Equatorial Maximum Research Articles

Influence of Orbital Forcing on the Snowball Earth Deglaciation

AbstractNeoproterozoic snowball Earth events lasted for multiple million years, experiencing many orbital cycles. Here we investigate whether the deglaciation of these events would be triggered more easily at certain orbital configurations than others, by using an atmosphere‐land model that considers meltpond formation on land ice. Results show that the threshold concentration of atmospheric CO2 (pCO2) required for deglaciation can vary from 6 to 10 × 104 ppmv under different orbital forcings. The threshold pCO2 decreases with the equatorial maximum monthly insolation (EMMI), which is affected most by the eccentricity and secondarily by obliquity. Therefore, we conclude that the snowball Earth deglaciation likely occurred when the eccentricity was high and obliquity was low. Compared to previous estimate that used present‐day orbital configuration which has a minimal eccentricity, the duration of snowball Earth events would likely be much shorter when the influence of orbital variations are considered.

Latituditual Structure of Dayside Polar Cusp Precipitation

The results of observations of low-altitude spacecraft crossing the daytime sector of the auroral zone and of high-apogee spacecraft in the equatorial plane of the magnetosphere were analyzed in order to identify the main processes leading to the formation of dayside polar cusps. Observations from the DMSP F7 spacecraft were used to analyze the latitudinal characteristics of ion precipitation in the cusp region and to study the latitudinal profile of ion pressure in the cusp depending on the IMF parameters. A significant difference was found in identifying the cusp boundaries using an automated data processing system and direct analysis of spacecraft observations. It is shown that for small negative values of the Bz-component of the IMF (〈Bz〉 = –3.0 nT), an ordinary feature of the cusp is the latitudinal profile of the ion pressure (Pi) with a width of ~1° of latitude with two maxima, one of which is located in the equatorward and the other in the poleward of the cusp. For large negative Bz values (–6, –8 nT), the polar maximum in the latitudinal profile Pi disappears; only the equatorial maximum remains, the Pi level at the maximum increases, and the width of the cusp decreases to ~0.7°. For Bz IMF 0, the most characteristic is the Pi profile with a maximum ion pressure in the polar part of the cusp. The cusp for Bz 0 is located at higher latitudes than for Bz 0, and its average latitudinal width increase to ~1.4° of latitude. In the prenoon sector MLT, the most typical for periods with a large negative By-component of the IMF (〈By〉 = –6.3 nT, 〈Bz〉 = –1.7 nT) is a cusp with a width of ~1.4° of latitude with a flat top in the latitudinal Pi profile. Comparison of the pressure distributions observed at low heights with data from high-apogee satellites confirmed the possibility of describing the formation of the cusp as a diamagnetic cavity and using observations in the cusp to determine the ion pressure in the magnetosheath.

Contributions to Loss Across the Magnetopause During an Electron Dropout Event.

Dropout events are dramatic decreases in radiation belt electron populations that can occur in as little as 30 minutes. Loss to magnetopause due to a combination of magnetopause shadowing and outward radial transport plays a significant role in these events. We examine the dropout of relativistic electron populations during the October 2012 geomagnetic storm using simulated electron phase space density, evaluating the contribution of different processes to losses across the magnetopause. We compare loss contribution from outward transport calculated using a standard empirical radial diffusion model that assumes a dipolar geomagnetic field to an event-specific radial diffusion model evaluated with a non-dipolar geomagnetic field. We additionally evaluate the contribution of Shabansky type 1 particles, which bounce along magnetic field lines with local equatorial maxima, to the loss calculated during this event. We find that the empirical radial diffusion model with a dipolar background field underestimates the contribution of radial diffusion to this dropout event by up to 10% when compared to the event-specific, non-dipolar radial diffusion model. We additionally find that including Shabansky type 1 particles in the initial electron phase space density, that is, allowing some magnetic field lines distorted from the typical single-minima configuration in drift shell construction, increases the calculated loss by an average of 0.75%. This shows that the treatment of the geomagnetic field significantly impacts the calculation of electron losses to the magnetopause during dropout events, with the non-dipolar treatment of radial diffusion being essential to accurately quantify the loss of outer radiation belt populations.

