Energy Regime Research Articles

Strategic Design of Anion-Responsive Triarylboranes Exhibiting Colorimetric and Fluorometric Red-Shift for Sensing and Optoelectronic Applications.

Triarylboranes (TABs) have been employed as colorimetric and/or fluorometric anion sensors. The majority of TAB-based anion sensors exhibit blue-shift modes of absorption and photoluminescence (PL) or turn off of PL, attributed to the intrinsic electronic polarity of the trivalent boron unit in their molecular designs. In this Concept article, we introduce a novel approach to modulating the photophysical properties of TABs toward a red-shift mode by balancing the dual, opposing roles of the amine-bridged TAB (phenazaborine). This molecular design strategy enables significant changes in color and emission response to anions, shifting to the lower energy regime in solution. Additionally, this approach is applicable to the solid-state modulation of PL in films and organic light-emitting diodes (OLEDs).

Comparative life cycle assessment of carbon-free ammonia as fuel for power generation based on the perspective of supply chains

In recent years, there has been a surge in ammonia demand due to growing interest in carbon-free fuel for decarbonization. Thus, it is crucial to identify the methods to fulfill the required demand, particularly for countries with resource scarcity or lacking well-established production infrastructure. The present study compares environmental impact analysis between domestic ammonia production and import ammonia for these countries by using life cycle assessment (LCA) methodology. In these ammonia supply paths, five different production ways were applied: gray (conventional Haber-Bosch process), blue (with carbon capture and storage), green (wind, solar, and nuclear powered water electrolysis with Haber-Bosch process). The assessment showed highest global warming potential (GWP) value at 2.64 ton CO2-eq/ton NH3 for imported gray while domestic nuclear-driven ammonia had the lowest value at 0.81 ton CO2-eq/ton NH3. In addition, contrary to expectations, the human and environment impact of green ammonias were all higher than gray and blue ammonia due to the production of raw materials. This means that environmental improvements of related production process are crucial in preparation for the coming new energy regime, which then lead to the production of environmentally friendly ammonia. Lastly, these results offer valuable guideline for future energy strategy planning.

Effect of Hydrogen on Albedo Neutrons in the Lunar Surface

The remote sensing observations of the lunar soil by using neutron spectroscopy as well as infrared spectroscopy in various studies suggest the presence of hydrogen in the lunar surface, particularly around the lunar polar regions. Additionally, the cosmic ray protons incident on the lunar surface induce the generation of secondary neutrons depending on the composition of the surface soil and the associated density, a certain number of which, called albedo neutrons, leak from the lunar regolith. Motivated by the interaction of the cosmic ray protons with the lunar surface in the absence and presence of hydrogen, a series of GEANT4 simulations are employed in the current study to unveil the influence of hydrogen on the energy spectrum of the albedo neutrons that escape from the lunar surface. Initially, a discrete 69-bin proton energy spectrum between 0.4 and 115 GeV based on the PAMELA spectrometer is implemented into GEANT4. Subsequently, a single-volume lunar surface of 2-m thickness is constructed where it is assumed that a single layer of either 1.6 or 1.93 g/cm^3 constitutes the lunar regolith. The material composition in the present study includes 43.7 wt.% oxygen, 0.3 wt.% sodium, 5.6 wt.% magnesium, 9 wt.% aluminium, 21.1 wt.% silicon, 8.5 wt.% calcium, 1.5 wt.% titanium, 0.1 wt.% manganese, and 10.2 wt.% iron in accordance with another study. Then, 0.1 wt.% hydrogen is introduced by replacing oxygen in order to assess the impact of hydrogen on the secondary neutrons. In the wake of irradiating a lunar surface of 3*2*3 m^3 with a planar vertical PAMELA proton beam of 20*20 cm^2, the depth profile of the generated neutrons as well as the corresponding initial energy spectrum is primarily obtained in the absence and presence of 0.1 wt.% hydrogen by voxelizing the entire geometry with 100 cells of 2-cm thickness. Next, a surface detector is placed at the top of the lunar surface in order to collect the albedo neutrons in both cases, and the energy spectra of the albedo neutrons are acquired in terms of thermal, epithermal, and fast neutrons. From the GEANT4 simulations in this study, it is shown that the presence of 0.1 wt.% hydrogen is observable in each energy regime of the albedo neutrons at the lunar surface, thereby providing an indication about the elemental variation of the lunar soil.

