Selective Enhancement Research Articles

Atomic decoration of MoS2 using Fe, Co or Ni for highly efficient and selective hydrodesulfurization

Hydrodesulfurization (HDS) is one of the most efficient processes for removing sulfur-containing molecules such as dibenzothiophene (DBT) from oil, whatever fossil based or bio-based. However, hydrodesulfurization using molybdenum sulfides (MoS2) as catalytic active centers and transition metals (X) as promoters is seriously challenged by the insufficient catalytic activity and selectivity because of the separate phases of sulfides, and sparse X-Mo-S active sites, leading to poor synergistic effect between the X promoter and MoS2 active centers. Herein, atomically doped MoS2 catalysts (denoted as XMo, X = Fe, Co or Ni) were synthesized by using polyoxometalate template-based synthetic strategy were proposed. The pre-organized Anderson-type POMs, [XMo6O24H6]n− (X = Fe, Co or Ni), acted as a pre-assembled molecular platform with intimate X-Mo interactions, ensure the uniform formation of X-Mo-S active sites after sulfuration. The promoter atoms, including Fe, Co and Ni, enhanced the efficiency of hydrodesulfurization of MoS2. Particularly, NiMo exhibits the highest HDS activity, while CoMo shows a moderate HDS activity with the highest DDS selectivity (∼85 %). Despite the lowest HDS activities, FeMo with the cheapest Fe promoter, shows good DDS selectivity (∼70 %). Further study reveal NiMo has the most laminated morphology and highest stacking slabs, resulting in the highest HDS activity. Benefiting from the Co(Fe)-Mo-S structure and abundant sulfur vacancy, CoMo and FeMo showed great enhancement in the DDS selectivity. Moreover, the DDS selectivity of these designed catalysts were supported energetically by first principle calculations. This research will expand on the ability to improve the HDS activities and DDS selectivity by precisely engineering catalytic active sites to achieve significant synergistic effect in atomic scale.

Selective Enhancer Gain of Function Deregulates MYC Expression in Multiple Myeloma

Abstract MYC deregulation occurs in the majority of multiple myeloma (MM) cases and is associated with progression and worse prognosis. Enhanced MYC expression occurs in about 70% of MM patients, but it is known to be driven by translocation or amplification events in only ~40% of myelomas. Here, we used CRISPR interference (CRISPRi) to uncover an epigenetic mechanism of MYC regulation whereby increased accessibility of a plasma cell-type specific enhancer leads to increased MYC expression. This native enhancer activity was not associated with enhancer hijacking events but led to specific binding of c-MAF, IRF4, and SPIB transcription factors that activated MYC expression in the absence of known genetic aberrations. In addition, focal amplification was another mechanism of activation of this enhancer in approximately 3.4% of MM patients. Together, these findings define an epigenetic mechanism of MYC deregulation in MM beyond known translocations or amplifications and point to the importance of non-coding regulatory elements and their associated transcription factor networks as drivers of MM progression.

A broad analysis of vegetative rescue and propagation of Moquiniastrum polymorphum (Less.) G. Sancho

Background: The primary method for propagating forest species is through seeds, which is cost-effective and ensures genetic adaptability to environmental changes. However, germination issues and genetic variability can hinder standardisation of productivity. In the case of Moquiniastrum polymorphum, a species known for its remarkable wood quality and pharmacological potential, seedling production and genetic improvement efforts have been limited. This study focused on the rescue and vegetative propagation of M. polymorphum, which are crucial steps for species selection and genetic enhancement. Methods: Protocols were tested to rescue and propagate propagules from different individuals collected in Lages, Santa Catarina (2020/2022). The vegetative rescue tests were: (I) epicormic sprouting induction through girdling techniques and detached branches; and (II) influence of individuals, disposition sense and time on the epicormic sprouting of detached branches. Vegetative propagation analyses included: (I) cutting according to individuals; and (II) relation between rooting environments and individuals on cutting. Results: The results indicated that the girdling techniques were not efficient for vegetative rescue, as only 8% of individuals produced epicormic sprouts. In contrast, detached branches showed a much higher success rate of 80% for epicormic sprouting, revealing significant differences in sprout development among individuals over time. Vertically oriented branches produced nearly three times more sprouts compared to horizontally oriented branches. Regarding vegetative propagation, certain individuals exhibited remarkable rooting rates of over 75%. However, no conclusive results were obtained when using epicormic materials or when considering different rooting environments. Conclusions: Given the significance of rescue and vegetative propagation in plant genetic improvement and the limited research addressing these aspects in M. polymorphum, this study holds substantial importance for future investigations. It is recommended to expand rescue and vegetative propagation studies to encompass additional populations, different individuals, and rooting environments, further advancing our understanding and efforts to enhance this species.