On the Speciation of Iodine in Marine Aerosol.

We have compiled and analyzed a comprehensive data set of field observations of iodine speciation in marine aerosol. The soluble iodine content of fine aerosol (PM1) is dominated by soluble organic iodine (SOI; ∼50%) and iodide (∼30%), while the coarse fraction is dominated by iodate (∼50%), with nonnegligible amounts of iodide (∼20%). The SOI fraction shows an equatorial maximum and minima coinciding with the ocean “deserts,” which suggests a link between soluble iodine speciation in aerosol and ocean productivity. Among the major aerosol ions, organic anions and non‐sea‐salt sulfate show positive correlations with SOI in PM1. Alkali cations are positively correlated to iodate and negatively correlated with SOI and iodide in coarse aerosol. These relationships suggest that under acidic conditions iodate is reduced to HOI, which reacts with organic matter to form SOI, a possible source of iodide. In less acidic sea‐salt or dust‐rich coarse aerosols, HOI oxidation to iodate and reaction with organic matter likely compete.

Correlation between the carbon isotopic composition of planktonic foraminifera-bound organic matter and surface water pCO2 across the equatorial Pacific

For times prior to those represented by the air trapped in Antarctic ice core records, the concentration of CO2 in the atmosphere must be reconstructed using geochemical proxies. The δ13C of particulate organic carbon (POC) produced in ocean surface waters has previously been observed to covary with the concentration of CO2 in the water. Relative to bulk sedimentary organic carbon, the minute quantity of organic matter trapped within the shell walls of planktonic foraminifera, “foraminifera-bound organic matter” (FBOM), has the potential advantage of being protected from diagenetic alteration and contamination by allochthonous organic matter. Here, with new protocols and instrumentation, FBOM-δ13C is investigated as a potential proxy for the aqueous CO2 concentration ([CO2(aq)]) and thus the partial pressure of CO2 (pCO2) in past surface waters. We achieve a full method precision for FBOM-δ13C of 0.4‰ (1SD) on sample sizes of 20 nanomole C by adding a cryofocus step, a helium sheath flow to the oxidation and reduction reactors, and other modifications to an elemental analyzer and by introducing new approaches to reduce contamination during sample preparation. FBOM-δ13C was analyzed in core-top sediments from the eastern tropical Pacific that span the equatorial maximum in surface water [CO2(aq)]. FBOM-δ13C is lower than predicted for marine phytoplankton, consistent with a substantial lipid component in FBOM. Anticorrelation is observed between FBOM-δ13C and climatological [CO2(aq)]; the relationship is statistically significant (P <0.05) in mixed-species samples and in 4 out of 5 picked species. The slope of the FBOM-δ13C:[CO2(aq)] anticorrelation is equivalent to or greater than has been measured for the δ13C of suspended POC in the surface ocean. Based on the few species analyzed in this study, endosymbiont-bearing and -barren species do not clearly differ from each other either in terms of their average value of FBOM-δ13C or the strength of the FBOM-δ13C:[CO2(aq)] anticorrelation, despite the recognized importance of the photosynthetic endosymbionts as a source of organic carbon for the symbiotic species. Correcting for variations in the δ13C of CO2(aq) and phytoplankton growth rate did not improve the significance of the FBOM-δ13C:[CO2(aq)] anticorrelation. The findings support the possibility that FBOM-δ13C can be used as a paleoceanographic proxy for surface water [CO2(aq)] and thus atmospheric pCO2.

Measuring the Ocular Morphological Parameters of Guinea Pig Eye with Edge Detection and Curve Fitting.

