Evaporation Kinetics Research Articles

Fixative effect of 2‐oxo‐2‐phenylacetates in fine fragrance and eau‐de‐toilette applications

AbstractThe evaporation of fragrances with volatilities spanning over several orders of magnitude results in a shift of the olfactive impression of a perfume over time. Fixatives have repeatedly been used to slow fragrance evaporation in multiple perfumery applications. We developed a simple and reliable method to measure the evaporation kinetics of individual fragrances in a model perfume and analysed the fixative effect of 2‐oxo‐2‐phenylacetates (α‐ketoesters) on perfume evaporation. 2‐Oxo‐2‐phenylacetates, some of which have been described as light‐sensitive profragrances, are commercially available or readily prepared by esterification or transesterification of commercial starting materials. (−)‐Menthyl 2‐oxo‐2‐phenylacetate afforded single crystals that were suitable for X‐ray crystal structure analysis. 2‐Oxo‐2‐phenylacetates were found to have a fixative effect on the evaporation of fragrances with volatilities below 5000 μg L−1 in fine fragrance and eau‐de‐toilette applications. The molecular structure of the compound rather than its molecular weight had an impact on the fixative effect to some extent.

Drying behaviour of nanofluid sessile droplets on self-affine vis-à-vis corrugated nanorough surfaces.

In recent years, evaporative self-assembly of sessile droplets has gained considerable attention owing to its wide applicability in many areas. While the phenomenon is well studied for smooth and isotropically rough (self-affine) surfaces, investigations comparing the outcomes on self-affine vis-à-vis corrugated surfaces remains to be done. In this experimental work, we compare the wetting and evaporation dynamics of nano-colloidal microlitre droplets on self-affine and corrugated nanorough surfaces having identical roughnesses and interface properties. The coupled influence of particle size, concentration, and surface structuring has been explored. Differences in wettability and evaporation dynamics are observed, which are explained via the interaction between wetting fluid and anisotropic surface roughness. Our findings exhibit different temporal behaviour of contact radius and angle in the evaporation process of the droplets. Further, the corrugated surface exhibits anisotropic wettability with a monotonic change in droplet shape as evaporation proceeds, finally giving rise to irregular dried patterns. The scaled rim width and crack spacing of the particulate deposits are examined. Our results can inspire fabrication of surfaces that can facilitate direction-dependent droplet motion for specific applications.

Land Cover Control on the Drivers of Evaporation and Sensible Heat Fluxes: An Observation‐Based Synthesis for the Netherlands

AbstractLand cover controls the land‐atmosphere exchange of water and energy through the partitioning of solar energy into latent and sensible heat. Observations over all land cover types at the regional scale are required to study these turbulent flux dynamics over a landscape. Here, we aim to study how the control of daily and midday latent and sensible heat fluxes over different land cover types is distributed along three axes: energy availability, water availability and exchange efficiency. To this end, observations from 19 eddy covariance flux tower sites in the Netherlands, covering six different land cover types located within the same climatic zone, were used in a regression analysis to explain the observed dynamics and find the principle drivers. The resulting relative position of these sites along the three axes suggests that land cover partly explains the variance of daily and midday turbulent fluxes. We found that evaporation dynamics from grassland, peatland swamp and cropland sites could mostly be explained by energy availability. Forest evaporation can mainly be explained by water availability, urban evaporation by water availability and exchange efficiency, and open water evaporation can almost entirely be explained by exchange efficiency. We found that the sensible heat flux is less sensitive to land cover type. This demonstrates that the land‐atmosphere interface plays an active role in the shedding of sensible heat. Our results contribute to a better understanding of the dynamics of evaporation over different land cover types and may help to optimize, and potentially simplify, models to predict evaporation.

Kinetics of indium and indium–tin soldering materials in vacuum volatilization

Vacuum volatilization is a clean and efficient method for metal purification, alloy separation, and comprehensive recovery of secondary resources. The evaporation kinetics of In and In–Sn alloys were investigated to better understand the evaporation mechanism during the vacuum volatilization of In. The evaporation rates of the In and In–Sn alloys at 1173–1373 K and 5 Pa increased significantly with increasing temperature in accordance with the equation ω = e(a+b∙T). The evaporation rates at 1323 K and 5 Pa decreased with increasing crucible depth in accordance with the equation ω = a2+(a1-a2)/(1+e(h-b)/c). For In and In–Sn, the total mass-transfer coefficients of In were obtained at different temperatures and crucible depths. A theoretical kinetic model of In was established and limiting links were obtained vacuum volatilization of In and In–Sn.

