Enhancement Of Electronic Conductivity Research Articles

Adsorption Isotherm Analysis for Hybrid Molecularly Imprinted Polymeric Gold-Decorated Nanoparticles Suitable for Reliable Quantification of Gluconic Acid in Wine

A class of hybrid molecularly imprinted polymeric nanoparticles (nanoMIPs) comprising the in situ formation of gold nanoparticles (AuNPs) immobilised in a molecularly imprinted D-gluconate polymer has been designed with the objective of attempting the electrochemical quantification of gluconic acid (GA) in a wine setting. The imprinted polymers were synthesised in the presence of AuNP precursors in a pre-polymerisation mixture, which were confined to one another during the polymerisation of the chains. This allowed the formation of hybrid electroactive responsive imprinted nanoparticles (hybrid AuNPs@GA-nanoMIP), which exhibited enhanced electron conductivity. The morphological characterisation of the produced nanoMIPs revealed a fully decorated Au spherical surface of 200 nm in diameter. This resulted in a large active surface area distribution, as well a pronounced electrochemical peak response at the commercial screen-printed platinum electrode (SPPtE), accompanied by enhanced electron kinetics. The AuNPs@GA-nanoMIP sensor demonstrated the ability to detect a broad range of GA concentrations (0.025–5 mg/mL) with exceptional selectivity and reproducibility. The calibration curves were fitted with different isotherm models, such as the Langmuir, Freundlich and Langmuir–Freundlich functions. Moreover, the efficacy of the detection method was demonstrated by the recovery rates observed in real samples of Italian red wine. This research contributes to the development of a robust and reliable electrochemical sensor for the on-site determination of gluconic acid in food analysis.

MOF-Derived Carbons Coupled CdSe Quantum Dots for Solar Hydrogen Production

Metal-organic framework (MOF)-derived carbons have increasingly captivated the scientific community, owing to their remarkable attributes such as mesoporous configurations, enhanced electron conductivity, and robust chemical stability. This study introduces a novel low-temperature synthesis approach for ZIF-67-derived carbons, further augmented by integration with CdSe quantum dots to boost photocatalytic efficiency for solar hydrogen production. Through detailed analysis using time-resolved photoluminescence spectroscopy and in-situ X-ray absorption spectroscopy, the electronic synergies between ZIF-67-derived carbons and CdSe quantum dots were thoughtfully explored. The resultant composites demonstrated a photocatalytic hydrogen production rate of 10.4 mmol g-1 hr-1, showcasing significant apparent quantum yields of 8.1% at 300 nm and 6.4% at 420 nm. Recycling assays revealed a superior chemical durability, effectively mitigating the typical photocorrosion issue of CdSe when coupled with ZIF-67-derived carbons. This investigation presents a groundbreaking paradigm in photocatalyst design, merging MOF-derived carbons with semiconductor nanostructures to advance the field of photocatalytic applications.

Enhanced anodic performance of CTF0 monolayer for Li-ion batteries through F and Si co-doping: A DFT insight

Covalent triazine frameworks (CTFs) have been identified as promising electrode materials for Li-ion batteries (LIBs) because of their high surface area, adjustable conjugated structures, and good chemical/thermal stability. However, their low electrical conductivity limits electron and ion conduction, leading to poor electrochemical performance. In this work, a novel CTF-based monolayer, namely F and Si co-doped CTF0 (F,Si-CTF0), was designed using density functional theory (DFT) calculations. The results demonstrated that the co-doping of F and Si atoms on the CTF0 surface creates more accessible adsorption sites for Li-ion adsorption. The energy analysis confirmed the stability of the F,Si-CTF0 monolayer, which exhibits a notable adsorption energy of −3.53 eV for Li-ion. The F,Si-CTF0 monolayer can accommodate five Li-ions, providing a theoretical specific capacity of 462 mAh g−1 and a positive redox potential of 2.57 V. adsorption of Li ions on the F,Si-CTF0 monolayer leads to a transition from a semiconducting to a metallic state, resulting in a notable enhancement in electronic conductivity. Moreover, the monolayer undergoes minor lattice variations (1.3 %) throughout the lithiation/delithiation process, demonstrating excellent cycling performance. Finally, Li-ion diffuses rapidly on the monolayer surface with a very small diffusion energy barrier of 0.078 eV. The findings suggest that the F,Si-CTF0 monolayer can be used as a viable anode material in next-generation LIBs. This research shows that F and Si co-doping is an effective and viable strategy for designing two-dimensional CTF-based materials as efficient electrodes for LIBs.