Aim To identify the guinea pig eyeball with edge detection and curve fitting and devise a noncontact technology of measuring ocular morphological parameters of small experimental animal. Methods Thirty-nine eyeballs of guinea pig eyeballs were photographed to obtain the anterior and posterior surface; transverse and sagittal planes after the eyeballs were eviscerated. Next, the eyeball photos were input into digital image analysis software; the corresponding photo pixels-actual length ratio was acquired by a proportional scale. The contour lines of the eyeballs were identified by edge detection technology; conic curve fitting was applied to fit the contour line of the eyeball. The maximum and minimum diameters, the horizontal and vertical diameters, eccentricity, tilt angle, cross-sectional area, equatorial circumference, retrobulbar equatorial maximum length, corneal radius of curvature (CRC) in central region, and the whole cornea were calculated according to the geometric principles. The corneal data of in vitro study were compared with the in vivo results. Results The contour line of the selected guinea pig eye was identified correctly by edge detection. There were no significant differences between anterior and posterior surfaces of one eyeball in the maximum diameters, eccentricity, cross-sectional area, equatorial circumference, and tilt angle (P > 0.01). There were significant differences of eccentricity and CRC between central region and the whole cornea (P < 0.01). There were no significant differences between keratometer in vivo and cornea in vitro. Conclusion It was feasible to measure an experimental animal eye in a noncontact way. Edge detection and curve fitting technology could accurately evaluate the ocular morphological parameters.

Representation of the equatorial stratopause semiannual oscillation in global atmospheric reanalyses

Abstract. This paper reports on a project to compare the representation of the semiannual oscillation (SAO) in the equatorial stratosphere and lower mesosphere within six major global atmospheric reanalysis datasets and with recent satellite Sounding of the Atmosphere Using Broadband Emission Radiometry (SABER) and Microwave Limb Sounder (MLS) observations. All reanalyses have a good representation of the quasi-biennial oscillation (QBO) in the equatorial lower and middle stratosphere and each displays a clear SAO centered near the stratopause. However, the differences among reanalyses are much more substantial in the SAO region than in the QBO-dominated region. The degree of disagreement among the reanalyses is characterized by the standard deviation (SD) of the monthly mean zonal wind and temperature; this depends on latitude, longitude, height, and time. The zonal wind SD displays a prominent equatorial maximum that increases with height, while the temperature SD reaches a minimum near the Equator and is largest in the polar regions. Along the Equator, the zonal wind SD is smallest around the longitude of Singapore, where consistently high-quality near-equatorial radiosonde observations are available. Interestingly, the near-Singapore minimum in SD is evident to at least ∼3 hPa, i.e., considerably higher than the usual ∼10 hPa ceiling for in situ radiosonde observations. Our measurement of the agreement among the reanalyses shows systematic improvement over the period considered (1980–2016), up to near the stratopause. Characteristics of the SAO at 1 hPa, such as its detailed time variation and the displacement off the Equator of the zonal wind SAO amplitude maximum, differ significantly among the reanalyses. Disagreement among the reanalyses becomes still greater above 1 hPa. One of the reanalyses in our study also has a version produced without assimilating satellite observations, and a comparison of the SAO in these two versions demonstrates the very great importance of satellite-derived temperatures in the realistic analysis of the tropical upper stratospheric circulation.

INFLUENCE OF NON-RADIOGENIC COSMIC HEAT GENERATION IN THE BOWELS OF THE EARTH AND PLANETS ON MUTUAL DISPLACEMENTS OF PLANETARY SHELLS Article 1. The Earth

We considered the influence of supposed planet non-radiogenic energy source of cosmic (galactic) origin on the process of mutual displacements of planetary shells. We found that the convection configuration in the Earth’s bowels has simultaneously three variants of topology of convective flows (single-cell, double-cell of open and closed types), a one-time existence of which is conditioned by nonuniform in space and time heating the bowels by an energy source of cosmic origin. Movement of masses during convection leads to mutual nutation of shells relative to the Earth’s axis of rotation. Such swings are characteristic of both the outer stone shell and the inner core of the planet. The motions of the shells are probably gravitationally synchronized, and certain resonances exist in these motions. Nutations occur in the certain corridor, which lies in the middle between the superplumes (African and Pacific), which are antipodally located on the equator. The axis, around which the shells are displaced, roughly coincides with the axis of equatorial maximum moment of inertia and passes through superplumes and positive geoidal undulations corresponding to them. Its existence is conditioned by general mantle isostatism, which causes the emergence of heated segments of the stone shell, forming the Earth's figure and the distribution of its rotational moment.

