Excellent Microwave Research Articles

Hollow engineering and component optimization strategy to construct flower-like yolk-shell structure SiO2@Void@C@WS2 multicomponent nanocomposites for microwave absorption

Hollow engineering plays a crucial role in enhancing interfacial polarization, which is an essential factor in microwave absorption. Herein, an in-situ growth approach was adopted to successively coating C layer and WS2 nanosheets on the surface SiO2 nanosphere. The obtained results suggested that the formed SiO2@Void@C@WS2 multi-component nanocomposites (MCNCs) reveal a representative flower-like yolk-shell structure, which were manufactured massively through a simple channel. Additionally, the obtained SiO2@Void@C@WS2 MCNCs presented a more and more obvious yolk-shell structure and reduced WS2 content with decreasing the addition of SiO2@C or tungsten and sulfur sources. Because of their distinctive structures and remarkable cooperative effects, the SiO2@Void@C@WS2 displayed excellent microwave absorption performances. Through the majorization of hollow structure and WS2, improved properties of SiO2@Void@C@WS2 MCNCs could be acquired owing to their boosted polarization and conductive loss capabilities. Amongst, the resulting SiO2@Void@C@WS2 MCNCs exhibited the effective absorption band and minimum reflection loss values of 5.40 GHz and −45.50 dB with matching thicknesses of 1.78 and 1.55 mm, respectively. Therefore, our findings employed hollow engineering and optimization strategies for components to design and fabricate the yolk-shell structure flower-like MCNCs, which acted as highly efficient wide-band microwave absorbing materials.

Synchronous enhancement and broadening of dielectric loss and magnetic loss induced by substituted Gd in GdFeO3-encapsulated Fe (Gd) nanoparticles

Synchronous enhancement and broadening of dielectric loss and magnetic loss is a key factor for achieving excellent microwave absorption behavior. However, one term’s reinforcement always comes at the expense of the other one. In this work, a new kind of core-shell structured nanoparticle has been designed and prepared by arc-discharge method, in which GdFeO3 is shell and Fe (Gd) solid solution works as core, respectively. Except for the typical interfacial polarization and natural resonance, the new dipole induced by asymmetric electric charge arising from substituted Gd in Fe lattice results in enhanced and broadened dielectric loss, and the strong local magnetic anisotropy induced by intensive magnetic Fe-Gd coupling between 3d-4 f electrons leads to enhanced and broadened magnetic loss. Synchronously widened and enhanced dielectric and magnetic loss ensure that GdFeO3-encapsulated Fe(Gd) nanoparticles have effective absorption bandwidth of 4.16 GHz (10.48–14.64 GHz) at 2.3 mm, compared with that (2.32 GHz at 4.9 mm) of Fe nanoparticles. This study develops an approach for synchronously enhancing dielectric loss and magnetic loss, which has potential for achieving excellent EM absorption behaviors.

Template-sacrificing synthesis of hollow Co@C nanorods for excellent microwave absorption

Metal organic frameworks (MOFs) have been widely used as microwave absorption (MA) materials owing to their varied structures and large specific surface area. However, it is still challenging to endow MOF derivatives with a rational structure to achieve outstanding microwave absorption. In this work, the hollow Co@C nanorods (HCCN) with lots of winding carbon nanotubes on the surface are obtained based on a template-sacrificing method which employs ZnO nanorods as templates and ZIF67 nanoparticles as ornaments. The HCCNs possess large pore size and specific surface area, efficiently improving the impedance matching. The 1D structure, abundant heterointerfaces and defects trigger strong conduction loss, interfacial and dipole polarization, respectively. Therefore, HCCNs exhibits excellent MA properties: the strong reflection loss of −66.8 dB at the thickness of 2.1 mm and the effective absorption bandwidth of 5.68 GHz at 2.5 mm. Radar cross section (RCS) simulation results have confirmed the practicality of HCCNs. This study proposes an inspiration for the structural designing of MOF materials and derivatives to realize amazing MA performance.

Microwave De-Icing Efficiency Improvement of Asphalt Mixture with Structural Layer Optimization and Heat-Resistance Design.

