Enriched Sr Research Articles

Assessment of the heavy metal sources and concentrations in the Nador Lagoon sediment, Northeast-Morocco

This study investigates the heavy metals (HM) and sulfurs concentration, enrichment level and potential sources in the bottom sediments of Nador lagoon, North-East Morocco. 50 samples of sediments from Nador lagoon heavy metals were analyzed by ICP-MS, while their spatial distribution and source identification were evaluated by Enrichment Factor (EF), QGis Inverse Distances Weighted (IDW) interpolation models, multivariate statistical techniques (Principal Component Analysis - Agglomerative Hierarchical Clustering - Pearson correlation matrix), Positive matrix factorization (PMF model) and grain size/organic matter analysis. The average heavy metal concentrations in the sediments are in the decreasing order: Sr > Ba > V > Zr > Zn > Cr > Rb > La > Cu > Pb > Ni > Ce > Nd > Co > Sc > Nb > Ga > Th > Y > Hf, and the Sulfurs. The results showed that the average concentrations of the S, Sr, Pb, and Nd in bottom sediments were higher than their background contents. The EF values demonstrated that HM contents were enriched by anthropogenic activities, especially for Sr and S, and secondly for Th, V, Ce, Nd, and Pb. The potential HM and sulfurs identified sources showed that: 1) Ga, Y, Hf, Nb, Rb, Sc, Zr, Nb, Co, Zn, Th, Ni, V, Ba, Cr, and Cu were derived industrial activities related to stealing and mining; 2) Wastewater treatment station and lagoon watershed were the main sources of Sr in the lagoon; 3) Zn, Cu, and Pb also linked to sulfurs, mostly origin from agriculture inputs and mining activities; 4) Ce, Cr, and Ni linked to sulfurs, mainly origin form metallurgical activities and solid wastes. The results suggest that heavy metal concentrations were significantly affected anthropogenic activities. Severe enrichment of Sr was found in the lagoon ecosystem with no correlation with carbonates, with four sources of heavy metals apportioned by Geostatistics and Positive matrix factorization. Solid waste, water waste and industrial activities were the main anthropogenic source. Lutite fraction and organic matter show a high accord with heavy metals concentration distribution.

Temporal and Spatial Variations of Enriched Source Components in Linzizong Volcanic Succession, Tibet, and Implications for the India–Asia Collision

Abstract The temporal and spatial distribution of enriched source components at sites of continent–continent collision provides critical insights into mantle dynamic processes associated with subduction- and collision-related events. However, determining the origin of such enriched components remains a significant challenge. We report a comprehensive dataset of the Linzizong volcanic succession (LVS) from four locations with varying distance across-strike to the Indus–Yarlung suture in southern Tibet, which marks the exposed surface expression of the India–Asia collision zone. The LVS rocks in this study can be divided into two groups: a calc-alkaline Group 1 (69–55 Ma), mainly including basaltic–andesitic varieties, and a shoshonitic Group 2 (52–50 Ma), consisting predominantly of silicic rocks with minor mafic compositions. Group 1 samples are likely derived from the fractional crystallization of primitive basaltic melts as a result of the partial melting of a metasomatized mantle wedge. These samples are decoupled in Nd–Hf isotopic compositions, suggesting an incorporation of subducting sediment-derived melts into the mantle wedge. The influence of sediment-derived melt on the mantle source increases away from the suture zone toward Asia (i.e., from the south to the north) as indicated by the more enriched Sr, Nd, Pb, and Hf isotopic compositions, as well as elevated Th/La and La/Sm ratios. The heavy δ26Mg values, and high Ba/Th and Sr/Th ratios of samples close to the suture coincide with the dehydration of the subducting Neo-Tethyan slab. Group 2 mafic samples have depleted and coupled εNd–εHf isotopic compositions and are characterized by elevated (La/Yb)N and Dy/Yb ratios as well as low Zr/Nb ratios, indicating an origin of enriched garnet-bearing lithospheric mantle with contributions from asthenosphere-derived materials. Group 2 silicic samples are isotopically enriched both near and far away from the suture, which can be attributed to the involvement of ancient lower crust-derived melt from Tethyan Himalaya and central Lhasa subterrane basement, respectively. Our results show that the LVS are the magmatic response to late subduction (Group 1), and to initial India–Asia collision and slab breakoff (Group 2). Negative trends in the whole-rock Nd and zircon Hf isotopic compositions at ~51 Ma should be treated with caution for geodynamic interpretations, depending on the distance between the samples and the India–Asia suture.

Anthropogenic influences on sedimentary geochemistry of Itapessoca Estuarine Complex, Pernambuco, Brazil.

The Itapessoca Estuarine Complex is characterized by a history of intense economic activities developed on the banks of its tributary rivers, often exercised without any control or planning. In order to relate natural and/or anthropic events to the sediment age, radiometric dating method was performed by determining excess 210Pb in the sediment using the proportional gas flow technique. To investigate possible disturbances in recent sedimentation processes in studied area, 20 surfaces sediment samples and 2 sediment cores were collected for determination of concentrations of the chemical elements. Al, Ca, Fe, K, Mg, Mn, Ni, Pb, Si, Sr, Ti and Zn concentrations were determined by the energy-dispersive X-ray fluorescence (EDXRF) technique. Through the enrichment factors and ratios among some elements associated with geochronological data, it was possible identify geochemical changes in sedimentation of sampled points, with increase of minerals associated with fine fractions and decrease of the proportions of elements associated with coarse fractions. The radiometric dating reveals that Pb enrichment and the exacerbated increase of Ca and Sr enrichment factors are strongly related to the anthropic activity in the region.