Long-Term Integration of a Global Non-Hydrostatic Atmospheric Model on an Aqua Planet

A global non-hydrostatic atmospheric model, i.e., GRAPES_YY (Global/Regional Assimilation and Prediction System on the Yin–Yang grid), with a semi-implicit semi-Lagrangian (SISL) dynamical core developed on the Yin–Yang grid was coupled with the physical parameterization package of the operational version of GRAPES. A 3.5-yr integration was carried out on an aqua planet to assess the numerical performance of this non-hydrostatic mo-del relative to other models. Specific aspects of precipitation and general circulation under two different sea surface temperature (SST) conditions (CONTROL and FLAT) were analyzed. The CONTROL SST peaked at the equator. The FLAT SST had its maximum gradient at about 20° latitude, giving a broad equatorial SST maximum in the tropics and flat profile approaching the equator. The tropical precipitation showed different propagation features in the CONTROL and FLAT simulations. The CONTROL showed tropical precipitation bands moving eastward with some envelopes of westward convective-scale disturbance. Less organized westward-propagating rainfall cells and bands were seen in the FLAT and the propagation of the tropical wave varied with the SST gradient. The Inter Tropical Convergence Zone (ITCZ), Hadley cell, and westerly jet core were weaker and more poleward as the SST profile flattened from the CONTROL to FLAT. The climatological structures simulated by GRAPES_YY, such as the distribution of precipitation and the large-scale circulation, fell within the bounds from other models. The stronger ITCZ precipitation, accompanied with stronger Hadley cells and convective heating in the CONTROL simulation, may be summed up as a result of stronger parameterized convection and the non-hydrostatic effects in GRAPES_YY. In addition, mechanism of the zonal mean circulation maintaining is analyzed for the different SST patterns referring the transient eddy flux.

Investigating African trace gas sources, vertical transport, and oxidation using IAGOS-CARIBIC measurements between Germany and South Africa between 2009 and 2011

Between March 2009 and March 2011 a commercial airliner equipped with a custom built measurement container (IAGOS-CARIBIC observatory) conducted 13 flights between South Africa and Germany at 10–12 km altitude, traversing the African continent north-south. In-situ measurements of trace gases (CO, CH4, H2O) and aerosol particles indicated that strong surface sources (like biomass burning) and rapid vertical transport combine to generate maximum concentrations in the latitudinal range between 10°N and 10°S coincident with the inter-tropical convergence zone (ITCZ). Pressurized air samples collected during these flights were subsequently analyzed for a suite of trace gases including C2-C8 non-methane hydrocarbons (NMHC) and halocarbons. These shorter-lived trace gases, originating from both natural and anthropogenic sources, also showed near equatorial maxima highlighting the effectiveness of convective transport in this region. Two source apportionment methods were used to investigate the specific sources of NMHC: positive matrix factorization (PMF), which is used for the first time for NMHC analysis in the upper troposphere (UT), and enhancement ratios to CO. Using the PMF method three characteristic airmass types were identified based on the different trace gas concentrations they obtained: biomass burning, fossil fuel emissions, and “background” air. The first two sources were defined with reference to previously reported surface source characterizations, while the term “background” was given to air masses in which the concentration ratios approached that of the lifetime ratios. Comparison of enhancement ratios between NMHC and CO for the subset of air samples that had experienced recent contact with the planetary boundary layer (PBL) to literature values showed that the burning of savanna and tropical forest is likely the main source of NMHC in the African upper troposphere (10–12 km). Photochemical aging patterns for the samples with PBL contact revealed that the air had different degradation histories depending on the hemisphere in which they were emitted. In the southern hemisphere (SH) air masses experienced more dilution by clean background air whereas in the northern hemisphere (NH) air masses are less diluted or mixed with background air still containing longer lived NMHC. Using NMHC photochemical clocks ozone production was seen in the BB outflow above Africa in the NH.

