Rate Of Evolution Research Articles

Blue large-amplitude pulsators formed from the merger of low-mass white dwarfs

Blue large-amplitude pulsators (BLAPs) are a recently discovered group of hot stars pulsating in radial modes. Their origin needs to be explained, and several scenarios for their formation have already been proposed. We investigate whether BLAPs can originate as the product of a merger of two low-mass white dwarfs (WDs) and estimate how many BLAPs can be formed in this evolutionary channel. We used the Modules for Experiments in Stellar Astrophysics (MESA) code to model the merger of three different double extremely low-mass (DELM) WDs and the subsequent evolution of the merger product. We also performed a population synthesis of Galactic DELM WDs using the COSMIC code. We find that BLAPs can be formed from DELM WDs provided that the total mass of the system ranges between 0.32 and 0.7\,M$_ BLAPs born in this scenario either do not have any thermonuclear fusion at all or show off-centre He burning. The final product evolves to hot subdwarfs and eventually finishes its evolution either as a cooling He WD or a hybrid He/CO WD. The merger products become BLAPs only a few thousand years after coalescence, and it takes them 20\,--\,70 thousand years to pass the BLAP region. We found the instability of the fundamental radial mode to be in fair agreement with observations, but we also observed instability of the radial first overtone. The calculated evolutionary rates of period change can be both positive and negative. From the population synthesis, we found that up to a few hundred BLAPs born in this scenario can exist at present in the Galaxy. Given the estimated number of BLAPs formed in the studied DELM WD merger scenario, there is a good chance to observe BLAPs that originated through this scenario. Since strong magnetic fields can be generated during mergers, this scenario could lead to the formation of magnetic BLAPs. This fits well with the discovery of two likely magnetic BLAPs whose pulsations can be explained in terms of the oblique rotator model.

Influenza A virus within-host evolution and positive selection in a densely sampled household cohort over three seasons.

While influenza A virus (IAV) antigenic drift has been documented globally, in experimental animal infections, and in immunocompromised hosts, positive selection has generally not been detected in acute infections. This is likely due to challenges in distinguishing selected rare mutations from sequencing error, a reliance on cross-sectional sampling, and/or the lack of formal tests of selection for individual sites. Here, we sequenced IAV populations from 346 serial, daily nasal swabs from 143 individuals collected over three influenza seasons in a household cohort. Viruses were sequenced in duplicate, and intrahost single nucleotide variants (iSNVs) were identified at a 0.5% frequency threshold. Within-host populations exhibited low diversity, with >75% mutations present at <2% frequency. Children (0-5 years) had marginally higher within-host evolutionary rates than adolescents (6-18 years) and adults (>18 years, 4.4 × 10-6 vs. 9.42 × 10-7 and 3.45 × 10-6, P < .001). Forty-five iSNVs had evidence of parallel evolution but were not over-represented in HA and NA. Several increased from minority to consensus level, with strong linkage among iSNVs across segments. A Wright-Fisher approximate Bayesian computational model identified positive selection at 23/256 loci (9%) in A(H3N2) specimens and 19/176 loci (11%) in A(H1N1)pdm09 specimens, and these were infrequently found in circulation. Overall, we found that within-host IAV populations were subject to genetic drift and purifying selection, with only subtle differences across seasons, subtypes, and age strata. Positive selection was rare and inconsistently detected.

Transcriptomic data support phylogenetic congruence and reveal genomic changes associated with the repeated evolution of annualism in aplocheiloid killifishes (Cyprinodontiformes)