Enhanced selectivity of reactive intermediates by modifying electrodes with layered materials for the green high-salinity wastewater treatment

Improving the selectivity of the reactive intermediates such as ClO− and •OH by modifying nickel foam electrodes with ion exchangeable layered materials would greatly enhance the efficiency of high-salinity wastewater treatment. A universal pattern was verified herein that through functioning as a permeable overlayer regulating the transport of cations/anions, ClO− and •OH could be the predominant intermediates in the anionic/cationic layered material modified electrode. The significance of selectivity enhancement includes improving electrochemical efficiency and reducing the usage of chemical reagents. For instance, it is demonstrated that electrochemically degrading high salinity azo wastewater using decorated electrodes would be as effective as chemical treatment. Furthermore, electrochemical oxidation using cation layered material modified electrode could reduce the pKa of the oxidized cellulose filter paper as effectively as using H2O2.

Heterostructure ZIF-8@MXene with sieving effect in mixed matrix membranes for CO2 separation

At the present time, the realm of gas separation membranes is predominantly centered on the development of membrane materials that simultaneously exhibit exceptional gas permeability and selectivity. Mixed Matrix Membranes (MMMs) hold significant promise in addressing the long-standing challenge of balancing membrane selectivity with permeability. By incorporating a molecular sieving mechanism, an enhanced gas separation process is achieved. In this research endeavor, single-layer MXene nanosheets serve as an ideal substrate for the direct growth of ZIF-8 nanoparticles, yielding heterogeneously structured nanofillers, coined ZIF-8@MXene. The composite filler, ZIF-8@MXene, maintains a two-dimensional lamellar structure reminiscent of MXene, while also integrating ZIF-8 nanoparticles with their optimal pore size of 3.4 Å. This optimal pore size efficiently facilitates the unimpeded passage of CO2 molecules through the channels, creating a preferential pathway. Conversely, N2 molecules encounter greater difficulty traversing these channels, effectively coupling the solubility-diffusion mechanism with the molecular sieving mechanism to enhance selectivity in gas separation processes. Consequently, the mixed matrix membrane exhibits a remarkable enhancement in gas selectivity. Particularly, under sub-ambient conditions (−20 °C), the PEO/ZIF-8@MXene-0.3 % membrane achieves an exceptional CO2/N2 selectivity of 294.1, accompanied by a high CO2 permeability of 115.58 Barrer. This outstanding performance surpasses the 2019 upper bound, underscoring the significant potential of heterostructured nanofillers to be harnessed in advancing various mixed matrix membranes (MMMs) towards high-performance gas separation capabilities.

Identification of coating layer pipeline defects based on the GA-SENet-ResNet18 model

Detecting damage in coated pipelines is a challenging and costly task. This study proposes a method for pipeline defect identification based on VMD-DWT noise reduction and GA-SENet-ResNet18. Combining wavelet transform to convert denoised defect signals into time-frequency representations enhances the model's ability to capture both time-domain and frequency-domain features of defect signals, thereby improving its recognition capability for different types of defects. The study analyzed the feature extraction capabilities of ALexNet, GooleNet, VGG16, ResNet18, SENet-ResNet18, and GA-SENet-ResNet18 models in pipeline defect recognition. Experimental results show that SENet-ResNet18 achieved an accuracy of 0.9591 on the training set in 9m38s, significantly outperforming the first four models. GA-SENet-ResNet18 achieved 96.83 % accuracy, 96.67 % precision, 96.73 % recall, and 96.68 % F1 score in pipeline defect signal recognition. Compared to ResNet18, it improved accuracy by 2.06 %, precision by 1.94 %, recall by 2.09 %, F1 score by 2.37 %, with a reduction in time by 1m1s. The study demonstrates that the combined improvement of GA and SENet enhances ResNet18 not only in feature selection and response enhancement but also significantly improves its performance compared to traditional ResNet18 networks, making it more effective in pipeline defect recognition tasks. This research is crucial for ensuring pipeline system integrity and preventing pipeline accidents.