Nanofibers endow NASICON-type Na3.3La0.3Zr1.7Si2PO12 electrolyte/Na4MnCr(PO4)3 cathode excellent electrochemical properties

All-solid-state sodium-ion batteries (ASSSIBs) using composite polymer electrolytes (CPEs) are promising candidates for addressing the high cost, safety issues, and limited energy density of traditional lithium-ion batteries. The microstructure and morphology of active ceramic filler and cathode seriously affect the construction of ion/electron transport channels and electrochemical performance, while the contact tightness at the electrode/CPE interface determines the release of energy storage performance in ASSSIBs. Here, NASICON-type Na3.3La0.3Zr1.7Si2PO12 (NLZSP) ceramic nanofibers (NFs) and Na4MnCr(PO4)3@C (NMCP@C) NFs are prepared via electrospinning. NLZSP long NFs (L-NFs) can be uniformly dispersed in PVDF-HFP using ultrasonic treatment to create rapid ion transport pathways within the ceramic and polymer/ceramic interphases, enabling the CPE to achieve high ionic conductivity of 3.36 × 10−4 S·cm−1, wide electrochemical stability window (ESW) exceeding 5 V, low activation energy (Ea) of 0.28 eV and sodium-ion transference number (TNa+) of 0.65 at room temperature. Meanwhile, NMCP@C NFs can enhance electron conductivity and reduce the sodium ion migration path, and finally achieve a superhigh specific capacity (161 mAh·g−1) and energy density (534 Wh·kg−1) at 0.1C. Additionally, the integrated NMCP@C/CPE structure is incorporated into NMCP@C/CPE//Na solid state sodium metal batteries (SMBs), which exhibits excellent rate performance and high capacity retention of 78.8 % at 1C (1.4–4.3 V) and 70.5 % at 0.5C (1.4–4.6 V) after 200 cycles. This study offers valuable insights into constructing high-performance ASSSIBs.

Interlayer Space Engineering-Induced Pseudocapacitive Zinc-Ion Storage in Holey Graphene Oxide-Bearing Vertically Oriented MoS2 Nano-Wall Array Cathode for Aqueous Rechargeable Zn Metal Batteries.

Transition metal dichalcogenides, particularly MoS2, are acknowledged as a promising cathode material for aqueous rechargeable zinc metal batteries (ARZMBs). Nevertheless, its lack of hydrophilicity, poor electrical conductivity, significant restacking, and restricted interlayer spacing translate into inadequate capacity and rate performance. Herein, the unique porous structure and additional functional groups present in holey graphene oxide (hGO) are taken advantage of to dictate the vertical growth pattern of oxygen-doped MoS2 nanowalls (O-MoS2/NW) over the hGO surface. Compared to conventional graphene oxide (GO), the presence of nano-pores in hGO facilitates the homogeneous dispersion of Mo precursors and provides stronger interaction sites, promoting the uniform vertical alignment of O-MoS2/NW. The synergistic interaction between O-MoS2-NW and hGO translates to enhanced electron conductivity, efficient electrolyte penetration, enhanced interlayer spacing, reduced restacking, and enhanced surface area. As a consequence of precise control of various factors that decide the overall battery performance, a high discharge capacity (227mAhg-1 at 100mAg-1) cathode material with significantly lower charge transfer resistance (66Ω) compared to pristine O-MoS2 (153Ω) is developed. These findings underscore the potential of hGO as a multifunctional platform for nanoengineering high-performance cathode materials for the next generation of efficient and durable ARZMBs.

