Effect Of Evaporation Research Articles

Interfacial evaporation characteristics of three-dimensional Cu-Fe3O4 nanoparticle film

In an effort to further enhance the evaporation effect of interfacial evaporation, a super-hydrophilic nanoparticle film was prepared by ultrasonic impregnation in this paper. Then, by improving the structure and configuration design of nanoparticle film, the nanoparticle film was transformed from two-dimensional structure to three-dimensional structure. The effects of three-dimensional structure shape, radiation intensity and three-dimensional structure height on the evaporation capacity of nanoparticle films were studied. It was found that the evaporation rate of the three-dimensional rectangular Cu-Fe3O4 nanoparticle film with a rectangular height of 15 mm achieved 1.2 kg/m2/h under one sun radiation intensity. The evaporation efficiency can reach 75.44 %, and the thermal efficiency can reach 111.91 %. The design of the three-dimensional structure enables the nanoparticle film to perform double-sided evaporation. At the same time, under the action of natural air convection, the nanoparticle film evaporation efficiency is greatly improved, which provides a design strategy for the nanoparticle film in the field of solar-driven interface evaporation.

Collaborative water-electricity operation optimization of a photovoltaic/pumped storage-based aquaculture energy system considering water evaporation effects

The increasing global population, economic development, and urbanization trends have led to a heightened demand for seafood, presenting a significant challenge to the growth trajectory of the food industry. As the most rapidly expanding segment within the food industry, aquaculture presents a sustainable solution to mitigate the overexploitation of marine resources and address the growing demand for food. Aquaculture's sufficient aquatic expanses offer considerable potential for PV deployment, thereby relieving the demand for limited land resources. However, existing research rarely addresses the collaborative operation of water and electricity in aquaculture systems. The effects of water evaporation from PV panel-covered water surfaces on the collaborative water-electricity operation are generally neglected. Hence, this work proposes a collaborative water-electricity operation of a photovoltaic (PV)-pumped storage-based aquaculture energy system considering the water evaporation effects. This optimization method accounts for the reduced water evaporation due to PV panel shading. Water surface PV and pumped storage are integrated into the system to fulfill electricity needs, with pumped storage serving as a dual-purpose device for water and electricity supply. Environmentally sustainable water-electricity generation and aquaculture energy system requirements are established. Water surface PV electricity generation is modeled based on climate and engineering conditions, while aquaculture pond electricity requirement includes oxygenation, feeding, and water replenishment. Finally, a collaborative water-electricity operation model is introduced to optimize operation strategies for various devices. A case study on a fish-light complementation project demonstrates that this optimization method can reduce reliance on the utility grid and overall system operational costs.

Room temperature quantitative liquid concentration device and application to interleukins analysis in a B-cell culture medium.

In biological analysis and medical diagnosis, there is an increasing demand for improving the lower detection limit without deteriorating the quantitativity; however, it is usually challenging. In this study, we utilized a cyclone flow device and established a liquid concentration method. An air cyclone flow induced a liquid cyclone flow in the concentration devices and enhanced the air/liquid interface area, which allowed an effective concentration of liquid from mL to mL at room temperature. The heating temperature and actual temperature inside the liquid were investigated to know the cooling effect of evaporation. The collection efficiency of larger than 98% was confirmed with a standard solution. Finally, the analytical procedure to realize a quantitative concentration was established, and the concentration and quantification of interleukins (IL-8, IL-17, and IL-23) from the supernatant of the B-cell culture medium was demonstrated. The B-cell was stimulated with CD40L, and the supernatant was concentrated 27 times at maximum.

Hydrovoltaic-Photoelectric Coupling Strategy Triggered a Robust Output Signal for High-Performance Self-Powered Electrochemical Sensing.