Three-dimensional Numerical Simulations of a Liquid RP-2/O[formula omitted] based Rotating Detonation Engine

Rotating detonation engines (RDEs) offer increased thermal efficiencies and continuous thrust in a compact design. While non-premixed RDEs, where fuel and oxidizer are injected into the combustor through separate streams, have been extensively studied through experiments and numerical simulations, practical realizations of this technology mandate the use of the liquid fuels that power propulsion devices today. As a result, the strength and stability of the detonation wave are heavily influenced by not only the injection scheme but also the quality of the fuel mixture prepared for detonation. This mixture is a product of the dispersion and evaporation dynamics of liquid droplets in the presence of propagating detonation waves. To this end, the multiphase RDE system is investigated through high-fidelity simulations of a rocket-type RDE (RDRE) with liquid RP-2 fuel and gaseous oxygen. The Eulerian-Lagrangian compressible flow solver developed here provides detailed insight into the physical mechanisms important in a multiphase environment. A series of simulations are employed to understand both the droplet dynamics and mechanisms that lead to stable multiphase detonations and their resulting detonation structure. The interaction of the oxidizer injector, liquid droplets, and the detonation wave is discussed extensively. The injector dynamics lead to variations in droplet motion, where the injector recovery process enforces recirculation zones. Most importantly, the penetration of the injected droplets is crucial in their ability to evaporate; the lack thereof can quench detonation and result in a chaotic, deflagration-like mode. The injection scheme is crucial in the dispersion and evaporation of liquid droplets and the formation of detonable mixtures, perhaps more so than in gas-phase systems. The simulations provide detailed insight into the design of liquid-fueled RDE systems.

Experimental Investigation and Modeling: Considerations of Simultaneous Surface Steel Droplets’ Evaporation and Corrosion

The present work focuses on the problem of steel surface corrosion as a kinetic expression when water droplets are repeatedly deposited and evaporated on/from its surface. This process, together with the rainwater film corrosion process, belongs to the theoretical foundations of the problem of atmospheric corrosion. It was considered that the formation of water droplets on surfaces is a random but repetitive process, as well as the fact that experimental and theoretical observations show that the droplet corrosion front of a metal surface is located in its zone circumference. We thus aimed to establish how the corrosion process evolves on a steel plate when many drops are deposited and removed repeatedly. An experimental setup and working procedure were used to obtain data characterizing the simultaneous process of steel surface corrosion and water droplet evaporation. For natural convection conditions with a variable relative humidity and temperature environment, an extensive data set consisting of the dynamics of individual droplet evaporation coupled simultaneously with the corrosion of the steel surface under the droplet was obtained. The mathematical models for evaporation and corrosion under the droplet have the same dynamic transfer surface for water evaporation and oxygen supply in the droplet. An approach for determining this surface depending on the momentary droplet mass was considered. Several simultaneous measurements of evaporation–corrosion dynamics were used to calibrate the coupled models, which were then used to show their compatibility with experimental data.

From waste to value: Characterization of recycled cellulose acetate for sustainable waste management

Cellulose acetate (CA) is a versatile polymer with various industrial applications, but its recycling process is still far from diffuse adoption. In this study, the purification of CA was confirmed through FTIR analysis, which exhibited characteristic peaks corresponding to cellulose molecules and acetylation. The rheological behavior of regenerated CA demonstrated shear thinning properties, making it suitable for applications requiring viscosity reduction under shear. Oscillation strain and frequency sweep tests revealed the formation of a gel-like network structure in CA solutions due to extensive hydrogen-bonding networks between water and acetone. The evaporation kinetics of acetone from CA films were found to be temperature and thickness-dependent, exhibiting both Fickian and non-Fickian diffusion mechanisms. The diffusion coefficient of acetone in CA films was determined and correlated with film porosity. Mechanical testing indicated comparable strain at rupture and ultimate strength between recycled and commercial CA, while a limited reduction was observed for the elastic modulus. These findings suggest potential applications of recycled CA in packaging and textile sectors, highlighting the importance of further research in optimizing its properties for specific industry requirements.

