Energy Modulation Research Articles

Spectral Manifestations of Energy Modulation of the Porphine Macrocycle Electronic Orbitals Upon Rotation of an NO2 Substituent

Spectral Manifestations of Energy Modulation of the Porphine Macrocycle Electronic Orbitals Upon Rotation of an NO2 Substituent

The scintillating fiber tracker of the Ziré detector on the NUSES space mission

NUSES is a pathfinder satellite to be deployed in low Earth orbit, equipped with new technologies for space-based detectors. It will carry two payloads: Terzina, for detecting ultra-high-energy cosmic-ray and neutrino air showers, and Ziré, for measuring low energy cosmic rays and gamma rays. Zirè includes several subdetectors: a Fiber TracKer (FTK), a Plastic Scintillator Tower (PST), a calorimeter (CALOg), an AntiCoincidence System (ACS), and a Low Energy Module (LEM). The majority of Ziré will be based on scintillators with Silicon Photomultiplier (SiPM) readout. The FTK is based on thin scintillating fibers readout by SiPM arrays. We assembled several fiber tracker prototypes and tested them with custom developed Front-End Boards (FEBs) based on PETIROC2A and CITIROC. A full, reduced scale protptype of Ziré, Zirettino was designed and assembled. The FTK prototypes and Zirettino were tested in the laboratory and at the CERN PS and SPS facilities.

Variable-energy cocktail beam technology for investigating synergistic damage in nuclear materials on LEAF platform

This study addresses the critical issue of synergistic radiation damage in structural materials of fusion reactors, focusing on the interaction between the displacement defects and transmutation-produced hydrogen and helium. These effects are simulated and investigated by employing the advanced multi-beam ion implantation capabilities of the LEAF (Low Energy high intensity highly charged ion Accelerator Facility) platform. Firstly, high-intensity cocktail beams, such as “4He+ and 56Fe14+" and “4He+ and 58Ni15+", are generated and characterized successfully. Then, a complex radiation environment is mimicked within the fusion reactors by applying variable-energy irradiation. Secondly, similar penetration depths for different ions, which are crucial for studying synergistic effects, are obtained by precisely controlling the energy of the cocktail beams through the innovative energy modulation system of the LEAF platform. Finally, the post-irradiation analyses, performed by using the transmission electron microscopy (TEM) and nanoindentation, revealed distinct microstructural changes and alterations in material properties, providing insights into the degradation mechanisms under irradiation. This work not only generates diverse and high-intensity “cocktail” ion beams but also achieves rapid energy switching of the beams. Further, the work is expected to pave the way for the implementation of a novel multi-beam irradiation technique in advanced heavy-ion linear accelerators, and also to provide innovative experimental methods and technical support for studying the synergistic effects of nuclear materials.

Optically driven ultraviolet-C glowing from an in situ trapping-detrapping approach.

In recent years, the world has witnessed rapid progress in research on ultraviolet luminescent materials, ranging from high-level anticounterfeiting and solar-blind optical tagging to antibacterial applications. In particular, a background-signal free solar-blind surveillance of ultraviolet-C photons provides an opportunity in bright indoor and outdoor environments. However, ambient daylight or inevitable external photostimulation is always eliminated or underestimated in the research of persistent phosphors. Herein, an in situ trapping-detrapping experimental procedure is employed to reveal more information on the total trap energy and trap modulations after photostimulation. Our findings reveal the presence of optically active trapping defects with photostimulated detrapping and retrapping behavior. This work provides a fundamental advance in revealing the trap distribution and trap reshuffling during glowing-in-the-daylight events, offering what we believe to be new insights into manipulating traps.

Design of a multi-carrier X-ray source for communication with energy modulation information.

X-ray communication is a kind of space communication technology which uses X-ray as information carrier. In order to improve the information transmission capacity, communication rate and anti-interference ability of X-ray communication, we proposes to design a novel multi-target X-ray source. The source is composed of a fast switching module of light channels based on FPGA technology and four photoelectric X-ray tubes with different target materials: Cr, Fe, Ni, and Cu. Using Geant4 software, we determined the optimal target thickness for each material, which enabled us to fully leverage the characteristic X-rays for multi-channel signal modulation transmission. Moreover, using CST software for particle trajectory simulation and optimization of the electron beam revealed that at a tube voltage of 20 kV, the focus area measures approximately 1.2 mm×1.2 mm. The simulations show that four kinds of spectra with high distinctiveness can be generated from the Cr, Fe, Ni, and Cu targets. Within a single modulation period, these spectra can be combined in various ways to create 16 different X-ray spectra signals, thereby increasing the number of communication elements and enhancing the information transmission rate.

