency of 90.5% after 10,000 cycles at 10 A g-1, a wide voltage window of 1.5 V, a high energy density of 102.5 W h kg-1, and a power density of 2963.7 W kg-1. The fabricated coin cell ASC devices, which include glowing red light-emitting diodes, were demonstrated in practical applications. The optimization strategy for developing Na-Ti3C2Tx/CNF provides essential technical support for integrating Na-Ti3C2Tx/CNF into the next generation of portable and adaptable wearable electrochemical energy storage devices.

Effect of Zr addition on the corrosion resistance of Ti-Mo alloy in the H2O2-containing inflammatory environment

Reactive oxygen species (ROS), produced by immune cells during inflammatory reaction, are known to promote corrosion of standard biomedical materials such as CP-Ti and Ti-6Al-4V. Electrochemical corrosion in the ROS environment can be further accelerated in the vicinity of fretting regions, where titanium can be polarized towards negative potentials. This study considers both of these aspects and presents corrosion analysis under complex inflammatory conditions for Ti-Mo and Ti-Mo-Zr alloys, which offer exceptional strain-hardening behavior and ductility. Combining electrochemical impedance spectroscopy (EIS) and atomic emission spectroelectrochemistry (AESEC) allowed us to understand the origin of ROS-induced corrosion. At free corrosion conditions, Zr was found to suppress oxide layer growth without any significant effect on the dissolution process. On the other hand, Zr suppressed dissolution rate under cathodic potentials. Although applying cathodic potential resulted in a rapid increase of dissolution rate, cross-section transmission electron microscopy (TEM) analysis did not reveal significant influence of the short cathodic polarization on the oxide film growth during further prolonged exposure at free corrosion conditions.

Optimization of vehicle crashworthiness problems using recent twelve metaheuristic algorithms

Abstract In recent years, numerous optimizers have emerged and been applied to address engineering design challenges. However, assessing their performance becomes increasingly challenging with growing problem complexity, especially in the realm of real-world large-scale applications. This study aims to fill this gap by conducting a comprehensive comparative analysis of twelve recently introduced metaheuristic optimizers. The analysis encompasses real-world scenarios to evaluate their effectiveness. Initially, a review was conducted on twelve prevalent metaheuristic methodologies to understand their behavior. These algorithms were applied to optimize an automobile structural design, focusing on minimizing vehicle weight while enhancing crash and noise, vibration, and harshness characteristics. To approximate the structural responses, a surrogate model employing radial basis functions was utilized. Notably, the MPA algorithm excelled in automobile design problems, achieving the lowest mass value of 96.90608 kg during both mid-range and long-range iterations, demonstrating exceptional convergence behavior.

Microwave-Assisted Synthesis of CdS-MOF MIL-101 (Fe) Composite: Characterization and Photocatalytic Performance.

The present study outlines the synthesis of cadmium sulfide-metal-organic framework (CdS-MOF) MIL-101 (Fe) heterojunctions achieved via fast microwave-assisted reactions. Thus, different CdS-MOF MIL-101 (Fe) ratios were prepared to study their effectiveness as photocatalysts. These compounds were employed in the photocatalytic degradation of methylene blue (MB) under UV and visible irradiation. Structural, morphological, textural, compositional, and optical properties of the synthesized compounds determined by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), UV-vis spectroscopy, Raman spectroscopy, and Fourier transform infrared (FTIR) spectroscopy were utilized to characterize the structural, morphological, textural, compositional, and optical properties. Electrochemical impedance spectroscopy (EIS) was also employed to determine photovoltage and photocurrent densities. The resulting valence band offset (Vfb) and band gap energy values were utilized to construct an energy band scheme. Our research revealed that the CdS-MOF MIL-101 (Fe) heterojunction enhances the efficiency of electron-hole pair separation, thereby mitigating charge carrier recombination effects. Moreover, the type I electronic band structure established an efficient reaction mechanism, effectively suppressing the recombination of photogenerated electron-hole pairs. The photocatalytic system demonstrated exceptional behavior, achieving complete MB removal within 30 min of reaction time and exhibiting outstanding stability and reusability after four reaction cycles. These findings highlight the potential of the synthesized compounds in the field of wastewater treatment for organic pollutants, offering a promising alternative to current environmental issues.

