Plasma Energy Research Articles

Assessment of Cytotoxicity and Genotoxicity of Plasma-Treated Perfluorooctanesulfonate Containing Water Using In Vitro Bioassays

The contamination of ground and surface waters with per- and polyfluoroalkyl substances (PFASs) is of major concern due to their potential adverse effects on human health. The carbon–fluorine bond makes these compounds extremely stable and hardly degradable by natural processes. Therefore, methods for PFAS removal from water are desperately needed. In this context, plasma treatment of water has been proposed as an effective method with reported removal rates exceeding 90%. However, the high reactivity of plasma discharge results in the formation of many reactive species, like radicals, ozone, or even solvated electrons, which lead to a complex reaction cascade and, consequently, to the generation of a wide variety of different chemical products. The toxicological properties of these PFAS breakdown products are largely unknown. The present study focuses on a toxicological assessment of PFAS-containing plasma-treated water samples. Aqueous solutions of long-chain perfluorooctanesulfonate (PFOS) were treated with various plasma-atmospheric regimes. Subsequently, plasma-treated water samples were subjected to in vitro bioassays. Cytotoxicity and genotoxicity were assessed with the MTS assay using human liver cells (HepG2) and the Ames MPFTM assay using Salmonella Typhimurium strains. Our results demonstrate varying cyto- and genotoxic properties of water containing PFAS breakdown products depending on the atmosphere present during plasma treatment. Based on the results of this study, the atmosphere used during plasma treatment affects the toxicological properties of the treated sample. Further studies are therefore needed to uncover the toxicological implications of the different treatment parameters, including the PFAS starting compound, the atmosphere during treatment, as well as the quantity of plasma energy applied.

ERICH4 is not involved in the assembly and secretion of intestinal lipoproteins

Background and AimsThe small intestine plays a central role in lipid metabolism, most notably the uptake of dietary fats that are packaged into chylomicrons and secreted into the circulation for utilisation by peripheral tissues. While microsomal triglyceride transfer protein (MTP) is known to play a key role in this pathway, the intracellular assembly, trafficking, and secretion of chylomicrons is incompletely understood. Methods and ResultsUsing human transcriptome datasets to find genes co-regulated with MTTP, we identified ERICH4 as a top hit. The gene encodes for glutamate-rich protein 4, a protein of unknown function. REACTOME gene-function prediction tools indicated that ERICH4 is involved in intestinal lipid metabolism. In addition, GWAS data point to a strong relationship between ERICH4 and plasma lipids. To validate ERICH4 as a lipid gene, we generated whole-body Erich4 knockout (Erich4-/-) mice. ERICH4 deficiency, however, did not result in changes in body weight and composition, food intake, circulating plasma lipids, energy absorption and excretion, and tissue weights compared to controls. Additionally, there were no morphological abnormalities seen in the small intestine. Challenging mice with a high-fat diet did not give rise to a phenotype either. ConclusionsDespite prediction tools indicating ERICH4 as a strong candidate gene in intestinal lipid metabolism, we here show that ERICH4 does not play a role in intestinal lipid metabolism in mice. It remains to be established whether ERICH4 plays a role in human lipid metabolism.

Development of ITER first wall heat load feedback control

Real-time monitoring and control of thermal loads on tungsten plasma-facing components is mandatory for ITER to avoid their overheating during plasma discharges. For the Start of Research Operations (SRO) phase, dedicated First Wall Heat Load Control (FWHLC) functions are included in the ITER Plasma Control System (PCS) to prevent the development of excessive plasma heat loads on the inertially cooled first wall (FW). In this work, we propose a FWHLC design with a model-based approach, which features a simplified thermal model for the FW armour. This control-oriented model simulates the thermal response of ITER FW to slow changes in plasma equilibrium and energy, which during ITER operation will be monitored by the real-time wide angle infrared camera system. This allows computationally efficient runs for rapid controller performance assessment but can also assist operation scenario design by pre-empting potential heat load issues. FWHLC is designed to react to measured and predicted FW temperatures overcoming predesigned limits with real-time variations of the plasma shape or auxiliary power references, aiming to reduce thermal loads before a premature plasma termination is required to protect the FW. The new scheme is tested in closed loop simulations, where perturbations to nominal ITER low current scenarios are introduced in the wall thermal model to trigger the response of FWHLC, supporting the effectiveness of the proposed policy.