Validating coupled flow theory for bare‐soil evaporation under different boundary conditions

AbstractEvaporation from bare soil is an important hydrological process and part of the water and energy balance of terrestrial systems. Modeling bare‐soil evaporation is challenging, mainly due to nonlinear couplings among liquid water, water vapor, and heat fluxes. Model concepts of varying complexity have been proposed for predicting evaporative water and energy fluxes. Our aim was to test a standard model of coupled water, vapor, and heat flow in the soil using data from laboratory evaporation experiments under different boundary conditions. We conducted evaporation experiments with a sand and a silt loam soil and with three different atmospheric boundary conditions: (i) wind, (ii) wind and short‐wave radiation, and (iii) wind and intermittent short‐wave radiation. The packed soil columns were closed at the bottom (no water flux) and instrumented with temperature sensors, tensiometers, and relative humidity probes. We simulated the evaporation experiments with a coupled water, vapor, and heat flow model, which solves the surface energy balance and predicts the evaporation rate. The evaporation dynamics were predicted very well, in particular the onset of stage‐two evaporation and the evaporation rates during the stage. A continuous slow decrease of the measured evaporation rate during stage‐one could not be described with a constant aerodynamic resistance. Adding established soil resistance parametrizations to the model significantly degraded model performance. The use of a boundary‐layer resistance, which takes into account the effect of point sources of moisture, improved the prediction of evaporation rates for the sandy soil, but not for the silt loam.

Vacuum drying of cherry varieties Lyazat, Merey and Aigerim growing in the southern regions of RK

This article presents the results of vacuum drying of cherry varieties: Lyazat, Merey and Aigerim. The dynamics of moisture evaporation shows that the largest amount of moisture evaporates in the time interval from the beginning to 4.0 hours of drying time. For example, in the Aigerim sweet cherry variety, in the considered period of time, for each hour of drying time, depending on the sweet cherry variety, an average of 3.21 g of moisture, and over the next drying time, the intensity of moisture evaporation monotonously decreases of 3,21 g to 1.5 g.Upon reaching the critical humidity in the product of evaporation, moisture drops sharply of 1.5 g to 0.75 g and below. Similar results with slight differences in moisture evaporation are observed for other varieties of cherries. Slight differences in the nature of moisture evaporation in the considered varieties of cherries are explained by the chemical composition, the form of moisture bonding in the product. Studies have established that when drying cherries, two periods of drying are observed. The duration of the first drying period for all studied varieties of cherries averages 6.10...6.25 hours, and the second period 4.50...4.35 hours. The critical humidity for all considered sweet cherry varieties aver-ages 30.5 ... 30.7%.The obtained experimental data on the kinetics of moisture evaporation and the curve of the drying rate of cherries at the next stage of the study make it possible to choose the optimal modes of their drying.

Self‐Assembled Nanofibrous Hydrogels with Tunable Porous Network for Highly Efficient Solar Desalination in Strong Brine

AbstractHydrogel‐based solar evaporators (HSEs) emerged as energy‐efficient designs for water purification due to the reduced vaporization enthalpy in the hydrated polymeric network. However, it remains challenging for HSEs to achieve stable performance in desalination, partly due to the tradeoff between desired evaporation dynamics and salt tolerance. Here, composite hydrogels with tunable self‐assembled nanofiber networks are exploited for the engineering of solar evaporators with both high evaporation performance and resistance to salt accumulation. The nanofibrous hydrogel solar evaporators (NHSEs) present an intrinsic open network with high porosity, above 90%, enabling continuous water channels for efficient mass transfer. Theoretical modeling captures the complex nexus between microstructures and evaporation performance by coupling water transfer, thermal conduction, and vaporization enthalpy during evaporation. The mechanistic understanding and engineering tuning of the composites lead to an optimum configuration of NHSEs, which demonstrate a stable evaporation rate of 2.85 kg m−2 h−1 during continuous desalination in 20% brine. The outstanding performance of NHSEs and the underlying design principles may facilitate further development of practical desalination systems.

