Energy Storage Infrastructure Research Articles

Development of Organic Positive Electrodes for Rechargeable Aqueous Zinc-Ion Batteries for Stationary Energy Storage Systems

The rising concern towards the amount of anthropogenic carbon emissions and their effects on the environment has motivated the transition away from fossil fuels. The implementation of renewable energy sources has promoted the decarbonization of the power sector, but the variability of wind and solar energy necessitates the parallel deployment of high-performance energy storage infrastructure to ensure a reliable on-demand supply of green electricity to the grid. To this end, aqueous rechargeable zinc-ion batteries (ZIBs) are a promising new option for stationary energy storage owing to their high safety and low cost, when compared to established storage technologies like lithium-ion batteries. However, ZIBs are still limited by several technological challenges that hinder their uptake for commercial energy storage installations. In particular, the positive electrode materials, mostly comprised of metal oxides, are restraining the energy density and stability of the batteries and are yet under investigation. Low cost, long cycle life, and natural abundance are required properties of materials used in batteries for stationary energy storage. The search for materials with these properties has motivated the investigation of alternatives to metal oxides. One group of materials attracting considerable research attention is organic compounds which offer advantages like their natural abundance and high theoretical capacities. In this work, we developed an organic positive electrode for ZIBs using carbonyl groups as redox-active centers to provide energy storage capacity at round-trip energy efficiencies that are higher than the conventionally utilized manganese oxide electrodes. Furthermore, we investigated the effects of the conductive carbon additive on the deliverable capacity of the battery and elucidated the charge storage mechanism of this positive electrode material through detailed characterization. The results indicated that both Zn2+ and H+ are involved in the energy storage process of this organic electrode material. In addition to studying the energy storage process, degradation mechanisms were identified through nuclear magnetic resonance (NMR) and mass spectroscopy (MS). Both dissolution of the reduced form of the active material from the electrode and the formation of unwanted decomposition products are important contributors to the capacity fade of the battery. The technological and scientific insights provided in this presentation will thereby contribute towards the development of high-performance and naturally abundant electrode materials for the next generation of ZIBs to enable clean energy grid storage.

Solidify Eutectic Electrolytes via the Added MXene as Nucleation Sites for a Solid-State Zinc-Ion Battery with Reconstructed Ion Transport.

Stationary energy storage infrastructure based on zinc-ion transport and storage chemistry is attracting more attention due to favorable metrics, including cost, safety, and recycling feasibility. However, splitting water and liquid electrolyte fluidity lead to cathode dissolution and Zn corrosion, resulting in rapid attenuation of the capacity and service life. Herein, a new architecture of solid-state electrolytes with high zinc ionic conductivity at room temperature was prepared via solidification of deep eutectic solvents utilizing MXene as nucleation additives. The ionic conductivity of MXene/ZCEs reached 6.69 × 10-4 S cm-1 at room temperature. Dendrite-free Zn plating/stripping with high reversibility can remain for over 2500 h. Subsequently, the fabricated solid-state zinc-ion battery with eliminated HER and suppressed Zn dendrites exhibited excellent cycling performance and could work normally in a range from -10 to 60 °C. This design inspired by eutectic solidification affords new insights into the multivalent solid electrochemistry suffering from slow ion migration.

Thermodynamic and economic analyses of a modified adiabatic compressed air energy storage system coupling with thermal power generation

With the proposal of "Carbon peaking and carbon neutrality", Adiabatic Compressed Air Energy Storage (A-CAES) has emerged as a significant component within China's energy storage infrastructure. But its thermodynamic efficiency and economical return need yet to be raised. The present paper proposed a modified system coupling with thermal power plant to utilize the excess compression heat. Utilizing advanced transient modeling software, an A-CAES plant is modeled and validated. The operation performance of the coupled system is compared with non-coupled system, which shows that the system efficiency is raised from 54.8 % to 76.7 % and the investment return rate is improved from 9.18 % to 10.43 %.