Zeolite-promoted platinum catalyst for efficient reduction of nitrogen oxides with hydrogen

Internal combustion engine fueled by carbon-free hydrogen (H2-ICE) offers a promising alternative for sustainable transportation. Herein, we report a facile and universal strategy through the physical mixing of Pt catalyst with zeolites to significantly improve the catalytic performance in the selective catalytic reduction of nitrogen oxides (NOx) with H2 (H2-SCR), a process aiming at NOx removal from H2-ICE. Via the physical mixing of Pt/TiO2 with Y zeolite (Pt/TiO2 + Y), a remarkable enhancement of NOx reduction activity and N2 selectivity was simultaneously achieved. The incorporation of Y zeolite effectively captured the in-situ generated water, fostering a water-rich environment surrounding the Pt active sites. This environment weakened the NO adsorption while concurrently promoting the H2 activation, leading to the strikingly elevated H2-SCR activity and N2 selectivity on Pt/TiO2 + Y catalyst. This study provides a unique, easy and sustainable physical mixing approach to achieve proficient heterogeneous catalysis for environmental applications.

Tandem Pt/TiO2 and Fe3C catalysts for direct transformation of CO2 to light hydrocarbons under high space velocity

CO2 hydrogenation to hydrocarbons under high space velocity is crucial for industrial applications, but traditional Fe-based catalysts often suffer from the low activity and poor stability. Herein, we report a new tandem catalyst system combining Pt/TiO2 catalysts with Fe3C catalysts for the direct conversion of CO2 into C2-C4 hydrocarbons under high space velocity. The Pt/TiO2 component promotes *CO intermediate production with an enhanced Reverse Water-Gas Shift (RWGS) reaction efficiency, providing a highly reactive species for the Fe3C catalyst to achieve Fischer-Tropsch synthesis (FTS). By maximizing the contact interface between the Pt/TiO2 and Fe-based components through a granule mixing configuration, we achieve significant enhancements in both CO2 conversion rate (24.0 %) and C2-C4 hydrocarbons selectivity (51.1 %) under the gaseous hourly space velocity (GHSV) of 100000 mL gcat−1h−1. Besides, excellent stability is achieved by the tandem catalysts with continuous catalysis for up to 80 h without significant decrease in activity. Through modulation of the reduction states of iron oxide, we effectively tune the composition of Fe-based catalyst, thereby tailoring the product distribution. Through this work, we not only offer a promising avenue for reducing CO2 for efficient CO2 utilization but also highlight the importance of catalyst design in advancing sustainable chemical synthesis.

Spatial segregation of catalytic sites within Pd doped H-ZSM-5 for fatty acid hydrodeoxygenation to alkanes

Spatial control over features within multifunctional catalysts can unlock efficient one-pot cascade reactions, which are themselves a pathway to aviation biofuels via hydrodeoxygenation. A synthesis strategy that encompasses spatial orthogonality, i.e., one in which different catalytic species are deposited exclusively within discrete locations of a support architecture, is one solution that permits control over potential interactions between different sites and the cascade process. Here, we report a Pd doped hierarchical zeolite, in which Pd nanoparticles are selectively deposited within the mesopores, while acidity is retained solely within the micropores of ZSM-5. This spatial segregation facilitates hydrodeoxygenation while suppressing undesirable decarboxylation and decarbonation, yielding significant enhancements in activity (30.6 vs 3.6 moldodecane molPd−1 h−1) and selectivity (C12:C11 5.2 vs 1.9) relative to a conventionally prepared counterpart (via wet impregnation). Herein, multifunctional material design can realise efficient fatty acid hydrodeoxygenation, thus advancing the field and inspiring future developments in rationalised catalyst design.

Research on Vertical Collaborative Innovation Mode Selection and Sustainability Enhancement of Industrial Cluster ‘Chain Master’

Research on Vertical Collaborative Innovation Mode Selection and Sustainability Enhancement of Industrial Cluster ‘Chain Master’

Selective signal enhancement in Fourier space as a tool for discovering ultrastructural organization of macromolecules from in situ TEM

