A new generation of electrocardiogram (ECG) electrodes have been fabricated and superficially modified by a special controlled precorrosion process. The electrodes have been characterized by scanning electron microscopy (SEM), resistance-capacitance measurements (RCM) and simulated defibrillation recovery (SDR). The resulting surface of the Sn alloys was rough, and, consequently, a large active surface area was available. As a result, a higher electrocardiogram electrode performance, including low alternating current (a.c.) impedance, excellent time stability and improved SDR, was achieved. Such new design can surely find important future applications in clinical diagnosis.