Diversity and distribution of hyperiid amphipods along a latitudinal transect in the Atlantic Ocean

As commensals and parasitoids of gelatinous plankton, hyperiid amphipods play unique and important ecological roles in pelagic food webs. Because the diversity and biogeography of this group in oceanic waters is poorly known, we examined diversity and distribution patterns of hyperiids along a basin-scale meridional transect in the Atlantic Ocean (Atlantic Meridional Transect cruise 22). Hyperiids were collected from epipelagic and upper mesopelagic depths at 27 stations between 39°N and 45°S. A total of 70 species in 36 genera and 17 families were identified, the majority of which belonged to the epipelagic Physocephalata infraorder. We observed maximum species and genus richness in the equatorial upwelling region (up to 35 species, 27 genera per station; 7°N–8°S), which appeared largely driven by increased diversity in the superfamily Platysceloidea, as well as a significant and positive relationship between species richness and sea surface temperature. Cluster analyses of hyperiid species assemblages along the transect broadly supported a division into gyral, equatorial, transitional, and subantarctic assemblages, congruent with Longhurst’s biogeochemical provinces. Steepest transitions in hyperiid species composition occurred at the southern subtropical convergence zone (34–38°S). The majority of zooplankton groups show maximal diversity in subtropical waters, and our observations of equatorial maxima in species and genus richness for hyperiids suggest that the mechanisms controlling diversity in this group are distinct from other zooplanktonic taxa. These patterns may be driven by the distribution and diversity of gelatinous hosts for hyperiids, which remain poorly characterized at ocean basin scales. The data reported here provide new distributional records for epipelagic and upper mesopelagic hyperiids across six major oceanic provinces in the Atlantic Ocean.

Representation of the tropical stratospheric zonal wind in global atmospheric reanalyses

Abstract. This paper reports on a project to compare the representation of the monthly-mean zonal wind in the equatorial stratosphere among major global atmospheric reanalysis data sets. The degree of disagreement among the reanalyses is characterized by the standard deviation (SD) of the monthly-mean zonal wind and this depends on latitude, longitude, height, and the phase of the quasi-biennial oscillation (QBO). At each height the SD displays a prominent equatorial maximum, indicating the particularly challenging nature of the reanalysis problem in the low-latitude stratosphere. At 50–70 hPa the geographical distributions of SD are closely related to the density of radiosonde observations. The largest SD values are over the central Pacific, where few in situ observations are available. At 10–20 hPa the spread among the reanalyses and differences with in situ observations both depend significantly on the QBO phase. Notably the easterly-to-westerly phase transitions in all the reanalyses except MERRA are delayed relative to those directly observed in Singapore. In addition, the timing of the easterly-to-westerly phase transitions displays considerable variability among the different reanalyses and this spread is much larger than for the timing of the westerly-to-easterly phase changes. The eddy component in the monthly-mean zonal wind near the Equator is dominated by zonal wavenumber 1 and 2 quasi-stationary planetary waves propagating from midlatitudes in the westerly phase of the QBO. There generally is considerable disagreement among the reanalyses in the details of the quasi-stationary waves near the Equator. At each level, there is a tendency for the agreement to be best near the longitude of Singapore, suggesting that the Singapore observations act as a strong constraint on all the reanalyses. Our measures of the quality of the reanalysis clearly show systematic improvement over the period considered (1979–2012). The SD among the reanalysis declines significantly over the record, although the geographical pattern of SD remains nearly constant.