We present a Fourier transform (FT) based analytical method that allows to obtain of ultrastructural details from TEM images at sub-nanometer scale applying a selective filtering for singular macromolecule electron microscopy density information. It can be applied to high-pressure frozen, frozen hydrated and epoxy freeze substituted and embedded biological species. Both 2D projections and orthoslices from reconstructed tomograms can be used as a source of structural information. The key to the method is to select the macromolecule or organelle of interest with an accuracy of ≥ 7 – 3 nm (depending on pixel size of initial tilt series or singular image acquisition) and explore both the central low frequency FT intensity and diffraction regions to obtain the spatial structural organization and its dimensional characteristics, respectively. We also introduce a structure-specific selective mask FT filtering approach that can significantly improve image information even in poorly contrasted TEM of resin sections without heavy metal been used. The described method elucidates chromatin architecture without the need of averaging. A zigzag symmetry of 30 nm diameter chromatin fibers which in general is a controversial topic of research has been identified for C. elegans cells in vivo with sub-nanometer details being preserved in the images.

When enough is enough: The impact of combined graphical impression management on financial judgement

The literature on impression management has identified three main types of graph manipulation: presentation enhancement, selectivity, and distortion. Nevertheless, no paper has analyzed the combined impact of all three techniques. Through an experiment involving 1701 certified public accountants, participants were exposed to graphs featuring all three manipulation techniques using distinct colors (blue, black, and red), all juxtaposed against graphs with no manipulation or a singular manipulation type. Our results show that selectivity alone has the same impact as distortion, selectivity, and presentation enhancement combined. Additional results demonstrate that the choice of color (blue versus red) in presentation enhancement, when combined with measurement distortion and selectivity, impact participants' perception differently. However, this effect is not observed when colorblind professionals are included.

Preparation of phosphorus-doped Cu-based catalysts by electrodeposition modulates *CHxO adsorption to facilitate electrocatalytic reduction of CO2 to CH4

Catalysts for the generation of methane in electrochemical CO2 reduction reactions (CO2RR) must have suitable adsorption energies for the intermediate products. In this study, we used a one-step electrodeposition method to prepare nitrogen(N) and phosphorus(P)-doped copper(Cu)-based catalysts. The introduction of P to the catalyst resulted in a significant change in the CO2RR pathway, leading to efficient and highly selective methane production. The Cu-N2-P2 electrocatalyst exhibits a CH4 Faradaic efficiency (FE) of 73 % at a potential of −1.6 V vs RHE, and it was found to be more effective in promoting the hydrogenation process of *CHO-*CH2O-*CH3O, which was confirmed by in-situ IR, X-ray absorption techniques and DFT calculations. P serves as the primary electron donation site in the catalyst, thereby influencing the charge distribution properties of the surrounding Cu atoms. This, in turn, facilitates the regulation of intermediate adsorption, representing the primary factor in the notable enhancement of methane selectivity.

Phenotypic and Molecular-Markers-Based Assessment of Jamun (Syzygium cumini) Genotypes from Pakistan

Jamun plant displays enormous diversity throughout Pakistan, which necessitates its screening, evaluation, and validation to document elite genotypes having better traits for the benefit of the fruit industry and farmers. Surveys were made in natural Jamun habitats across Punjab, Pakistan, and genotypes were marked based on visual diversity of trees and fruits. In total, 60 Jamun genotypes were selected for characterization based on phenotypic and genetic markers. Phenotypic characters related to trees, leaf, and flower along with fruit qualitative traits were assessed in situ. Results revealed significant diversity with high (>25%) coefficient of variance values and the first two components of correspondence analysis exhibited 41.71% variation among genotypes. A strong association was observed among traits like upright tree and round fruit shape (0.74), bluish-colored fruit and pinkish pulp (0.85), and elliptic-shaped fruit with low fruit waxiness (−0.72). Leaves of phenotypically characterized plants were brought to Wheat Biotechnology Lab., University of Agriculture, Faisalabad, Pakistan, where Jamun genotypes were investigated genetically using Random Amplified Polymorphic DNA (RAPD) and Inter Simple Sequence Repeat (ISSR) markers. A total of 132 bands were scored, of which 108 were polymorphic, corresponding to almost 81% polymorphism among collected genotypes. High polymorphism information content values were observed against RAPD (0.389) and ISSR (0.457) markers. Genotypes were compared in relation to genetic markers, which exhibited that almost 86% of genetic variability was attributed to differences among accessions, while 14% of variation was due to differences between collections of different areas. Findings of this study confirmed wide phenotypic and genetic distinctness of Jamun in Pakistan that can aid breeders for marker-assisted selection and germplasm enhancement for future crop improvement programs.