Hydrovoltaic self-powered electrochemical sensors hold significant potential for constructing wearable, portable, and real-time detection devices, but the low output signal due to the slow phase transition rate of water molecules and the intricate nature of integration limits their applications. In this work, a hydrovoltaic-photovoltaic coupling effect-enhanced self-powered electrochemical sensor was prepared by combining zinc oxide (ZnO) nanowire arrays with cerium-organometallic framework (Ce-MOF) materials, which greatly improved the electrical output of self-powered electrochemical systems and provided a new detection strategy for an efficient self-powered electrochemical sensing system. The heterojunction constructed by ZnO arrays and Ce-MOF could generate a built-in electric field under the action of light irradiation and promote the separation of the photocarriers. Moreover, the number of charged particles in the film further boosted the water evaporation effect. Notably, the optimal ZnO/Ce-MOF-based self-powered electrochemical device by hydrovoltaic-photoelectric coupling strategy displayed an outstanding output signal, which was 11-fold that of a pure hydrovoltaic-based device. As a proof of concept, the self-powered electrochemical sensing platform was explored for sensitive detection of lincomycin via electrostatic adsorption for the binding of an aptamer. The self-powered sensor showed superior performances, including a wide linear range from 1 fM to 1 nM with a detection limit of 0.2 fM, good stability, and satisfactory recoveries for the determination of lincomycin in real samples, holding great promise in environmental monitoring and food analysis. This study provides a promising avenue to boost the energy conversion efficiency with a high output signal for constructing sensitive self-powered biosensors.

Analysis of Water Dynamics at the Effluent Treatment Station of Cooperoque: Evaluation of Precipitation, Evaporation, and Infiltration of Effluent from a Milk Refrigeration Station

Purpose: The study aims to analyze water dynamics at the Cooperoque Effluent Treatment Station, focusing on the interactions between precipitation, evaporation, and effluent infiltration to enhance water resource management. Theoretical reference: The research references various studies and methodologies related to the quantification of evaporation from lakes and reservoirs, particularly in semi-arid regions, utilizing the Jensen-Haise Method for evaporation estimation. The research aligns with previous studies, such as Mallmann (2014), on water infiltration in soil management, emphasizing the importance of understanding water dynamics for sustainable resource management. Method: The study employs the Jensen-Haise Method to calculate evaporation rates, covering the period from January 2023 to October 2024. It examines the effects of precipitation, evaporation, and effluent infiltration on tank levels. Results and conclusion: The results reveal that tank levels are influenced by precipitation, evaporation, and effluent infiltration, with more significant declines during dry months and smaller reductions during periods of high precipitation. Evaporation rates, calculated using the Jensen-Haise Method, are higher in warmer months, contributing to lower tank levels, while these rates decrease in colder months. A notable anomaly occurred in May 2024 when effluent infiltration exceeded the volume of generated effluents and rainfall due to the activation of an irrigation system. Key findings indicate that lake levels drop more during dry months, with a significant negative water balance observed in May 2024 due to excessive infiltration during heavy rainfall. The study concludes that adaptive water management strategies are necessary to address climatic variations and improve the efficiency of the effluent treatment system. Implications of research: The research provides valuable insights for developing adaptive water management strategies to address climatic variations and improve the efficiency of effluent treatment systems. Continuous monitoring is emphasized as crucial for sustainable water resource management. Originality/value: The study highlights the complex interactions between precipitation, evaporation, and effluent dynamics, offering a foundation for improved water management practices and contributing to the preservation of regional water resources. The study contributes to the understanding of water dynamics at effluent treatment stations, offering practical insights for managing water resources effectively. It highlights the importance of adaptive strategies and continuous monitoring to maintain pond levels and optimize the treatment process.

Performance Analysis and Novel Cross-Flow Scheme of Low-Temperature Multi-Effect Distillation for Treating High-Mineralized Mine Water