Low-cost debris deorbiting plus planetary protection

Space debris can be deorbited by a coating of volatile material that evaporates in sunlight. Consider a roque CubeSat that gets splashed with black gel while on the night side of its orbit. As it emerges into the rays of the Sun, kinetic evaporation provides a retro force relative to the orbital velocity, causing speed to diminish. At midpoint of orbital dayside, the net force is downward, towards the Earth’s atmosphere, where drag increases. If sufficient gel remains unevaporated during the transition back to nightside, there could be acceleration, but the dose of gel is limited to avoid this. Gel balls can be delivered from a standoff distance such that orbital matching need not be perfect, saving time and fuel for the debris-hunter. Larger chunks of debris can be shot with multiple gel balls designed that rupture and wet the surface, similar to a paint marking capsule (“paintball”), to provide more retroforce. For very large objects, such as earth orbit-crossing asteroids, judicious application of volatile material can provide a net force away from the Sun, altering the trajectory sufficiently to avoid impact. This work considers the velocity distribution in a liquid assuming the Maxwell-Boltzmann equation, the vapor pressure using the Clausius-Clapeyron equation, and the evaporative flux using the explicit Schrage equation to model vapor kinetics from the Knudsen layer under direct solar irradiation. A concept of operations for a notional debris-hunter satellite design allows an estimate of debris mass that can be deorbited in a given period of time. From this, and an estimate of launch mass, the number and mass of space junk that can be removed from a higher low-earth orbit (LEO) can be calculated. These expenses are sufficiently smaller than the consequence of a Kessler syndrome to compel spacefaring nations to implement this proactive approach without delay.

Conditions of enhanced evaporation for nanofluids droplet and inhibition of coffee-ring effect under buoyancy and Marangoni convection

Evaporation of nanofluid droplets whose size is larger than capillary length is common in industrial processes, but there is currently a lack of research on the evaporation kinetics and more complex deposition patterns under the combined effects of buoyancy and Marangoni convection of large evaporating droplet. Experimental investigations on evaporation of Al2O3H2O nanofluid sessile droplet with initial contact line diameter of 4 mm on heating PTFE coating substrate are reported. The variation in contact angle, contact radius, and droplet volume over time under different conditions were obtained through experiments. The average evaporation rate is calculated. Internal flow characteristics are inferred through the surface temperature distribution detected by the top view infrared camera. The constant contact radius mode takes place at the beginning of evaporation. Then mixed evaporation mode and stick slip mode may occur for different substrate temperature, nanoparticle mass concentration and nanoparticle size. Increasing nanoparticle size causes a decrease in average evaporation rate. Whether the use of nanofluids can improve evaporation rate and heat transfer or not depends on multiple factors. Convection cells exist, and three kinds of deposition patterns are formed due to the underlying coupled transport phenomena. Under the combined effect of buoyancy and Marangoni convection in this article, the most common coffee-ring pattern does not appear. The deposition patterns are directly affected by the pinning stability, which decrease at higher temperature.

Thermodynamic and kinetic analyses and experimental verification of tellurium and bismuth recovery from bismuth telluride waste by selective sulfidation-vacuum volatilization

The recovery of tellurium and bismuth from bismuth telluride waste is of great significance in improving the utilization levels of renewable resources, protecting the ecological environment and alleviating the problem of resource shortages. In this paper, tellurium and bismuth were recovered from bismuth telluride waste by selective sulfidation–vacuum volatilization. The Gibbs free energy, phase diagram and thermodynamic equilibrium diagram for the core reaction were calculated and analyzed to determine the possible reactions and the conditions required for the stability of bismuth telluride during the sulfidation process. After calculating the saturated vapor pressures, it was concluded that tellurium and bismuth sulfide could be separated by vacuum volatilization. The thermogravimetric analyses and differential scanning calorimetry were then used to analyze the reaction between bismuth telluride and sulfur. The results indicated that the temperature range for the sulfidation reaction should be 491–620 K. The volatilization temperature of tellurium should be greater than 695 K. The evaporation kinetics for tellurium and bismuth sulfide showed that the evaporation rate of tellurium was much higher than that of bismuth sulfide. Furthermore, experiments were conducted to verify the reliability of the theoretical analysis, and these were in good agreement with the thermodynamic and kinetic results. The direct yields of tellurium and bismuth were 99.65% and 99.49%, respectively. These results confirmed that the selective sulfidation-vacuum volatilization method is a feasible alternative for recovery of tellurium and bismuth from bismuth telluride waste.

Influence of Growth Time and Temperature on Optical Characteristics and Surface Wetting in Nano-Crystalline Graphene Deposited by PECVD Directly on Silicon Dioxide

Unique electronic properties of graphene offer highly interesting ways to manipulate the functional properties of surfaces and develop novel structures which are sensitive to physical and chemical interactions. Nano-crystalline graphene is frequently preferable to crystalline monolayer in detecting devices. In this work, nano-crystalline graphene layers were synthesized directly on SiO2/Si substrates by plasma-enhanced chemical vapour deposition (PECVD). The influence of the deposition time and temperature on the characteristics of the structures were studied. The optical properties and evaporation kinetics of pure water droplets were analysed, along with arrangement and composition of the grown layers. The nano-crystalline graphene layers grown at 500 °C were characterised by the refraction index 2.75 ± 0.35 and the normalised excess Gibbs free energy density 0.85/γwater 10−4 m, both being similar to those of the monolayer graphene. The changes in the refraction index and the excess Gibbs free energy were related to the parameters of the Raman spectra and a correlation with the technological variables were disclosed.

