Abstract Indian Mythology has many complex characters that reflect contemporary issues. Vaishnavi Patel and Kavita Kane, renowned women writers, have reinterpreted the epic tales of the Ramayana and the Mahabharata through a modern perspective. This paper examines human behaviour using a psychological approach in Patel’s “Kaikeyi”and Kavita Kane’s “Karna’s Wife: The Outcast’s Queen”. Patel’s“Kaikeyi”explores the protagonist’s optimistic traits, her childhood longings, and her feminist qualities. Traditionally depicted as a villain in the Ramayana, Kaikeyi is recognized as Rama’s stepmother who instigates his exile. However, before assuming this role, she experienced a difficult and challenging childhood in the Kingdom of Kekaya. The novel sheds light on the darker aspects of Kaikeyi’s past, providing a deeper understanding of her character. Kavita Kane’s interest lies in unveiling the complexities of classic women in her literary works. In “Karna’s Wife”, Uruvi, the protagonist, is portrayed as the marginalized wife of Karna, who belongs to the Sutapura lineage. Uruvi, a princess from the Kshatriya family of Pukeya kingdom is depicted as an optimistic character with great skills, knowledge, and mental strength.These two novels focus on the lives of classic women, their behavioural changes, and their insecurities in different situations. Women are inherently multifaceted and encounter various challenges throughout their lives. Different approaches are required to address these challenges. According to Sigmund Freud, the human psyche consists of three aspects that interact and influence each other to create complex human behaviour. Freud’s psychological theory can be used to analyse the characters of Kaikeyi and Uruvi in these novels. The study attempts to highlight the need for women to overcome feelings of insecurity, emotional dependence, to achieve self-realization, and build resilience, which are essential qualities in the contemporary era.