In this study, the AC impedance responses of concrete with different microstructures and water contents at elevated temperatures are examined. First, an equivalent circuit model of concrete is proposed. The simulation results of the equivalent circuit are in good agreement with the AC impedance spectrum. Then, semi-infinite, infinite, and barrier diffusion modes of water diffusion within concrete are proposed. The quantitative relationships between AC impedance parameters and moisture content of concrete are established. Finally, the equivalent porosity and thermal damage are characterized using AC impedance parameters. Both show linear relation with the total porosity obtained experimentally by porosity tests. Therefore, AC impedance spectroscopy can quantitatively characterize the internal microstructure and moisture content evolution, and further reveal the mechanism of the macro performance of concrete.
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