Fracture Mechanisms and Toughness in Polymer Nanocomposites: A Brief Review

This article underlines the observation that, unlike the underperformance of nanocomposites in as far as their static mechanical properties of modulus and strength are concerned, fracture toughness exhibits exceptional behavior. This is attributed to the fact that fracture toughness expresses a measure of the energy absorbed in crack propagation, namely, the energy involved in creating new surface area, which, in turn, is controlled by a specific type of energy-dissipating interaction of the crack front with nanoparticles. This concise review focuses on two micromechanisms that are considered representative of energy dissipation due to their frequent presence in nanocomposites of both nanoparticles and nanofibers. Examples taken from recent relevant articles are presented to showcase fracture toughness improvements by nanoparticles.

Efficient synthesis of highly hydrophobic lignin nanoparticles and their application as nano fillers for multifunctional composite membranes

Controlling the hydrophobic behaviors of lignin nanoparticles (LNPs) is crucial and advantageous for their application as film Nano Fillers, yet it poses a significant challenge. Herein, we successfully developed a novel method for the preparation of LNPs with highly hydrophobic behaviors using ternary deep eutectic solution (DES)-H2O systems. The resulting LNPs exhibit a significantly reduced content of hydrophilic groups on their outer surface, leading to a zeta potential value of only −4.9 mV, and up to 140.0° of water contact angle (WCA). Afterwards, a “Dissolution-Restructuration” mechanism was proposed to explain the formation of the prepared LNPs. Firstly, DES demonstrates superior H-bonding capabilities, facilitating the complete disruption of inter- and intramolecular H-bonding in lignin, and resulting in the formation of a highly homogenized lignin network. Subsequently, the DES system undergoes compromise after adding water, triggering the reformation of both inter- and intramolecular H-bonding and π-π interactions. Consequently, lignin orderly self-assembles into LNPs with highly hydrophobic characteristics. Especially, using the as-prepared LNPs as Nano fillers, a series of LNPs-containing polyvinyl alcohol (PVA) films were successfully fabricated, exhibiting exceptional hydrophobic behaviors (with contact angles reaching up to 124.0°). Furthermore, the mechanical strength, UV-shielding capabilities, and biodegradability of the PVA films are significantly enhanced. This study introduces a sustainable and efficient approach for the synthesis of hydrophobic LNPs, thereby facilitating the broadening of applications for lignin-based functional composite film materials.

NiO nanolayer electrodeposited with Cobalt and Phosphide as a novel supercapacitor with high areal capacitance

In the present work, a novel supercapacitor electrode is fabricated via a two-step synthesis procedure. A NiO nanolayer was initially fabricated on a nickel foam electrode using hydrothermal synthesis to obtain a substrate with a high electrocatalytic area and good adhesive properties. Subsequently, the NiO-decorated nickel foam (NF) was employed as a substrate for the electrodeposition of cobalt and phosphorous. Morphological, structural, and surface characterization, along with various electrochemical tests, were conducted to gain insight into structure-property relationships. The as-prepared electrode (CoP@NF) exhibited excellent electrochemical behavior with an ultra-high areal capacitance of 3340 mF cm−2 at 5 mA cm−2 and high capacitance values even at high current densities. The exceptional electrochemical behavior can be attributed to the morphological and electronic modifications induced by aliovalent doping and the synergetic effect between the different electrode counterparts.

Marigold flower-like structured battery-type Cu2O/Co(OH)2 composite electrode material for high-performance supercapacitors

Addressing the limitations of individual Cu2O and Co(OH)2 components, this study aims to develop a high-performance supercapacitor electrode by synergistically combining these materials. A composite electrode material of Cu2O/Co(OH)2 was effectively synthesized on nickel foam via a facile hydrothermal method for supercapacitor applications. The as-fabricated Cu2O/Co(OH)2 composite electrode exhibits a hierarchical marigold flower-like morphology that comprises of many interspersed nanoflakes. This unique morphology offers several advantages, including increased surface area, abundant electroactive sites, and enhanced electrolyte accessibility, all of which contribute to superior electrochemical performance. The Cu2O/Co(OH)2 electrode demonstrates exceptional battery-type supercapacitor behavior, characterized by prominent redox peaks in cyclic voltammetry curves and a well-defined potential plateau during galvanostatic charge-discharge measurements. The electrode delivers an outstanding specific capacitance of 90.21 mA h g⁻1 at a current density of 1.25 A g⁻1 and retains a remarkable 81.91 % capacitance at a high current density of 12.5 A g⁻1. Furthermore, the electrode exhibits impressive cycling stability, maintaining approximately 107.84 % of its initial specific capacity value after 200 cycles at 7.5 A g⁻1. Electrochemical impedance spectroscopy measurements reveal low solution resistance and charge-transfer resistance, signifying efficient charge-transfer kinetics within the electrode. These findings highlight the potential of Cu2O/Co(OH)2 composite electrodes as promising candidates for high-performance supercapacitor applications.