Engineering ceria oxide with nickel doping and rich oxygen vacancies for enhanced electrocatalytic degradation of aromatic organics

Aromatic dyes are widely applicable in the textile, leather, and ink industries yet receive serious contamination issues to water bodies, soil, and even air. Herein, we develop an efficient electrocatalytic oxidation method for degrading aromatic dyes via developing supportive CeO2-based electrode materials decorating with highly dispersive Ni and rich oxygen vacancies. The decorating Ni species are in situ converted from a composite of CeO2 nanocrystals and formamide-derived polyaminoimidazole (PAI)-coordinated Ni to ensure the high dispersion of Ni species. The decomposition of PAI ligands also helps to create the localized reductive atmosphere for the generation of rich surface oxygen vacancies, which further benefits the enhancement of electronic conductivity and charge transport ability. The effects of Ni doping concentrations, Rhodamine B (RhB, as a simulating aromatic dye) concentrations, pH of RhB solution, types and concentrations of electrolytes, and working current densities on the degradation performance are comprehensively investigated. Electrocatalytic measurements reveal that the CeO2 catalyst with optimal Ni concentration and fine single-crystal sizes of 5.5 ± 0.03 nm (termed as Ni0.025-CeO2-x) exhibits very promising degradation efficiency (96.9 %) and structural durability (repeated use for 5 cycles with limited activity decrease).

Efficient CQDs/Cu2S @Ti-TPA-MOF heterojunction incorporation: A visible-light-photocatalytic composite with extended separated charges lifetime

A sustainable strategy to tackle water pollution involves using innovative composites based on MOFs for photodecomposing antibiotic contaminants. A core-shell structure was synthesized using a solvothermal method, combining Cu2S, carbon quantum dots (CQDs), and Ti-TPA-MOF, resulting in a material with excellent visible-light capture capabilities. Spectroscopic (XRD, XPS, BET, DRS, DLS, ESR, and PL), electrochemical (photocurrent), and microscopic (TEM) analyses were performed to characterize the photocatalyst. Adding 20 mg of Cu2S and CQDs greatly improved gentamicin photodegradation compared to other prepared photocatalysts. This was due to enhanced electron conductivity, increased photocurrent density, a narrower energy gap, and a longer charge separation lifetime. The heterojunction composites at 150 mg/l showed a 2–6 times increase in efficiency after 90 min, surpassing the pure materials. The outcomes showed evidence of pseudo-first-order kinetics, photocatalytic activity, and excitation by visible light in the photodegradation. The stability of the photocatalytic process is evident after five cycles.

Multi-Doping Exploration of (Sb, Bi and Ba) by First Principles on Ordered Zn–Si–P Compounds as High-Performance Anodes for Next-Generation Li-Ion Batteries

Chalcopyrite ZnSiP2 has emerged as a promising anode material for next generation Li-ion-based batteries due to its high theoretical capacity. First principles multiple-dopant effect computations were made on the structural, electronic, magnetic, and thermodynamic responses for chalcopyrite ZnSiP2(1−x)Sbx, ZnSiP2(1−x)Bix, Zn(1−x)BaxSiP2, and Zn1−xBaxSiP2(1−x)Sbx, using both the norm conserving, ultra-soft pseudopotentials with generalized gradient approximation (GGA+PBE) and the main frame of density functional theory. Lattice coefficient volume, bulk modulus, formation energy, and total energy of host materials were computed and compared with experimental and theoretical results. Energy band gap for the pure chalcopyrite ZnSiP2 system (1.4 eV) matches previous data and validates the accuracy of current calculations as doping concentration (x = 0.6, 0.9, and 0.12) of (Sb, Bi, and Ba) at Zn and P sites increases. The corresponding band gap decreases, resulting in greater enhancement in electronic conductivity. Finally, the phonon dispersion relation, phonon density of states, vibration frequencies of phonon, Gibbs free energy, enthalpy, entropy effect, and Debye temperature (θ D) were estimated to confirm the thermodynamic stability of both pure and doped systems. These investigations are predicted to contribute a deeper sympathy of the doping effects on ZnSiP2, facilitating further advancements in anode materials design for Li-ion batteries.