Petrogenesis and Tectonic Setting of Early Cretaceous Intrusive Rocks in the Northern Ulanhot Area, Central and Southern Great Xing’an Range, NE China

Abundant Early Cretaceous magmatism is conserved in the central and southern Great Xing’an Range (GXR) and has significant geodynamic implications for the study of the Late Mesozoic tectonic framework of northeast China. In this study, we provide new high-precision U–Pb zircon geochronology, whole-rock geochemistry, and zircon Hf isotopic data for representative intrusive rocks from the northern part of the Ulanhot area to illustrate the petrogenesis types and magma source of these rocks and evaluate the tectonic setting of the central-southern GXR. Laser ablation inductively coupled plasma–mass spectrometry (LA-ICP-MS) zircon U–Pb dating showed that magmatism in the Ulanhot area (monzonite porphyry: 128.07 ± 0.62 Ma, quartz monzonite porphyry: 127.47 ± 0.36, quartz porphyry: 124.85 ± 0.34, and granite porphyry: 124.15 ± 0.31 Ma) occurred during the Early Cretaceous. Geochemically, monzonite porphyry belongs to the metaluminous and alkaline series rocks and is characterized by high Al2O3 (average 17.74 wt.%) and TiO2 (average 0.88 wt.%) and low Ni (average 4.63 ppm), Cr (average 6.69 ppm), Mg# (average 31.11), Y (average 15.16 ppm), and Yb (average 1.62 ppm) content with enrichment in Ba, K, Pb, Sr, Zr, and Hf and depletion in Ti, Nb, and Ta. The granitic rocks (e.g., quartz monzonite porphyry, quartz porphyry, and granite porphyry) pertain to the category of high-K calc-alkaline rocks and are characterized by high SiO2 content (>66 wt.%) and low MgO (average 0.69 wt.%), Mg# (average 31.49 ppm), Ni (average 2.78 ppm), and Cr (average 8.10 ppm) content, showing an affinity to I-type granite accompanied by Nb, Ta, P, and Ti depletion and negative Eu anomalies (δEu = 0.57–0.96; average 0.82). The Hf isotopic data suggest that these rocks were the product of the partial melting of juvenile crustal rocks. Notably, fractionation crystallization plays a crucial role in the process of magma emplacement. Combining our study with published ones, we proposed that the Early Cretaceous intrusive rocks in the Ulanhot area were formed in an extensional tectonic background and compactly related to the subduction of the Paleo-Pacific Ocean plate.

Dynamical ejecta of neutron star mergers with nucleonic weak processes I: nucleosynthesis

ABSTRACT We present a coherent study of the impact of neutrino interactions on the r-process element nucleosynthesis and the heating rate produced by the radioactive elements synthesized in the dynamical ejecta of neutron star–neutron star (NS–NS) mergers. We have studied the material ejected from four NS–NS merger systems based on hydrodynamical simulations which handle neutrino effects in an elaborate way by including neutrino equilibration with matter in optically thick regions and re-absorption in optically thin regions. We find that the neutron richness of the dynamical ejecta is significantly affected by the neutrinos emitted by the post-merger remnant, in particular when compared to a case neglecting all neutrino interactions. Our nucleosynthesis results show that a solar-like distribution of r-process elements with mass numbers $A \gtrsim 90$ is produced, including a significant enrichment in Sr and a reduced production of actinides compared to simulations without inclusion of the nucleonic weak processes. The composition of the dynamically ejected matter as well as the corresponding rate of radioactive decay heating are found to be rather independent of the system mass asymmetry and the adopted equation of state. This approximate degeneracy in abundance pattern and heating rates can be favourable for extracting the ejecta properties from kilonova observations, at least if the dynamical component dominates the overall ejecta. Part II of this work will study the light curve produced by the dynamical ejecta of our four NS merger models.

Forearc lava stratigraphy of the Beila Ophiolite, north-central Tibetan Plateau: Magmatic response to initiation of subduction of the Bangong-Nujiang Meso-Tethys Ocean