Cationic Amphiphilic Comb-Shaped Polymer Emulsifier for Fabricating Avermectin Nanoemulsion with Exceptional Leaf Behaviors and Multidimensional Controlled Release.

The development of intelligent multifunctional nanopesticides featuring enhanced foliage affinity and hierarchical target release is increasingly pivotal in modern agriculture. In this study, a novel cationic amphiphilic comb-shaped polymer, termed PEI-TA, was prepared via a one-step Michael addition between low-molecular-weight biodegradable polyethylenimine (PEI) and tetradecyl acrylate (TA), followed by neutralization with acetic acid. Using the emulsifier PEI-TA, a positively charged avermectin (AVM) nanoemulsion was prepared via a phase inversion emulsification process. Under optimal formulation, the obtained AVM nanoemulsion (defined as AVM@PEI-TA) demonstrated exceptional properties, including small size (as low as 67.6 nm), high encapsulation efficiency (up to 87.96%), and high stability toward shearing, storage, dilution, and UV irradiation. The emulsifier endowed AVM@PEI-TA with a pronounced thixotropy, so that the droplets exhibited no splash and bounce when they were sprayed on the cabbage leaf. Owing to the electrostatic attraction between the emulsifier and the leaf, AVM@PEI-TA showed improved leaf adhesion, better deposition, and higher washing resistance in contrast to both its negatively charged counterpart and AVM emulsifiable concentrate (AVM-EC). Compared to the large-sized particles, the small-sized particles of the AVM nanoemulsion more effectively traveled long distances through the vascular system of veins after entering the leaf apoplast. Moreover, the nanoparticles lost stability when exposed to multidimensional stimuli, including pH, temperature, esterase, and ursolic acid individually or simultaneously, thereby promoting the release of AVM. The release mechanisms were discussed for understanding the important role of the emulsifier in nanopesticides.

Copper cluster regulated by N, B atoms for enhanced CO2 electroreduction to formate

Electrochemical CO2 conversion into formate by intermittent renewable electricity, presents a captivating prospect for both the storage of renewable electrical energy and the utilization of emitted CO2. Typically, Cu-based catalysts in CO2 reduction reactions favor the production of CO and other by-products. However, we have shifted this selectivity by incorporating B, N co-doped carbon (BNC) in the fabrication of Cu clusters. These Cu clusters are regulated with B, N atoms in a porous carbon matrix (Cu/BN-C), and Zn2+ ions were added to achieve Cu clusters with the diameter size of ∼1.0 nm. The obtained Cu/BN-C possesses a significantly improved catalytic performance in CO2 reduction to formate with a Faradaic efficiency (FE) of up to 70 % and partial current density (jformate) surpassing 20.8 mA cm−2 at −1.0 V vs RHE. The high FE and jformate are maintained over a 12-hour. The overall catalytic performance of Cu/BN-C outperforms those of the other investigated catalysts. Based on the density functional theory (DFT) calculation, the exceptional catalytic behavior is attributed to the synergistic effect between Cu clusters and N, B atoms by modulating the electronic structure and enhancing the charge transfer properties, which promoted a preferential adsorption of HCOO* over COOH*, favoring formate formation.

Synthesis of Ultrathin FeS Nanosheets via Chemical Vapor Deposition.

Fe-based 2D materials exhibit rich chemical compositions and structures, which may imply many unique physical properties and promising applications. However, achieving controllable preparation of ultrathin non-layered FeS crystal on SiO2/Si substrate remains a challenge. Herein, the influence of temperature and molecular sieves is reported on the synthesis of ultrathin FeS nanosheets with a thickness as low as 2.3nm by molecular sieves-assisted chemical vapor deposition (CVD). The grown FeS nanosheets exhibit a non-layered hexagonal NiAs structure and belong to the P63/mmc space group. The inverted symmetry broken structure is confirmed by the angle-resolved second harmonic generation (SHG) test. In particular, the 2D FeS nanosheets exhibit exceptional metallic behavior, with conductivity up to 1.63 × 106S m-1 at 300K for an 8nm thick sample, which is higher than that of reported 2D metallic materials. This work provides a significant contribution to the synthesis and characterization of 2D non-layered Fe-based materials.