The application of microwave de-icing technology in road engineering is constrained by its low energy utilization rate, which can be attributed to low heat production rates and ineffective heat dissipation to the underlying pavement. In this work, asphalt mixtures are designed as an upper layer (heating layer) and a lower layer (thermal-resistance layer). Magnetite slag was selected as a microwave-sensitive source for generating heat, and expanded perlite powder was incorporated into the lower layer as a thermal resistance material. Structural layer optimization and thermal-resistance layer design of the asphalt mixture were carried out by changing the thickness of the upper and lower layers to further improve the heat production rates. The design effectiveness is comprehensively evaluated by factors such as the changing law of the average surface temperature of mixtures, ice-melting time, and cost-effectiveness analyses. The results show that EP possesses better thermal stability, lower microwave energy conversion ability and more excellent heat-resistance potential compared with mineral powder. The heat-resistance layer with EP can prevent heat from being conducted to the lower layer and promote it to concentrate on the specimen surface, which can endow the microwave heating efficiency of specimens to be further improved by up to 26.97% and the de-icing time reduced by 10%, ascribed to the heat-resistance design. Furthermore, the collaborative design of the structural layer optimization and heat-resistance layer can increase energy utilization efficiency and save microwave-absorbing materials while ensuring excellent microwave de-icing efficiency.

Effect of LiF and LBSCA glass on the microwave dielectric properties of 0.5BaCuSi4O10–0.5BaCuSi2O6‐based ceramics for LTCC applications

AbstractIn this work, the 0.5BaCuSi4O10–0.5BaCuSi2O6‐based ceramics were synthesized using a standard solid‐phase reaction process, and the inherent relationship between crystal structure and microwave dielectric properties was thoroughly explored. The crystal structure of the 0.5BaCuSi4O10–0.5BaCuSi2O6 ceramic was determined by X‐ray diffractometer, which confirmed the existence of two phases. Microstructure observation of the ceramics was obtained by scanning electron microscope (SEM). Excellent microwave dielectric properties with a low ԑr ∼6.52, a high Q × f ∼46 010 GHz, and the temperature coefficient of resonant frequency (TCF) ∼−14 ppm°C−1 were obtained in the 0.5BaCuSi4O10–0.5BaCuSi2O6 ceramic sintered at 1060°C. By adding sintering additives LiF and Li2O–B2O3–SiO2–CaO–Al2O3 (LBSCA) glass, the sintering temperature was decreased from 1060°C to 870°C. Good microwave dielectric properties with a ԑr ∼6.59, a Q × f ∼18 820 GHz, and TCF ∼−14 ppm°C−1 were achieved in the 0.5BaCuSi4O10–0.5BaCuSi2O6 ‐2 wt.% LiF, 1 wt.% LBSCA (2F1LBSCA) ceramic sintered at 870°C. The low‐temperature firing ceramics could also be well co‐fired with Ag with good chemical compatibility. These results indicated that the 0.5BaCuSi4O10–0.5BaCuSi2O6 ceramic with 2F1LBSCA additions can be utilized in low‐temperature co‐fired ceramics technology to produce high‐frequency communication components.

Multifunctional mullite fiber reinforced SiBCN ceramic aerogel with excellent microwave absorption and thermal insulation performance

Mullite fibers have been widely used in thermal protection materials, but they still face challenges related to inefficient wave absorption performance. SiBCN aerogel has the advantage of tunable dielectric properties, outstanding microwave absorption performance, low density and low thermal conductivity, making it an ideal candidate for enhancing mullite fibers. Herein, a novel SiBCN aerogel/mullite fiber composite (SiBCN/MF composite) was prepared by sol-gel, freeze-drying and high temperature thermal treatment for the first time. By tuning the concentration of polyborosilazane (PBSZ), the density, microwave absorption performance, and thermal insulation properties were regulated. The obtained composites displayed low density (0.151–0.190 g/cm3), excellent microwave absorption performance (the minimum reflection loss as low as −67.83 dB and effective absorption bandwidth of 5.40 GHz) and low thermal conductivity (0.056–0.081 W/(m·K)). The outstanding comprehensive performance of the fabricated composites makes them promising candidates for use in the thermal protection system of aerospace vehicles.