Hysteresis in seasonal land-atmospheric interactions over India and its characteristics across croplands and forests

Abstract Satellite-derived Vegetation Optical Depth and Soil Moisture (SM) data reveal the critical role of the soil-vegetation continuum in storing rainwater during the Indian Summer Monsoon and supporting evapotranspiration (ET) during the dry non-monsoon season. During the non-monsoon drier period, the climatologically estimated spatial mean of ET exceeds precipitation input, a phenomenon known as the Soil-Vegetation Capacitor (SVC) effect, which is pivotal in maintaining ecosystem productivity. Notably, our analysis reveals significant variations in the capacitor period between croplands and forests, with croplands exhibiting a ~77 days longer due to dual crop seasons influenced by regional precipitation. The well-recognized hysteresis curves, observed in magnetization and soil-water characteristic curves (SWCC), highlight phenomena where a system's state is influenced by its historical inputs or states and are integral to our findings. We report a previously undocumented seasonal hysteresis in the relationship between the evaporative fraction (EVF) and SM for Indian croplands and forests. We further found that the croplands SM-EVF relation exhibits a reversal in hysteresis in the case of root-zone SM. The surface SM-EVF hysteresis is not present in forests with large root depths and reduced soil evaporation due to high canopy shading, and yet it is present for the root-zone SM. With its reversal for croplands, the newly found hysteresis must be addressed in redefining the critical SM threshold to demarcate the energy and water-limiting regimes. It should be incorporated in the land surface modeling parameterization. Additionally, we observed hysteresis in the soil moisture-gross primary productivity (SM-GPP) relationship across both land covers and soil profiles (surface and root-zone), underscoring the need to investigate such processes to consider their dynamics in future ecological and hydrological models.

The New Energy State: Offshore Governance Regimes for Renewables as Natural Resources

Maturing renewable energy technologies are birthing new industry configurations, with offshore wind—with the EU holding 80 percent of global capacity—and “energy islands,” as notable examples. However, a clear conceptualization of the role of the state and governance framework is lacking, alongside growing pressure for the state to define the path forward. This paper analyzes recent developments in emerging EU offshore renewable energy regimes, drawing three implications that show the need for new governance frameworks. First, there is a reconfiguration of energy industry structures around changing economics and policies, in a repeat of historical experience. Second, energy islands increasingly represent features of a natural resource in fixed supply, with the economic nature of offshore energy gradually transiting from the sub-domain of renewable energy economics towards natural resource economics. Third, to realize their economic value, governance frameworks are needed to enable these resources to harmonize with other resources in fixed supply, such as the land on which they are sited, which is constitutionally under the stewardship of the state. We set out criteria for governance of these emerging offshore renewables, to underpin the changing industry landscape and new role of the state within it. JEL Classification: L22, L24, L51, Q20, Q24, Q28, Q32, Q38, Q48

Ortho-Para Conversion for H+ + H2 Collision in Low Temperature: A Fully Close-Coupled Time-Dependent Wave Packet Study.

The collision-induced rate coefficients of ortho-para conversion for the H+ + H2 reaction provide accurate information to probe the lifetime of cold environments in interstellar media. Rotationally resolved reaction probabilities are calculated at the low collision energy regime (0 < Ecol ≤ 0.3 eV) by employing the coupled three-dimensional (3D) time-dependent wave packet (TDWP) formalism in hyperspherical coordinates on a recently constructed ab initio ground adiabatic potential energy surface of H3+ [J. Chem. Phys. 2014, 141, 204306] for the process H+ + H2 (v = 0, j = 0-5) → H+ + H2 (v' = 0, j'). Cross-sections are then computed from the converged reaction probabilities as a function of total angular momentum (J) over the same energy regime and subsequently employed to obtain the rate constants for the ortho-to-para (O-P) and para-to-ortho (P-O) conversions and their ratio. The ratio of ortho-para conversion shows (a) appropriate convergence with the inclusion of a higher number of initial rotational states as well as a reasonable agreement with the results from a quantum statistical method and (b) a peak at lower temperature that could be due to the available collision energy for transitions involving lower rotational states (j = 0 → j' = 1).

Dismantling or greening the fossil-fuel energy regime? Decarbonation struggle and the making of electricity capital in Guadeloupe

Dismantling or greening the fossil-fuel energy regime? Decarbonation struggle and the making of electricity capital in Guadeloupe

Exploring the pre-inflationary dynamics in loop quantum cosmology with a DBI scalar field

