The mass entransy and its dissipation extremum principle have opened up a new direction for the mass transfer optimization. Firstly, the emergence and development process of both the mass entransy and its dissipation extremum principle are reviewed. Secondly, the combination of the mass entransy dissipation extremum principle and the finite-time thermodynamics for optimizing the mass transfer processes of one-way isothermal mass transfer, two-way isothermal equimolar mass transfer, and isothermal throttling and isothermal crystallization are summarized. Thirdly, the combination of the mass entransy dissipation extremum principle and the constructal theory for optimizing the mass transfer processes of disc-to-point and volume-to-point problems are summarized. The scientific features of the mass entransy dissipation extremum principle are emphasized.