Boosting Uniformity and Efficiency of Large‐Area Inverted Organic Photovoltaics Via ZnO Surface Energy Modulation

Boosting Uniformity and Efficiency of Large‐Area Inverted Organic Photovoltaics Via ZnO Surface Energy Modulation

Real‐Time Detection of Coherent Vibrational Dynamics in TiN Films

AbstractTitanium nitride (TiN) has recently gained considerable interest because of its remarkable plasmonic properties and for its strong electron–phonon (e–ph) coupling, leading to extremely fast (<100 fs) electron‐lattice cooling. Here, the generation of coherent phonons in TiN films is reported, along with their real‐time detection by means of broadband transient reflection spectroscopy with sub‐15‐fs temporal resolution. The measurements show damped oscillations, superimposed to excited state electronic decay. A coherent vibrational mode is revealed, with ≈10 THz frequency ascribed to defect‐activated normal modes, consistent with spontaneous Raman scattering data, and a dephasing time of ≈250 fs. Two π‐phase flips are also observed located at photon energies corresponding to interband optical transitions (at 3.2 and 2.5 eV), ascribed to selective coupling of the vibrational mode to these transitions; the energy modulation induced by the vibrational coherence is evaluated. It is shown that the displacive excitation of coherent phonons model describes the coherent response in terms of temporal behavior and of spectral amplitude profile. Overall, a comprehensive and detailed analysis of coherent phonons in TiN films, so far undected, is provided and relevant information on TiN photo‐physical properties, potentially useful for its applications, is given.

System dynamic model of water, energy and food nexus for policy implementation

In this study, a spatiotemporal disaggregated simulation model was developed based on water–food–energy (WFE) nexus approach to assess water and food supply security considering ecosystem provisioning services. The main components of the developed model in this study (SD-WFE model) are population, water, agriculture, and energy modules. The model, which was developed using system dynamics (SD) approach, was utilized to simulate effectiveness of sectoral municipal, industrial, and agricultural water and energy consumption management and environmental protection policies in improving ecosystem provisioning services during a 20-year period. Through sensitivity analysis utilizing the Monte Carlo model, the study addresses the formulation of sustainable water resource policies across four main categories: water demand management, water supply management, food resource management, and energy resource demand management. Additionally, it explores the integration of policies within an optimal framework. The simulation of proposed solutions revealed that a combination of water demand management and food resource management yielded the most promising outcome. Specifically, the recommended solution entails enhancing water irrigation efficiency by 18% through the expansion of pressurized irrigation network coverage, adjusting cropping patterns by 14%, reducing agricultural product losses by 8% via improved food supply management, minimizing food demand by 9% due to reduced food consumption losses, and achieving an annual 10% increase in crop performance. These selected policies form the foundation for sustainable water resource management strategies.

The Ziré instrument onboard the NUSES space mission

The Ziré experiment is an instrument on board the NUSES (NeUtrino and Seismic Electromagnetic Signals) satellite dedicated to test new techniques for the study of low energy cosmic radiation, Sun–Earth environment, space weather and magnetosphere–ionosphere–lithosphere coupling (MILC). Ziré will consist of a fiber tracker, a stack of plastic scintillators, an array of LYSO crystals and an anticoincidence system. A dedicated Low Energy Module (LEM) will extend the sensitive energy range down to the MeV scale for charged particles. In this work, a general overview of the Ziré payload will be given, together with a focus on the design and the review of dedicated tests on the first prototype.

Experimental validation of fuzzy logic controller based on voltage perturbation algorithm in battery storage photovoltaic system

Introduction. Solar photovoltaic (PV) has recently become very important especially in electrical power applications for countries with high luminosity because it is an effectively unlimited available energy resource. Depending on solar radiation and temperature, the PV generator has a non-linear characteristic with a maximum power point (MPP). The novelty is the efficiency improvement of a PV energy module, it is necessary to track the MPP of the PV array regardless of temperature or irradiation circumstances. Purpose. This paper presents the modeling and the digitally simulation under MATLAB/Simulink of a Fuzzy Logic Controller based on Voltage Perturbation Algorithm (FLC-VPA) applied to PV battery charging system, which consists of PV module, DC-DC boost converter, MPP tracking (MPPT) unit and battery storage. Methods. The DSP1104 is then used to experimentally implement this MPPT algorithm for real-time driving. The obtained results show the high precision of the proposed FLC-VPA MPPT around the optimal point compared to the conventional VPA under stable and changing meteorological conditions. Practical value. The experimental results approve the effectiveness and validity of the proposed total control system in the PV system. References 30, tables 3, figures 17.

