Lightweight porous concrete (LPC) typically exhibits low early strength, which can be addressed by enhancing early strength through carbon dioxide (CO2) mineralization curing while achieving permanent CO2 sequestration. The efficacy of this process relies on maintaining optimal moisture levels. This study investigates the influence of moisture content on the performance of solid waste-based lightweight porous concrete blocks (RSFAC) subjected to microwave heating pretreatment. Moisture levels were adjusted to 10%, 20%, 30%, and 40% (initial water-to-cement ratio of 45.4%) before undergoing mineralization curing within an environment set at a temperature of 20 °C, relative humidity 75%, and a CO2 concentration of 40% for a duration of 0.5 h. The impact of moisture content on RSFAC's compressive strength, carbon sequestration rate, mineralization products, and microstructure was evaluated. Results indicate that compared to conventional oven pretreatment methods requiring nearly 10 h, microwave pretreatment technology achieves equivalent water content within just 50 min, significantly reducing the time needed for mineralization pretreatment. RSFAC, when pretreated with microwave heating, outperforms untreated samples (Ref-0 and Ref-1) in terms of compressive strength and carbon sequestration efficiency. Optimal performance was observed at a moisture content level of 30%, with the highest recorded compressive strength achieved at 1, 3, and 7 d respectively. At the curing age of 7 d, the compressive strength reached up to 2.32 MPa while the carbon sequestration rate reached approximately 11.61%. Furthermore, aragonite and calcite (tetrahedral and hexahedral), without poorly crystalline spherulites, were identified as the main crystalline CaCO3 generated by RSFAC under this specific moisture content condition; pores larger than 50 nm served as primary reaction sites for RSFAC mineralization curing, whereas there was a significant increase in pore proportion with sizes less than 20 nm after filling with mineralization products.