Yearly variations of the stratospheric tides seen in the CFSR reanalysis data

The three main tidal components, i.e., the migrating components DW1, SW2 and the non-migrating component DE3, at the two stratospheric altitudes (20 and 43km) and in the latitude range between ±60°, are obtained from the temperature data of National Centers for Environmental Prediction (NCEP) Climate Forecast System Reanalysis (CFSR) during the interval from 1979 to 2010. We analyze in detail these components and obtain the main properties of their yearly variations. It is found that the migrating tidal components (i.e., DW1, SW2) occur mainly in two regions of latitudes: roughly the mid-latitudes and equatorial latitudes. The mid-latitudinal tidal component appears mainly in the upper stratosphere (43km), extending to the lower stratosphere (20km) and to the higher low-latitudes (20–30°). This kind of components manifests chiefly the seasonal variation: DW1 is stronger in summer than in winter months, while SW2 is stronger in winter than in summer months. At the same time, the equatorial maximum of the tidal component appears mainly in the lower stratosphere, extending to the upper stratosphere. The equatorial DW1 component displays mainly the semi-annual variation that the amplitudes are larger in months around solstices than in those around equinoxes at the two altitudes. It should be noticed that the equatorial SW2 component displays the semi-annual variation: in the lower stratosphere, the peak and valley amplitudes occur respectively at equinoctial and solstitial months, while in the upper stratosphere they appear in the opposite months. In addition, the seasonal and semi-annual variations can also be seen in the non-migrating component DE3, although the yearly variations are not as remarkable as those of the migrating components. Comparing with GSWM model, the yearly variations of the diurnal tidal component DW1 in the CFSR reanalysis are good at reproducing realistic tides. At the same time, the SW2 and DE3 components are different from the results of GSWM model. In summary, the above yearly variations of the main tidal components may demonstrate that the CFSR reanalysis data can be used as a supplementary observation in the investigation of the stratospheric tidal components.

Seamless Precipitation Prediction Skill in the Tropics and Extratropics from a Global Model

Abstract The skill with which a coupled ocean–atmosphere model is able to predict precipitation over a range of time scales (days to months) is analyzed. For a fair comparison across the seamless range of scales, the verification is performed using data averaged over time windows equal in length to the lead time. At a lead time of 1 day, skill is greatest in the extratropics around 40°–60° latitude and lowest around 20°, and has a secondary local maximum close to the equator. The extratropical skill at this short range is highest in the winter hemisphere, presumably due to the higher predictability of winter baroclinic systems. The local equatorial maximum comes mostly from the Pacific Ocean, and thus appears to be mostly from El Niño–Southern Oscillation (ENSO). As both the lead time and averaging window are simultaneously increased, the extratropical skill drops rapidly with lead time, while the equatorial maximum remains approximately constant, causing the equatorial skill to exceed the extratropical at leads of greater than 4 days in austral summer and 1 week in boreal summer. At leads longer than 2 weeks, the extratropical skill flattens out or increases, but remains below the equatorial values. Comparisons with persistence confirm that the model beats persistence for most leads and latitudes, including for the equatorial Pacific where persistence is high. The results are consistent with the view that extratropical predictability is mostly derived from synoptic-scale atmospheric dynamics, while tropical predictability is primarily derived from the response of moist convection to slowly varying forcing such as from ENSO.

The Aqua-Planet Experiment (APE): Response to Changed Meridional SST Profile

This paper explores the sensitivity of Atmospheric General Circulation Model (AGCM) simulations to changes in the meridional distribution of sea surface temperature (SST). The simulations are for an aqua-planet, a water covered Earth with no land, orography or sea- ice and with specified zonally symmetric SST. Simulations from 14 AGCMs developed for Numerical Weather Prediction and climate applications are compared. Four experiments are performed to study the sensitivity to the meridional SST profile. These profiles range from one in which the SST gradient continues to the equator to one which is flat approaching the equator, all with the same maximum SST at the equator. The zonal mean circulation of all models shows strong sensitivity to latitudinal distribution of SST. The Hadley circulation weakens and shifts poleward as the SST profile flattens in the tropics. One question of interest is the formation of a double versus a single ITCZ. There is a large variation between models of the strength of the ITCZ and where in the SST experiment sequence they transition from a single to double ITCZ. The SST profiles are defined such that as the equatorial SST gradient flattens, the maximum gradient increases and moves poleward. This leads to a weakening of the mid-latitude jet accompanied by a poleward shift of the jet core. Also considered are tropical wave activity and tropical precipitation frequency distributions. The details of each vary greatly between models, both with a given SST and in the response to the change in SST. One additional experiment is included to examine the sensitivity to an off-equatorial SST maximum. The upward branch of the Hadley circulation follows the SST maximum off the equator. The models that form a single precipitation maximum when the maximum SST is on the equator shift the precipitation maximum off equator and keep it centered over the SST maximum. Those that form a double with minimum on the equatorial maximum SST shift the double structure off the equator, keeping the minimum over the maximum SST. In both situations only modest changes appear in the shifted profile of zonal average precipitation. When the upward branch of the Hadley circulation moves into the hemisphere with SST maximum, the zonal average zonal, meridional and vertical winds all indicate that the Hadley cell in the other hemisphere dominates.