Intercalation chemistry engineering strategy enabled high mass loading and ultrastable electrodes for High-Performance aqueous electrochemical energy storage devices

Aqueous electrochemical energy storage devices (AEESDs) are considered one of the most promising candidates for large-scale energy storage infrastructure due to their high affordability and safety. Developing electrodes with the merits of high energy density and long lifespan remains a challenging issue toward the practical application of AEESDs. Research attempts at electrode materials, nanostructure configuration, and electronic engineering show the limitations due to the inherent contradictions associated with thicker electrodes and ion-accessible kinetics. Herein, we propose an intercalation chemistry engineering strategy to enhance the electrolyte ion (de)intercalation behaviors during the electrochemical charge–discharge. To validate this strategy, the prototypical model of a high-mass-loading MnO2-based electrode is used with controlled intercalation of Na+ and H2O. Theoretical and experimental results reveal that an optimal content of Na+ and H2O on the MnO2-based electrode exhibits superior electrochemical performance. Typically, the resultant electrode exhibits an impressive areal capacitance of 1551 mF/cm2 with a mass loading of 9.7 mg/cm2 (at 1 mA/cm2). Furthermore, the assembled full-cell with obtained MnO2-based electrode delivers a high energy density of 0.12 mWh/cm2 (at 20.02 mW/cm2) and ultra-high cycling stability with a capacitance retention percentage of 89.63 % (345 mF/cm2) even after 100,000 cycles (tested over 72 days).

Transition-metal ions intercalation chemistry enabled the manganese oxides-based cathode with enhanced capacity and cycle life for high-performance aqueous zinc-ion batteries.

Aqueous zinc-ion batteries (AZIBs) employing mild aqueous electrolytes are recognized for their high safety, cost-effectiveness, and scalability, rendering them promising candidates for large-scale energy storage infrastructure. However, the practical viability of AZIBs is notably impeded by their limited capacity and cycling stability, primarily attributed to sluggish cathode kinetics during electrochemical charge-discharge processes. This study proposes a transition-metal ion intercalation chemistry approach to augment the Zn2+ (de)intercalation dynamics using copper ions as prototypes. Electrochemical assessments reveal that the incorporation of Cu2+ into the host MnO2 lattice (denoted as MnO2-Cu) not only enhances the capacity performance owing to the additional redox activity of Cu2+ but also facilitates the kinetics of Zn2+ ion transport during charge-discharge cycles. Remarkably, the resulting AZIB employing the MnO2-Cu cathode exhibits a superior capacity of 429.4 mA h g-1 (at 0.1 A g-1) and maintains 50% capacity retention after 50 cycles, surpassing both pristine MnO2 (146.8 mA h g-1) and non-transition-metal ion-intercalated MnO2 (MnO2-Na, 198.5 mA h g-1). Through comprehensive electrochemical kinetics investigations, we elucidate that intercalated Cu2+ ions serve as mediators for interlayer stabilization and redox centers within the MnO2 host, enhancing capacity and cycling performance. The successful outcomes of this study underscore the potential of transition-metal ion intercalation strategies in advancing the development of high-performance cathodes for AZIBs.

Unraveling the electrochemical charge storage dynamics of defective Oxides-Based cathodes toward High-Performance aqueous Zinc-Ion batteries

Aqueous Zinc ion batteries (AZIBs) show tremendous potential for large-scale energy storage infrastructure owing to high affordability and high safety but are plagued by the undesired rate capability and inevitable capacity deterioration of the used cathodes. Defect engineering has been recognized as one of the most effective strategies for the electrochemical performance enhancement of cathodes. However, its underlying electrochemical kinetics and performance-enhancing mechanism are still immature. Herein, we performed comprehensive studies on the charge storage dynamics with the prototypical of defective manganese oxides (d-ZMO) by combining the three-dimensional (3D) Bode map and theoretical calculations. Bode analysis reveals that the d-ZMO exhibits the most significant values of real capacitance and the largest phase angle compared to that of the pristine MnO2 (MO) electrode, demonstrating the validity of defects on the electrochemical kinetic enhancement. Further theoretical results indicate the lowest zinc ions diffusion energy barrier (0.52 eV) of d-ZMO (1.23 eV of MO) with significantly enhanced ion kinetics, corroborating well with the Bode analysis. As expected, the configured AZIBs with d-ZMO cathode deliver an appreciable specific capacity of 419.7 mAh·g−1 (at 0.1 A·g−1) and exceptional cycle stability with capacity retention of 81.76 % (at 3 A·g−1) after 1000 cycles.