Low-temperature multi-effect distillation (LT-MED) can be used to desalinate and demineralize highly mineralized mine water, facilitating the recycling and reuse of water resources. This study conducted a simulation of LT-MED technology for treating highly mineralized mine water using Aspen Plus and proposed a novel cross-flow optimization scheme. Initially, the impact of operational parameters such as process configuration, number of evaporation effects, and steam input on the gained output ratio (GOR) and scaling risk of a conventional LT-MED system was analyzed. It was found that the number of effects and heating steam flow rate had the most significant influence on GOR, while different processes exhibited limitations regarding GOR and scaling trends. To address these issues, this paper introduced a cross-flow operation process that combined forward, backward, and parallel flow. The simulation results indicated that, under conditions of eight effects, a maximum evaporation temperature of 70 °C, a temperature difference between adjacent effects of 4 °C, and a feed temperature of 45 °C, the cross-flow process—where the feed was introduced from the sixth effect—achieved the highest GOR and significantly reduced scaling risks compared to parallel and backward flow configurations. Finally, to further utilize low-pressure exhaust steam from the final effect of the cross-flow LT-MED system, mechanical vapor compression (MVC) and thermal vapor compression (TVC) were integrated into the LT-MED process. The thermodynamic performance of the coupled system was analyzed, and the simulations demonstrated that the coupled system outperformed the standalone use of either TVC or MVC, with the LT-MED-MVC-TVC system showing superior performance overall.

Sn Penetrated Zincophilic Interface Design in Porous Zn Substrate for High Performance Zn-Ion Battery.

Rechargeable zinc-ion batteries are considered an ideal energy storage system due to their low cost and nonflammable aqueous electrolyte. However, dendrite growth, hydrogen evolution reaction, and self-corrosion of zinc anode brought about serious safety risks including short circuits and electrode expansion. Therefore, a modified host-design strategy with a 3D porous structure and bulk-phase penetrated zincophilic interface is proposed to boost the stability and lifetime of the Zn anode. The porous Zn substrate is constructed by universal HCl etching and the uniform and tight Sn-penetrated zincophilic interface is formed by effective electron beam evaporation (EBE). The porous substrate can uniform zinc ion flux and the Sn coating could effectively improve zinc ion deposition behavior, thus inhibiting the risk of dendrites growth and side reaction. As a result, the 3D Zn substrate with Sn interface (3D Zn@Sn) exhibits prolonged galvanostatic cycling performance up to 4500h with a low polarization of ≈25mV (1mAcm-2, 1mAhcm-2) in the symmetric cell. The full cell assembled with KVOH@Ti could maintain a high specific capacity of 148.6mAhg-1 after 500 galvanostatic cycles (10Ag-1). This work proposed an improved electrode design to realize the high performance of zinc ion batteries.

Application of Hydrochemical Parameters as Tool for Sustainable Management of Water Supply Network

Effective management of Water Supply Systems (WSSs) is crucial for ensuring safe drinking water. The WSS of Varaždin County is a complex network involving three groundwater sources: Bartolovec and Vinokovščak wellfields (alluvial aquifers) and Bela karstic spring. To achieve a comprehensive characterization of WSSs, routine laboratory data was integrated with stable isotopes and geochemical modeling. Within this study, all measured parameters remain below the Maximum Contaminant Level (MCL), ensuring water safety for human consumption. The Piper diagram identified variations in water sources based on their chemical composition, providing a simplified overview of mixing patterns within WSSs. Among the modeling approaches, inverse modeling (IM) was found to be more reliable than forward modeling (FM) and mass balance modeling (MB). Despite the limited capacity of δ18O to provide accurate mixing results, it was revealed that the reservoir water was in equilibrium with the air (no evaporation effects), indicating well-sealed reservoirs. Mixing modeling showed that the western, southwestern, and northern parts of the WSS mixed all three sources, whereas the eastern and southeastern areas primarily relied on the deeper aquifer of the Bartolovec source, indicating potential vulnerability. Strict validation criteria ensured the reliability of results, demonstrating the effectiveness and applicability of geochemical modeling in water security management plans.

Influence of Evaporation and High‐Frequency Seawater Inundation on Salinity Dynamics in Swash Zones