Ab Initio Prediction of Two-Dimensional GeSiBi2 Monolayer as Potential Anode Materials for Sodium-Ion Batteries.

The conceptualization and deployment of electrode materials for rechargeable sodium-ion batteries are key concerns for next-generation energy storage systems. In this contribution, the configuration stability of single-layer GeSiBi2 is systematically discussed based on first-principles calculations, and its potential as an anode material is further investigated. It is demonstrated that the phonon spectrum confirms the dynamic stability and the adsorption energy identifies a strong interaction between Na atoms and the substrate material. The electronic bands indicative of inherent metallicity contribute to the enhancement of electronic conductivity after Na adsorption. The multilayer adsorption of Na provides a theoretical capacity of 361.7 mAh/g, which is comparable to that of other representative two-dimensional anode materials. Moreover, the low diffusion barriers of 0.19 and 0.15 eV further guarantee the fast diffusion kinetics. These contributions signal that GeSiBi2 can be a compatible candidate for sodium-ion batteries anodes.

Pseudocapacitive TiNb0.8O4 microspheres for fast-charging and durable sodium storage

Titanium niobium oxides are promising anode materials for sodium-ion batteries (SIBs) due to their efficient ion diffusion channels. However, their poor electronic conductivity impedes the longevity of SIBs. To address these issues, core@shell TiNb0.8O4/C@C microspheres (TNO/C@C) have been developed to enhance electron conduction. The TNO/C@C, featuring a bulk and surface dual conductive configuration, outperforms pure TNO and other control samples such as TNO/C and TNO@C that rely solely on either bulk or surface electronic conductors. Thus, the TNO/C@C achieves a fast-charging rate of 200 C, allowing full charging in 2 s, and demonstrates long-term stability over 10,000 cycles. In-situ Raman analysis reveals a zero-strain feature during sodiation/desodiation, which minimizes structural degradation over repeated cycles. In-situ electrochemical impedance spectroscopy test indicates low electron resistance, enhancing both the rate capability and stability. Therefore, the bulk and surface dual conducting strategy offers new insights into robust and fast-charging SIBs.

A novel composite (Bi2WO6/TiS2) presenting an excellent Z-scheme photocatalytic degradation for methylene blue dye under the visible light irradiation

The current research direction in the field is the development of a Z-scheme composite photocatalyst for the purpose of degrading organic materials in water. The Solvo-thermal synthesis method was employed to successfully synthesize a novel Z-scheme photocatalyst namely Bi2WO6/TiS2@3 %, Bi2WO6/TiS2@6 % and Bi2WO6/TiS2@9 % which is driven by visible light. The materials physicochemical properties were assessed using several analytical methods i.e. XRD, EDX, SEM, TEM, FTIR, UV–vis, PL, Raman spectroscopy and EIS. The Bi2WO6/TiS2@6 % composite revealed the maximum photocatalytic efficiency in the removal of MB dye (98 %) in 70 min. The results of the free radical trap studies indicate that h+ and •O2− are the primary free radicals involved in the photocatalytic degradation. The photocatalytic performance of the composite was improved due to the creation of a heterojunction between Bi2WO6 and TiS2 resulted in enhanced electron conduction, efficient separation of photogenerated e- and h+. Furthermore, it has been shown through six cycle test that the hybrid material consisting of Bi2WO6/TiS2@6 % exhibited a consistent degrading capability (91 %) during the photodegradation process. This distinctive heterojunction photocatalyst material exhibits extensive potential for application in the elimination of organic contaminants and cleanup of the environment.

