The influence of environment on the formation and evolution of early-type galaxies is, as yet, an unresolved issue. Constraints can be placed on models of early-type galaxy formation and evolution by examining their stellar populations as a function of environment. We present a catalogue of galaxies well suited to such an investigation. The magnitude-limited (b_J<19.45) sample was drawn from four clusters (Coma, A1139, A3558, and A930 at <z>=0.04) and their surrounds. The catalogue contains luminosities, redshifts, velocity dispersions and Lick line strengths for 416 galaxies, of which 245 are classified as early-types. Luminosity-weighted ages, metallicities, and alpha-element abundance ratios have been estimated for 219 of these early-types. We also outline the steps necessary for measuring fully-calibrated Lick indices and estimating the associated stellar population parameters using up-to-date methods and stellar population models. In a subsequent paper we perform a detailed study of the stellar populations of early-type galaxies in clusters and investigate the effects of environment.