Abstract Precipitable Water Vapor (PWV) is crucial for weather forecasting and climate change research. However, accurate PWV estimation is challenging, especially in the absence of measured meteorological data. In this study, we develop a conversion model based on the random forest algorithm, called RPWV, which can directly derive PWV from zenith total delay (ZTD) without measured meteorological data. The results indicate that the RPWV model demonstrates high accuracy and reliability for PWV retrieval across North America. Specifically, using global navigation satellite system (GNSS) PWV as a reference, the bias and root mean square (RMS) values for RPWV are 0.01 mm and 1.87 mm, respectively. Moreover, compared with the conventional linear model and backpropagation neural network model, the accuracy of the RPWV is improved by 81.3% and 13.4%, respectively. In contrast to radiosonde (RS) PWV, the bias and RMS values of the RPWV are 1.85 mm and 3.40 mm, respectively. This model provides a straightforward and efficient method for estimating PWV and has potential for weather forecasting and climate research in environments where meteorological data is scarce.
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