Preparation and electromagnetic wave absorption properties of CAU-Al MOF and graphene oxide aerogel composites

The application of microwave technology has penetrated all aspects of life, but also lead to the electromagnetic pollution, therefore the research of high efficiency microwave absorption materials has been widely concerned. In this work, a new type of Al based CAU-10-H MOF was prepared by hydrothermal method. The particles were polyhedral in size of 2 [Formula: see text]m. After high temperature annealing, the interplanar spacing increased with the annealing temperature, and the lattice structure was destroyed at 400°C. CAU-Al/rGO aerogels were prepared by freeze-drying of hydrogels. With the increase of CAU-Al content and the annealing temperature, the carbon crystallinity decreases, and the pores of the aerogels became larger and fluffier. The real parts of permittivity of CAU-Al/rGO aerogels were between 5 and 30, which can be tuned by the annealing temperature and CAU-Al content. For the microwave absorption performance, the CAU-Al/rGO aerogel with a ratio of 3:1 achieved the minimum reflection loss of −37.8 dB at 3 mm. Moreover, the CAU-Al/rGO aerogels showed a wide effective bandwidth, which reached 5.1 GHz under the thickness of 2.5 mm. Therefore, the CAU-Al/rGO aerogels could be used as a kind of broadband microwave absorber with excellent microwave absorption performance.

Effect of insulation materials and power on microwave heating characteristics of SiC susceptor under material–specific parametric conditions

High-quality microwave absorber materials play a crucial role in the efficient and uniform processing of variety of materials through microwave hybrid heating. Silicon carbide (SiC) is an excellent microwave absorber at room temperature, which enhances the heating rate of the target materials significantly. In the present study, effects of heat insulation materials and their configurations on microwave heating characteristics of SiC were investigated at different power levels. The responses were assessed in terms of the heating capability (maximum temperature achieved), radiation heat loss, temperature gradient, and heating uniformity under different parametric conditions. A 3D COMSOL Multiphysics simulation model, coupled with microwave heating and heat transfer module, was developed with surface-to-ambient radiation boundary conditions. Electromagnetic and thermal properties of the SiC utilized in the model were selected based on physical properties, such as porosity/density, particle size, and chemical composition of SiC. The model outputs were validated with experimental findings. Results showed that microwave heating characteristics were highly sensitive to the susceptor (SiC) properties, insulation materials and power levels. Insulation materials prevented heat losses significantly; at the same time, different insulation configurations altered the electrical field intensity distribution within the SiC sample, which affected the responses. Microwave power levels also influenced the responses and quantity of insulation required.

All-Around Electromagnetic Wave Absorber Based on Ni-Zn Ferrite.

Exploring a convenient, scalable, yet effective broadband electromagnetic wave absorber (EMA) in the gigahertz (GHz) region is of high interest today to quench its expanding demand. Ni-Zn ferrite is considered as a potential EMA; however, their performance study as a scalable effective millimeter-length absorber is still limited. Herein, we investigated EM wave attenuation properties of Ni0.5Zn0.5Fe2O4 (NZF) samples substituting Mn ion in place of Fe3+ as well as Zn2+ within a widely used frequency range of 0.1-9 GHz. Through composition optimization, Ni0.5Zn0.4Mn0.1Fe2O4 (NZM0.1F) EMA demonstrates excellent microwave absorption performance accompanied by simultaneous maximum reflection loss (RL) of -50.2 dB and wide BW of 6.8 GHz (with RL < -10 dB, i.e., attenuation >90%) at an optimum thickness of 6 mm. Moreover, the attenuation constant significantly increases from ∼217 to 301 Np/m with Mn doping. The key contribution arises from magnetic-dielectric properties synergy along with enhanced dielectric and magnetic losses owing to cation chemistry and site occupation in spinel NZF. In addition, porosity is induced in the system by a controlled two-step heat treatment process that promotes total loss with multiple internal reflections of the EM wave. Furthermore, RL is simulated by varying incident EM wave angles for the NZM0.1F sample displaying its angle insensitivity up to 50°. Our results reveal NZM0.1F as a futuristic environment-friendly microwave absorber material that is suitable for practical high-frequency applications.

Mixed-Dimensional Assembly Strategy to Construct Reduced Graphene Oxide/Carbon Foams Heterostructures for Microwave Absorption, Anti-Corrosion and Thermal Insulation

HighlightsReduced graphene oxide/carbon foams (RGO/CFs) vdWs heterostructures are efficiently fabricated via a simple mixed-dimensional assembly strategy.Linkage effect of optimized impedance matching and enhanced dielectric loss abilities endows the excellent microwave absorption performances of RGO/CFs vdWs heterostructures.Multiple functions such as good corrosion resistance performances and outstanding thermal insulation capabilities can be integrated into RGO/CFs vdWs heterostructures.

