This paper proposes a compliant ortho-planar spring piezoelectric vibrational energy harvester (COPS-PVEH) using a H-I structure that exploits a nonlinearity and an asymmetric mono-stability to enhance the bandwidth of the device. The main structure is based on a double clamped beam (I-structure) coupled with four cantilever beams (H-structure) and an ortho-planar spring in the centre of the I-structure. Finite element analysis (FEA), analytical modelling, and experimentation were performed to analyse the dynamical and electrical behaviour of the harvester. The device was fabricated using polylactide (PLA). Six bimorph PZT-5H piezoelectric materials, electrically connected in parallel, were used as piezoelectric generators. The device was tested using an optimum load resistor of 90 kΩ under sinusoidal and sine sweep excitation in the gravity (vertical) direction. The pre-load (due to gravitation) causes a softening nonlinearity and an asymmetric mono-stability in the potential energy function. The results show that multiple peaks are observed in the output voltage of the harvester in the FEA, analytical modelling, and experimentation under harmonic excitation in the sub 15 Hz frequency range. Furthermore, analytical modelling and experimentation exhibit softening nonlinearity and chaotic behaviour, reaching a maximum amplitude power of 1.01 mW (at 8.3 Hz) and 1.07 mW (at 9.5 Hz) respectively under sine sweep excitation (amplitude of 0.6 g (g = 9.81 m/s2)). Experimentally, the harvester also generates an average power greater than 46 µW with a 6.8 Hz bandwidth under the same excitation. The softening nonlinearity and asymmetric mono-stability enhance the bandwidth of the harvester in the low frequency region where most broadband ambient vibrations are available in practical environments.