It has been suggested that boninites and associated volcanic rocks found in supra-subduction zone (SSZ) ophiolites form in a forearc setting, meaning that these rocks could provide crucial constraints on understanding the magmatic response to subduction initiation. Here, we report newly documented forearc basalts (FAB) and boninites from the Beila Ophiolite of the Bangong–Nujiang Suture Zone, north-central Tibetan Plateau. The lava stratigraphy, from bottom to up, includes FAB, basaltic boninites, and boninites, similar to lavas from the Izu–Bonin–Mariana (IBM) forearc. The FAB has geochemical characteristics similar to those of IBM forearc basalts, with nearly flat REE patterns, and shows enrichment in Rb, Ba, Pb, and Sr and depletion in Nb, Ta, and Zr, suggesting an origin by decompression melting of a depleted mantle source with minor input of subducting plate materials. The basaltic boninites and boninites show similar petrological features, as well as porphyritic textures with phenocrysts of olivine, clinopyroxene, and minor orthopyroxene. The basaltic boninites and boninites display uniform major- and trace-element characteristics that are similar to those of typical boninites, with high MgO (>10.78 wt%), Cr, and Ni contents, extremely low TiO2 (<0.21 wt%), rare earth element (REE), and high-field-strength element (HFSE) contents, and U-shaped REE patterns. In addition, the basaltic boninites and boninites have lower ɛNd(t) values than those of the FAB and display variable degrees of influence by slab melts and fluids. Geochemical modeling further suggests that the boninites were generated later during residual highly depleted mantle fluxing by the subducting plate. Together with contemporary boninitic and arc-related magmas along the Bangong-Nujiang Suture Zone and adjacent terranes (the North Lhasa and South Qiangtang), it suggests that the whole Meso-Tethys Ocean was subducted since the Middle Jurassic. Moreover, the Beila lava stratigraphy with FAB overlain by boninite is similar to that found in the IBM forearc and in many ophiolites (e.g., Troodos, Oman, and Xigaze), and represents a continuous geochemical transition from MORB-like to boninitic affinities. This similarity suggests that initiation of subduction might be commonly involved in the formation of ophiolites.

Petrogenesis of Cretaceous volcanic rocks from islands off Fujian Province, East China Sea, and implications for episodic slab rollback of the paleo-Pacific plate

This study constrains the petrogenesis and regional tectono-magmatic evolution of volcanic rocks from Fuying and Dayushan Islands, northeast Fujian Province, southeast (SE) China, using petrological, zircon U–Pb geochronological, whole-rock geochemical and Sr–Nd–Pb isotopic data. New zircon U–Pb data show that volcanism occurred between 118 and 99 Ma. The volcanic rocks are dominantly alkalic to alkali-calcic, ferroan, and peraluminous in composition, and are characterized by strongly fractionated LREE and HREE, with depletion in Nb, Ta, Sr, and Eu. These features, together with their relatively enriched Sr–Nd–Pb isotopic compositions, imply that the volcanic rocks were derived from ancient lower crust and experienced extensive assimilation and fractional crystallization in the shallow crust. Taking into account previously published data, we conclude that the Fuying and Dayushan volcanic rocks were generated in a back-arc extensional setting in response to episodic slab rollback after flat subduction of the paleo-Pacific plate during the Cretaceous.

Petrogenesis of the Tampanchi Ultramafic–Mafic Complex (Ecuador): Geodynamic implications for the northwestern margin of South America during the late Cretaceous

The Tampanchi Ultramafic–Mafic Complex (TUMC), located in the central segment of the Cordillera Real (Ecuador), is an oval-shaped intrusive body of approximately 18 km2 emplaced within a Cretaceous metavolcano-sedimentary sequence. Field investigations, zircon geochronology, mineral and whole-rock elemental and isotopic compositions constrain the nature of the parental magma as well as the physical conditions of emplacement, age of crystallization and tectonic setting of formation of the TUMC. The Complex consist of wehrlite and olivine-hornblende clinopyroxenite crosscut by hornblende gabbros and minor dikes/veins of diorite and granite. Hornblendites formed mainly at the contact between the olivine-hornblende clinopyroxenite and the intrusive hornblende gabbros by reaction-replacement processes. Geochemical data for both the wehrlites and pyroxenites define a trend with dominantly olivine and clinopyroxene accumulation, whereas a second trend is formed by hornblende gabbros that differentiated to leucocratic rocks, with amphibole as the dominant fractionating mafic phase. The trace elements show enrichment in large-ion lithophile elements, depletion in high field strength elements (Nb, Zr, Ti) and P, and enrichment in Pb, Sr and Ba relative to primitive mantle, indicating subduction-related parental liquids. The Nd and Sr isotopic composition suggests a uniform mantle source metasomatized by subducted crustal components. Thermobarometric estimations constrain emplacement and crystallization at intermediate to shallow continental crust levels (∼12.5 km depth) of hydrated basaltic melt under oxygen fugacity conditions above the nickel-nickel oxide buffer (ΔNNO = 0 to 2). Zircon SHRIMP U-Th-Pb age data constrain crystallization at 75.1–76.0 Ma, with scarce inherited zircons that record limited recycling of the Cordillera Real basement. These results confirm magmatic arc activity at the continental margin of South America during the late Cretaceous as a result of an E-dipping subduction zone prior to the accretion of the Ecuadorian-Colombian-Caribbean oceanic plateau, and support simultaneous double subduction at the northwest margin of South America during the Cretaceous.