Monitoring solar irradiance and PV module performance in mobile applications

The paper presents a comprehensive evaluation of a PV module attached to an electric vehicle using a custom developed PV monitoring system to estimate the effect of PV energy production on the driving range.A rigid crystalline silicon photovoltaic (PV) module with a nominal peak power of 192.4 W accompanied with four irradiance sensors (positioned horizontally and vertically to the left, right and back) was mounted on an electric car, and various driving scenarios were executed, with data recorded for analysis. The results of a two-month continuous monitoring of the car's usage mainly in the Central Slovenia region in late winter and early springtime, show that the daily energy generation by the installed PV module contributed an additional driving range of up to 5 km per day, totalling 93 km of additional range in the entire monitoring period. Based on irradiance monitoring results applied to a hypothetical case where all sides would be covered with a state-of-the-art PV, the driving range would extent to 471 km in total for the same period. When compared to a fixed, ideally installed PV module at our outdoor PV monitoring site in Ljubljana, the average performance ratio (PR) of the mobile PV module in the two-month period was 87 %, whereas the PR of the fixed installed PV module was 83 %. The energy yield varied significantly under the varying conditions resulting from different car usage scenarios and on average it reached 41 % of the fixed PV module's energy yield. Through real-world experiments and data collection, different car use cases under various driving and parking conditions are presented and evaluated in detail. From these, the base specifications of a dedicated mobile VIPV monitoring system are identified.

Sodium disilicate pretreatment enhancing methane production from anaerobic digestion of waste activated sludge

Improving the efficiency of digestion is a major focus of waste activated sludge (WAS) anaerobic digestion (AD) research. This study investigates the viability and mechanism of sodium disilicate (SD) in enhancing the digestive efficacy of WAS. Batch AD experiments for the sludges pretreated by varied amounts of SD were carried out, and the results revealed that a dosage of 90 mmol/L resulted in the highest methane yield (247.9 mL/g·VS), marking a 90.0 % increase compared to the raw sludge. Mechanistic investigations highlighted that SD pretreatment facilitated EPS degradation, cell lysis, and modulation of interfacial interaction energy, ultimately enhancing sludge disintegration and methane generation. Microbial community analysis unveiled an enrichment of crucial functional microorganisms associated with hydrolysis, acidification, and methanation. The heightened presence of acetotrophic and hydrogenotrophic methanogens significantly boosted methane production. Furthermore, metagenomic analysis corroborated that the SD pretreatment stimulated amino acid metabolism, energy metabolism (specifically ABC transporter proteins), and carbohydrate metabolism, thereby enhancing methanogenic activity through increased microbial metabolic activities and upregulated key enzyme expression. This research underscores the potential of SD-assisted pretreatment strategies in augmenting WAS digestion, introducing supplementary pretreatment avenues for optimizing anaerobic biotechnology.

Hybrid simulation of a capacitive Ar/SiH4 discharge driven by electrically asymmetric voltage waveforms

Voltage waveforms associated with the electrical asymmetry effect (EAE) have the potential to be used in the deposition of the silicon-based film, since they are expected to decouple ion energy and flux at the wafer surface, and further facilitate control of the process. In this study, a one-dimensional fluid/electron Monte Carlo hybrid model is employed to examine the EAE in a capacitively coupled argon-silane discharge, encompassing both amplitude asymmetry effect (AAE) and slope asymmetry effect (SAE). In the case of AAE, with the increasing pressure, the discharge electronegativity gradually intensifies, in conjunction with a transition of the electron heating mode from α to drift-ambipolar, a reduction of the absolute value of the DC self-bias voltage, and a decrease in Ar+ content, with an increase in SiH3 + content. For SAE, the trend in the discharge characteristics with the increasing pressure is similar to that for AAE, but the details are different. In SAE, the electronegativity and bulk electric field are much enhanced, resulting in higher content of high-energy electrons and Ar+ in the bulk. In addition, the absolute value of the self-bias is lower, but shows a fewer decline with the increasing pressure. The deposition rate is lower in SAE, due to the lower electron heating efficiency. However, larger voltage drop difference between two sheaths leads to a wider range of ion energy modulation at higher pressures. This study systematically investigates and compares Ar/SiH4 discharges driven by two electrically asymmetric voltage waveforms across various parameters including electron dynamics, ion and neutral transport properties, and deposition rates, with the aim of providing valuable insights and a reference for industrial applications.