Distinct melanocyte subpopulations defined by stochastic expression of proliferation or maturation programs enable a rapid and sustainable pigmentation response.

The ultraviolet (UV) radiation triggers a pigmentation response in human skin, wherein, melanocytes rapidly activate divergent maturation and proliferation programs. Using single-cell sequencing, we demonstrate that these 2 programs are segregated in distinct subpopulations in melanocytes of human and zebrafish skin. The coexistence of these 2 cell states in cultured melanocytes suggests possible cell autonomy. Luria-Delbrück fluctuation test reveals that the initial establishment of these states is stochastic. Tracking of pigmenting cells ascertains that the stochastically acquired state is faithfully propagated in the progeny. A systemic approach combining single-cell multi-omics (RNA+ATAC) coupled to enhancer mapping with H3K27 acetylation successfully identified state-specific transcriptional networks. This comprehensive analysis led to the construction of a gene regulatory network (GRN) that under the influence of noise, establishes a bistable system of pigmentation and proliferation at the population level. This GRN recapitulates melanocyte behaviour in response to external cues that reinforce either of the states. Our work highlights that inherent stochasticity within melanocytes establishes dedicated states, and the mature state is sustained by selective enhancers mark through histone acetylation. While the initial cue triggers a proliferation response, the continued signal activates and maintains the pigmenting subpopulation via epigenetic imprinting. Thereby our study provides the basis of coexistence of distinct populations which ensures effective pigmentation response while preserving the self-renewal capacity.

Impact of Exposed Crystal Facets on Oxygen Reduction Reaction Activity in Zeolitic Imidazole Frameworks

Oxygen reduction reactions (ORR) are critical reactions for efficient sustainable and renewable energy storage. However, the limitation of ORR is a slow kinetic reaction due to the multi-step transfer mechanism of electrons. Therefore, electrocatalysts with high ORR activity and stability are needed to overcome the reaction limitations. Zeolitic imidazole framework-67 (ZIF-67) has attracted attention in electrochemical applications due to its multiple redox-active sites and high stability in alkali conditions. The Co-doped porous carbon catalysts derived from ZIF-67 have the potential to be used as ORR catalysts with high performance, while pure phase ZIF-67 electrocatalyst for ORR is rarely studied. The work studies the importance of crystal facets on ORR reactivity. The results show that ZIF-67 nanocube exhibits excellent ORR activity with lower half wave-potential and faster kinetics process compared to its bulk structure. It is proposed that ZIF-67 nanocube provides improvement of selectivity for the four-electron pathway, which is a favorable process with higher reaction efficiency. The density functional theory (DFT) calculations suggest unsaturated Co2+ active sites with enriched (100) facets in the cubic crystal. Therefore, the fast diffusion of oxygen molecules to active sites and strong interaction with intermediate are observed in a cubic structure. The correspondence between experiment and calculation offers enhancement of ORR activity and selectivity from control-specific growth of (100) facet with cubic shape. The work introduces a new strategy for designing highly efficient ORR electrocatalysts with facet-controlled, allowing further study in other electrochemical reactions.

Novel Cu(200)/Ti cathode for the enhancement of N2 selectivity in direct ammonia electrolysis: The controls of Cu cathode facet orientation

Direct electrochemical ammonia oxidation reaction (AOR) using NiCu-based anodes is effective in removing ammonia from wastewater. However, this type of anode frequently produces undesired byproducts NO3−. Here, we investigated three configurations of novel Cu/Ti cathodes (Cu(111)/Ti, Cu(200)/Ti, Cu(220)/Ti) coupled with Cu/Ni foam (Cu/NF) anode to enhance N2 selectivity (SN2) in a direct ammonia electrolysis cell. Cu(200)/Ti cathode improved SN2 from 35 % (bare Ti cathode) to 60 % and it achieved 10–15 % higher SN2 compared to Cu(111)/Ti and Cu(220)/Ti. The improvement of SN2 on Cu(200) facet was ascribed to the high nitrate electroreduction activity and its conversion to N2. In real wastewater, Cu/NF anode-Cu(200)/Ti cathode paired electrolysis system demonstrated its excellent capability of 88 % NH3 removal with 95 % SN2. Our electrolysis system was capable to maintain the residual NH3-N and the NO3-N below 8 mg L−1, meeting effluent discharge standards. Our findings highlighted the importance of the control of Cu cathode facet orientations for an efficient elimination of NO3– and improvement of N2 production during direct ammonia electrolysis.

