SummaryIn wireless power transfer (WPT) systems, extended transmission distances significantly impede efficiency, posing a major challenge to their practical application. This paper presents a novel ortho‐octagonal double‐helix metamaterial that can effectively enhance the transmission efficiency of WPT systems. It has theoretically derived and experimentally verified the enhancement of evanescent wave transmission by this metamaterial dielectric plate. A WPT simulation system operating at 10.78 MHz is constructed by HFSS software, and the effects of adding passive relay coils and different shapes of metamaterials on the transmission efficiency are comparatively investigated. Simulated data converge to indicate that integrating variously shaped metamaterials at the transceiver's end distinctly elevates the WPT system's transmission efficiency. When the transceiver coil spacing of the WPT system is greater than 22 cm, the effect of metamaterials on the system transmission efficiency enhancement shows an increasing and then decreasing trend as the distance increases. The positive octagonal metamaterial improves 12% over the circular metamaterial in the mid‐range transmission distance due to its better magnetic coupling effect. When the transceiver coil spacing is 22 cm, the open‐circuit voltage of the receiving coil after loading the metamaterial is stabilized to be enhanced by nearly five times, and it has the best effect at 30 cm, and the transmission efficiency is enhanced from 30% to 60%, which verifies the effective enhancement of the metamaterial on the transmission efficiency of the WPT system.