Triboplasma assisted chemical conversion in granular systems: a semi-analytic model

Abstract We present a semi-analytic model for a novel plasma-assisted chemical conversion pathway using triboplasmas generated in granular flows. Triboelectric charge relaxation is a well known phenomena where the potential generated from contact charging of particles exceeds the breakdown voltage of the background gas. In this work, we extend the triboelectric charge relaxation theory to include non equilibrium plasma energy and particle balance equations to predict the formation of dissociated and excited species that act as precursors to chemical conversion, for example in plasma-assisted ammonia synthesis. 
Our example case study with nitrogen background gas and Teflon/aluminum tribomaterial system yielded high excited nitrogen species densities per collision that are comparable to current plasma-assisted conversion pathways. We also present a regime diagram for various gases where Paschen breakdown parameters are used to determine whether triboplasmas can be formed for a given effective work-function difference between two materials. Our sensitivity studies indicate particle velocity, particle radius, solids fraction and space charge effects play a critical role in overall plasma densities and excited species production.

ACSL3 is a promising therapeutic target for alleviating anxiety and depression in Alzheimer's disease.

Alzheimer's disease (AD), the leading cause of dementia, affects over 55 million people worldwide and is often accompanied by depression and anxiety. Both significantly impact patients' quality of life and impose substantial societal and economic burdens on healthcare systems. Identifying the complex regulatory mechanisms that contribute to the psychological and emotional deficits in AD will provide promising therapeutic targets. Biosynthesis of omega-3 (ω3) and omega-6 fatty acids (ω6-FA) through long-chain acyl-CoA synthetases (ACSL) is crucial for cell function and survival. This is due to ω3/6-FA's imperative role in modulating the plasma membrane, energy production, and inflammation. While ACSL dysfunction is known to cause heart, liver, and kidney diseases, the role of ACSL in pathological conditions in the central nervous system (e.g., depression and anxiety) remains largely unexplored. The impact of ACSLs on AD-related depression and anxiety was investigated in a mouse model of Alzheimer's disease (3xTg-AD). ACSL3 levels were significantly reduced in the hippocampus of aged 3xTg-AD mice (via capillary-based immunoassay). This reduction in ACAL3 was closely associated with increased depression and anxiety-like behavior (via forced swim, tail suspension, elevated plus maze, and sucrose preference test). Upregulation of ACSL3 via adenovirus in aged 3xTg-AD mice led to increased protein levels of brain-derived neurotrophic factor (BDNF) and vascular endothelial growth factor C (VEGF-C) (via brain histology, capillary-based immunoassay), resulting in alleviation of depression and anxiety symptoms. The present study highlights a novel neuroprotective role of ACSL3 in the brain. Targeting ACSL3 will offer an innovative approach for treating AD-related depression and anxiety.

Effect of detachment on Magnum-PSI ELM-like pulses: direct observations and qualitative results

Abstract Conditions similar to those at the end of the divertor leg in a tokamak were replicated in the linear plasma machine Magnum-PSI. The neutral pressure in the target chamber is then increased to cause the target to transition from an attached to a detached state. Superimposed to this steady state regime, edge localised mode (ELM)-like pulses are reproduced, resulting in a sudden increase in plasma temperature and density, such that the heat flux increases transiently by half an order of magnitude. Visible light emission, target thermography, and Thomson scattering are used to demonstrate that the higher the neutral pressure the more energy is removed from the ELM-like pulse in the volume. If the neutral pressure is sufficiently high, the ELM-like pulse can be prevented from affecting the target and the plasma energy is fully dissipated in the volume instead (ID 4 in table 1). The visible light images allow the division of the ELM-plasma interaction process of ELM energy dissipation into 3 ‘stages’ ranging from no dissipation to full dissipation (the target plasma is detached). In the second publication related to this study, spectroscopic data is analysed with a Bayesian approach, to acquire insights into the significance of molecular processes in dissipating the plasma energy and particles.