Loop quantum cosmology is a symmetry-reduced application of loop quantum gravity. The theory predicts a bounce for the universe at the Planck scale and resolves the singularity of standard cosmology. The dynamics is also governed by an effective Hamiltonian, which predicts a modified Friedmann equation containing the quadratic terms of the energy density. The term plays an essential role in the high energy regime, but the equations return to the standard form in the low energy regime. The evolution of the universe in the pre-inflationary period is studied in the framework of loop quantum cosmology, where the DBI scalar field is assumed to be the dominant component of the universe. Using the numerical method, we provide the evolution of the DBI field. The background evolution shows that there are three phases as: bouncing phase, transition phase and slow-roll inflationary phase. There is also a short period of super-inflation just at the beginning of the bounce phase. The field first climbs the potential and then reaches the turning point where ϕ̇ disappears and the potential energy becomes the dominant part of the energy density. This is the time when the slow roll inflation begins and the field slowly rolls down the potential. The results indicate that there are a few e-fold expansions in the bounce phase, about N = 3.5–4, and the universe experiences about N = 59 e-fold expansions in the slow-roll inflation phase.

Implications of the Spin-Induced Accretion Disk Truncation on the X-ray Binary Broadband Emission

Black hole X-ray binary systems consist of a black hole accreting mass from its binary companion, forming an accretion disk. As a result, twin relativistic plasma ejections (jets) are launched towards opposite and perpendicular directions. Moreover, multiple broadband emission observations from X-ray binary systems range from radio to high-energy gamma rays. The emission mechanisms exhibit thermal origins from the disk, stellar companion, and non-thermal jet-related components (i.e., synchrotron emission, inverse comptonization of less energetic photons, etc.). In many attempts at fitting the emitted spectra, a static black hole is often assumed regarding the accretion disk modeling, ignoring the Kerr metric properties that significantly impact the geometry around the usually rotating black hole. In this work, we study the possible implications of the spin inclusion in predictions of the X-ray binary spectrum. We mainly focus on the most significant aspect inserted by the Kerr geometry, the innermost stable circular orbit radius dictating the disk’s inner boundary. The outcome suggests a higher-peaked and hardened X-ray spectrum from the accretion disk and a substantial increase in the inverse Compton component of disk-originated photons. Jet-photon absorption is also heavily affected at higher energy regimes dominated by hadron-induced emission mechanisms. Nevertheless, a complete investigation requires the full examination of the spin contribution and the resulting relativistic effects beyond the disk truncation.

Mechanism Behind the Enhanced Ferromagnetic Contributions Upon Ru Substitution in Ca3Mn2O7 from X-Ray Absorption Spectroscopies.

We have studied the local structure and electronic and magnetic properties of hybrid improper ferroelectric Ca3Mn2O7 upon Ru substitution at the Mn site by a combination of atomic-selective X-ray absorption spectroscopies in the soft and hard X-ray energy regimes. Ru substitution enhances the macroscopic ferromagnetic contributions, whose origin is here elucidated. In particular, soft X-ray magnetic circular dichroism (XMCD) data indicate that the spin moments of Mn and Ru are aligned in opposite directions, with the effective magnetic moments of Ru being about 1 order of magnitude smaller than for Mn. The XMCD results also demonstrate the presence of an intrinsic ferromagnetic component in the Mn sublattice for Ru contents x ≥ 0.3, although the values of the net Mn magnetic moment are much smaller than expected for a fully saturated Mn4+ magnetic sublattice. Soft and hard X-ray absorption spectroscopy measurements show that Mn keeps a +4 valence state independently of the Ru content, whereas Ru is in an intermediate valence state, ranging between +4.7 (x ≤ 0.1) and +4.4 (x ≥ 0.7). Analysis of the extended X-ray absorption fine structure (EXAFS) signals at the Mn and Ru K-edges suggests the lack of a complete solid solution in the local structure across the entire range of compositions. These findings disclose the existence of charge transfer between Mn and Ru atoms, so the weak ferromagnetic component is attributed to a canting of the antiferromagnetically ordered Mn4+ spins caused by the oxygen-mediated hybridization between localized Mn4+ 3d and itinerant intermediate valence Ru 4d bands, in analogy to the mechanism proposed for ferromagnetism in ordered doubled perovskites with 3d and 4d/5d transition-metal ions. In the present case, disorder prevents the formation of long-range ferromagnetism.

Spatiotemporal patterns in the active cyclic Potts model

Abstract The nonequilibrium dynamics of a cycling three-state Potts model is studied on a square lattice using Monte Carlo simulations and continuum theory. This model is relevant to chemical reactions on a catalytic surface and to molecular transport across a membrane. Several characteristic modes are formed depending on the flipping energies between successive states and the contact energies between neighboring sites. Under cyclic symmetry conditions, cycling homogeneous phases and spiral waves (SW) form at low and high flipping energies, respectively. In the intermediate flipping energy regime, these two modes coexist temporally in small systems and/or at low contact energies. Under asymmetric conditions, we observed small biphasic domains exhibiting amoeba-like locomotion and temporal coexistence of SW and a dominant non-cyclic one-state phase. An increase in the flipping energy between two successive states, say state 0 and state 1, while keeping the other flipping energies constant, induces the formation of the third phase (state 2), owing to the suppression of the nucleation of state 0 domains. Under asymmetric conditions regarding the contact energies, two different modes can appear depending on the initial state, due to a hysteresis phenomenon.