Two episodes of Mesozoic mafic magmatism in the Nansha Block: Tectonic transition from continental arc to back-arc basin

It has been proposed that the proto-South China Sea (PSCS) existed in the southeastern continental margin of the South China Block (SCB) before the opening of the present South China Sea (SCS). However, the age of initial spreading and the geodynamics of the opening of the PSCS remain enigmatic. Here we present geochronological and geochemical data for diorite and diabase samples from Well NK-1, which was drilled into the Nansha Block in the Dangerous Grounds area of the southern SCS, to investigate their petrogenesis and their association with the formation of the PSCS. The Early Jurassic diorites (ca. 177 Ma) are geochemically similar to continental arc basalt, with enrichment in Rb, Ba, Pb, and Sr, and pronounced negative Nb, Ta, and Ti anomalies. They were originated from a mantle source metasomatized by subducted-sediment-derived melts in a continental arc setting related to subduction of the Paleo-Pacific plate beneath the SCB. The Early Cretaceous diabases (ca. 124 Ma) are compositionally similar to back-arc basin basalt, with enrichment in Rb, Ba, and Pb, and negligible Nb, Ta, Ti, Zr, and Hf anomalies. The mantle source of the diabases was metasomatized by aqueous fluids derived from the subducted slab in a back-arc basin associated with subduction of the Paleo-Pacific plate. Furthermore, the diabase samples are geochemically similar to mafic rocks and ophiolite complexes previously regarded as remnants of the PSCS oceanic crust. Therefore, the Early Cretaceous diabases in the Nansha Block are interpreted as representing coeval magmatism of the nascent ocean of the PSCS, indicating that the PSCS during the Early Cretaceous was a spreading back-arc basin associated with retreat of the subducting Paleo-Pacific plate.

Early Paleozoic long-lived silicic volcanism in the Eastern Puna Magmatic Belt, Argentina

In several locations along the Eastern Puna Magmatic Belt (EPMB) porphyritic rhyolite facies are interbedded with thinly bedded mudstone and fine-grained sandstone deposited during deepening of the marine setting. Previous research mainly focused on the northern part of EPMB, identified four main syn-sedimentary rhyolitic-dacitic volcanic episodes from Early to Late Ordovician, the oldest being Tremadocian (earliest Ordovician). In this contribution, we describe coherent rhyolite facies associated with volcaniclastic breccias in the central part of the EPMB (Cajón, Tuzgle, Concordia and Agua de Castilla creeks), and we present new geochemical data and U/Pb zircon ages on coherent rhyolite facies (Cajón, Huancar and Opla). The studied rhyolites are syn-sedimentary sills with peperitic margins. The coherent rhyolites have SiO2 content of ∼65–71 wt%, peraluminous signature, enrichment in LILE (Cs, Rb, Ba) and marked negative Sr, Ti and P anomalies. The REE patterns normalized to chondrite show a higher content of the light REE and a negative Eu anomaly (Eu/Eu* between 0.44 and 0.52). The integration of the regional data with our results suggests that at least two rhyolitic-dacitic volcanic episodes occurred during the Ordovician evolution of the EPMB: The Early Ordovician (∼485-462 Ma) including Tremadocian and Arenigian facies (Rio Taique, Niño Muerto, Huancar, Opla, northern Pastos Chicos, Agua Cavada, Muñayoc, oldest Quichagua, Cordón de Escaya, Cajón, Tuzgle, Concordia and Agua de Castilla); and the youngest Late Ordovician facies (∼449-443 Ma; Oplita, southern Pastos Chicos, Cordón de Escaya and youngest Quichagua). Hence, sedimentation and silicic volcanism across the Eastern Puna Magmatic Belt spanned at least in two episodes along the Ordovician period with more volume and duration during the Early Ordovician (ca. 20 Ma).

Mineralogical characteristics and Sr–Nd–Pb isotopic compositions of banded REE ores in the Bayan Obo deposit, Inner Mongolia, China: Implications for their formation and origin

Rare earth elements (REEs) are a focus of current research due to their importance in a wide range of industries and technologies. Bayan Obo in China is the largest REE deposit in the world. Although some studies have investigated the banded REE ores in the Bayan Obo deposit, the origin and formation processes of the ores are unclear. In this study, we used X-ray powder diffraction, electron microprobe, laser ablation–inductively coupled plasma–mass spectrometry, and mass spectrometry methods to investigate the mineral assemblages and geochemical characteristics of minerals in banded ores in the Bayan Obo REE deposit. Based on petrographic observations, the early minerals that precipitated were alkali- and Fe-rich silicates, such as aegirine–augite and arfvedsonite, followed by bastnäsite, fluorite, barite, calcite, and monazite in the late stage. The REE minerals in the banded REE ores are mainly monazite, bastnäsite, and parisite (1–10 vol%) that overprinted gangue minerals, suggesting that REE mineralization occurred during the late hydrothermal stage. The sequence of mineral formation and their evolution caused progressive enrichment in REEs, F, Sr, and Ba. For example, fluorite in the banded REE ores has high concentrations of Sr (252–1910 ppm), Ba (1040–8230 ppm), and light REEs (1001–16,079 ppm), but is depleted in Nb and Ta. The bastnäsite is enriched in Sr (885–4046 ppm), Ba (1073–80,809 ppm), and ΣREEs (99,631–158,227 ppm). The fluorite, arfvedsonite, and bastnäsite in the banded REE ores have ɛNd(t) values of −3.68–1.78, −5.54, and 0.05, and initial (87Sr/86Sr)i (ISr) ratios of 0.70352–0.70478, 0.70620, and 0.70346, respectively. Based on these data, and the regional geological setting and Pb isotope data, it is proposed that fluorite and bastnäsite crystallized from ferrocarbonatite and fine-grained dolomite, and the REE source was a mixture of HIMU mantle and global marine sediments. We also suggest that the carbonatite- or dolomite-hosting ores in Bayan Obo formed by melting of the subcontinental lithospheric mantle, which might have been previously metasomatized by REE- and CO2-rich fluids derived from subducted marine sediments.