AbstractThe interactions between the atmosphere, ocean, and beach in the swash zone are dynamic, influencing water flux and solute exchange across the land‐sea interface. This study employs groundwater simulations to examine the combined effects of waves and evaporation on subsurface flow and salinity dynamics in a shallow beach environment. Our simulations reveal that wave motion generates a saline plume beneath the swash zone, where evaporation induces hypersalinity near the sand surface. This leads to the formation of a hypersaline plume beneath the swash zone during periods of wave recession, which extends vertically downward to a maximum depth of 30 cm, driven by the resulting vertical density gradients. This hypersaline plume moves approximately 2 m landward to the top of the swash zone and down the beachface due to wave‐induced seawater infiltration and is subsequently diluted by the surrounding saline groundwater. Furthermore, swash motion increases near‐surface moisture, leading to an elevated evaporation rate, with dynamic fluctuations in both moisture and evaporation rate due to high‐frequency surface inundation caused by individual waves. Notably, the highest evaporation rates on the swash zone surface do not always correspond to the greatest elevations of salt concentration within the swash zone. This is because optimal moisture is also required—neither too low to impede evaporation nor too high to dilute accumulated salt near the surface. These insights are crucial for enhancing our understanding of coastal groundwater flow, biogeochemical conditions, and the subsequent nutrient cycling and contaminant transport in coastal zones.

Groundwater Geochemistry in the Karst-Fissure Aquifer System of the Qinglian River Basin, China

The Qinglian River plays a significant role in China’s national water conservation security patterns. To clarify the relationship between hydrogeochemical properties and groundwater quality in this karst-fissure aquifer system, drilling data, hydrochemical parameters, and δ2H and δ18O values of groundwater were analyzed. Multiple indications (Piper diagram, Gibbs diagram, Na+-normalized molar ratio diagram, chloro-alkaline index 1, mineral saturation index, and principal component analysis) were used to identify the primary sources of chemicals in the groundwater. Silicate weathering, oxidation of pyrite and chlorite, cation exchange reactions, and precipitation are the primary sources of dissolved chemicals in the igneous-fissure water. The most relevant parameters in the karst water are possibly from anthropogenic activities, and other chemicals are mostly derived from the dissolution of calcite and dolomite and cation exchange reactions. Notably, the chemical composition of the deep karst water from the karst basin is mainly influenced by the weathering of carbonate and cation exchange reactions and is less affected by human activities. The hydrogeochemical properties of groundwater in the karst hyporheic zone are influenced by the dissolution of carbonates and silicates, evaporation, and the promotion effect of dissolution of anorthite or Ca-containing minerals. Moreover, the smallest slope of the groundwater line from the karst hyporheic zone among all groundwater groups revealed that the mixing effects of evaporation, isotope exchange in water–rock interaction or deep groundwater recharge in the karst hyporheic zone are the strongest. The methods used in this study contribute to an improved understanding of the hydrogeochemical processes that occur in karst-fissure water systems and can be useful in zoning management and decision-making for groundwater resources.

Molecular Insights into Gas-Particle Partitioning and Viscosity of Atmospheric Brown Carbon.

Biomass burning organic aerosol (BBOA), containing brown carbon chromophores, plays a critical role in atmospheric chemistry and climate forcing. However, the effects of evaporation on BBOA volatility and viscosity under different environmental conditions remain poorly understood. This study focuses on the molecular characterization of laboratory-generated BBOA proxies from wood pyrolysis emissions. The initial mixture, "pyrolysis oil (PO1)", was progressively evaporated to produce more concentrated mixtures (PO1.33, PO2, and PO3) with volume reduction factors of 1.33, 2, and 3, respectively. Chemical speciation and volatility were investigated using temperature-programmed desorption combined with direct analysis in real-time ionization and high-resolution mass spectrometry (TPD-DART-HRMS). This novel approach quantified saturation vapor pressures and enthalpies of individual species, enabling the construction of volatility basis set distributions and the quantification of gas-particle partitioning. Viscosity estimates, validated by poke-flow experiments, showed a significant increase with evaporation, slowing particle-phase diffusion and extending equilibration times. These findings suggest that highly viscous tar ball particles in aged biomass burning emissions form as semivolatile components evaporate. The study highlights the importance of evaporation processes in shaping BBOA properties, underscoring the need to incorporate these factors into atmospheric models for better predictions of BBOA aging and its environmental impact.

