Porous wicks, characterized by high capillary pumping force, lightweight, and excellent permeability, have been widely used in heat transfer. Currently, porous wicks are fabricated using powder sintering, porous foaming, and solvent volatilization techniques. However, there is the problem that the shape, size, and pore distribution of the porous structure are difficult to control. This paper proposes a novel 3D printing method to fabricate porous wicks using selective laser melting. The unit diameter and length are optimized to obtain a porous wick with high porosity and capillary pumping force. The effect of laser power on the surface morphology and porosity of the porous wick is investigated by modulating the 3D printing process parameters. The results show that the porosity of the porous wick can be regulated by changing the diameter and length of the pore unit. Decreasing the laser processing power and attaching unmelted solid-phase particles to the pore surface can further increase the porosity. When the laser power is 125 W, the unit diameter is 0.4 mm, and the unit length is 0.6 mm, the porous wick has strong capillary pumping force. The 316L porous material is modified by heat treatment to obtain super-hydrophilic properties. The porous wick is applied to the evaporator of the loop heat pipe, which significantly improves the heat transfer performance. When the heat load is 200 W, the evaporator temperature is 57.09 °C, and the thermal resistance is 0.025 °C/W.
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