Performance and stability analysis of SOFC containing thin and dense gadolinium-doped ceria interlayer sintered at low temperature

Gadolinium-doped ceria (GDC) interlayers are required to prevent the interfacial reaction between La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) cathode and Y2O3-stabilized ZrO2 (YSZ) electrolyte in solid oxide fuel cells (SOFCs). However, it's difficult to prepare a thin and dense GDC interlayer on the sintered half-cell at a low temperature. In this study, the physical vapor deposition (PVD) method was employed to successfully manufacture dense GDC interlayers with the thickness of 1 μm. The influences of GDC sintering temperature (900 °C, 1000 °C and 1100 °C) on cell performance characteristics and degradation behavior were investigated. The cell with GDC interlayer sintered at 1100 °C showed the lowest degradation rate during the 216-h operation. The best stability was attributed to the most effective inhibition of Sr diffusion by the GDC interlayer, which was demonstrated by the almost unchanged Ohmic and polarization resistances during the aging stage and the negligible Sr enrichment at YSZ/GDC interface. Compared to the conventional screen-printed GDC interlayers (sintered above 1250 °C), the GDC interlayer prepared by the PVD method and sintered at 1100 °C was significantly denser and thinner, showing a promising application prospect due to its benefits for cell stability.

Phonotephrite and phonolite in the Tarim Large Igneous Province, northwestern China: Petrological, geochemical and isotopic evidence for contrasting mantle sources and deep carbon recycling

The igneous units of Permian Tarim Large Igneous Province (TLIP) is typically characterized by alkaline affinity. Here we report for the first time the petrological, geochemical and isotopic characteristics of phonotephrite and phonolite dykes from the Wajilitag complex in the northwestern margin of the TLIP. Our data, especially Sr-Nd-Mg isotopes, suggest that the dykes have different mantle sources. Phonotephrite with mantle-like Mg isotope values (−0.295 to −0.382 ‰), relatively enriched Sr isotopes (0.70487 to 0.70574) and slightly lower εNd(t) values (−0.23 to +2.06), were possibly derived from a lithospheric mantle source that was metasomatized by calcitic carbonate melt. The phonotephrites are highly evolved rocks formed through fractional crystallization from a parental magma which is similar to that of the mafic–ultramafic intrusions. Phonolites show relatively depleted Sr isotopes (0.70362 to 0.70409), higher εNd(t) values (+1.27 to +3.45), markedly lighter Mg isotopes (−0.851 to −0.906‰) than the normal mantle indicating a mantle plume source with the involvement of carbonated eclogite. The parental magma of phonolites may be related to the liquid immiscibility with calciocarbonatites present in the Wajilitag complex due to their similar extremely light Mg isotopic compositions. The distinct geochemical features between two series of dykes in the Wajilitag complex reflect the diversity of mantle source of the TLIP, and their Sr-Nd-Mg isotopic characteristics indicate the role of subducted recycled sedimentary carbonates at different depths in the mantle.

Sr Surface Segregation; Implications for Oxygen Electrode Behavior and Routes to Mitigate Impact

The activation energy of the oxygen evolution/oxygen reduction process at perovskite type oxygen electrode materials is slightly higher than that of oxygen transport in the classical electrolyte materials, and also of that of the steam-splitting/hydrogen oxidation process at the fuel electrode. Today at 750 oC – 800 oC state of the art oxygen electrodes do not limit overall SOEC/SOFC performance, but when pushing the operation temperature lower, towards 600 oC the oxygen electrode can become limiting. Hence, there is still a need to develop high performing and importantly, durable, oxygen electrodes.One mechanism that has been reported to reduce oxygen exchange rates at Sr-containing perovskite type electrode materials is Sr segregation to the surface. This has especially been studied and observed on model systems like thin films [1, 2] and bulk materials [3, 4]. A surface enrichment in Sr will potentially make an electrode more vulnerable to degradation by reaction with gas-phase impurities like CO2 and Sulphur-species, but also to Cr-poisoning. Hence, it is important to study what drives such surface enrichment and how to mitigate its consequences.We have studied this in some detail on La0.6Sr0.4FeO3 both on thin films [2] and on bulk samples [4]. Interestingly, on the thin film model system, one can to some extent alleviate the consequences of the enrichment by leaching away excess Sr [1,2]. On the bulk samples, we have found that the oxygen exchange kinetics decrease with aging at low temperature (650 oC), but that the samples can be rejuvenated by a short high temperature treatment [4].In this contribution, we shall present the relation between the oxygen exchange rates measured on La0.6Sr0.4FeO3 surfaces and the chemistry of the surface. It turns out, that Sr enrichment to the surface occurs very fast and the “rejuvenation” treatment does not affect the Sr content at the surface, but rather in which phase/environment the Sr is found.We shall further discuss the implications of the learnings on above presented model-type-systems to the technical level, where often the materials are applied in form of composites.[1] Z. Cai, M. Kubicek, J. Fleig and B. Yildiz, Chem. Mater., 2012, 24, 1116–1127[2] Tripković, D., Küngas, R., Mogensen, M. B. & Hendriksen, P. V., 2020, Physical Chemistry Chemical Physics. 22, 27, p. 15418-15426[3] Edith Bucher, Werner Sitte, Solid State Ionics 192 (2011) 480–482.[4] Đ. Tripković, R. Küngas, M. B. Mogensen and P. V. Hendriksen, J. Mater. Chem. A, 2019, 7, 11782–11791. Figure 1