Design and Additive Manufacturing of Electrodes for Electrochemical Energy Storage

Supercapacitors exhibit rapid charge/discharge times and have attracted considerable attention within the automotive, aerospace, and telecommunication industries. The high electrical conductivity and surface area of porous carbons have been attractive for supercapacitor electrodes. Fabricating thick electrodes is one strategy to further increase energy density due to a higher volume fraction of active material. However, thick electrodes suffer from sluggish charged species transport. In this work, we investigate the use of computational optimization and additive manufacturing to design and fabricate thick porous electrodes with improved performance. Electrode performance was maximized by designing their morphologies via topology optimization and printing by projection micro stereolithography (PµSL) using commercial resin (PR48). The PR48 resin was then pyrolyzed (PR48-P) to create the final conductive electrode. The optimized PR48-P electrodes exhibited 99% improvement in capacitance compared to control electrodes printed with cubic lattice morphologies. To further improve performance, we formulated a resin combining graphene oxide (GO) and trimethylolpropane triacrylate (TMPTA). Electrodes printed with 3 wt% GO in TMPTA exhibited improved capacitance retention after pyrolysis compared to the PR48-P electrodes. This work demonstrates the enormous potential of leveraging topology optimization and additive manufacturing to resolve many challenges in the electrochemical storage and renewable energy regimes. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344. Lawrence Livermore National Security, LLC Figure 1

Unlocking the potential of lignin: Towards a sustainable solution for tire rubber compound reinforcement

This study tackles the persistent challenge of producing highly reinforced lignin-rubber composites, emphasizing the transformation of agro-industrial residues into value-added products. To address this challenge, we introduce a novel approach termed “in-situ surface modification utilizing a thermo-chemo-mechanical approach” which incorporates the utilization of biomass-derived kraft lignin and a thermally stable organofunctional surface modifier, specifically (3-aminopropyl) triethoxysilane. The resulting material exhibits unprecedented tensile strength (∼15 MPa) along with ∼300 % elongation at break, while typical gum rubber offers 1–2 MPa tensile strength. Additionally, for the other tensile properties like 100 %, and 200 % tensile modulus, the improvement is 7-fold (∼5.6 MPa) and 10-fold (∼11.3 MPa), respectively. Furthermore, this composite presents a higher degree of reinforcement than a passenger car radial (PCR) tire model compound (tensile strength ∼14.5 MPa, 100 % tensile modulus ∼2.2 MPa, and 200 % tensile modulus ∼5.6 MPa) comprised of silica and polysulfide-based coupling agent, with exactly a similar loading of filler. The dynamic mechanical and stress relaxation behavior of the composites are critically discussed concerning the dispersion of the lignin in the sSBR/BR rubber matrix. The morphological orientation and involved chemical interaction in the presence of a surface modifier are also studied in detail. Tear fatigue analysis using pure shear specimens indicates superior fracture toughness at a lower tearing energy regime compared to silica-filled PCR tire compounds. Overall, this study showcases the potential of lignin-reinforced elastomers, offering a promising route for sustainable engineering materials and commercial viability.

Three incumbents restructuring the Swedish energy and steel regimes: the case of Hybrit

ABSTRACT This paper addresses the role of incumbent firms in driving transitions that entail multiple sectors, conditioned by multiple regimes. We analyse the case ‘HYBRIT’, a radical innovation venture championed by three incumbents from the steel and energy regimes. We investigate what conditions the incumbents’ agency and how they enacted their agency targeting restructuring of the regime elements – actors, institutions, and materiality. We find that eight endogenous and exogenous factors coincide and condition the incumbents’ agency, from which they act in a novel direction of change. We contribute by showing how the collaboration within and across regimes enabled the accomplishment of actions that would have been challenging for individual incumbents to achieve alone. In this setting of scale-intensive industries, incumbents have characteristics that give them a significantly larger capacity to stimulate change than newcomers. The timing and combination of endogenous and exogenous factors, enabling incumbents to collectively drive a transition.