Improved sintering behavior and microwave dielectric properties on BaZnP2O7-based ceramics

The effects of Ca2+ substitution for Ba2+ in BaZnP2O7 ceramics on the phase composition, sintering behavior, and microwave dielectric mechanism were systematically investigated. When x ≤ 0.02, the ceramics crystallized into a single-phase solid solution of BaZnP2O7, whereas samples with x ≥ 0.04 showed mixed phases of BaZnP2O7 and CaZnP2O7. The sintering behavior was ameliorated by Ca2+ substitution, and the sintering temperature of Ba1-xCaxZnP2O7 (0 ≤ x ≤ 0.1) was reduced from 920 to 840 °C effectively. The Raman spectra and P–V-L theory confirmed that the compressed P–O bond caused by Ca2+ substitution is beneficial to reducing the lattice anharmonic vibration and enhancing the lattice energy (U), which is conducive to the improvement of the Q × f value of the Ba1-xCaxZnP2O7 ceramic when x = 0.02. Excellent microwave dielectric properties were obtained for the Ba0.98Ca0.02ZnP2O7 ceramic after sintered at 880 °C for 4 h, i.e., εr = 8.29, Q × f = 84,116 GHz, τf = −23.84 ppm/°C.

Engineered biochar-based catalytic pyrolysis of Spirulina plantensis microalgae for the production of high value compounds in microwave reactor

Energy demands are continually increasing as a result of population growth and industrialization, prompting the completion of new research to examine biochar-based catalytic pyrolysis of Spirulina plantensis (SP) microalgae for the generation of high-value chemicals in a microwave reactor. Biochar-based catalysts have excellent microwave absorption, a porous structure, and high catalytic activity, making them ideal for microwave-induced biomass pyrolysis. Initially, raw biomass, biochar, and Zn-BC were characterized based on XRD, FTIR, nitrogen adsorption-desorption and SEM-EDS analysis to determine the phases, functional groups, BET surface area and morphology, respectively. The thermogravimetric analysis results demonstrated the favourable impact of Zn-BC by displaying a drop in the reaction's temperature requirements. The kinetic study revealed that catalytic pyrolysis has a lower activation energy (27.62 kJ/mol) than non-catalytic pyrolysis (32.99 kJ/mol). FTIR measurement of the bio-oil indicated that at particular peak positions, intensity has changed or disappeared. The GCMS results revealed a significant reduction in the nitrogen-containing (19 %) chemicals at the same time increase in acidic chemicals for the catalytic bio-oil.

Study on the characteristics of microwave pyrolysis of pine wood catalyzed by bimetallic catalysts prepared with microwave-assisted hydrothermal char

Bimetallic hydrothermal char catalysts (Co-Ni/MHC, Fe-Co/MHC, Fe-Ni/MHC) were prepared through ionic hydrothermal methods and microwave high-temperature activation. During catalyst preparation, different metals synergistically promoted the formation of ordered carbon structures such as carbon nanotubes and carbon microspheres, respectively. Serving both as microwave absorbers and catalysts for the microwave pyrolysis of pine wood, the bimetallic catalysts exhibited distinct advantageous characteristics. Fe-Ni/MHC exhibited excellent microwave absorption properties and was able to assist the PW to heat up rapidly at a rate of 6.17 °C/s, benefiting from which PW achieved a high bio-oil yield of 44.0 % in the microwave-assisted catalytic pyrolysis process. Using Co-Ni/MHC as a catalyst resulted in bio-oil with up to 42.7 % styrene content and had good catalytic effects on the formation of CO and H2. This study provides a scientific reference for the application of hydrothermal treatment and microwave-assisted pyrolysis in biomass pyrolysis technology.

Low-density, large-sized SiCnw/SiOC composite aerogels with excellent thermal insulation, microwave absorption, and thermostability