HPC-PAA-PAM semi-solid hydrogel with interpenetrating network for energy-saving smart windows

Hydrogels demonstrate significant potential as materials for fabricating energy-saving smart windows. Nevertheless, their liquid nature poses challenges and renders them susceptible to leakage during operation. In this study, we developed an HPC-PAA-PAM semi-solid hydrogel through a two-step polymerization process at 80 °C, with acrylamide serving as the curing agent. The resulting hydrogel exhibited a precisely tunable lower critical solution temperature (LCST) spanning from 31.5 °C to 36.2 °C. Additionally, we constructed double-layered glass-encapsulated HPC-PAA-PAM semi-solid hydrogel smart windows, which demonstrated remarkable optical transmittance (Tlum = 88.3 %), excellent solar energy modulation (ΔTsol = 47.9 %), and remained stability through 100 heating and cooling cycles. Thermal regulation tests conducted in model houses revealed outstanding heat-shielding performance of these hydrogel smart windows, surpassing conventional double-glazed windows and double-glass encapsulated water windows. Notably, after 90 days of outdoor exposure, the HPC-PAA-PAM semi-solid hydrogel smart window experienced only a minimal reduction in solar modulation, underlining its exceptional weather durability in practical applications. Consequently, the HPC-PAA-PAM semi-solid hydrogel presents substantial promise for the production of smart windows, particularly suited for energy-efficient buildings in tropical and subtropical regions, where it can effectively prevent the intense summer sun's heat from penetrating indoors, fostering a more pleasant indoor temperature.

Tuning Circularly Polarized Afterglow Color via Modulation of Energy and Chirality Transfer in Co‐Doped Films

AbstractCircularly polarized luminescence (CPL) materials offer exciting potential due to their unique light properties. However, controlling the color of afterglow emission, a key feature for many applications remains a challenge. Here, a co‐doping strategy is presented for precise control of multicolor CPL afterglow in films. This approach utilizes chiral naphthylphosphoric acid derivatives as energy and chirality transfer donors, commonly used fluorescent dye rhodamine B (RB) and PVA are selected as the acceptor and the polymeric matrix, respectively. Remarkably, the co‐doped films exhibit ultra‐long green circular polarization phosphorescence lasting several seconds with high efficiency (14.23%), lifetime (1025.5 ms), and dissymmetry factor (8.44 × 10−3). Crucially, by adjusting the acceptor content, it can precisely tune the phosphorescence‐to‐fluorescence ratio and achieve multicolor afterglow. This control stems from a combination of Förster resonance energy transfer, chirality transfer, and color‐mixing effects. Furthermore, this approach significantly improves the asymmetry factor of the CPL afterglow by an order of magnitude (5.17 × 10−2). It is anticipated that this straightforward approach to precisely regulating the afterglow color of CPL will provide invaluable insights for the future design of highly efficient and innovative CPL materials.

Fermi energy modulation by tellurium doping of thermoelectric copper(I) iodide

Copper(I) iodide (CuI) is the leading inorganic p-type transparent conductor, attracting major attention for its promising optoelectronic properties and facile growth methods, although, commercial uptake is limited due to its as-of-yet insufficient electrical conductivity. Doping CuI with the chalcogens (O, S, Se, Te) is a viable route to tune its electrical conductivity for applications such as in thin film transistors, hole transport layers in solar cells, and transparent thermoelectric generators. The heaviest chalcogen element, Te, is yet to be explored in heavily intrinsically p-type doped CuI at non-alloying concentrations, the subject of the present work. We report the effects of tellurium at the boundary between the doping and alloying regime (up to a maximum of 2.4 % Te) in CuI thin films and investigation the variation in the thermoelectric properties and electronic band structure of the material. Ion implanting tellurium into CuI led to a progressive reduction in the films' work functions from 4.9 eV to 4.5 eV while the ionization potential remained unchanged, measured through photoemission spectrometry. This signified a modulation of the Fermi energy relative to the valence band edge, having a major effect on the materials' electrical conductivity and Seebeck coefficient, the former decreasing by 3 orders of magnitude, while the latter increased by 80 %. We conducted density functional theory (DFT) calculations to elucidate the effect of tellurium doping on the band structure of CuI. Tellurium doping corroborated the shift of Fermi energy, the incorporation of impurity acceptor states deeper into the band gap, in addition to disordering the valence band maximum. This work shows that, the Fermi energy in heavily p-type doped CuI can be moved away from the valence band through Te doping in addition to introducing band disorder, useful for controlling the hosts’ transport properties.