Heavy metal migration and enrichment in desulfurization wastewater during low-temperature triple effect evaporation process

Zero discharge of desulfurization wastewater from coal-fired power plants has become important. Desulfurization wastewater and gypsum from different stages of the low-temperature triple-effect evaporation process of a coal-fired power plant were collected and investigated. The results showed that after low-temperature triple-effect evaporation, the concentrations of Na+, Mg2+, K+, and Cl− in the desulfurization wastewater increased by 7.91, 7.15, 8.49, and 8.35 times, respectively. With the progress of low-temperature triple effect evaporation process, the concentrations of As, Cd, Co, Cr, Cu, Mn, Se, and Zn in the wastewater after the triple effects were 5.85, 75.44, 1.28, 2.34, 13.66, 5.58, 8.59, and 4.35 times higher than those in the raw wastewater. Mn and Se exceeded the emission limits by 40 and 10 times, respectively. After triple-effect evaporation, the concentrations of As, Cd, Co, Cr, Cu, Pb, Se, and Zn in gypsum decreased to 46%, 26%, 66%, 41%, 35%, 97%, 39%, and 51% of the raw gypsum, respectively. Compared with that of other metal sulfates, the solubility of PbSO4 was extremely low under low-temperature conditions, and some PbSO4 precipitated during the triple-effect evaporation process, leading to a gradual decrease in the Pb concentration in the liquid phase. The mercury compounds in gypsum after the first and second effects were the same as those in raw gypsum, both of which were HgS and HgO. After third effect, the mercury compound in gypsum also included HgSO4. In addition, owing to the promoting effect of the pH of desulfurization wastewater approaching 5.50 on the generation of HgS, the proportion of HgS gradually increased, and the proportion of HgO gradually decreased from the raw gypsum to the third effect gypsum. Therefore, the stability of the mercury compounds in gypsum was enhanced. It can provide a good reference for the migration and enrichment of heavy metals in the low-temperature triple-effect evaporation process, which is beneficial for the clean production and efficient utilization of coal.

ТЕОРЕТИЧНЕ ДОСЛІДЖЕННЯ ТЕПЛОВИХ ПРОЦЕСІВ НА ВУГЛЕЦЕВИХ ЕЛЕКТРОДАХ В РЕЗУЛЬТАТІ ДІЇ ПЛАЗМИ ПРИ ГЕНЕРАЦІЇ НАНОСТРУКТУР У ВАКУУМНІЙ ДУЗІ

A mathematical model has been refined to determine the thermophysical and thermomechanical processes on electrodes during the plasma formation of nanostructures. The model takes into account the effects of electrode spots, evaporation, sputtering, and thermal stresses in the electrode bodies. Calculations of temperature distribution on the surfaces of the graphite cathode and anode were carried out, considering the conditions necessary for obtaining nanostructures. An analysis of the thermophysical processes on the surfaces of the graphite cathode and anode during the transition to the working regime was conducted. The stability of the electrodes during plasma generation of nanostructures was determined by changes in the geometry of the electrodes. Calculations of the temperature fields on the end surface of the graphite cathode showed that with a continuous increase in the cathode surface temperature, the nature of its distribution does not change fundamentally. Calculation of temperature fields along the radius of the graphite cathode at different moments in time during the transition to the working regime showed a slight impact of evaporation on the change in the cathode's geometry. Determining the temperature fields along the generatrix of the anode showed the greatest impact of evaporation on the small area of the anode closest to the cathode. The dependencies of the acting stresses on temperature for the graphite cathode and anode were obtained. Studies of the dynamics of changes in thermal stresses on the electrodes during the formation of nanostructures in a plasma environment indicate that the values of thermal stresses are far from the material's strength limit. A theoretical study of the thermophysical and thermomechanical processes on the graphite cathode was carried out and compared with experimental measurements. The calculation of the electrodes' lifespan during the creation of carbon nanostructures in a plasma environment was 2.52∙105 s. The experimental lifespan of the graphite cathode is 2.88∙105 s, which is quite close to the calculated value. The coincidence of the obtained theoretical and experimental results indicates the viability of the developed model. The article may be of interest when designing equipment for obtaining nanostructures in a plasma environment and for further research on the physical parameters of electrodes.