Polymer-derived ceramic aerogels are promising materials for thermal insulation and microwave absorption in harsh environments because their microstructures can be controlled at the molecular level. Silicon oxycarbide (SiOC) aerogels are considered as potential high-temperature electromagnetic wave (EMW) absorbers, but their application range is limited by complex preparation process and unsatisfactory microwave-absorption performance. This paper reports a new SiC nanowire/SiOC composite aerogel (SCA) synthesized through the sol–gel process, environmental pressure drying, and high-temperature treatment. The SCA performance is adjusted by controlling the ratio of SiC nanowires, obtaining low thermal conductivities (0.04–0.042 W m−1 K−1) and excellent mechanical properties (4.37–5.45 MPa). Increasing the SiC nanowire content gradually increases the EMW absorption capacity of SCA. The optimal reflection loss is −53.64 dB and the effective absorption bandwidth is 3.88 GHz, substantially higher than that of SiOC aerogels. This high performance is mainly attributable to the appropriate impedance matching characteristics and strong polarization loss ability. Moreover, the performance of the composite aerogels was retained after long-term treatment in an air environment at 800 °C. SCA also exhibits excellent high-temperature insulation and flame retardancy. Owing to its light weight, strong microwave-absorption ability, good thermal insulation performance, and oxidation resistance, SCA is a highly promising alternative material for use in extreme environments.

One-step thermal-plasma synthesis of sulphur and nitrogen dual-doped graphene with improved microwave-absorption efficiency

This study presented the one-step synthesis of sulphur (S) and nitrogen (N) dual-doped graphene using atmospheric thermal plasma. The doped graphene was synthesized in the magnetically rotating arc plasma with CS2 as the sulphur source, N2 as the nitrogen source and CH4 as the carbon source. At the same reaction temperature, the concentrations of S and N in S and N dual-doped graphene were higher than those in S/ N -doped graphene, which indicated that the dual-doped mode had a promoting effect on the doping level. In addition, increasing the input power effectively increased the doping levels of S and N atoms, which were up to 15.0 at% and 6.9 at%, respectively, at an input power of 19 kW. The S and N dual-doped graphene displayed excellent microwave absorption capability, with an optimal reflection loss of −56.4 dB at 16.3 GHz, and the effective absorption bandwidth reached 5.7 GHz when the doping levels of S and N atoms were 12.2 at% and 5.1 at%. This simple and rapid method for preparing S and N dual-doped graphene might facilitate the application of heteroatom doped graphene.

Modulating multiple interfaces, defects, and dual-scale interlinked frameworks of cotton-derived spiral CF@Ni@CNT fibers for boosted thermal conduction and microwave absorption

Developing dual-functional materials with excellent thermal conduction and microwave absorption has emerged as a critical strategy for addressing increasingly serious electromagnetic pollution and heat dissipation difficulties. While the advancements in these materials are constrained by their high loading and incompatible performance. To develop a thermally conductive and microwave-absorbing material with a low load, this work fabricates a series of cotton-derived spiral fibers, i.e., carbon fibers (CFs), carbon fiber/Ni (CF@Ni) fibers, and carbon fiber/Ni/carbon nanotube (CF@Ni@CNT) fibers, via a freeze-drying calcination method. By controlling the amount of nickel acetate (n) and methylbenzene volume (V), we finely modulated the multiple heterostructure interfaces, dual-scale interconnected network, defects, and magnetic/dielectric-loss of the spiral CF@Ni@CNT fibers. Results show that the comprehensive properties of spiral CF@Ni and CF@Ni@CNT fibers, obtained by combining spiral CFs with magnetic Ni nanoparticles and/or CNTs, are significantly improved. The spiral CF@Ni fibers formed at n = 8.4 mmol exhibit a lower thermal conductivity (TC = 3.64 W/m⋅K) but a wider absorption bandwidth (EAB = 6.4 GHz; 10 wt% load) than CFs. Besides, the spiral CF@Ni@CNT fibers formed at n = 4.2 mmol and V = 2 mL bear a higher TC (4.27 W/m⋅K) and a larger EAB (7.52 GHz/mm) at the same load (10 wt%). The low load could be ascribed to the low percolation threshold of a dual-scale interconnected framework consisting of CFs, CNTs, and Ni0. Additionally, the simultaneous improvement in thermal conduction and microwave absorption of the spiral CF@Ni@CNT fibers is associated with their magnetic-dielectric dual loss, electron-phonon co-transmission, and dual-scale interconnected framework.