Cation doping and oxygen vacancies in the orthorhombic FeNbO4 material for solid oxide fuel cell applications: A density functional theory study.

The orthorhombic phase of FeNbO4, a promising anode material for solid oxide fuel cells (SOFCs), exhibits good catalytic activity toward hydrogen oxidation. However, the low electronic conductivity of the material specifically in the pure structure without defects or dopants limits its practical applications as an SOFC anode. In this study, we have employed density functional theory (DFT + U) calculations to explore the bulk and electronic properties of two types of doped structures, Fe0.9375A0.0625NbO4 and FeNb0.9375B0.0625O4 (A, B = Ti, V, Cr, Mn, Co, Ni) and the oxygen-deficient structures Fe0.9375A0.0625NbO3.9375 and FeNb0.9375B0.0625O3.9375, where the dopant is positioned in the first nearest neighbor site to the oxygen vacancy. Our DFT simulations have revealed that doping in the Fe sites is energetically favorable compared to doping in the Nb site, resulting in significant volume expansion. The doping process generally requires less energy when the O-vacancy is surrounded by one Fe and two Nb ions. The simulated projected density of states of the oxygen-deficient structures indicates that doping in the Fe site, particularly with Ti and V, considerably narrows the bandgap to ∼0.5eV, whereas doping with Co at the Nb sites generates acceptor levels close to 0eV. Both doping schemes, therefore, enhance electron conduction during SOFC operation.

Improved cycle stability and high-rate capability of LiNbO3-coated Li3VO4 as anode material for lithium-ion battery

Lithium vanadate (Li3VO4) has garnered considerable attention as an alternative negative electrode material for non-aqueous lithium-ion batteries due to its high capacity, energy efficiency, and stable discharge voltage. Nonetheless, the Li3VO4 material displays a low rate capability, attributed mainly to its poor intrinsic electronic conductivity. Here, we report the synthesis of lithium niobate LiNbO3-coated Li3VO4 (LVO@LNO) using a one-pot sol-gel method. The resulting LVO@LNO demonstrates a high reversible capacity of approximately 530 mAh/g, which is more than double that of free Li3VO4. To explore the effect of the LNO coating process on the morphological and structural properties, Raman, XRD, operando XRD, XPS, SEM and HTEM analyses were conducted. To explain the enhancement of electronic conductivity in our modified material after a LiNbO3 coating, we conducted an Ex-Situ electrochemical impedance (EIS) and Density Functional Theory (DFT) computational study. Additionally, we designed a full cell utilizing a 1 wt% LNO-coated LVO anode and NMC-811 cathode. The cell yielded an output voltage of approximately 2.8 V with a high initial specific capacity of 350 mAh/g versus to the anode, at 1C with a capacity retention of 85 % after 100 cycles.

Titania/graphene nanocomposites from scalable gas-phase synthesis for high-capacity and high-stability sodium-ion battery anodes

In sodium-ion batteries (SIBs), TiO2 or sodium titanates are discussed as cost-effective anode material. The use of ultrafine TiO2 particles overcomes the effect of intrinsically low electronic and ionic conductivity that otherwise limits the electrochemical performance and thus its Na-ion storage capacity. Especially, TiO2 nanoparticles integrated in a highly conductive, large surface-area, and stable graphene matrix can achieve an exceptional electrochemical rate performance, durability, and increase in capacity. We report the direct and scalable gas-phase synthesis of TiO2 and graphene and their subsequent self-assembly to produce TiO2/graphene nanocomposites (TiO2/Gr). Transmission electron microscopy shows that the TiO2 nanoparticles are uniformly distributed on the surface of the graphene nanosheets. TiO2/Gr nanocomposites with graphene loadings of 20 and 30 wt% were tested as anode in SIBs. With the outstanding electronic conductivity enhancement and a synergistic Na-ion storage effect at the interface of TiO2 nanoparticles and graphene, nanocomposites with 30 wt% graphene exhibited particularly good electrochemical performance with a reversible capacity of 281 mAh g−1 at 0.1 C, compared to pristine TiO2 nanoparticles (155 mAh g−1). Moreover, the composite showed excellent high-rate performance of 158 mAh g−1 at 20 C and a reversible capacity of 154 mAh g−1 after 500 cycles at 10 C. Cyclic voltammetry showed that the Na-ion storage is dominated by surface and TiO2/Gr interface processes rather than slow, diffusion-controlled intercalation, explaining its outstanding rate performance. The synthesis route of these high-performing nanocomposites provides a highly promising strategy for the scalable production of advanced nanomaterials for SIBs.