Theorising resistance in times of fossil fuels: Ecological grief, righteous anger and interaction rituals in Sweden's energy regime shift

The emerging shift from fossil fuels to renewable energy engages a broad spectrum of society. Through protests, social media campaigns and civil unrest, different groups seek to impact the speed, direction and distributional effects of this transformation. In this paper, we develop a conceptualisation of how such resistance is socially mobilised. We ask how people come to resort to open resistance in the context of energy regime dynamics. The growing literature on the topic highlights that declining material and social capital are not enough to understand resistance in times of fossil fuels. We suggest in this study that attention to a wider spectrum of emotions is crucial for understanding the political and ethical contestations through which changes in energy provision materialize. We draw upon sociological theory, in particular the notion of interaction rituals, to understand the social and affective process of resistance. The concept of interaction rituals captures the movement from feeling aggrieved to mobilisation of resistance through attention to the sharing and transformation of emotions. We apply our theorisation in two Swedish examples of contemporary resistance – the Forest Rebellion and the Petrol Protest – to illustrate the grievances that underpin these movements, and how interaction rituals mobilise and justify resistance. We end the paper with a discussion and comparison of the two examples, and the implications of our findings for (academic) knowledge about the role of resistance in relation to energy regimes.

Effects of shape/phase transition regions on neutron capture cross sections

A recent study found a new, purely empirical correlation between two-neutron separation energies and neutron capture cross sections in keV neutron energy regimes. In shape/phase transition regimes, such as that near A= 150, S2n\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_{2n}$$\\end{document} values show an anomaly—a flattening of the normal near linear decrease with neutron number. This paper addresses two questions: (1) Using this new correlation, is this anomaly in S2n\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_{2n}$$\\end{document} values sizeable enough to produce an observable effect in capture cross sections? and (2) Can the correlation be used to quantitatively reproduce the cross sections in the transition region? It is found that the answer to both questions is in the affirmative. Possible relations to the r-process are briefly discussed.

Log Preservation in Custody Dual Blockchain With Energy Regime and Obfuscation Shuffle

Log Preservation in Custody Dual Blockchain With Energy Regime and Obfuscation Shuffle

Carbon Technocracy: Energy Regimes in Modern East Asia by Victor Seow (review)

Carbon Technocracy: Energy Regimes in Modern East Asia by Victor Seow (review)

DEVELOPMENT OF AN ALGORITHM FOR ADAPTING A MATHEMATICAL MODEL OF THE PROCESS OF MIXING AND MELTING COPPER CONCENTRATES

The paper describes the information base of the system, which is formed by algorithms of centralized control, automated analytical control system and control data of material flows. The data processing algorithm according to a special program generates additional information necessary to solve the control tasks of the system and includes algorithms for processing analytical data information, as well as data for monitoring material flows, calculations of additional electric furnace variables, loading of charge into furnace bunkers and technological variables by department. The simulation model of the functioning of the complex "technological process – control system" is implemented in the form of a package of interconnected software modules. The package implementing the simulation model is divided into three complexes: a set of programs for "Data collection and processing"; a complex for "Optimal process control"; a set of programs for "optimal energy regime management".

Economic, equity, and political trade-offs in energy transition in irrigation in Bihar, India

Affordable and reliable energy is an important driver for improving access to irrigation in South Asia. Policies for improving electricity access and augmenting supply are likely to impact affordability and equity in irrigation access, especially in regions where agriculture is the mainstay of the economy. In this paper, we focus on the state of Bihar in eastern India to study trade-offs across economic, equity, and political dimensions of energy transition in irrigation. We argue that in the context of the nascent but steadily increasing solar-powered irrigation, a decentralised energy regime is techno-economically and socio-politically distinct from a conventional centralised grid supply. With different economic costs, governance issues, and varied incentives of stakeholders, there are significant trade-offs associated with the two pathways of energisation. We further assess the multidimensional trade-offs associated with the conventional ‘centralised’ and the modern ‘decentralised’ energy supply systems for irrigation to present a comprehensive understanding of the technical systems aiming to address economic development and livelihood security issues. We find that the life cycle costs (LCC) of centralised grid supply are not only higher than that of decentralised solar-powered irrigation (SIP) but also the LCC for grid supply has a high sensitivity to average cost to supply electricity (ACS). We also find that at lower pumping hours or lower average cost to supply (ACS), grid electricity is competitive compared to SIP, but with an increase in pumping hours, ACS or both, there is a considerable increase in the LCC of the grid connected pump, making SIP a more economical option. Furthermore, we augment the analysis using primary data on farmers to examine the economic, equity, and political trade-offs. By highlighting the complexities associated with the diffusion of decentralised energy solutions in irrigation, our findings provide useful insights for public policy related to energy transition in irrigation in India.