Composition design and property investigation of bismaleimide by branched crosslinking structure with low dielectric permittivity and high toughness

AbstractDue to the high‐power environments of electronic components, achieving the exceptional dielectric properties and mechanical behavior necessary for electronic packaging materials presents a significant challenge. In this study, a trifunctional maleimide (HTMI) was synthesized by reacting hexamethylene diisocyanate trimer (HDI trimer) with Maleic anhydride (MA), followed by the preparation of Bismaleimide (BMI) resin featuring a micro‐branching structure through its reaction with diallyl bisphenol A (DBA) ether and BMI. The intentionally designed micro‐branching structure resulted in an increase in the free volume within BMI, leading to an 8.8% reduction in the dielectric constant. Additionally, this micro‐branching architecture imparted superior mechanical properties to the BMI resin, as demonstrated by a 140% increase in bending strength and a 149% increase in impact strength of the cured product.

Structural, electronic, thermoelectric and optical properties of 2D hexagonal beryllium telluride under DFT investigation

In this study we have investigated structural, electronic, thermoelectric and optical properties of monolayer beryllium telluride compound in the hexagonal lattice phase (h-BeTe) using first principle calculations under density functional theory (DFT) approach. Using the frequency dependent phonon dispersion curves, we have analyzed the stability of the h-BeTe compound. The investigation of structural properties, including density of states (DOS) and band structure, demonstrates that h-BeTe is a direct bandgap semiconductor material with bandgap value of 3.054 eV. The h-BeTe compound exhibits exceptional thermoelectric behavior for a temperature range of 50–800 K, as confirmed by the calculated thermoelectric parameters, including thermal conductivity, electrical conductivity, Seebeck coefficient and figure of merit (ZT). It is vital that h-BeTe exhibits exceptional thermoelectric properties specifically, the figure of merit (ZT > 0.9) provides the efficiency of h-BeTe compound in temperature range of 300–800 K. The optical properties of h-BeTe are investigated for the first time with its interaction in applied external electric field based on various optical parameters such as real and imaginary dielectric constant, refractive index n(ω), extinction coefficient k(ω), absorption coefficient α(ω) and reflectivity R(ω). The optical properties analysis reveals the monolayer hexagonal beryllium telluride to be mostly active in the visible-UV spectrum. These findings have the potential to foster researchers to explore h-BeTe compound experimentally for possible optoelectronic applications.

A ratiometric, turn-on fluorosensor for specific detection of Zn2+ ions

A potentially active fluorescent chemosensor (E)-2-(((2-(1H-benzo[d]imidazol-2-yl)phenyl)imino)methyl)-5-(diethylamino)phenol (BMDP) is developed by the condensation of 2-(2-aminophenyl)-1H-benzimidazole and 4-(diethylamino)salicylaldehyde. It shows an exceptional ratiometric fluorescence behavior when exposed to Zn2+ ions and the photoluminescence color is changed from blue to cyan under the exposure of a 365 nm UV light which is also strongly evident from the color chromaticity diagram. The exceptional ratiometric fluorescence behavior in the presence of Zn2+ ions is found to be due to the chelation-enhanced fluorescence (CHEF). The 1:1 stoichiometry of BMDP and Zn2+ ions in Zn2+ ions chelated BMDP complex is confirmed through Job’s plot analysis. Remarkably, Cd2+ does not interfere with the selective ratiometric fluorescence behavior induced by Zn2+ ions. The lowest detection limit and quantification limit are estimated to be 28 nM and 92 nM respectively. The cyan fluorescence of the Zn2+ ions chelated BMDP complex is interestingly reversed to the original BMDP in the presence of ethylenediamine tetraacetic acid (EDTA). At the molecular level, this can be thought of as a complimentary “INHIBIT” logic gate. Furthermore, it is possible to utilize the probe for on-site identification in test strips with improved Zn2+ ions selectivity. We have also used a smartphone-based method to demonstrate the usefulness of BMDP for the immediate quantification and detection of Zn2+ ions. In light of this, probe BMDP is a trustworthy fluorescence probe for on-site monitoring that can accurately identify Zn2+ ions even when some other metals and anions compete.

Elucidating the role of recycled concrete aggregate in ductile engineered geopolymer composites: Effects of recycled concrete aggregate content and size

