Reversible protonic ceramic electrochemical cell (RePCEC) is one of the most promising energy conversion and storage devices. Because of the low to intermediate operating temperatures (300-650oC), RePCECs demonstrated great potential for simultaneously achieving high performance, long-term durability and low cost of materials 1,2. However, the state-of-the-art RePCECs still cannot satisfy with practical demand, which is significantly ascribed to the high polarization resistance from oxygen (O2) electrode 3. Modification of the phase interfaces in the composite O2 electrodes played vital roles in enhancing the performance by extending active sites, which were extensively investigated in the field of oxygen-ion conducting solid oxide electrochemical cells (O-SOECs) 4,5. However, the engineering of the interfaces in the composite O2 electrode, especially in nanoscale, has not been extensively studied for RePCECs 6. In this work, O2 electrode scaffolds based on the barium cerate-zirconate co-doped with ytterbium and yttrium (BaCe0.7Zr0.1Y0.1Yb0.1O3-δ) are decorated by dual phase triple (e-/O2-/H+) conducting oxide (TCO) nanoparticles of BaCeFeCoO, BaCeFeO and BaCeYCoFeO, respectively. The low O2 electrode polarization resistance, excellent power output and water electrolysis performance were achieved below 600℃. References Duan, C., Kee, R., Zhu, H., Sullivan, N., Zhu, L., Bian, L., Jennings, D. and O’Hayre, R., 2019. Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel production. Nature Energy, 4(3), p.230.Duan, C., Tong, J., Shang, M., Nikodemski, S., Sanders, M., Ricote, S., Almansoori, A. and O’Hayre, R., 2015. Readily processed protonic ceramic fuel cells with high performance at low temperatures. Science, 349(6254), pp.1321-1326.Fabbri, E., Pergolesi, D. and Traversa, E., 2010. Materials challenges toward proton-conducting oxide fuel cells: a critical review. Chemical Society Reviews, 39(11), pp.4355-4369.Dai, H., He, S., Chen, H., Yu, S. and Guo, L., 2015. Performance enhancement for solid oxide fuel cells using electrolyte surface modification. Journal of Power Sources, 280, pp.406-409.Chao, C.C., Hsu, C.M., Cui, Y. and Prinz, F.B., 2011. Improved solid oxide fuel cell performance with nanostructured electrolytes. ACS nano, 5(7), pp.5692-5696.Bi, L., Shafi, S.P., Da'as, E.H. and Traversa, E., 2018. Tailoring the Cathode-Electrolyte Interface with Nanoparticles for Boosting the Solid Oxide Fuel Cell Performance of Chemically Stable Proton‐Conducting Electrolytes. Small, 14(32), p.1801231.