Incorporating Plant Access to Groundwater in Existing Global, Satellite‐Based Evaporation Estimates

AbstractGroundwater is an important water source for evaporation, especially during dry conditions. Despite this recognition, plant access to groundwater is often neglected in global evaporation models. This study proposes a new, conceptual approach to incorporate plant access to groundwater in existing global evaporation models, and analyses the groundwater contribution to evaporation globally. To this end, the Global Land Evaporation Amsterdam Model (GLEAM) is used. The new GLEAM‐Hydro model relies on the linear reservoir assumption for modeling groundwater flow, and introduces a transpiration partitioning approach to estimate groundwater contributions. Model estimates are validated globally against field observations of evaporation, soil moisture, discharge and groundwater level for the time period 2015–2021, and compared to a regional groundwater model. Representing groundwater access influences evaporation in 22% of the continental surface. Globally averaged, evaporation increases by 2.5 mm year−1 (0.5% of terrestrial evaporation), but locally, evaporation can increase up to 245.2 mm year−1 (149.7%). The groundwater contribution to transpiration is highest for tall vegetation under dry conditions due to more frequent groundwater access. The temporal dynamics of the simulated evaporation improve across 75% of the stations where groundwater is a relevant water source. The skill of the model for variables such as soil moisture and runoff remains similar to GLEAM v3. The proposed approach enables a more realistic process representation of evaporation under water‐limited conditions in satellite‐data driven models such as GLEAM, and sets the ground to assimilate satellite gravimetry data in the future.

Chemically Resolved Evaporation Dynamics of Dicarboxylic Acid Mixtures in Solid Particles.

The evaporation rate and corresponding vapor pressure of dicarboxylic acids have been the subject of numerous scientific studies over the years, with reported values spanning several orders of magnitude. Recent work has identified the importance of considering the phase state of the material during evaporation, likely accounting for some of the variability in measured vapor pressures. In the homologous series of dicarboxylic acids, the phase state under dry conditions may be crystalline or amorphous, with particles of odd-carbon-numbered acids exhibiting tendencies to remain amorphous and spherical. Although measurements of vapor pressures for pure components make up most of the available literature data, for many applications, these compounds are not present in isolation. Additionally, many systems containing a semi-volatile material exist in a solid state, especially under dry and low relative humidity conditions. In this work, we explore the evaporation of compounds present in mixed solid-state particles. Specifically, we use single particle levitation coupled with mass spectrometry to measure the evolving composition of solid particles containing mixtures of glutaric acid and succinic acid, glutaric acid and adipic acid, and malonic acid and succinic acid. Under dry conditions, these systems exhibit non-spherical geometries consistent with crystallization of one or both components into an organic crystal. Our measurements allow the evaporation of each component in the mixture to be characterized independently and effective vapor pressures of the pure components to be inferred. The resulting vapor pressures are compared against pure component vapor pressures. We demonstrate that these mixtures exhibit thermodynamic ideality but can be influenced by limited diffusion in the solid phase. These are the first results in the literature that explore the thermodynamic and kinetic factors that control the evaporative evolution of mixed solid-state particles.

Understanding the Role of Removable Solid Additives: Selective Interaction Contributes to Vertical Component Distributions.

Sequentially deposited organic solar cells (SD-OSCs) have attracted great attention owing to their ability in achieving a more favorable, vertically phase-separated morphology to avoid the accumulation of counter charges at absorber/transporting layer interfaces. However, the processing of SD-OSCs is still quite challenging in preventing the penetration of small-molecule acceptors into the polymer donor layer via erosion or swelling. Herein, solid additives (SAs) with varied electrostatic potential distributions and steric hinderance are introduced into SD-OSCs to investigate the effect of evaporation dynamics and selective interaction on vertical component distribution. Multiple modelings indicate that the π-π interaction dominates the interactions between aromatic SAs and active layer components. Among them, p-dibromobenzene shows a stronger interaction with the donor while 2-chloronaphthalene (2-CN) interacts more preferably with acceptor. Combining the depth-dependent morphological study aided by multiple X-ray scattering methods, it is concluded that the evaporation of SAs can drive the stronger-interaction component upward to the surface, while having minor impact on the overall molecular packing. Ultimately, the 2-CN-treated devices with reduced acceptor concentration at the bottom surface deliver a high power conversion efficiency of 19.2%, demonstrating the effectiveness of applying selective interactions to improve the vertical morphology of OSCs by using SAs with proper structure.