Energy Storage and Environmental Justice: A Critical Examination of a Proposed Pumped Hydropower Facility in Goldendale, Washington

AbstractRenewable energy sources such as solar and wind produce electricity intermittently, creating challenges in balancing electricity supply and demand for increasingly renewable‐dominated grids. This is driving efforts to increase energy storage infrastructure, such as pumped hydroelectric power storage (pumped storage). In this research, we examine environmental justice issues in a case study of a proposed pumped storage facility in Goldendale, Washington, which has been highly controversial and actively contested by a coalition of Indigenous and environmental communities. Drawing from frameworks of political ecology, just transitions, and Indigenous environmental justice, we focus on processes of consultation and engagement around permitting as a key arena for environmental justice contestation, and critically examine the driving assumptions behind the project. Despite popular framings of renewable energy infrastructures as new and green, we argue that the environmental justice impacts of this and similar projects represent continuity with past patterns of settler colonialism and extractive development.

Smart microgrid construction in abandoned mines based on gravity energy storage

The share of new energy in China's energy consumption structure is expanding, posing serious challenges to the national grid's stability and reliability.As a result, it is critical to construct large-scale reliable energy storage infrastructure and smart microgrids. Based on the spatial resource endowment of abandoned mines' upper and lower wells and the principle characteristics of the gravity energy storage system, an intelligent microgrid system model for abandoned mines based on gravity energy storage is proposed, and the system's feasibility and key influencing factors are discussed and analyzed from the standpoint of economic benefits. The gravity energy storage system principle, system structure, subsurface powerhouse, underground storage, and transit system are all examined and analyzed.The viability of establishing intelligent microgrid systems in abandoned mines is proved using the resource conditions, technical conditions, economic advantages, and social benefits of Panyidong Mine in Huainan Coal Mine.The findings indicate that the project concept has good economic and social benefits as well as practical viability.Next, from the perspectives of technology, policy, and the ecological environment, several recommendations for the development of a smart microgrid system based on gravity energy storage power station are made. This study presents a novel concept for the advancement of energy storage technology and the reuse of abandoned mine resources, which is critical to the long-term development of abandoned mine resources and the advancement of energy storage technology.

3D Printed TiO2 Negative Electrodes for Sodium-Ion and Lithium-Ion Batteries Using Vat Photopolymerization

Additive manufacturing represents a unique approach to develop three-dimensional shape-conformable batteries with enhanced surface area, ion diffusion, and power. For the first time, a composite photocurable resin loaded with solid particles of active materials and conductive additives was prepared and used as feedstock to print negative electrodes for sodium-ion and lithium-ion batteries by means of a vat photopolymerization (VPP) 3D printer. In alignment with NASA’s Artemis mission goals to develop sustainable lunar energy storage infrastructure to support long-term human operations, TiO2 was selected as an active material for the negative electrode due to its abundance on the lunar surface. The TiO2 loading in the composite photocurable resin was increased as high as possible to maximize the electrochemical performance of the printed electrodes, while simultaneously ensuring printability and good mechanical strength for sample handling. The effect of thermal post-processing on the electrical, electrochemical, and mechanical performance is reported. A configurational study is implemented to identify the impact of electrode designs (cubic and gyroid) on the electrochemical performance. This work addresses the difficulties related to the introduction of solid particles within a photocurable resin and the need for a compromise between the electrochemical performances and printability to obtain fully functional VPP-printed electrodes.

