Porous metal materials are widely used in heat-absorbing, biomedical parts and other fields because of their excellent mechanical properties and biocompatibility. Further applications of porous metal materials are inseparable from secondary precision machining. However, traditional cutting methods tend to compromise the original porosity of the material surface. Electrical discharge machining (EDM) is a type of non-conventional machining method which is more preferable to overcome these defects. In the present study, the main target is to investigate the effect of four input electrical machining parameters (current, frequency, efficiency and gap voltage) on the five output responses (material removal rate (MRR), electrode wear, surface roughness (SR), noise and time consumption value of environmental particulate matter (PM2.5)) when electrical discharge machining porous 316L stainless steel and compared with that of pure 316L stainless steel. The Taguchi method was employed to determine the relationship between electrical discharge machining parameters and output responses. The analysis of variance (ANOVA) was used to evaluate the effect of input parameters on output responses. The effects of electrical machining parameters on above responses were analyzed by main effects, and the order of influence was obtained, respectively. Finally, the surface morphology was observed by scanning electron microscope (SEM), and the effect of electrical machining parameters on the characteristics and formation of machined surface of porous stainless steel was mainly analyzed.