Advancing Nanofiber Research: Assessing Nonsolvent Contributions to Structure Using Coaxial Electrospinning.

In this study, we explored the influence of molecular interactions and solvent evaporation kinetics on the formation of porous structures in electrospun nanofibers, utilizing polyacrylonitrile (PAN) and polystyrene (PS) as model polymers. The coaxial electrospinning technique was employed to control the injection of water and ethylene glycol (EG) as nonsolvents into polymer jets, demonstrating its potential as a powerful tool for manipulating phase separation processes and fabricating nanofibers with tailored properties. Our findings highlighted the critical role of intermolecular interactions between nonsolvents and polymers in governing phase separation and porous structure formation. Additionally, we observed that the size and polarity of nonsolvent molecules affected the phase separation process. Furthermore, solvent evaporation kinetics were found to significantly impact phase separation, as evidenced by less distinct porous structures when using a rapidly evaporating solvent like tetrahydrofuran (THF) instead of dimethylformamide (DMF). This work offers valuable insights into the intricate relationship between molecular interactions and solvent evaporation kinetics during electrospinning, providing guidance for researchers developing porous nanofibers with specific characteristics for various applications, including filtration, drug delivery, and tissue engineering.

Transport phenomena and dynamics of an evaporating water meniscus at low heat fluxes

It is known that evaporation efficiency of novel solar thermal vapor generation/desalination systems can potentially increase by incorporating interfacial heat localization techniques utilizing porous wicks. The ensuing efficiency is a strong function of the geometric and thermal properties of the wicks and the ambient operating parameters. We investigate the role of these critical process parameters on the evaporation dynamics of pure and saline water from a single-layered wire mesh operating at low heat fluxes (1 kW/m2, 5 kW/m2and 10 kW/m2), which are typical for devices working on solar energy. Evaporation rates of water from stainless steel and nylon meshes are determined using non-invasive infra-red thermography and digital microscopy. A finite element based computational model is developed to understand local transient evaporation phenomenon at the microscale. Arbitrary Lagrangian-Eulerian (ALE) formulation is used to solve the coupled transport equations on a deforming computational grid, incorporating the Fick's law of diffusion at the evaporating water-air interface. With increasing heat fluxes, there is a deviation from purely diffusion-based transport. Higher evaporation rates are observed in meshes with smaller wire diameter and higher thermal diffusivity. In addition, the decisive role of local thin capillary films is exemplified. Simulations also indicate the diminutive role of thermocapillary convection during evaporation at such low input heat fluxes. Finally, we also investigate the effect of mesh size on the nature of salt crystallization. The evolution of salt concentration gradient at the microscale is computed that complements the experimental observations. Optimal exploitation of heat localization technique for enhanced evaporation necessitates understanding of microscale mesh level local transport effects.

Evaporation kinetics and quality attributes of grape juice concentrate as affected by microwave and vacuum processing

ABSTRACT In this study, grape juice was concentrated through a microwave vacuum-assisted technique. The concentrate was prepared at different powers (30, 50, 80 W) and vacuum pressures (35, 50, 70 kPa) for different time intervals to optimize the processing conditions. The highest evaporation rate (5.32 g/100 g min) and the lowest moisture ratio (0.18) were observed at a higher level of microwave power (80 W) and vacuum pressure (70 kPa). Moreover, different mechanistic models were used to predict the values of the moisture ratio. Among them, the Midilli (R2 = 0.999, SSE = 1.970 × 10−8, RPD = 0.012%) model best fits the experimental values. The effective diffusivity (1.69 × 10−14 m2/s), activation energy (1.56 W/kg), and extraction yield (69.30%) possessed maximum values at 80 W and 70 KPa. While concentrate had exhibited higher antioxidant activities (77.2%) than fresh juice (25.28%) at 30 W. Overall results indicated that the microwave-vacuum technique had significantly reduced the processing time and energy requirement.