A ceramic core is the key component in the manufacture of the hollow turbine blades of aeroengines. Compared with the traditional injection molding method, 3D printing is more suitable for manufacturing ceramic cores with a complex geometry at high precision. However, the stair-stepping effect is inevitable in the 3D printing process and affects the surface roughness and strength of the ceramic core. In this study, to explore the influence of nano-silica content on the microstructure and properties of the ceramic core, silicon-based ceramic cores were fabricated with the addition of nano-silica powder by digital light processing and subsequent sintering at 1200 °C. The results showed that the apparent porosity and pore size of the ceramic core gradually decreased as both the nano-silica powder content and bulk density increased. Meanwhile, the printing interlayer spacing was significantly reduced, resulting in a low surface roughness, high flexural strength, and creep-resistance. To simulate the entire casting process of a superalloy blade, the thermal deformation behavior of the ceramic core was observed by heating and cooling cycles performed in a thermal dilatometer at 1540 °C. The total linear shrinkage decreased as the nano-silica powder content increased, which was mainly due to the phase transformation of cristobalite and the densification of the ceramic core sintered at 1200 °C. The low surface roughness and linear shrinkage as well as high flexural strength of the ceramic core can contribute to the excellent quality of cast superalloy blades.