Along with the increasingly stringent dust emission concentration standards for the thermal power plants and the challenge of market competition, wet electrostatic precipitators (ESPs) have been widely used as terminal equipment for the flue gas treatment. The wet ESPs pilot test platform using the modified carbon steel collectors with hydrophilic properties was established in this paper and the experimental research on PM2.5 removal characteristics were carried out. The mechanism of the particles removal efficiency enhancement by water film on the surface of modified collectors was studied. The effect of gas temperature, residence time, working voltage, inlet concentration and flushing water flowrate on the particles removal efficiency was investigated. The results indicated that the fibrous layer over the surface of the modified collectors could reduce the effect of the airflow recoil and the electromigration resistance of particles. The surface of the modified collectors could also maintain a uniform and stable water film with a lower amount of water consumption. The water film could restrain the back corona and the re-entrainment of dust. And the evaporation of water film increased the humidity of the flue gas, meanwhile, the particles charge capacity and electromigration velocity increased. Those all could improve the particles removal efficiency. The particles removal efficiency increased with the increase of the flue gas residence time and the applied voltage, but the particles removal efficiency improved less with the increase of the particles inlet concentration and flushing water flow rate after maintaining uniform and stable water film. The modified rigid collector provided high removal efficiency for particles with diameters of 0.04~0.48 μm under lower energy and water consumption. Implications: The wet electrostatic precipitators (ESPs) have been widely used as terminal equipment of the flue gas treatment to purify the flue gas deeply. The surface of the modified carbon steel collectors with hydrophilic properties could maintain a uniform and stable water film with a lower amount of water consumption. The evaporation of water film improved the particle charge capacity and electromigration velocity. The wet ESPs using the modified rigid collector exhibited significantly higher removal efficiency of particles than using the conventional rigid collector especially to the particles with diameter of 0.04~0.48 μm.