Epoxy Resin Insulation Materials Research Articles

Novel functionalized isocyanate groups polyhedral oligomeric silsesquioxanes/epoxy composites with advanced thermal and moisture resistance properties

AbstractThe rapid development of the electronic packaging industry has necessitated the production of epoxy resin insulation materials with high heat resistance and low water absorption. In this study a new cross‐linking composite composed of polyhedral oligomeric silsesquioxane (POSS) functionalized with isocyanate groups and epoxy resin (EP) containing phenolic hydroxyl groups. By employing an isocyanate‐hydroxyl process, the cage structure of Ph7POSS with isocyanate functionalization (MP) can be suspended on EP, leading to a significant improvement in the thermal and moisture resistance of the MP/EP composite. Our DSC and TGA studies revealed that the addition of 3% MP to the epoxy resin increased the glass transition temperature by 27.1°C and raised the initial thermal breakdown temperature to 334.5°C. We also utilized a novel quartz crystal microbalance (QCM) technique to continuously monitor the moisture resistance of the composite, and our results showed that the composite absorbed only 0.03% of water. Moreover, the porosity and cross‐linking of the POSS molecules further restricted the movement of the polymer chains, thereby reducing the dielectric constant and dielectric loss of the composite. Consequently, the MP‐modified epoxy composites exhibit excellent properties, which suggest promising applications in the field of electronic packaging.

Effects of Y-nodes in DGEBA/TDE-85/MTHPA blends on their thermal and mechanical properties: MD simulation and experimental study

With the development of alternate electrical power system and the improvement of voltage level, the operation conditions faced by epoxy resin (ER) insulation materials are becoming more and more complex. The traditional ER materials have been difficult to meet the increasingly stringent requirements. In this paper, the thermal and mechanical properties of DGEBA/TDE-85/MTHPA blend system were studied by molecular dynamics (MD) simulation and experiment. The results show that the addition of TDE-85 can significantly improve the thermal and mechanical properties, and the comprehensive improvement effect is the best when the molar ratio of DGEBA and TDE-85 is about 8:2. The experimental results are consistent with the simulation results. Further analysis of the micro-parameters of the monomer and the cross-linking network found that the torsional energy barrier of TDE-85 is higher than DGEBA. And the compatibility of the two ER is better when the ratio is 8:2. In addition, TDE-85 can introduce high-stability Y-nodes into the system, making the cross-linked network more stable, which has a significant effect on improving the thermal and mechanical properties. The research provide a reference for the blending modification of high-performance ER for high-voltage insulation.

Electrical Tree Characteristics of Bisphenol A Epoxy Resin/Maleopimaric Anhydride Curing System.

Epoxy resin insulation materials are mainly derived from petrochemical materials which have the disadvantages of resource consumption and environmental pollution. In order to cure bisphenol A epoxy resin, a maleopimaric anhydride (MPA) curing agent was prepared from rosin, a renewable resource, and blended with a petroleum-based curing agent (methylhexahy-drophthalic anhydride). The influence of maleopimaric anhydride content on the initiation and growth characteristics of electrical trees was studied and analyzed in this paper using molecular dynamics simulation (MD) and electrical tree tests at an 18-kilovolt power frequency voltage. When the MPA content used was ≤10%, the free volume percentage of the curing system increased with MPA content, and thus the initiation voltage became lower; when the MPA content was ≥20%, the hydrogenated phenanthrene ring structure content increased significantly with increasing MPA content, and the rigidity of the curing system increased significantly; thus, the initiation voltage gradually increased. MPA4 had an 11.11% higher initiation voltage than the petroleum-based control group. The effect of the polar rigid structure within the curing system significantly inhibited the growth rate and length of electrical trees as MPA content increased. Electrical trees developed into light-colored, thin, and narrow dendritic structures when the MPA content reached 40%. The results show that curing epoxy resin with the rosin-based curing agent maleopimaric anhydride (MPA), in place of a petroleum-based curing agent, can produce environmentally friendly resins with excellent electrical tree resistance and potential application prospects.

Preparation and characteristics of silicone-modified aging-resistant epoxy resin insulation material

Preparation and characteristics of silicone-modified aging-resistant epoxy resin insulation material

Study On Dissociation Characteristics of EP Under Different Temperature Conditions and PD Active Products Based On ReaxFF

The Bisphenol F epoxy resin insulation material commonly used in the terminal of superconducting power equipment is subjected to large temperature gradient and strong electric field at the same time, which makes the insulation material at the terminal equipment withstand more intense partial discharge (PD), and the reliability of the insulation material decreases. In this paper, reactive force field (ReaxFF) is used to study the aging pyrolysis characteristics of crosslinked bisphenol F epoxy resin for superconducting power equipment under different PD active products and temperatures conditions. The simulation results show that the pyrolysis degree of epoxy resin increases with the increase of PD active product concentration, and the initial pyrolysis temperature increases with the increase of temperature rise rate. The active product acting on the hydroxyl group on the cross-linked structure is the main reason for the decrease in the thermal stability of the epoxy resin, which will result in a substantial increase in the yield of the pyrolysis product with a smaller relative molecular mass and aggravate the thermal aging of insulating materials.