Repeated evolution of novel life histories that are correlated with ecological variables offers opportunities to study convergence in genetic, developmental, and metabolic features. Nearly half of the 800 species of Aplocheiloid killifishes, a clade of teleost fishes with a circumtropical distribution, are “annual” or seasonal species that survive in ephemeral bodies of water that desiccate and are unfeasible for growth, reproduction, or survival for weeks to months every year. But the repeated evolution of adaptations that are key features of the annual life history among these fishes remains poorly known without a robust phylogenetic framework. We present a large-scale phylogenomic reconstruction of aplocheiloid killifishes evolution using newly sequenced transcriptomes obtained from a diversity of killifish lineages representing putative independent origins of annualism. Ancestral state estimation shows that developmental dormancy (diapause), a key trait of the killifish annual life cycle, may have originated up to seven times independently among African and South American lineages. To further explore the genetic basis of this unique trait, we measure changes in evolutionary rates among orthologous genes across the killifish tree of life by quantifying codon evolution using dN/dS ratios. We show that some genes have higher dN/dS ratios in lineages leading to species with annual life history. Many of them constitute key developmental genes or nuclear-encoded metabolic genes that control oxidative phosphorylation. Lastly, we compare these genes with higher ω to genes previously associated to developmental dormancy and metabolic shifts in killifishes and other vertebrates, and thereby identify molecular evolutionary signatures of repeated transitions to extreme environments.

Tungsten based nanostructured hybrid electrocatalysts in neutral medium for hydrogen evolution reaction

Generating a clean and sustainable hydrogen using the naturally available electrocatalysts to split water is among the primary energy resources adopted by the global industries. Transition metal dichalcogenides such as tungsten disulfide (WS2) provide abundant active sites to foster hydrogen evolution reaction (HER). A simple hydrothermal process was employed to synthesize WO3·H2O (hydrated tungsten trioxide) and WO3 nanoparticles. The inclusion of WS2 into the oxide has enhanced the ionic movement, which has improved the catalytic performance of the composite. The hydrophilic nature of WO3 has facilitated the conversion of water molecules into adsorbed hydrogen, which was then spilled over the HER active sites of WS2 to produce hydrogen. Thus, the WO3·H2O/WS2 catalyst achieved a current density of 10 mA cm−2 at an overpotential of 383 mV with Tafel slope of 77 mV dec−1 under neutral conditions and a hydrogen evolution rate of 0.33 mmol h−1 cm−2 at −0.5 V versus RHE.

Ingenious regulation and activation of sites in the 2H-MoS2 basal planes by oxygen incorporation for enhanced photocatalytic hydrogen evolution of CdS

The 2H phase of MoS2 has the advantages of stable phase structure and tunable preparation approach, while the unfavorable H adsorption ability at the basal plane sites hinders the H2 evolution performance. Here, we developed an effective strategy for the regulation of the basal plane properties of MoS2 via oxygen doping. It is demonstrated that the Gibbs free energy of hydrogen adsorption (ΔGH*) at the sites in the basal plane can be effectively optimized. Using oxygen-doped MoS2 (OMoS) as a cocatalyst, the constructed OMoS/CdS heterojunction photocatalyst shows a stronger built-in electric field and improved photocatalytic H2 production activity. The optimized OMoS/CdS sample with only 0.3 wt% OMoS loading amount achieved an H2 evolution rate of 58.47 mmol g-1h−1 under AM 1.5 light irradiation, which is significantly superior to that of conventional MoS2 modified CdS and even higher than the 1 wt% Pt modified CdS. Our results not only highlighted the significant potential of OMoS as a photocatalyst for hydrogen production, but also proposed a superior to and effective conception for optimizing the H2 evolution activity at the basal plane sites of 2H-MoS2.

Understanding sediment and carbon accumulation in macrotidal minerogenic saltmarshes for climate resilience

Coastal saltmarshes play an essential role in providing services such as sediment and carbon storage, coastal protection and support for biodiversity. Despite their importance, understanding the factors controlling sediment and carbon accumulation in these minerogenic saltmarshes remains challenging due to their diversity and site-specific characteristics. Understanding the respective role of these drivers is essential for effective coastal management, particularly for mitigating the impacts of climate change. This study evaluates the control of forcing factors on the lateral and vertical morphological evolution and carbon burial rates of three minerogenic saltmarshes located on the French Atlantic coast (Pertuis Charentais region). By focusing on these sites, the study isolates specific factors such as wind and wave exposure, inundation frequency, and sediment availability, while minimizing confounding influences like climate and tidal range. Results reveal significant lateral expansion of saltmarsh boundaries towards the sea across all sites, with the highest rates of progradation observed in the protected areas influenced by geomorphological features such as sand spits and sheltered bay heads. Sediment and mass accumulation rates (SAR; MAR), derived from 210Pb and 137Cs profiles of sediment cores (n = 14), range from 0.48 to 2.22 cm yr−1, among the highest reported globally, with notable variability within and between sites. Inundation frequency and accommodation space explain SAR variability within sites, while sediment availability predominantly determines spatial differences in vertical accumulation rates between sites. Organic carbon burial rates range from 75 to 345 gC m−2 yr−1, and show a strong correlation with SAR (r = 0.9, p < 0.001, n = 13) but no dependence on carbon content or density (r = 0.2, p > 0.05, n = 13). This highlights the role of sediment input in the accumulation and sequestration of carbon by minerogenic saltmarshes. Furthermore, isotopic analysis indicates a marine source dominance in organic carbon sediment. This research provides insights into how different environmental conditions affect saltmarsh morphological evolution and carbon sequestration rates, informing targeted coastal management strategies focused on enhancing ecosystem resilience and climate resilience.