Photoisomerization-modulated supramolecular chirality inversion and energy-transfer efficiency in a cyanostilbene-glutamide-based self-assembly system

Manipulating chirality and energy transfer simultaneously in a single self-assembly system is important but remains challenging. In this study, we design a cyanostilbene-glutamide-based amphiphile L-GC bearing a long alkyl chain. It can form gels in methanol and exhibit circular dichroism (CD) signals. Upon ultraviolet-light irradiation, the CD signals are inverted and the morphology transforms from fibers to spheres. Chirality and energy transfer can be achieved when L-GC co-assembles with the energy acceptor DBTOC18, which is conjugated to a long alkyl chain. Moreover, the energy-transfer efficiency of the co-assembly can be modulated via photoirradiation-induced isomerization. Molecular dynamics simulation was conducted to elucidate the photomodulated assembly behavior. This study realizes the dual modulation of chirality and energy and presents some perspectives for information exchange in chiroptical materials.

An inverse free electron laser-bunching driven shallow-angle superradiant Compton source

A coherent soft x-ray Compton source driven by a density modulated electron beam is investigated. The density modulation is attained by an inverse free electron laser prebuncher, which offers strong energy modulation at the relevant beam energies for Compton scattering in an shallow-angle oblique scattering geometry using relatively low laser beam power. In particular, we study the case of a 101.7 MeV electron beam produced by a state-of-the-art high brightness accelerator beamline. Calculations show that 1011 coherent soft x-ray photons per second can be generated in an ultra-narrow relative bandwidth of 0.002% from a 250 pC microbunched electron bunch colliding with a 23 mJ laser pulse at 10 kHz.

Acceleration-induced spectral beats in strongly driven harmonic oscillators

The harmonic modulation of coherent systems gives rise to a wealth of physical phenomena, e.g., the AC-Stark effect and Mollow triplets, with important implications for coherent control and frequency conversion. Here, we demonstrate a novel regime of temporal coherence in oscillators harmonically driven at extreme energy modulation amplitudes relative to the modulation quantum. The studies were carried out by modulating a confined exciton-polariton Bose-Einstein condensate (BEC) by an acoustic wave. Features of the new regime are the appearance, in the spectral domain, of a comb of resonances termed acceleration beats with energy spacing tunable by the modulation amplitude and, in the time domain, of temporal correlations at time scales much shorter than the acoustic period, which also depend on the modulation amplitude. These features are quantitatively accounted for by a theoretical framework, which associates the beats with accelerated energy-change rates during the harmonic cycle. These observations are underpinned by the high sensitivity of the BEC energy to the acoustic driving, which simultaneously preserves the BEC’s temporal coherence. The acceleration beats are a general feature associated with accelerated energy changes: analogous features are thus also expected to appear under highly accelerated motion e.g., in connection with Cherenkov and Hawking radiation.

Performance prediction and analysis of a solar assisted medium-deep geothermal heating system

Abstract The solar assisted medium-deep geothermal heating (SAMGH) system is a novel kind of heating system that can combine the benefits of geothermal and solar energy. However, the variations in borehole heat exchanger (BHE) performance and the intermittency of solar energy pose challenges for predicting the overall performance of the coupled system and designing the operational strategies. To conduct simulation on the SAMGH system for performance prediction and analysis, a coaxial medium-deep borehole heat exchanger coupled with the solar energy heating system for an office building in Xi’an was developed. The TRNSYS software was employed to establish the model of the coupled system. A ground source heat pump (GSHP) heating system was used for comparison. The simulation results showed that with the introduction of the solar energy and heat storage modules, the annual operating time of the geothermal system only accounts for 32.06%. The energy consumption of the coupled system can be reduced from 63585 kW to 44586 kW, and the energy consumption proportion of the geothermal system in total value decreased from 69.10% to 40.58%. Therefore, the average coefficient of performance (COP) of the heat pump and the system were improved by 63.71% and 91.77%, respectively. Moreover, because the solar energy is beneficial to the ground heat recovery, the average ground temperature increased from 42.5 °C to 43.88 °C after ten years of operation. The proposed design method and simulation results can serve as a reference for design method and performance analysis of the geothermal and solar coupled system.