Numerical simulation of detonation propagation and extinction in two-phase gas-droplet ammonia fuel

Numerical simulations of detonation propagation and extinction in ammonia droplet-laden premixed ammonia–oxygen gas are performed in a 2-D planar channel. The sustained propagation and ultimate quenching of detonation with perturbations from ammonia droplets are observed under lower and larger values of initial droplet number density (Nd,0) and diameter (d0), respectively. The detonation always quenches under d0=15μm. The detonation propagation/extinction behaviour and cell structure are dependent on both d0 and Nd,0. The positive correlations between droplet volume fraction, inter-phase mass, momentum, and energy transfers and d0 are more nonlinear than their counterparts of Nd,0. The post-Mach stem region experiences higher-intensity detonative combustion and thus droplet evaporative, accelerative, and heating effects than the post-incident wave region. During the detonation extinction process, the detonation wave degenerates into detonative spots which then decouple into shock and reaction fronts; gaseous pressure, heat release rate, and nitric oxide volume fraction peaks decline.

Investigation on supersonic jet noise reduction by water injection: Effects of water injection parameters

In order to protect the payload and the rocket structure from severe vibrations, water injection is commonly used on launch pads to reduce the high noise level radiated by supersonic plumes at lift-off. Even if this technique is widely used, the mechanisms behind sound reduction remain unclear. Sound reduction occurs due to multiple phenomena, each of them having different effects on the jet noise. Experiments based on acoustic measurements have been carried out on a hot supersonic jet on MARTEL facility (Mach number of 3 and a total temperature of 1700 K) to deeper identify the effect of evaporation and water injection parameters. Water flow rate, water injection speed and injection distance to the nozzle have been tested independently to identify the most important water injection parameters. It appears that water flow rate is the most important parameter to decrease noise level and that injecting water at high speed results in noise increase in the downstream direction. Results also highlight the importance of having liquid droplets at the end of the potential core to reduce noise.

Bionic solar-Driven interfacial evaporator for synergistic photothermal-Photocatalytic activities and salt collection during desalination

Solar-driven interfacial evaporation plays an essential part in the production of potable water. Nevertheless, the intricate water conditions in real-world scenarios continue to pose limitations on its utilization. This study prepared a novel bionic PPy/BiVO4-PI/MXene aerogel composite material with radial center structure through directional freezing as the evaporator, which integrates both photothermal and photocatalytic properties into the evaporation system. In order to evaluate the efficacy of photocatalytic degradation and salt collection during interfacial evaporation, high-concentration saline water, simulated seawater and dyeing wastewater were employed as substitutes for real contaminated water bodies. After being exposed to 1 kW/m−2(−|-) of irradiation, the PPy/BiVO4-PI/MXene composite exhibits an evaporation rate of 1.64 kg m-2h−1 and achieves a photothermal efficiency of 96.77 %. In high-concentration saltwater containing 20 wt% NaCl, the PPy/BiVO4-PI/MXene exhibited an evaporation rate of 1.32 kg m-2h−1 and a photothermal conversion efficiency of 77.41 %. Furthermore, approximately 26.7 g of salt can be collected after 15 days’ continuous evaporation. Furthermore, the PPy/BiVO4-PI/MXene demonstrated exceptional photocatalytic capabilities to organic dyes such as MB, RhB, CR and MG with removal efficiencies of 79.28 %, 70.96 %, 76.70 % and 80.95 %, respectively. This study realizes the synergistic effect of interfacial evaporation, photocatalysis and salt collection, providing a highly promising choice for the treatment of high-salt dyeing wastewaters.

Achieving an Ultralow-κ yet Strong and Transparent Film by Antisolvent-Confined Nanowelding of Electrospun Polyimide Nanofibers.

Developing ultralow-κ (dielectric constant) polyimides (PIs) that are mechanically robust while also being optically transparent is challenging. For the first time, we report a nanoporous PI film with an ultralow κ of 1.8 in combination with a tensile strength of up to 180 MPa, a Young's modulus of up to 6 GPa, and a transmittance of ∼88%. This is achieved by direct nanowelding of a porous electrospun PI nanofiber membrane using a simple mixture of ethanol-dominating DMAc. Benefiting from the effective evaporation of the antisolvent ethanol upon heating, the proposed nanowelding approach allows for the localized surface dissolution of the PI nanofibers, which enables the dissolved PI to "glue" the nanofibers and occupy vacant space in the membrane, resulting in the formation of a dense but nanoporous self-reinforced nanocomposite film. Our findings provide a renewed understanding of the potential of electrospun nanofibrous materials, and the underlying principle can hopefully be applied to other commodity polymers.