Multiomic analysis of genes related to oil traits in legumes provide insights into lipid metabolism and oil richness in soybean

Soybean (Glycine max) and common bean (Phaseolus vulgaris) diverged approximately 19 million years ago. While these species share a whole-genome duplication (WGD), the Glycine lineage experienced a second, independent WGD. Despite the significance of these WGDs, their impact on gene families related to oil-traits remains poorly understood. Here, we report an in-depth investigation of oil-related gene families in soybean, common bean, and twenty-eight other legume species. We adopted a systematic approach that included a total of 605 RNAseq samples for transcriptome and co-expression analyse s, identification of orthologous groups, gene duplication modes and evolutionary rates, and family expansions and contractions. We curated a list of oil candidate genes and found that 91.5% of the families containing these genes expanded in soybean in comparison to common bean. Notably, we observed an expansion of triacylglycerol (TAG) biosynthesis (∼3:1) and an erosion of TAG degradation (∼1.4:1) families in soybean in comparison to common bean. In addition, TAG degradation genes were two-fold more expressed in common bean than in soybean, suggesting that oil degradation is also important for the sharply contrasting seed oil contents in these species. We found 17 transcription factor hub genes that are likely regulators of lipid metabolism. Finally, we inferred expanded and contracted families and correlated these patterns with oil content found in different legume species. In summary, our results do not only shed light on the evolution of oil metabolism genes in soybean, but also present multifactorial evidence supporting the prioritization of promising candidate genes that, if experimentally validated, could accelerate the development of high-oil soybean varieties.

Sexual Dimorphism and Divergent Evolutionary Pathways in Primate Cranial Biomechanics: Insights From a Theoretical Morphology Framework.

The mammalian order Primates is known for widespread sexual dimorphism in size and phenotype. Despite repeated speculation that primate sexual size dimorphism either facilitates or is in part driven by functional differences in how males and females interact with their environments, few studies have directly assessed the influence of sexual dimorphism on performance traits. Here, we use a theoretical morphology framework to show that sexual dimorphism in primate crania is associated with divergent biomechanical performance traits. The degree of dimorphism is a significant covariate in biomechanical trait divergence between sexes. Males exhibit less efficient but stiffer cranial shapes and significant evolutionary allometry in biomechanical performance, whereas females maintain performance stability across their size spectrum. Evolutionary rates are elevated for efficiency in females whereas males emphasize size-dependent cranial stiffness. These findings support a hypothesis of sex-linked bifurcation in masticatory system performance: larger male crania and faster size evolution partially compensate for low efficiency and reflect a de-emphasis of mechanical leverage, whereas female crania maintain higher mechanical efficiency overall and evolve more rapidly in molar-based masticatory performance. The evolutionary checks-and-balances between size dimorphism and cranial mechanical performance may be a more important driver of primate phenotypic evolution than has been hitherto appreciated.

Drivers of interlineage variability in mitogenomic evolutionary rates in Platyhelminthes.