Improving the insulating performance of epoxy resin in humid environments byHTPDMSmodification

AbstractThe rapid development of the electronic packaging industry imposes stringent requirements on epoxy resin insulation materials for lower water absorption and higher insulation properties. Here, hydroxy‐terminated polydimethylsiloxane (HTPDMS) was grafted on the molecular chain of the epoxy resin for enhanced waterproof and insulating properties of the epoxy resin. The HTPDMS‐modified epoxy resin specimens were prepared and subjected to water absorption and water absorption insulation performance tests. The experimental results indicated that the water absorption rate of the modified epoxy resin was reduced by 34.2%, resulting in a 25.2% reduction of the dielectric loss, an 11.6% increase of the breakdown strength, and a 98.3% increase of the volume resistivity. The satisfactory performance of the HTPDMS‐modified epoxy resin insulation material is attributed to the low surface energy and flexible SiO bond of the introduced HTPDMS. Simultaneously, the reduction of surface defects is also conducive to the epoxy resin insulation performance. Thus, HTPDMS‐modified epoxy resin insulation materials can maintain excellent insulation properties in humid environments, making them a promising application in the field of electronic packaging.

An Investigation of Surface Tracking Characteristics and Factors Influencing Epoxy Resin Pouring Insulation for Dry-type Reactors

This study aimed to understand the deterioration mechanisms of epoxy resin pouring insulation for outdoor dry-type reactors under the effect of long-term surface tracking discharge. Epoxy resin insulation boards similar to the main insulation composition of the dry-type reactor were poured as the experimental material. A tracking experimental platform of insulation materials was built using an inclined plate method. The tracking discharge characteristics and surface erosion of the insulation materials were measured and analyzed. The characteristics of partial discharge, erosion, hydrophobicity and surface roughness were measured experimentally. Surface morphology, three-dimensional morphology and Fourier infrared images at different stages during erosion of the epoxy resin insulation material were analyzed. The effect of glass fiber content on the tracking resistance to erosion was characterized. The results show that the tracking process of epoxy resin insulation material experienced initiation, stability, development and outbreak periods. The flashover discharge corresponding to the development period was the main reason for the carbonization of the insulating material. During the tracking process, with a change in surface topography and formation of surface products, the surface roughness of the material generally increased along with the surface roughness which rose fastest during the discharge outbreak period. The changes in the surface morphology and three-dimensional morphology of the epoxy resin material constitute the basis for assessing the condition of the insulation surface and development of the erosion. The discharge capacity of epoxy resin generally shows an exponential increase. Adding 20 wt% of glass fibers that are evenly distributed and have reduced exposure can improve the tracking resistance of epoxy resin insulation materials.

Electrical performance of TGPAP and DGEBF-based epoxy resin insulation materials for superconducting magnets

For the insulation materials of the superconducting magnet, the mechanical and electrical properties should be guaranteed under stresses of cryogenic temperature and intense radiation. In this study, two types of epoxy resins were prepared, which consist of diglycidyl ether of bisphenol-F (DGEBF) and triglycidyl-p-aminophenol (TGPAP) as matrixes respectively, and diethyl toluene diamine (DETD), isopropylidenebisphenol bis[(2-glycidyloxy-3-n-butoxy)-1-propylether] (IPBE) and boron-free glass fibre were used as curing, toughing and reinforcing agents for each resin. The direct-current (dc) electric breakdown strength and flashover voltage, dielectric properties and space charge characteristics of both epoxy composites were investigated. According to the results, DGEBF composite shown a higher dielectric strength, lower permittivity and dielectric loss at cryogenic temperature and smaller shallow trap density, which makes it more potential to be used for the cryogenic insulation.