Pore-confined strategy to achieve controllable growth of Co/CoO in carbon nanofibers for the fabrication of lightweight and enhanced microwave absorbers

In recent years, magnetic metal nanoparticles (NPs)/carbon nanofibers (CNFs) composites have become very promising electromagnetic waves (EMWs) absorbers. However, how to achieve controllable growth of magnetic metals in CNFs is still an urgent problem to be solved. Herein, we reported a pore-confined strategy for constructing the porous Co/CoO/CNFs. By introducing different amounts of acetone (0.20 g, 0.30 g and 0.40 g) into the aqueous phase spinning solution to construct the porous structure, we achieved uniform distribution of Co/CoO NPs and ultimately obtained the porous Co/CoO/CNFs microwave absorbers (MAs) with excellent microwave absorption performance. Thanks to the excellent impedance matching and enhanced polarization loss, the porous Co/CoO/CNFs obtained the minimum reflection loss (RL) of −52.2 dB with a thickness of 3.0 mm, and the effective bandwidth (EBW) was 3.02 GHz when the acetone addition in the spinning solution was 0.30 g. Therefore, the pore-confined strategy proposed herein is conducive to the design of the MAs with excellent performance and low infilling rates based on CNFs. Furthermore, the porous structure of CNFs also improves the lightweight performance of the MAs.

Suppressed conductive loss of flower-like NiCo2O4-wrapped flaky FeSiAl for excellent low-frequency microwave absorption

Flaky FeSiAl is a high potential absorbent for low-frequency microwave applications. However, impedance mismatching due to its excessively high complex permittivity presents a challenge. Herein, inspired by the surface modification strategy, flaky FeSiAl wrapped with flower-like NiCo2O4 (NiCo2O4@flaky FeSiAl) was developed via a hydrothermal method. The introduction of a surface NiCo2O4 insulating layer was expected to reduce the complex permittivity and increase the high complex permeability in the NiCo2O4@flaky FeSiAl composite. Subsequently, an excellent low-frequency microwave absorption performance was achieved. The designed NiCo2O4@flaky FeSiAl displayed a robust minimum refection loss (RL min) of −33.41 dB at 6.32 GHz and increased the effective absorption bandwidth (EAB, RL < −10 dB) to 4.08 GHz when the matching thickness was 1.6 mm. The enhanced low-frequency microwave absorption performance was mainly attributed to the improvement in impedance matching, which originated from the collaborative regulation of electromagnetic parameters. This study provides a promising approach for designing flaky FeSiAl-based composites and high-performance low-frequency microwave absorbents.

Lightweight Fe-doped MnO2@C hollow nanocubes for ultra-broadband microwave absorption

The rational structural design and compositional merits as well as the synergistic coupling effect can break the properties of single material and broaden the microwave absorption band. Herein, the unique lightweight Fe-doped MnO2@C hollow nanocubes are rationally designed and successfully synthesized via a scalable wet chemical process and polydopamine coating followed by high-temperature calcination. By virtue of the unique structure and compositional merits, the as-obtained Fe-doped MnO2@C hollow nanocubes (Fe–MnO2@C-HNBs) displayed notable microwave absorption performance (MAP), simultaneously achieving ultra-broad absorption bandwidth and strong absorption characteristics at a low thickness of 2.3 mm (the reflection loss of −41.02 dB and the effective absorption bandwidth of 5.86 GHz). Surprisingly, the effective absorption bandwidth (RL < −10 dB) could reach up to 8.08 GHz and the minimum reflection loss (RLmin) was −38.20 dB at the thickness of 2.7 mm. The results further confirmed that the excellent microwave attenuation ability of the as-prepared Fe–MnO2@C-HNBs composites benefitted from the special “air@core-shell” structure and multiple heterointerfaces as well as multi-component recombination. These results demonstrated that the as-obtained Fe–MnO2@C-HNBs composites could be attractive candidates for broadband microwave absorption materials.

Co-Doped Porous Carbon/Carbon Nanotube Heterostructures Derived from ZIF-L@ZIF-67 for Efficient Microwave Absorption.

Carbon-based magnetic metal composites derived from metal-organic frameworks (MOFs) are promising materials for the preparation of broadband microwave absorbers. In this work, the leaf-like co-doped porous carbon/carbon nanotube heterostructure was obtained using ZIF-L@ZIF-67 as precursor. The number of carbon nanotubes can be controlled by varying the amount of ZIF-67, thus regulating the dielectric constant of the sample. An optimum reflection loss of -42.2 dB is attained when ZIF-67 is added at 2 mmol. An effective absorption bandwidth (EAB) of 4.8 GHz is achieved with a thickness of 2.2 mm and a filler weight of 12%. The excellent microwave absorption (MA) ability is generated from the mesopore structure, uniform heterogeneous interfaces, and high conduction loss. The work offers useful guidelines to devise and prepare such nanostructured materials for MA materials.