Exposure history, petrology, and shock‐induced sulfidization reaction of Alatage Mountain 001 strewn field samples

AbstractSeveral hundred meteorites with a total mass of over 100 kg were collected as the Alatage Mountain (AM) strewn field located in the Kumtag desert, Xinjiang Province, China. Twelve AM meteorites were studied in this work. Petrography, mineralogy, bulk chemistry, bulk oxygen isotopic compositions, and light noble gas concentrations and isotopic compositions were determined for all or for a selection of the meteorites. The studied meteorites are L‐chondrites that suffered a very strong impact; impact melt veins and melt pockets are widely distributed. More than 50% of the troilite exists in the form of blebs and veins in olivine and pyroxene. Some of these meteorites are impact melt recrystallized rocks (e.g., AM 037). The strong impact caused the decomposition of troilite, which led in AM 034 to the sulfidization reaction of olivine. The metal in most meteorites is almost completely altered, and the troilite has been significantly oxidized. Weathering resulted in the depletion of Mg, Fe, Co, and Ni, and the enrichment of Sr, Ba, Pb, and U in these meteorites. The cosmic ray exposure (CRE) ages measured for these specimens range between 6.2 ± 1.9 Ma and 9.0 ± 2.7 Ma, depending on the cosmogenic nuclide used. The average CRE age is 7.6 ± 1.3 Ma. Both 4He and 40Ar gas retention ages indicate that the strong impact which caused the shock effects occurred about 320 Ma ago.

Low-Ti gabbroic pluton in Dali, SW China: new evidence for back-arc lithospheric melting inducing early-stage magmatism of the Emeishan large igneous province

The Emeishan large igneous province (LIP) was emplaced on the western Yangtze plate during the Permian and its formation is primarily attributed to a mantle plume. Recent research has shown that material from this plume modified the melts in the Palaeotethys subduction zone. However, it remains poorly understood whether, in turn, the subduction of Palaeotethys affected the formation of the Emeishan LIP. We report here geochronological, petrological, geochemical and isotopic studies of a gabbroic intrusion located in Jiangwei, in the Dali area of the Emeishan LIP. The gabbro has a weighted mean SHRIMP U–Pb age of c. 262 Ma. The key geochemical features include: depletion in Nb, Ta and Ti; enrichment in Th, U and Sr; low light to heavy rare earth element ratios; 87 Sr/ 86 Sr (t) values of c. 0.707; and ε Nd (t) values of c. −0.21. We conducted pMELTS thermodynamic modelling and batch-melting calculations to evaluate the origin and evolution of the gabbro based on real components of low-Ti picrites and xenoliths from the Yangtze lithosphere. Our results show that 3% melting of a hydrated spinel peridotite source from the Yangtze lithosphere can produce magma equivalent to the gabbroic intrusion. Integrating this conclusion with the tectonic background of the western Yangtze plate and the volcano-stratigraphic record of the Emeishan LIP, we infer that the early-stage magmatism of the Emeishan LIP was triggered by Palaeotethys back-arc extension with fluid modification from the subducting slab. Supplementary material: Tables S1–S7 are available at https://doi.org/10.6084/m9.figshare.c.5433267

Cu-Ni mineralization in Early Permian mafic complexes in the Kalatage area of eastern Tianshan (NW China): Petrogenetic constraints from geochronology, geochemistry, and Hf-Sr-Nd-Os isotopes