Application of coal mining waste in civil and road construction

Aim: This study analyzes the potential for processing coal mining waste in civil and road construction. Materials and Methods. The research focused on rock dumps from eight mines in the Lugansk People’s Republic. According to current methods, samples of dump rock were collected and analyzed in the laboratory for various properties, including Al2O3 content (up to 22%), total sulfur (up to 4%) in rock samples of varying degrees of metamorphism, indicators of its plasticity, and radiation characteristics (up to 220 Bq/kg). Results. This study addresses the processing of rock dumps from coal mines in the Lugansk People’s Republic as a source of raw materials for building materials. A brief analysis of existing methods for obtaining various building materials from waste rocks was carried out. The laboratory tests on waste rock samples from several mines demonstrated their potential use in civil, industrial, and road construction. Conclusion. The research provides a detailed analysis of various indicators and properties of coal mining waste in the Lugansk People’s Republic, including specific effective activity and evaporation coefficient. Findings suggest that the waste rock can be effectively used as raw material in the construction industry, supporting the production of materials for industrial, civil, and road construction.

Development of an Ultrasonic Nebulization System for an Inverse Low Temperature Plasma Ionization Source.

An effective nebulization and evaporation of a liquid sample, like in liquid chromatography, mass spectrometry (LC-MS) couplings, is an essential requirement for the ionization of analyte molecules in the gas phase by, for example, atmospheric pressure chemical ionization (APCI) or the novel low temperature plasma (LTP)-based ion source. These LTP-based ion sources have recently gained interest in the field of atmospheric pressure ion sources, as they can cover a wide range of polarity and molecular mass. They can be used in combination with separation techniques like liquid chromatography or used as an ambient ion source. However, commercial nebulizer systems are of course not constructed to fit to home-built LTP-based ion sources, and this was one incentive to develop a new nebulization system. Instead of an atmospheric pressure chemical ionization (APCI) nebulizer, two commercial nebulizers were disassembled and remodeled to be used as nebulizing systems in an LC-MS setup using an LTP-based ion source. Based on these results, a novel nebulizer system was subsequently developed. To further improve the degree of ionization, cones to focus the LC eluent spray on the plasma region, heating applications, and auxiliary nitrogen gas for dispersion of the solvent droplets were implemented. The LOD that could be calculated via the rule of three resulted in an average of 2.0 μg/L for the APCI-nebulizer and 41 μg/L for the USN. Both could be reduced to 1.4 and 18 μg/L, respectively, by using a TPI-configuration instead of an iLTP. The linearity was equally good for both types of nebulization devices. The final nebulizer could also be operated with a high water content and flow rates higher than those of the two previous ones, indicating an important improvement step.

Comparing energy and exergy of multiple effect freeze desalination to MEE MSF RO

Freeze desalination is a promising technique for wastewater treatment and zero/minimum liquid discharge systems, often requiring multiple stages to produce potable water. This research focuses on developing a Multiple Effect Freeze Desalination (MEFD) system based on experimental data for Single-Stage Desalination Efficiency (SSDE) and Single-Stage Recovery Rate (SSRR). The study analyzes various MEFD setups, calculating cooling energy consumption and correlating it with electrical usage through the coefficient of performance (COP). Comparisons with Reverse Osmosis (RO), Multi Effect Evaporation (MEE), and Multi-Stage Flashing (MSF) suggest that MEFDs may face challenges in matching RO efficiency but can compete with MEE and MSF within specific operational ranges. Exergy assessments indicate difficulties against even 10-stage MSF systems. Achieving SSDE and SSRR levels above 65% enables MEFDs to rival 10-stage MSF plants in terms of energy efficiency, surpassing MEE and MSF at over 85% efficiency. Despite these challenges, MEFDs offer benefits for treating high salt concentrations and resisting corrosion.