Saturn’s tropospheric composition and clouds from Cassini/VIMS 4.6–5.1 μm nightside spectroscopy

The latitudinal variation of Saturn’s tropospheric composition (NH 3, PH 3 and AsH 3) and aerosol properties (cloud altitudes and opacities) are derived from Cassini/VIMS 4.6–5.1 μm thermal emission spectroscopy on the planet’s nightside (April 22, 2006). The gaseous and aerosol distributions are used to trace atmospheric circulation and chemistry within and below Saturn’s cloud decks (in the 1- to 4-bar region). Extensive testing of VIMS spectral models is used to assess and minimise the effects of degeneracies between retrieved variables and sensitivity to the choice of aerosol properties. Best fits indicate cloud opacity in two regimes: (a) a compact cloud deck centred in the 2.5–2.8 bar region, symmetric between the northern and southern hemispheres, with small-scale opacity variations responsible for numerous narrow light/dark axisymmetric lanes; and (b) a hemispherically asymmetric population of aerosols at pressures less than 1.4 bar (whose exact altitude and vertical structure is not constrained by nightside spectra) which is 1.5–2.0× more opaque in the summer hemisphere than in the north and shows an equatorial maximum between ±10° (planetocentric). Saturn’s NH 3 spatial variability shows significant enhancement by vertical advection within ±5° of the equator and in axisymmetric bands at 23–25°S and 42–47°N. The latter is consistent with extratropical upwelling in a dark band on the poleward side of the prograde jet at 41°N (planetocentric). PH 3 dominates the morphology of the VIMS spectrum, and high-altitude PH 3 at p < 1.3 bar has an equatorial maximum and a mid-latitude asymmetry (elevated in the summer hemisphere), whereas deep PH 3 is latitudinally-uniform with off-equatorial maxima near ±10°. The spatial distribution of AsH 3 shows similar off-equatorial maxima at ±7° with a global abundance of 2–3 ppb. VIMS appears to be sensitive to both (i) an upper tropospheric circulation (sensed by NH 3 and upper-tropospheric PH 3 and hazes) and (ii) a lower tropospheric circulation (sensed by deep PH 3, AsH 3 and the lower cloud deck).

Global Warming Pattern Formation: Sea Surface Temperature and Rainfall*

Abstract Spatial variations in sea surface temperature (SST) and rainfall changes over the tropics are investigated based on ensemble simulations for the first half of the twenty-first century under the greenhouse gas (GHG) emission scenario A1B with coupled ocean–atmosphere general circulation models of the Geophysical Fluid Dynamics Laboratory (GFDL) and National Center for Atmospheric Research (NCAR). Despite a GHG increase that is nearly uniform in space, pronounced patterns emerge in both SST and precipitation. Regional differences in SST warming can be as large as the tropical-mean warming. Specifically, the tropical Pacific warming features a conspicuous maximum along the equator and a minimum in the southeast subtropics. The former is associated with westerly wind anomalies whereas the latter is linked to intensified southeast trade winds, suggestive of wind–evaporation–SST feedback. There is a tendency for a greater warming in the northern subtropics than in the southern subtropics in accordance with asymmetries in trade wind changes. Over the equatorial Indian Ocean, surface wind anomalies are easterly, the thermocline shoals, and the warming is reduced in the east, indicative of Bjerknes feedback. In the midlatitudes, ocean circulation changes generate narrow banded structures in SST warming. The warming is negatively correlated with wind speed change over the tropics and positively correlated with ocean heat transport change in the northern extratropics. A diagnostic method based on the ocean mixed layer heat budget is developed to investigate mechanisms for SST pattern formation. Tropical precipitation changes are positively correlated with spatial deviations of SST warming from the tropical mean. In particular, the equatorial maximum in SST warming over the Pacific anchors a band of pronounced rainfall increase. The gross moist instability follows closely relative SST change as equatorial wave adjustments flatten upper-tropospheric warming. The comparison with atmospheric simulations in response to a spatially uniform SST warming illustrates the importance of SST patterns for rainfall change, an effect overlooked in current discussion of precipitation response to global warming. Implications for the global and regional response of tropical cyclones are discussed.