The Early Permian was a critical period in the long history of accretion and collision of the southern Altaid orogen. Early Permian mafic-(ultramafic) intrusions and mafic–ultramafic-related sulfide Cu-Ni deposits are common in the eastern Tianshan, but the sulfide Cu-Ni deposits related to the mafic intrusions are still poorly studied, and yet provide key information on the ambient tectonic evolution. In order to help understand their petrogenesis, we report new data on the Early Permian mafic intrusions and related sulfide Cu-Ni deposits in the Dananhu arc of the eastern Tianshan in NW China. The ore-bearing Yueyawan complex is a well-differentiated, zoned mafic intrusion consisting of troctolite, olivine gabbro, layered gabbro, gabbro, and leucogabbro from the bottom upwards. The ore bodies are primarily strata-bound within olivine gabbros and troctolites at the bottom of the complex. The ores are more enriched in Cu than Ni than the more enriched, disseminated, veined and massive equivalents. Gabbros from the mafic complex yield zircon crystallization ages that range from 265 Ma to 273 Ma. The gabbros are tholeiitic and characterized by typical subduction-related geochemical signatures with low TiO2 contents, enrichments in Rb, Ba, U, K, Pb, and Sr, depletion in Nb and Ta, positive Eu and Ti anomalies, high εNd(t) values of +7.44 to +8.06, zircon εHf(t) values of +11.68 to +20.58, and low (87Sr/86Sr)i (0.703322–0.703416). The gabbroic rocks have positive correlations between SiO2 and TiO2, Al2O3, CaO, Nb, and Y, and negative correlations between SiO2 and MgO, Ni, and Co. The (187Os/188Os)i and γOs values of sulfides from the Yueyawan complex that contains Cu-Ni deposits range from 0.266 to 0.372 and 112 to 197, respectively. These geological, petrological, and geochemical characters indicate that the gabbros were mantle-derived, and that fractionation and crustal contamination were essential for the genesis of the magmatic Cu-Ni sulfide deposits. After integrating our data with those of previous investigations, we conclude that the protoliths of the sulfide deposits were probably derived from an asthenospheric garnet-free mantle in a subduction setting in the Early Permian. Oblique ocean-ridge subduction and a resultant slab window plausibly induced asthenospheric upwelling that gave rise to the generation of the mantle-derived melts, which likely moved into strike-slip faults through a slab window in the supra-subduction zone. Strong fractionation, crustal contamination, and multi-stage eruptions led to formation of the Cu-Ni sulfide deposits.

Geodynamic Setting and Cu-Ni Potential of Late Permian Xiwanggou Mafic-Ultramafic Rocks, East Kunlun Orogenic Belt, NW China

Several magmatic Cu–Ni sulfide deposits have recently been explored along the deep Middle Kunlun fault related to the extension of the East Kunlun orogenic belt in Qinghai Province, NW China. The Xiwanggou mafic–ultramafic rocks associated with Cu–Ni sulfide mineralization are first to be dated as late Permian compared to most of the deposits formed during late Silurian–early Devonian in this region. The Xiwanggou complexes located in the junction area between the East Kunlun and West Qinling belts, are composed of gabbros, olivine-gabbros, pyroxenites, olivine-pyroxenites, and peridotites. The Cu–Ni mineralization are mainly hosted in the olivine-pyroxenites and pyroxenites, whereas the sulfide-poor mineralization distributed in gabbros and olivine-gabbros. Zircon LA-ICP-MS U–Pb dating of the gabbro and olivine-pyroxenite revealed their crystallized ages of 250.8 ± 0.8 Ma and 257.3 ± 0.7 Ma, respectively. The trace element characteristics of the Xiwanggou fertile mafic-ultramafic rocks shows the enrichments in Sr, Rb, Th, Ba and light rare earth elements, and depletions in Nb and Ta, which are associated with the slab derived fluid input and dehydration melting of amphiboles. Meanwhile, Sr–Nd and Hf isotopic compositions of the gabbro [εNd(t) = 0.66–1.18; εHf(t) = 5.2–12] and olivine-pyroxenite [εNd(t) = −1.09 – −0.43; εHf(t) = 5.4–17.7] show that the magma was mainly derived from the metasomatized portions of subcontinental lithospheric mantle (SCLM) source in the mantle wedge. The magma primarily experienced dehydration melting processes of amphiboles and subsequently underwent hydrated melting in the overlying mantle wedge and relatively reduced background. The cool subduction process of the Anemaqen oceanic lithosphere maybe trigger large melting in the mantle wedge resulting in a relative low-Ni content in the melt. The transpressional windows formed by the right-lateral strike-slip shearing action of the Wenquan and South Kunlun faults in the South Kunlun forearc belt created a significant conduit for the magma ascending. The thermometer of Fe and Ni exchange between coexisting olivine and sulfide melt indicates the magma were yielded in a temperature range of ca. 1200–1300°C and an oxygen fugacity range of ca. –10.57 to –8.98 (log unit), which suggested that the parental magma of the Xiwanggou complex derived from a relatively reduced source favoring Ni relative to Fe in the melt. The intermediate sulfide segregation from the melt resulted in a medium tenor potential for the Xiwanggou complex.

Cr-poor and Cr-rich clinopyroxene and garnet megacrysts from southern African Group 1 and Group 2 kimberlites: Clues to megacryst origins and their relationship to kimberlites

