BackgroundThe development of efficient and noble-metal-free photocatalysts is greatly essential for photocatalytic hydrogen production. However, the photocatalytic activity of a single photocatalyst is usually limited for various reasons. MethodsHerein, FeS2/Mn0.5Cd0.5S (FSMCS) heterojunctions were constructed by a simple solvent evaporation method. The morphological characterizations revealed a raspberry-like hollow microsphere structure for FeS2 and irregular granularity for Mn0.5Cd0.5S. Photoluminescence (PL) and electrochemical experiments indicated that the FSMCS composite effectively facilitated the separation of photogenerated electron-hole pairs. The UV–vis diffuse reflectance spectrum (DRS) showed that, in FSMCS composite, the visible light absorption range was effectively expanded to the full visible light. Significant findingsExcellent photocatalytic activity in FSMCS heterojunctions without loading noble metals because FeS2 could serve an active site for hydrogen production. The optimum FSMCS composite had excellent photocatalytic hydrogen production activity (6.1 mmol·g−1·h−1), which was 5.6 and 2.3 times higher than that of the pristine Mn0.5Cd0.5S (1.1 mmol·g−1·h−1) and Mn0.5Cd0.5S-1 %Pt (2.7 mmol·g−1·h−1). Meanwhile, in four round-robin tests, the activity of the 5FSMCS photocatalyst did not significantly decrease. This work proved that combining Mn0.5Cd0.5S and non-precious metal cocatalysts to construct heterojunctions is a promising strategy for photocatalytic hydrogen production.