Utilizing recycled fine aggregate (RFA) as silica sand replacement for ductile engineered geopolymer composites (EGC) provides a high value-added approach to recycling concrete waste and reduces the needs for high-cost silica sand. RFA contains abundant active alkaline substances which can promote the secondary geopolymerization of EGC. Substituting RFA for silica sand can improve EGC micro-characteristics, and the micro-structure of RFA-EGC is further refined with the decreased RFA size. The compressive/flexural strength of EGC is elevated as RFA is incorporated, and the decreased RFA size further enhances the compressive/flexural strength of RFA-EGC. Attributed to the micro-pores and micro-cracks in RFA, including RFA benefits the formation and development of crack, leading to an enhancement in the uniaxial tensile behavior of EGC. The tensile strength and tensile strain capacity of 100 % RFA blended EGC are 5.7 % and 8.6 % higher than those of 100 % silica sand blended EGC. The decreased RFA size can enhance the tensile strength, and an appropriate increase in RFA size improves the tensile strain capacity of RFA-EGC. When RFA size is 0.15–0.3 mm and 0.3–0.6 mm, the tensile strain capacity of 100 % RFA blended EGC is 8.6 % and 12.9 % larger than the reference EGC with 100 % silica sand (0.15–0.3 mm). A moderate increase in silicate modulus can further improve the tensile behavior, and the RFA-EGC with 1.5 M shows the best tensile behavior; besides, the longer fiber length results in the higher tensile strength of RFA-EGC. By optimizing the replacement rate and size of RFA, adjusting the silicate modulus and fiber characteristics, one can achieve a sustainable high-ductility RFA-EGC with exceptional mechanical behavior.

Thermally Oxidized Memristor and 1T1R Integration for Selector Function and Low-Power Memory.

Resistive switching memories have garnered significant attention due to their high-density integration and rapid in-memory computing beyond von Neumann's architecture. However, significant challenges are posed in practical applications with respect to their manufacturing process complexity, a leakage current of high resistance state (HRS), and the sneak-path current problem that limits their scalability. Here, a mild-temperature thermal oxidation technique for the fabrication of low-power and ultra-steep memristor based on Ag/TiOx/SnOx/SnSe2/Au architecture is developed. Benefiting from a self-assembled oxidation layer and the formation/rupture of oxygen vacancy conductive filaments, the device exhibits an exceptional threshold switching behavior with high switch ratio exceeding 106, low threshold voltage of ≈1V, long-term retention of >104s, an ultra-small subthreshold swing of 2.5mVdecade-1 and high air-stability surpassing 4 months. By decreasing temperature, the device undergoes a transition from unipolar volatile to bipolar nonvolatile characteristics, elucidating the role of oxygen vacancies migration on the resistive switching process. Further, the 1T1R structure is established between a memristor and a 2H-MoTe2 transistor by the van der Waals (vdW) stacking approach, achieving the functionality of selector and multi-value memory with lower power consumption. This work provides a mild-thermal oxidation technology for the low-cost production of high-performance memristors toward future in-memory computing applications.

Remarkable contribution of stress-induced martensitic transformation to strain-hardening behavior in Ti−Mo-based metastable β-titanium alloys

The role of stress-induced β → α″ martensitic transformation in contributing to the exceptional strain-hardening behavior of a Ti-11Mo (wt. %) model alloy was studied. The results reveal that the α″-martensite plates, undergoing relatively high transformation strains upon formation, act as effective barriers against dislocation motion. As deformation proceeds, the progressive generation of these plates dynamically reduces the dislocation mean free path (dynamic Hall-Petch effect), while simultaneously encouraging the accumulation of dislocations. These dual effects substantially enhance the flow stress with increasing strain, thereby resulting in remarkable strain-hardenability, a crucial factor for maintaining excellent ductility. This study presents innovative experimental evidence elucidating the mechanism of the transformation-induced plasticity effect in metastable β-titanium alloys, while also offering insights for designing novel alloys with superior strain-hardenability and ductility.

Auxetic textiles, composites and applications

Auxetic textiles are intriguing materials with unusual capabilities. These materials exhibit a negative Poisson’s ratio with extraordinary performance in toughness, resilience, shear resistance, and acoustic properties mainly due to their special structure and associated deformation mechanics. Auxetic materials can also have applications around energy absorption and can effectively be used for vibration damping and shock absorbency. The exceptional behaviour of auxetic textiles can be obtained by utilising specific fibrous materials and introducing auxetic geometry and structures differently during weaving, knitting, and nonwoven manufacturing. This issue of Textile Progress highlights the fundamental aspects of various auxetic structures and their properties in general and a detailed analysis of auxetic textile structures and composites, their manufacturing processes, modelling, characterisation, and applications. These materials can potentially revolutionise their applications in sports, automotive, construction industry, biomedical engineering, aerospace, marine, and defence personal protective equipment. Fundamental understanding of auxetic geometry, followed by developing and analysing these geometries by analytical and computational modelling, translating the geometry into appropriate textile structures for actual fabric production, characterisation of auxetic fabrics and their composites, and finally, some innovative applications in technical textiles are some of the fascinating issues addressed in this review.