Controversies surround the origin of kimberlite megacrysts, including whether and how they are genetically related to their host kimberlites, the relationship between the Cr-poor and Cr-rich suites and the dominant processes responsible for elemental and isotopic variations of megacrysts from a given kimberlite. We present new in-situ major and trace element and Sr isotopic results for clinoyroxene and garnet megacrysts from four southern African kimberlites: Colossus and Orapa (Group 1 kimberlites on the Zimbabwe craton), and Kalkput and Bellsbank (Group 2 kimberlites on the western Kaapvaal craton), that include both Cr-poor and Cr-rich megacryst varieties. Cr-poor megacrysts are present at Colossus, Orapa and Kalkput and the data exhibit tight, well-defined trends on major element diagrams as well as incompatible and rare earth element abundances similar to those previously reported for Cr-poor megacrysts. Cr-rich megacrysts, which are also present at Orapa and are the only variety present at Bellsbank, generally have higher Mg# values, lack well-defined major element trends and show stronger incompatible element enrichments as well as more radiogenic 87Sr/86Sri ratios than Cr-poor megacrysts from the same kimberlite group. Thermobarometry indicates that the Cr-poor megacrysts equilibrated at temperatures of ≈1200 to 1450 °C and pressures of 4.5 to 7.5 GPa. Cr-rich megacrysts, in contrast, extend to temperatures and pressures as low as 700 °C and 3 GPa, respectively. This indicates that, in the studied suites, Cr-poor megacrysts equilibrated at high temperatures in the lower lithosphere (>135 km), whereas Cr-rich megacrysts typically equilibrated at lower temperatures and pressures. Within the Cr-poor megacrysts from Group 1 and Group 2 kimberlites, there is a clear correspondence between kimberlite group, diagnostic incompatible element ratios (e.g., Nb/La) and Sr isotope ratios that parallel the differences noted between whole-rock Group 1 and Group 2 kimberlites. In the case of Cr-poor megacrysts, similar calculated melt compositions in equilibrium with garnet and clinopyroxene from the same kimberlite were obtained using recent high-pressure mineral‑carbonated melt partition coefficients. This suggests formation in conditions close to trace element equilibrium, and is consistent with crystallization from primitive melts with kimberlite-like trace element compositions. In the case of Cr-rich megacrysts, differences in the compositions of melts in equilibrium with clinopyroxene and garnet tend to be larger, and melts in equilibrium with Cr-rich clinopyroxene tend to show significantly greater incompatible element enrichments than those of estimated near-primary kimberlite melts. This could be due to the different behaviour of clinopyroxene and garnet during metasomatic melt-rock interaction, but the apparent disequilibrium between clinopyroxene and garnet could also be due to some of the Cr-rich megacrysts actually being peridotitic xenocrysts. We propose a model for the origin of southern African megacrysts in which carbonated protokimberlite melts formed stockwork-like bodies of variable size in the deep lithosphere (>130 km), which fed networks of melt-filled veins extending into the surrounding and overlying mantle. Crystallization of larger melt bodies resulted in megacryst assemblages dominated by Cr-poor megacrysts, and the incompatible element and isotopic characteristics of these dominantly reflect those of the protokimberlite melt. In contrast, crystallization of smaller melt bodies and their vein networks resulted in megacryst assemblages dominated by Cr-rich megacrysts, which formed as a result of extensive assimilation and metasomatic melt-rock interaction between protokimberlite and peridotite wallrock at low melt/rock ratios, particularly in the middle to shallow lithosphere where pre-existing potassic metasomatic heterogeneities are prevalent. The Cr-rich nature and enrichments in incompatible elements and radiogenic Sr in the Cr-rich megacrysts reflect extensive interaction of their parental magmas with this metasomatized peridotite.

Difference in the nature of ore-forming magma between the Mesozoic porphyry Cu-Mo and Mo deposits in NE China: Records from apatite and zircon geochemistry

Porphyry Cu-Mo and Mo deposits are the most important source of Mo in the world, but factors controlling their difference remain enigmatic. In recent years, many Mesozoic porphyry Cu-Mo and Mo deposits have been discovered in NE China, which provides a good opportunity to explore the difference between the Cu-Mo and Mo mineralization. In this region, porphyry Cu-Mo deposits (Wunugetushan, Jinchanggou) are distributed along the subduction zone, while the porphyry Mo deposits (Luming, Fu'anpu, Daheishan) are far away from the subduction zone. On the basis of whole rock geochemical studies, we present a comprehensive investigation on the apatite and zircon from Mesozoic typical porphyry Cu-Mo deposits and Mo deposits, in order to reveal the nature of parent magma constraints on Cu-Mo and Mo mineralization. Whole-rock geochemistry, in-situ apatite Sr-Nd and zircon Hf isotopic compositions from these granites in porphyry Cu-Mo and Mo deposits indicate that these granites originated from a juvenile crustal source. Apatites from the porphyry Cu-Mo mineralized granites show relatively high Cl and low F contents, accompanied by enrichment of fluid-mobile elements Ba and Sr, indicating that the magmatic source of porphyry Cu-Mo deposits were modified by subducted slab-derived fluids. In comparison, apatites from the porphyry Mo mineralized granites have high F and low Cl contents with correspondingly high F/Cl ratios, suggesting that these granites mainly formed in juvenile crustal dehydration self-metasomatism under the intra-continental environment. Additionally, apatites from porphyry Cu-Mo mineralized granites have higher OH contents than those from porphyry Mo mineralized granites, indicating that the original melt of porphyry Cu-Mo system was more hydrous, consistent with their higher (Ce/Nd)/Y and lower Dy/Yb ratios of zircon. It is here proposed that the formation of porphyry Cu-Mo deposits in NE China are related to partial melting of the juvenile crust, which metasomatized by slab-derived Cl-enriched fluids with carry significant amounts of Cu, whereas the porphyry Mo deposits are related to partial melting of juvenile crustal material with released F-enriched fluids by the dehydration of hydrous minerals.