Studies of forces driving interlineage variability in the evolutionary rates (both sequence and architecture) of mitochondrial genomes often produce contradictory results. Flatworms (Platyhelminthes) exhibit the fastest-evolving mitogenomic sequences among all bilaterian phyla. To test the effects of multiple factors previously associated with different aspects of mitogenomic evolution, we used mitogenomes of 223 flatworm species, phylogenetic multilevel regression models, and causal inference. Thermic host environment (endothermic vs. ectothermic) had nonsignificant impacts on both sequence evolution and mitogenomic size. Mitogenomic gene order rearrangements (GORR) were mostly positively correlated with mitogenomic size (R2 ≈ 20-30%). Longevity was not (negatively) correlated with sequence evolution in flatworms. The predominantly free-living "turbellaria" exhibited much shorter branches and faster-evolving mitogenomic architecture than parasitic Neodermata. As a result, "parasitism" had a strong explanatory power on the branch length variability (>90%), and there was a negative correlation between GORR and branch length. However, the stem branch of Neodermata comprised 63.6% of the total average branch length. This evolutionary period was also marked by a high rate of gene order rearrangements in the ancestral Neodermata. We discuss how this period of rapid evolution deep in the evolutionary history may have decoupled sequence evolution rates from longevity and GORR, and overestimated the explanatory power of "parasitism". This study shows that impacts of variables often vary across lineages, and stresses the importance accounting for the episodic nature of evolutionary patterns in studies of mitogenomic evolution.

Signature of climate dynamics on hydrological drought dynamics: A qualitative analysis

Understanding the complexity of climate dynamics is of paramount importance, because climate variability and change significantly affect water cycles and ecosystems. However, recurrent hydrological droughts that have been observed every 10 years on the two primary tributaries of the Congo River (the Ubangui and Kasaï Rivers) since the advent of the 1969 drought lack a plausible explanation for variability or climate change. This study proposes a plausible explanation for recurring hydrological droughts. Given the low rate of human activity and vegetation cover evolution in the Congo Watershed, we propose that climate dynamics play a crucial role in hydrological drought dynamics. By applying the Bayesian approach to a gridded precipitation database, we obtained posterior probability maps for each annual time step during our observational period (1940–2020). This provided a spatiotemporal representation of the areas affected by climatic disturbances, unlike previous studies that were limited to a spatial representation of the temporal location of the disturbances. Our qualitative analysis of the maximum intensity of the climate disturbance signal (CPS) revealed an average cycle of 10 years and eight months of signal migration. However, we observed that every 10 years since the advent of the drought during 1969, the hydrological drought occurrence dates coincided with CPS migration dates. This highlights the influence of this cycle on the hydrological drought dynamics. Nevertheless, because of the monthly scale involved in the propagation time from meteorological to hydrological drought, the error in this cycle was considered to be the propagation time of disturbances. Therefore, we recommend that future research should focus on estimating this time to test this hypothesis. This study underscores the significance of the cyclic dynamics of lengthy transient processes in understanding hydrological drought dynamics.

Freshwater Habitats Promote Rapid Rates of Phenotypic Evolution in Sculpin Fishes (Perciformes: Cottoidea).

AbstractInvasions of freshwater habitats by marine fishes provide exceptional cases of habitat-driven biological diversification. Freshwater habitats make up less than 1% of aquatic habitats but contain ∼50% of fish species. However, while the dominant group of freshwater fishes (Otophysi) is older than that of most marine fishes (Percomorphaceae), it is less morphologically diverse. Classically, scientists have invoked differences in the tempo and/or mode of evolution to explain such cases of unequal morphological diversification. We tested for evidence of these phenomena in the superfamily Cottoidea (sculpins), which contains substantial radiations of marine and freshwater fishes. We find that the morphology of freshwater sculpins evolves faster but under higher constraint than that of marine sculpins, causing widespread convergence in freshwater sculpins and more morphological disparity in marine sculpins. The endemic freshwater sculpins of Lake Baikal, Siberia, are exceptions that demonstrate elevated novelty akin to that of marine sculpins. Several tantalizing factors may explain these findings, such as differences in habitat stability and/or habitat connectivity between marine and freshwater systems.

Skull evolution and lineage diversification in endemic Malagasy carnivorans.