Reversible Enhancement of Electronic Conduction Caused by Phase Transformation and Interfacial Segregation in an Entropy‐Stabilized Oxide

AbstractEntropy‐stabilized oxide (ESO) research has primarily focused on discovering unprecedented structures, chemistries, and properties in the single‐phase state. However, few studies discuss the impacts of entropy stabilization and secondary phases on functionality and in particular, electrical conductivity. To address this gap, electrical transport mechanisms in the canonical ESO rocksalt (Co,Cu,Mg,Ni,Zn)O are assessed as a function of secondary phase content. When single‐phase, the oxide conducts electrons via Cu+/Cu2+ small polarons. After 2 h of heat treatment, Cu‐rich tenorite secondary phases form at some grain boundaries (GBs), enhancing grain interior electronic conductivity by tuning defect chemistry toward higher Cu+ carrier concentrations. 24 h of heat treatment yields Cu‐rich tenorite at all GBs, followed by the formation of anisotropic Cu‐rich tenorite and equiaxed Co‐rich spinel secondary phases in grains, further enhancing grain interior electronic conductivity but slowing electronic transport across the tenorite‐rich GBs. Across all samples, the total electrical conductivity increases (and decreases reversibly) by four orders of magnitude with heat‐treatment‐induced phase transformation by tuning the grains’ defect chemistry toward higher carrier concentration and lower migration activation energy. This work demonstrates the potential to selectively grow secondary phases in ESO grains and at GBs, thereby tuning the electrical properties using microstructure design, nanoscale engineering, and heat treatment, paving the way to develop many novel materials.

STUDY OF VOLTAGE AND ELECTRIC CURRENT GENERATED FROM CU-ZN ELECTRODES IN A MEDIUM OF SAWDUST AND COAL STOCKPILE WASTEWATER.

Industrialization has positive effects on the economy, but on the other hand, it also adversely impacts the environment and energy needs. This phenomenon needs to be solved in an integrated way, including using wastewater from coal stocks and sawdust as electrolyte media to generate electrical energy. This study aims to analyze the voltage and electric current generated by electrode pairs consisting of copper (Cu) and zinc (Zn) immersed in different sawdust media denoted as M1 (2 grams), M2 (4 grams), M3 (6 grams), and M4 (8 grams), dissolved in 100 milliliters of coal stockpile wastewater. Additionally, the study explores the effects of varying the distance between the Cu-Zn electrodes at 1, 2, and 3 cm. The results showed that the highest voltage generated from the combination of coal stockpile wastewater and sawdust was highest in M3 (6 grams of sawdust + 100 ml of coal stockpile wastewater at a distance of 1 cm at 0.736 volts. The highest electrical current generated by the Cu-Zn electrode in the M3 media combination was 0.221 mA. It is due to coal stockpile wastewater in M3 sawdust powder, which contains ions that enhance electron conduction compared to M4.