Determination of Hydrophobic Contact Angle of Epoxy Resin Compound Silicon Rubber and Silica

Epoxy resin is a thermosetting polymeric material which is very good for application of high voltage outdoor insulator in electrical power system. This material has several advantages, i.e. high dielectric strength, light weight, high mechanical strength, easy to blend with additive, and easy maintenance if compared to that of porcelain and glass outdoor insulators which are commonly used. However, this material also has several disadvantages, i.e. hydrophilic property, very sensitive to aging and easily degraded when there is a flow of contaminants on its surface. The research towards improving the performance of epoxy resin insulation materials were carried out to obtain epoxy resin insulating material with high water repellent properties and high surface tracking to aging. In this work, insulating material was made at room temperature vulcanization, with material composition: Diglycidyl Ether Bisphenol A (DGEBA), Metaphenylene Diamine (MPDA) as hardener with stoichiometric value of unity, and nanosilica mixed with Silicon Rubber (SiR) with 10% (RTV21), 20% (RTV22), 30% (RTV23), 40% (RTV24) and 50% (RTV25) variation. The usage of nanosilica and Silicon Rubber (SIR) as filler was expected to provide hydrophobic properties and was able to increase the value of surface tracking of materials. The performance of the insulator observed were contact angle of hydrophobic surface materials. Tests carried out using Inclined Plane Tracking procedure according to IEC 60-587: 1984 with Ammonium Chloride (NH4Cl) as contaminants flowed using peristaltic pumps. The results show that hydrophobic contact angle can be determined from each sample, and RTV25 has maximum contact angle among others.

Determination of Hydrophobic Contact Angle of Epoxy Resin Compound Silicon Rubber and Silica

Epoxy resin is a thermosetting polymeric material which is very good for application of high voltage outdoor insulator in electrical power system. This material has several advantages, i.e. high dielectric strength, light weight, high mechanical strength, easy to blend with additive, and easy maintenance if compared to that of porcelain and glass outdoor insulators which are commonly used. However, this material also has several disadvantages, i.e. hydrophilic property, very sensitive to aging and easily degraded when there is a flow of contaminants on its surface. The research towards improving the performance of epoxy resin insulation materials were carried out to obtain epoxy resin insulating material with high water repellent properties and high surface tracking to aging. In this work, insulating material was made at room temperature vulcanization, with material composition: Diglycidyl Ether Bisphenol A (DGEBA), Metaphenylene Diamine (MPDA) as hardener with stoichiometric value of unity, and nanosilica mixed with Silicon Rubber (SiR) with 10% (RTV21), 20% (RTV22), 30% (RTV23), 40% (RTV24) and 50% (RTV25) variation. The usage of nanosilica and Silicon Rubber (SIR) as filler was expected to provide hydrophobic properties and was able to increase the value of surface tracking of materials. The performance of the insulator observed were contact angle of hydrophobic surface materials. Tests carried out using Inclined Plane Tracking procedure according to IEC 60-587: 1984 with Ammonium Chloride (NH4Cl) as contaminants flowed using peristaltic pumps. The results show that hydrophobic contact angle can be determined from each sample, and RTV25 has maximum contact angle among others.

Development of On-Line Monitoring System and Aging Characteristics Research of Switchgear

For improving reliable operation of switchgear in power system, an approach for on-line monitoring the insulation characteristic and bus-bar temperature rising of the switchgear is proposed in this paper. Through comparing several existing temperature measurement methods for monitoring temperature rising elevation at bus-bas, a new design of temperature monitoring method is proposed. It adopts quick-magnetic saturated current transformer, temperature sensor and infrared transmission to solve the problem of high voltage isolation. The epoxy resin insulation material which is commonly used in switchgear its aging mechanism data is not complete, seriously restrict on-line monitoring for switchgear, so thousands hours of aging experiment is done on switchgear, systematic study various electrical characteristics variation law on the gradual aging process of epoxy resin insulation materials. Therefore, study on the aging characteristics of switchgearinsulation and its lifetime estimation method is the key technology to understand agingmechanism better, search for new fault diagnostic method and the way to extend theuseful lifetime of switchgear. At last, the system runs in real system and the result shows the on-line monitoring system is stable and reliable which can be provide reference for on-line monitoring system design of switchgear.

The Performance of High Voltage Insulator Based on Epoxy-Polysiloxane and Rice Husk Ash Compound in Tropical Climate Area

This paper presents the effect of natural aging upon the performance of the polymeric insulation materials made from Epoxy resins, Polydimethylsiloxane (PDMS), and Rice husk ash compound. The samples of epoxy resin insulation material consist of Diglycidyl Ether of Bisphenol A (DGEBA), Meta Phenylene Diamine (MPDA) as curing agent, and 325 mesh Rice Husk Ash (RHA) as filler, treated with variation of PDMS content. The research aims are to observe the Equivalent Salt Deposit Density (ESDD), critical leakage current, and flashover voltage on the insulation material surface that has undergone a natural aging. Experimental method was carried out through the following procedure. The samples were placed outdoor for natural aging test, outside the building of electrical engineering and information technology of Gadjah Mada University in Indonesia. Then the ESDD, critical leakage current, flashover voltage on the sample surface was measured every 2 weeks. The experiment results show that the performance of insulator material fluctuates during 52 weeks. The higher PDMS with RHA filler content the lower ESDD and surface leakage current. Furthermore the flashover voltage increases.