Madagascar is one of the world's foremost biodiversity hotspots with more than 90% of its species endemic to the island. Malagasy carnivorans are one of only four extant terrestrial mammalian clades endemic to Madagascar. Although there are only eight extant species, these carnivorans exhibit remarkable phenotypic and ecological diversity that is often hypothesized to have diversified through an adaptive radiation. Here, we investigated the evolution of skull diversity in Malagasy carnivorans and tested if they exhibited characteristics of convergence and an adaptive radiation. We found that their skull disparity exceeds that of any other feliform family, as their skulls vary widely and strikingly capture a large amount of the morphological variation found across all feliforms. We also found evidence of shared adaptive zones in cranial shape between euplerid subclades and felids, herpestids and viverrids. Lastly, contrary to predictions of adaptive radiation, we found that Malagasy carnivorans do not exhibit rapid lineage diversification and only marginally faster rates of mandibular shape evolution and to a lesser extent cranial shape evolution, compared to other feliforms. These results reveal that exceptional diversification rates are not necessary to generate the striking phenotypic diversity that evolved in carnivorans after their dispersal to and isolation on Madagascar.

3D Numerical Investigation of Bubble Upflow Condensation Behaviors During Subcooled Flow Boiling in Mini-Channel with VOSET

In the subcooled flow boiling process, bubble condensation is an inevitable basic phenomenon. This paper studies the condensation phenomenon of the single, double vertical/horizontal saturated bubbles rising in a three-dimensional mini-rectangular channel based on the interface capture method VOSET (coupled volume-of-fluid and level set method) and the phase transition model. Bubble condensation behaviors are investigated at different initial diameters, inlet velocity distributions, subcooling temperatures, bubble gaps, and arrangement for the two-bubble condensing system especially. The effects of these parametric on bubble motion trajectory, shape evolution, volume variation, and condensation rate are presented. The numerical results indicated that the initial bubble size and liquid subcooling play an important role in influencing the shape and volume variation of condensing bubble behaviors significantly, while the inlet velocity distribution only affects bubble motion trajectory. Furthermore, the interaction and coalescence between the bubbles will affect the bubble behaviors and the condensation rate. Finally, the condensation heat transfer coefficients at the bubble surfaces for different cases simulated in this paper are presented, seemingly first in the literature.

The multifaceted diversification of the sagitta otolith across the fish tree of life

Abstract Otoliths of actinopterygians are calcified structures playing a key role in hearing and equilibrium functions. To understand their morphological diversification, we quantified the shape of otoliths in both lateral and dorsal view from 697 and 323 species, respectively, using geometric morphometrics. We then combined form (i.e. size and shape) information with ecological data and phylogenetically informed comparative methods to test our hypotheses. Initially, the exploration of morphospaces revealed that the main variations are related to sulcus acusticus shape, elongation and lateral curvature. We also found strong integration between otolith and sulcus shape, suggesting that they are closely mirroring each other, reinforcing a shape-dependent mechanism crucial for otolith motion relative to its epithelium and validating the functional significance of otolith morphology in auditory and vestibular processes. After revealing that otolith shape and size retained a low phylogenetic signal, we showed that the disparity of otolith size and shape is decoupled from order age and from the level of functional diversity across clades. Finally, some traits in otolith disparity are correlated with their morphological evolutionary rate and the order speciation rate. Overall, we observed that the pattern of diversification of otoliths across the fish tree of life is highly complex and likely to be multifactorial.

Evolution of Influenza A(H3N2) Viruses in Bhutan for Two Consecutive Years, 2022 and 2023.

Influenza A viruses pose a significant public health threat globally and are characterized by rapid evolution of the hemagglutinin (HA) gene causing seasonal epidemics. The aim of this study was to investigate the evolutionary dynamics of A(H3N2) circulating in Bhutan during 2022 and 2023. We analysed 166 whole-genome sequences of influenza A(H3N2) from Bhutan, obtained from the GISAID database. We employed a Bayesian Markov Chain Monte Carlo (MCMC) framework, with a curated global dataset of HA sequences from regions with significant migration links to Bhutan. Phylogenetic, temporal, and phylogeographic analyses were conducted to elucidate the evolutionary dynamics and spatial dissemination of the viruses. Our phylogenetic analysis identified the circulation of influenza A(H3N2) Clade 3C.2a1b.2a.2 in Bhutan during 2022 and 2023, with viruses further classified into three subclades: 2a.3 (39/166), 2a.3a.1 (58/166) and 2a.3b (69/166). The TMRCA estimates suggest that these viral lineages originated approximately 1.93 years prior to their detection. Phylogeographic analysis indicates introductions from the United States in 2022 and Australia in 2023. The mean evolutionary rate across all gene segments was calculated to be 4.42 × 10-3 substitutions per site per year (95% HPD: 3.19 × 10-3 to 5.84 × 10-3), with evidence of purifying selection and limited genetic diversity. Furthermore, reassortment events were rare, with an estimated rate of 0.045 events per lineage per year. Our findings show that primary forces shaping the local evolution of the influenza A(H3N2) in Bhutan are largely stochastic, with only sporadic instances of adaptive change, and thus underscore the importance of continuous surveillance to mitigate the impact of evolving strains.