AHP algorithm used to select suitable abandoned underground mines for energy storage infrastructure – iCAES technology. A specific case study for León (Spain)

In the energy transition, the promotion of renewable sources entails the development of storage technologies to manage the mismatch between energy production and demand. In this scenario, the use of CAES (Compressed Air Energy Storage) technology enables the efficient and cost-effective storage of large amounts of energy. However, this technology is developed in salt domes who have an inherent risk associated of underground exploration phase. To address this, we propose to develop an infrastructure (iCAES) in abandoned underground mines, where the exploration phase is completed and well known. For its implementation, this paper defines a structure hierarchization method gathers the technical and socio-economic criteria. It involves a multi-criteria problem, and the correct selection of the location must be based on specific mathematical algorithms. For this case the Analytic Hierarchy Process (AHP) from multi-criteria decision making (MCDM) methods allows quantified by means of a scientific and mathematical scale and the assignment of weights, so that it is possible to evaluate different alternatives. This is possible thanks to the application of the AHP model in absolute terms. The information gathering has been based on the specific case study of coal basins in the north of Spain, in the region of León. Considering the proposed methodology, the most suitable alternative locations to implement iCAES in the region of León were identified.

Decarbonization of the electricity generation sector and its effects on sustainability goals

The substitution of fossil fuels, especially coal, with renewable energy is a crucial step for the CO2 emissions reduction and the avoidance of Global Climate Change. The electric power generation industry is the first economic sector that will have to transition to renewable energy. However, wind and solar energy, the two most abundant renewable energy forms, are not dispatchable. The high penetration of these renewables in the energy market will create a demand–supply mismatch, which can only be alleviated with large-scale energy storage. This paper uses the case of Texas—a state that generates and consumes more electricity than several large, industrialized nations—to quantitatively examine the required infrastructure for the decarbonization of the electricity generation industry, while satisfying the current electric power demand in the State. Among the parameters that are examined are: the additional solar and wind capacity; the necessary energy storage infrastructure; the energy dissipation in the storage/regeneration process; and the effect of decarbonization on the cost of electricity and the welfare of the citizens. The computations show that the technology is available for the transition to a decarbonized electric power sector but requires significant investment in new wind and photovoltaic units as well as substantial energy storage. This would increase the electricity prices by a factor between 2.9 and 3.7 and, would have a disproportionate impact on the citizens in the lower income brackets.

Complementary potential of wind-solar-hydro power in Chinese provinces: Based on a high temporal resolution multi-objective optimization model

In the context of carbon neutrality, renewable energy, especially wind power, solar PV and hydropower, will become the most important power sources in the future low-carbon power system. Since wind power and solar PV are specifically intermittent and space-heterogeneity, an assessment of renewable energy potential considering the variability of wind power and solar PV with high temporal resolution in different regions will facilitate more accurate identification of the decarbonization pathway of power system. In this paper, the complementary output potential of wind-solar-hydro power every 15 min in 31 Chinese provinces is evaluated by developing a multi-objective optimization model based on Nondominated Sorting Genetic Algorithm II. The results show that the total annual complementary power generation potential in China is 17.57 PWh, of which the three components account for 47.8%, 25.3% and 26.9%, respectively. Inner Mongolia and Tibet are the major renewable energy source provinces with annual complementary power generation potential of 5330 TWh and 3907 TWh, accounting for 30.3% and 13.7% of the total power generation potential, respectively. The temporal potential of wind-solar-hydro power varies greatly, with daily potential is more volatile than monthly. Seasonal and spatial heterogeneity of the complemental renewable potential makes some provinces suffer power shortage during long-hours period especially in winter. Our findings will encourage a higher penetration of renewable energy, the promotion of multi-energy complementarity, and the development of inter-provincial power transmission and energy storage infrastructure in China's future power sector.

Systematic bias in reanalysis-derived solar power profiles & the potential for error propagation in long duration energy storage studies

This study consolidates the literature relating to the systematic bias of model-derived irradiance data and further characterises the same for ERA-5 and MERRA-2, two reanalysis datasets that are frequently used to model renewable power in energy system modelling studies. The bias errors yielded when modelling Solar PV generation for solar parks in Australia and Northern Ireland are compared under the optics of typically clear versus typically cloudy respective climates. Evidence is presented that MERRA-2 exhibits a significant global overestimation bias, contrary to some literature that suggests local variation and underestimation in some locations. Based on the trends identified, it is proposed that overestimation bias proliferates in more cloudy climates for both reanalysis datasets. The implications of such bias for studies involving long-duration energy storage with low round-trip efficiency are investigated and an unfortunate mechanism for error propagation is highlighted. A simplified power system consisting of wind, solar, and energy storage is modelled to demonstrate this effect with solar power profiles derived from metered generation, ERA-5, and MERRA-2. It shown that greater systematic bias of MERRA-2, in combination with the opportunity for error propagation through low-round trip efficiency, has the potential to significantly distort the charging & discharging pattern, overall utilization, and total energy requirement of long duration energy storage infrastructure. ERA-5, despite also exhibiting systematic bias, was better able to reproduce the simulated results of the metered generation scenario. Finally, it is recommended that energy modellers using MERRA-2 data to simulate solar PV outputs should now migrate to ERA-5 if reanalysis data is to be used.