Oxygen Release Suppression and Electronic Conductivity Enhancement for High Performance Li‐ and Mn‐Rich Layered Oxides Cathodes by Chalcogenide Redox Couple and Oxygen Vacancy Generations

AbstractLi‐ and Mn‐rich layered oxides (LMROs) are promising cathode materials for next‐generation lithium‐ion batteries (LIBs) due to their high capacity and high energy density. However, they suffer from severe capacity and voltage fading during cycling, where the irreversible oxygen release during cycle is deemed to a severe factor. Herein, this put forward a general oxygen release suppression strategy by introducing small amounts of sodium chalcogenides during cathode slurry preparation. The formed unstable surface peroxide ions O22− of LMRO during charging is reduced to stable O2− by chalcogen ion and couples the formation of sodium chalcogenic oxides, which is reduced to sodium chalcogenides and O2− during discharging. As a result, the oxygen release is significantly suppressed and the structural stability of LMRO is greatly enhanced. Meanwhile, abundant surface oxygen vacancies are generated coupling with evidently increased carrier concentration and mobility, thus enhancing electronic conductivity significantly. The Li1.2Ni0.13Co0.13Mn0.54O2 cathode with 3 wt% Na2Se shows a capacity retention as high as 96.2% and a capacity of 225 mAh g−1 after 500 cycles at 1 C, coupling with a high capacity of 135 mAh g−1 at 10 C. The relevant mechanism for the improved electrochemical properties is revealed, which is hopefully helpful for novel strategy design to high‐performance LMRO cathodes.

Locally boosted Li2S nucleation on VO2 by loading carbon quantum dots for soft-packaged lithium-sulfur pouch cells.

VO2 affords ultrafast polysulfide adsorption on account of its oxidation potential, which matches the sulfur working window (1.7-2.8 V). Nevertheless, its nonconductive surface limits direct sulfur conversion. Herein, we gently load carbon quantum dots on VO2 to increase direct Li2S nucleation by enhanced electron conductivity. As a result, the soft-packaged lithium-sulfur pouch cell yields a capacity retention of 88.8% at 0.5C after 100 cycles and a decay rate of 0.17% per cycle over 200 cycles at 2C. The cell energy density of the multilayer cell is up to 386.1 W h kg-1.

An industrial mixed rare-earth oxide fuel cell with low cost and high electrochemical performance

Rare-earth oxides determine the commercialization and development of solid oxide fuel cells (SOFCs) for all the types, still remining challenges of high cost and low electrochemical performance. Here, we propose an industrial mixed rare-earth oxide fuel cell using the state-of-the-art industrial lanthanum-praseodymium-cerium (La-Pr-Ce, LCP) oxide electrolyte as a proof-of-concept, achieving low-cost and high electrochemical performance. The rare-earth oxides, La2O3, CeO2, PrO2 and LCP are prepared and studied by oversimplified solid reaction experiments with density functional theory (DFT) calculations. The LCP is simplified as La, Pr doped CeO2, in which the effects of rare-earth elements doping are concluded as follows: firstly, the Ce4+/Ce3+ redox pairs can be slightly suppressed by La, Pr co-doping; secondly, the bandgap of LCP is decreased to 2.01 eV with enhanced electron conductivity of 7.4 × 10−5 S cm−1, which may originate from Pr-doping. The power density output of industrial mixed rare-earth oxide fuel cells with La2O3, CeO2, PrO2 and LCP electrolytes achieve 630 mW cm−2, 639 mW cm−2, 469 mW cm−2 and 797 mW cm−2 at 500 °C, respectively, indicating that the LCP electrolyte presents ascendant performance output with the ionic conductivity of 0.248 S cm−1. The industrial mixed rare-earth oxide fuel cells not only broaden the exploit avenue for industrial mixed rare-earth oxides, but also unravel the roadblock for the industrialization of SOFCs at low temperatures below 500 °C.

Building g-C3N4/Fe2O3 heterojunctions on carbon nanotubes for enhanced electron conductivity and pseudocapacitive performances

Building g-C3N4/Fe2O3 heterojunctions on carbon nanotubes for enhanced electron conductivity and pseudocapacitive performances