Transferable Optical Enhancement Nanostructures by Gapless Stencil Lithography.

Optical spectroscopy techniques are central for the characterization of two-dimensional (2D) quantum materials. However, the reduced volume of atomically thin samples often results in a cross section that is far too low for conventional optical methods to produce measurable signals. In this work, we developed a scheme based on the stencil lithography technique to fabricate transferable optical enhancement nanostructures for Raman and photoluminescence spectroscopy. Equipped with this new nanofabrication technique, we designed and fabricated plasmonic nanostructures to tailor the interaction of few-layer materials with light. We demonstrate orders-of-magnitude increase in the Raman intensity of ultrathin flakes of 2D semiconductors and magnets as well as selective Purcell enhancement of quenched excitons in WSe2/MoS2 heterostructures. We provide evidence that the method is particularly effective for air-sensitive materials, as the transfer can be performed in situ. The fabrication technique can be generalized to enable a high degree of flexibility for functional photonic devices.

Constructing Microporous Ion Exchange Membranes via Simple Hypercrosslinking for pH‐Neutral Aqueous Organic Redox Flow Batteries

AbstractIon exchange membranes (IEMs) play a critical role in aqueous organic redox flow batteries (AORFBs). Traditional IEMs that feature microphase‐separated microstructures are well‐developed and easily available but suffer from the conductivity/selectivity tradeoff. The emerging charged microporous polymer membranes show the potential to overcome this tradeoff, yet their commercialization is still hindered by tedious syntheses and demanding conditions. We herein combine the advantages of these two types of membrane materials via simple in situ hypercrosslinking of conventional IEMs into microporous ones. Such a concept is exemplified by the very cheap commercial quaternized polyphenylene oxide membrane. The hypercrosslinking treatment turns poor‐performance membranes into high‐performance ones, as demonstrated by the above 10‐fold selectivity enhancement and much‐improved conductivities that more than doubled. This turn is also confirmed by the effective and stable pH‐neutral AORFB with decreased membrane resistance and at least an order of magnitude lower capacity loss rate. This battery shows advantages over other reported AORFBs in terms of a low capacity loss rate (0.0017 % per cycle) at high current density. This work provides an economically feasible method for designing AORFB‐oriented membranes with microporosity.

Enhanced electrocatalytic nitrate reduction via carbon material integration between Cu and Ni-foam: Mechanisms and performance analysis

This study investigates the electrocatalytic reduction of nitrates using three novel electrodes: Cu@CNFs/NF, Cu@CNTs/NF, and Cu@CB/NF, synthesized via an impregnation-calcination-electrodeposition technique. The emphasis is on the role of different carbon materials, which serve as the base or matrix for Cu, and their influence on nitrate reduction and nitrogen selectivity. Experimental results indicated that all three-electrode variants outperformed the conventional Cu/NF electrode in nitrate reduction and nitrogen selectivity. Among these, the Cu@CNFs/NF electrode emerged as the standout performer, achieving an impressive nitrate reduction rate of up to 98 % and a nitrogen selectivity of 51 % under the optimized experimental conditions (pH 7, nitrate concentration of 100 mg∙L-1 as NO3–-N, a current density of 8 mA cm−2, a sodium sulfate concentration of 0.5 g∙L-1, 120 min, anode: Ti/RuO2-IrO2). Stability tests confirmed that the Cu@CNFs/NF electrode maintained over 97 % nitrate removal efficiency across ten cycles, highlighting its robustness and potential for practical water treatment applications. A significant enhancement in nitrogen selectivity of Cu@CNFs/NF to 96 % was observed when using 0.75 g∙L-1 NaCl as the electrolyte during an extended electrolysis period of 180 min, underscoring its potential to optimize catalytic efficiency. Characterization data from SEM, XRD, and other analyses substantiate that the incorporation of carbon materials augments the active sites of copper; Nitrogen adsorption–desorption experiments further illustrate that the integration of carbon materials leads to an increase in mesoporous volume. This increase promotes adsorptive interactions, enhances the conversion of intermediates, and contributes to the improvement of nitrate reduction and nitrogen selectivity. These results highlight the potential of tailored carbon material integration for enhancing the electrocatalytic performance of electrodes in practical water treatment applications.