Realizing Renewable Energy Storage Potential in Municipalities: Identifying the Factors that Matter

Abstract The share of renewable energy in heat and power generation is expected to increase significantly and reach record levels in the coming decades. As a result, emerging energy storage technologies will be key elements in balancing the energy system. To compensate the variability and non-controllability of seasonally generated renewable energy (RES) (daily fluctuations in solar radiation intensity, wind speed, etc.) development of sufficient energy storage infrastructure in the regions will play a major role in transforming RES supply potential into reality. However, local public authorities that are responsible for creating an enabling policy environment for RES infrastructure development in regions encounter numerous challenges and uncertainties in deploying sufficient energy accumulation that often remain unanswered due to a lack of knowledge and on-site capacity, which in turn significantly hinders the regional path to climate neutrality. In this study, the PESLTE analytical framework and composite index methodology is applied to examine the multidimensional factors that influence the deployment of renewable energy storage technologies in municipalities: political, economic, social, legal, technological, and environmental. Developed model is approbated in a case study in a Latvian municipality where four different alternative energy storage technologies are compared: batteries for electricity storage, thermal energy storage, energy storage in a form of hydrogen, and energy storage in a form of biomethane.

Techno-economic comparison of centralized and distributed power generation to support large-scale transport electrification in Costa Rica

The rapid fall of photovoltaic generation and battery storage costs can pave the way for future distributed power systems. However, transitioning from centralized to distributed systems has economic implications for different power sector stakeholders: incumbent energy firms, new distributed generation investors, and consumers. Consumers can significantly increase demand by adopting electric transport, a crucial component of decarbonization. In turn, investors and firms will need to provide the capital and operating capability to supply more power, even for self-consumption. In this paper, we develop a methodology to assess the future average price of electricity for two fundamentally different systems: one based on utility-scale projects and another based on distributed generation. We also evaluate how prices affect the financial benefits of energy sector investors and transport users that result from transport electrification. We apply the methodology to Costa Rica's transport electrification objectives, a middle-income country with vast renewable generation capacity with pledges to reach net-zero emissions by 2050. We find that the future unit costs of solar and wind generation with energy storage infrastructure affect electricity prices more than other uncertainties. In turn, prices have a high correlation with transport benefits. We also find that low discount rates produce high benefits and low electricity prices.

Linking heat and electricity supply for domestic users: an example of power-to-gas integration in a building.

A novel power-to-X system, coupling electricity and gas grid in a building, is presented. This system operates a retrofit of the existing photovoltaic system, consuming the electricity overproduction in the local synthesis of methane instead of injecting it into the electricity grid. Methane can be stored in the gas grid and used in winter in the existing gas burners, providing the required heat to keep the building at a comfortable temperature. Additionally, the methanation system provides waste heat that is used to warm up the sanitary water, eliminating the need for an electric boiler. The system, fed by 800 m2 of solar panels, was optimized according to the weather conditions and the dimensions of the main pieces of equipment were determined. This allows the production of ca. 17 MW h of methane for seasonal storage. By retrofitting the building with the power-to-X unit, the energetic independence of the house is maximized, thanks to the synchronous production of electricity, gas, and heat, including energy storage. Therefore, the profitability of the photovoltaic system is ensured independently from the electricity feed-in tariffs. The system performance was evaluated in a case study in the north of Switzerland. When considering the purchase of renewable natural gas (i.e., from biogas), it was calculated that the system would be profitable for an electricity price below 0.05 € per kW h.

Recent development and challenges in fuel cells and water electrolyzer reactions: an overview.