The potential for evolutionary rescue in an Arctic seashore plant threatened by climate change.

The impacts of climate change may be particularly severe for geographically isolated populations, which must adjust through plastic responses or evolve. Here, we study an endangered Arctic plant, Primula nutans ssp. finmarchica, confined to Fennoscandian seashores and showing indications of maladaptation to warming climate. We evaluate the potential of these populations to evolve to facilitate survival in the rapidly warming Arctic (i.e. evolutionary rescue) by utilizing manual crossing experiments in a nested half-sibling breeding design. We estimate G-matrices, evolvability and genetic constraints in traits with potentially conflicting selection pressures. To explicitly evaluate the potential for climate change adaptation, we infer the expected time to evolve from a northern to a southern phenotype under different selection scenarios, using demographic and climatic data to relate expected evolutionary rates to projected rates of climate change. Our results indicate that, given the nearly 10-fold greater evolvability of vegetative than of floral traits, adaptation in these traits may take place nearly in concert with changing climate, given effective climate mitigation. However, the comparatively slow expected evolutionary modification of floral traits may hamper the evolution of floral traits to track climate-induced changes in pollination environment, compromising sexual reproduction and thus reducing the likelihood of evolutionary rescue.

Heat transfer-deformation characteristics and fracture damage analysis during LN2 freeze-thaw process in different rank coals

Exploring the heat transfer and deformation characteristics of coal bodies of different coal ranks during the freeze-thaw process is of significant importance for analyzing the fracture mechanism under the effect of liquid nitrogen (LN2). This experiment targets lignite, bituminite, and anthracite under both saturated and dry conditions. A real-time temperature-strain monitoring system was employed to observe the heat transfer and deformation characteristics of coal samples with different ranks throughout the freeze-thaw cycle. Additionally, a nuclear magnetic resonance system was utilized to examine the characteristics of pore damage before and after fracturing. The findings reveal: (1) During the freeze-thaw process, the absolute value of the temperature evolution rate for dry coal samples shows a negative correlation with coal rank, indicating a close link between temperature diffusion and intrinsic coal properties like oxygen content and porosity. (2) For saturated coal samples, the absolute value of the temperature change rate during freezing decreases as the coal rank increases, with the opposite trend observed during thawing. The phase change effect of water in fractures during freezing can enhance internal temperature diffusion in the coal body, while it acts as an inhibitor during thawing. (3) Based on the trend of strain fluctuations, the coal body deformation process during the freeze-thaw cycle can be segmented into seven stages, summarizing the general mechanisms of deformation failure. (4) Under saturated conditions, the amplitude of elastic deformation for each sample is negatively correlated with coal rank, with the sequence for dry coal samples being bituminite > anthracite > lignite. (5) The formation of a sealed space at the beginning of freezing is identified as a necessary condition for deformation during the freeze-thaw process, with the formation and strength of the sealed space depending on the temperature diffusion rate, moisture content, and inherent properties of the coal sample.