Nonempirical approach to the conformational analysis of 2,4-dimethyl-1,3,2-dioxaborinane and its oxonium ions

Using nonempirical quantum-chemical approximations RHF//STO-3G, 3-21G, 6-31G(d) and MP2//6-31G(d,p) a conformation isomerism of 2,4-dimethyl-1,3,2-dioxaborinane and its oxonium ions was studied. It was shown that the potential energy surface of the studied molecules has minima corresponding to equatorial (main minimum) and axial sofa forms and maxima corresponding to equatorial and axial conformations of 2,5-twist forms. Calculated values of the barriers of internal rotation of methyl group at the ring C4 atom were found. It was also established that the heat of protonation of the cyclic boric ester was smaller than of the non-boric analog, cis-2,4-dimethyl-1,3-dioxane, owing to decrease in basicity of the oxygen atoms in the cyclic boric ester due to partial double bond character of B-O bond.

Spatiotemporal variation of the ozone QBO in MLS data by wavelet analysis

Abstract. Spatiotemporal characteristics of the ozone quasi-biennial oscillation (QBO) over the tropical-subtropical stratosphere (40° S–40° N) have been examined by analyzing data from the Microwave Limb Sounder (MLS) aboard Upper Atmospheric Research Satellite (UARS) for the period 1992–1999. A combination of regression analysis and wavelet analysis combines to act as an accurate QBO filter. Wavelet analysis provides inter-annual variability of amplitude and phase of the ozone QBO in the vertical structure of tropical-subtropical stratosphere. It gives minute details of phase propagation and descend rates, which can be used as input to models. Latitude-height structure shows evidence of a secondary meridional circulation induced by the QBO as double peak structure at the equator with maximum amplitude at two pressure levels 30 hPa and 9 hPa and a node at 14 hPa. The equatorial maxima are out of phase with each other. The maximum amplitude (~1.4 ppmv) of the ozone QBO was observed near the equator at 10 hPa. Descent rate of the easterly phase is greater than westerly. The lag correlation of the ozone QBO with circulation and variation of descent rates in the vertical structure of the stratosphere are examined in detail. In the equatorial upper stratosphere ozone anomalies descent with the rate ~1.5 km/month but in tropics and subtropics (above 2 hPa) they propagate upward.

Features of ozone quasi-biennial oscillation in the vertical structure of tropics and subtropics

Summary Latitude-altitude structure of ozone QBO over the tropicalsubtropical stratosphere (40 � S–40 � N) has been explored by analyzing Microwave Limb Sounder (MLS) aboard Upper Atmospheric Research Satellite (UARS) data for the period 1992–1999 using the multifunctional regression model. The inferred ozone QBO shows two maxima located at 22 hPa and 10 hPa with coefficient of 2–3% per 10 m=s centered at the equator. The equatorial maxima are out of phase with each other. Subtropics exhibit two peak structure near 14 hPa but of opposite sign to that of equatorial maximum near 10 hPa. Over the equatorial region, positive (zonal winds westerly) coefficients overlay negative (zonal winds easterlies) coefficients which descend with time. A pattern of equatorial maximum and two subtropical minima appears in the months December to February near 10 hpa and it propagates upward with progression of seasons. Equatorial QBO is seasonally asynchronous while subtropical QBO is seasonally synchronous.