Water electrolysis is the most promising method for the production of large scalable hydrogen (H2), which can fulfill the global energy demand of modern society. H2-based fuel cell transportation has been operating with zero greenhouse emission to improve both indoor and outdoor air quality, in addition to the development of economically viable sustainable green energy for widespread electrochemical applications. Many countries have been eagerly focusing on the development of renewable as well as H2-based energy storage infrastructure to fulfill their growing energy demands and sustainable goals. This review article mainly discusses the development of different kinds of fuel cell electrocatalysts, and their application in H2 production through various processes (chemical, refining, and electrochemical). The fuel cell parameters such as redox properties, cost-effectiveness, ecofriendlyness, conductivity, and better electrode stability have also been highlighted. In particular, a detailed discussion has been carried out with sufficient insights into the sustainable development of future green energy economy.

Sustaining COVID-19 pandemic lockdown era air pollution impact through utilization of more renewable energy resources

The lock down engendered by COVID-19 pandemic has impacted positively on the environment through reduction of the emissions of green house gases, CO2, CO and other pollutants into the atmosphere below the pre-COVID-19 levels. There are fears that the gains made in the environment during COVID-19 may be frittered away as nations around the world make serious efforts to boost the COVID-19 recessed economy through massive investments in the sectors of the economy that are not environmentally friendly. This paper emphasizes on the essence of maintaining the COVID-19 pandemic era environmental impact levels in post COVID-19 era without retarding the efforts towards economic recovery. World health organization (WHO) data from six regions between April and August 2020 was evaluated. Emission levels during the COVID-19 lockdown were reviewed. The global renewable energy potentials were ascertained. The paper suggests that investment in renewable energy resources for various countries’ energy needs will help sustain the green and clean environment created by the COVID-19 lockdown even after COVID-19 era lockdown. Also, building large scale and distributed energy storage infrastructure and application of artificial intelligence would ensure security of energy supply and handle unstable nature of solar and wind energy. The COVID-19 lockdown significantly reduced air pollution. The application of biofuels to generate energy and power was found to significantly reduce air pollutant emissions similar to COVID-19 lockdown.

Propagation of Overvoltages in the Form of Impulse, Chopped and Oscillating Waveforms in Transformer Windings—Time and Frequency Domain Approach

This paper describes a comparison of overvoltage propagation in transformer windings. Expanding and evolving electrical networks comprise various classes of transient waveforms, related to network reconfigurations, failure stages and switching phenomena, including new sources based on power electronics devices. In particular, the integration of renewable energy sources—mainly solar and wind—as well as expanding charging and energy storage infrastructure for electric cars in smart cities results in network flexibility manifested by switching phenomena and transients propagation, both impulse and oscillating. Those external transients, having a magnitude below the applied protection level may have still a considerable effect on winding electrical insulation in transformers, mainly due to internal resonance phenomena, which have been the root cause of many transformer failures. Such cases might occur if the frequency content of the incoming waveform matches the resonance zones of the winding frequency characteristic. Due to this coincidence, the measurements were performed both in time and frequency domain, applying various classes of transients, representing impulse, chopped (time to chopping from 1 µs to 50 µs) and oscillating overvoltages. An additional novelty was a superposition of a full lighting impulse with an oscillating component in the form of a modulated wavelet. The comparison of propagation of those waveforms along the winding length as well as a transfer case between high and low voltage windings were analyzed. The presented mapping of overvoltage prone zones along the winding length can contribute to transformer design optimization, development of novel diagnostic methodology, improved protection concepts and the proper design of modern networks.

Using Electrical Energy Storage to Mitigate Natural Gas-Supply Shortages

The recent leak of the Aliso Canyon natural gas storage facility calls for coordinated planning of natural gas and electric power systems with specific consideration of electrical energy storage. This paper proposes a coordinated planning model that fills this need. The model is formulated as a two-stage stochastic optimization problem, in which electricity- and natural gas-demand growth and natural gas-supply uncertainties are represented. We analyze the tradeoff between building electrical, natural gas, and electrical energy storage infrastructure. The sensitivity of electrical energy storage investment to the modeling of the operating conditions is also studied. The model is tested using a California-based case study.