Green hydrogen production from thermoelectric condensation of ambient moist air

As the world transitions towards reducing carbon emissions, green hydrogen produced through solar-powered alkaline water electrolysis (AWE) presents a promising eco-friendly fuel option. In response to the challenges caused by global warming, including air moisture saturation leading to unbalanced rainfall, flooding, concern for freshwater depletion and the limited availability of water and energy sources in arid regions. The present study introduces a novel method of integrating thermoelectric water condenser (TEWC) and AWE for green hydrogen production in remote and arid regions where both the water and the conventional energy sources are scarce. Numerical simulations of the present study show that the impact of relative humidity, temperature, and air flow rate significantly affect water condensation, energy requirement, and hydrogen production. The TEWC and AWE models showed excellent agreement with the experimental data. TEWC model reveled that the highest water production rate of 1.50 kg/(m2h) is achieved at ambient air temperature of 308 K and relative humidity of 80%. Furthermore, increasing the moist air flow from 1 m/s to 2 m/s results in a 47.5% increase in water production rate. The AWE model showed that cell's performance improved with higher temperatures, lower electrode-separator gap, and overpotentials. The hydrogen evolution rate reached a maximum of 5.2 kg/(m2h) at current density of 1.4 A/cm2 and potential of 3.96 V. By optimizing the TEWC and AWE systems the integrated method proved to be an efficient way of converting moist air into green hydrogen using solar energy, making it a viable and sustainable setup in remote arid regions.

Robust photocatalytic hydrogen evolution performance of 0D/1D NiO/CdS S-scheme heterojunction

Constructing heterojunction, especially S-scheme heterojunction, is an effective strategy for achieving effective separation of photogenerated electron-hole pairs and obtaining high electrode potential. In this study, a unique 0D/1D NiO/CdS S-scheme heterojunction was constructed by solvent evaporation induced self-assembly method. The loading of NiO was found to greatly enhance the photogenerated carrier separation efficiency of CdS by photoluminescence (PL) spectroscopy, electrochemical impedance spectroscopy (EIS), Kelvin probe force microscopy (KPFM) and transient photocurrent tests. The best photogenerated carrier separation effect was observed at a NiO loading ratio of 15 wt% and the largest photocatalytic hydrogen evolution rate reached 7.89 mmol h-1g−1 under visible light, which was 24.66 times that of pristine CdS. In addition, the cycling experiments showed that the loading of NiO led to the alleviation of the photocorrosion phenomenon of CdS, and the performance remained at 94.2 % after five cycles. This is due to the fact that the formation of S-type heterojunction combines the photogenerated holes of CdS with the photogenerated electrons of NiO, which hinders the oxidation of S2- on the surface of CdS, thus alleviating the photocorrosion phenomenon of CdS and improving the stability of CdS. This work furnishes a new strategy for the development of stable and high-performance photocatalysts with inexpensive co-catalysts.

Synthesis, Characterization of KNb0.99Eu0.01O3 and improved Photo-catalytic H2-Production on Ag/La2NiO4/ KNb0.99Eu0.01O3 hetero-junction

The perovskite KNb0.99Eu0.01O3 prepared by nitrate combustion is applied as a hydrogen photocathode in heterojunction with La2NiO4 under visible light. The XRD pattern confirms the formation of KNb0.99Eu0.01O3 structure with orthorhombic single phase. The SEM images present grains between 0.2 and 0.4 µm while the optical band gap (3.14 eV) is calculated from the diffuse reflectance. Under illumination, the cyclic voltammetry (CV) and the capacitance measurements in Na2SO4 electrolyte show an increased current below ∼ -0.7 V vs. Ag/AgCl and p-type behavior with a conduction band (CB = −1.95 V) cathodically positioned with respect to H2 level, thus leading to H2 photo-production. The hetero-system La2NiO4/KNb0.99Eu0.01O3 shows a much higher activity than KNb0.99Eu0.01O3 where efficient H2-photoevolution occurs with concomitant oxidation of S2O32−, as reducing agent. So, the co-junction of La2NiO4 with KNb0.99Eu0.01O3 facilitates the charge transfer and increases the reaction efficiency. At neutral pH, the H2 evolution rate for the photocatalysts KNb0.99Eu0.01O3 and La2NiO4/ KNb0.99Eu0.01O3 are 11.15 and 57 µmol g−1 min−1; respectively. Further enhancement is observed with Ag-loaded La2NiO4/KNb0.99Eu0.01O3, reaching a maximum hydrogen production rate of 67 µmol g−1 min−1, attributed to the lower overpotential introduced by Ag. These findings highlight the potential of the ternary system Ag/La2NiO /KNb0.99Eu0.01O3 as an efficient photocathode for H2 generation.