Solar Vortex Tubes. III. Vorticity and Energy Transport

This study investigated the mechanisms of vorticity generation and the role of vortex tubes in plasma heating and energy transport. Vortex tubes were identified using the instantaneous vorticity deviation technique in the MURaM data set of a simulated solar plage region of the solar photosphere. Within 3D kinetic vortex tubes, the misalignment of the magnetic pressure and the inverse of the density gradient, rather than baroclinic effects, primarily drive vorticity within the tubes. During their lifetime, vortices become less dense as the Lorentz force pushes plasma outwards against pressure gradients. In the simulated upper photosphere, the Lorentz force contributes to adiabatic cooling and heating by expanding or compressing the plasma around the vortex tubes. In turn, vortex motion affects the magnetic field, enhancing current generation and intensifying the Lorentz force, which may further increase adiabatic cooling and heating. Moreover, our results confirm that vortices can significantly boost viscous and ohmic heating on intergranular scales in the photosphere. They generate more magnetic than kinetic energy, with energy transport by Poynting flux notably nonuniform and dominant at the vortex boundaries. This creates energy circulation in which the net upwards Poynting flux can enhance chromospheric plasma heating and support chromospheric temperatures.

Turbulent transport mechanisms and their impact on the pedestal top of JET plasmas with small-ELMs

Abstract Understanding the transport mechanisms that regulate the H-mode pedestal structure is crucial for developing regimes with edge dynamics that are compatible with the thermal and particle load constraints of plasma facing components. In this regard, at the JET tokamak, H-mode plasma regimes featuring small-ELM (BSE) dynamics have been developed, expelling less plasma energy per ELM compared to the standard type-I ELM. The pedestal of these new regimes remains stable against peeling-ballooning modes, leaving its structure unexplained. In this study, three baseline H-mode JET discharges—a reference with type-I ELM and two BSE regimes—are selected to investigate the turbulent transport mechanisms occurring in pedestals with different structures. The turbulence analysis is conducted using local gyrokinetic simulations around the pedestal top position. The results show that at ion scales, while hybrid ITG-KBM and KBM are destabilized in the type-I ELM discharge, the BSE regimes are dominated by hybrid ITG-TEM, suggesting a different role of turbulent transport in the two cases. At electron scales, both regimes are dominated by toroidal and slab ETG, the latter extending up to very small scales. Simulations of turbulence driven by hybrid ITG-TEM focuses on the impact and competition of electromagnetic (EM) effects and equilibrium E × B shearing. A strong EM stabilization mechanism is found, resulting in a saturated turbulence regime with spectra different from those in the electrostatic limit (ES l ). Additionally, while increasing E × B shearing reduces transport in ES l simulations, it is observed to have the opposite effect in the EM regime. Finally, stiff ETG transport is also shown to produce transport levels compatible with experimental observations. The findings of this study suggest the EM stabilization and its competition with E × B shearing as new key elements that determine the nature of the turbulent transport mechanisms around the pedestal top, which need to be considered in reduced models for pedestal limits.

Effects of discharge parameters on plasma acceleration and transmission characteristics of a coaxial gun operated in gas-prefilled mode

The effects of discharge parameters on the discharge process and plasma transport characteristics of a coaxial gun in the gas-prefilled mode are studied. The plasma optical intensity and ejection velocity are measured by photodiodes, the optical emission spectrum is taken by a spectroscopic system, and the plasma evolution in the transport process is captured by a high-speed camera. The plasma acceleration characteristics under different discharge parameters show that the velocity and electron density of the ejection plasma are mainly determined by the pre-filled pressure and discharge current, which is consistent with the snowplow model. The kinetic energy of ejection plasma can be significantly increased by reducing the outer loop inductance, which is conducive to increasing the energy utilization efficiency. The time-varying images of plasma radiation and the plasma density at different transport locations illuminate the transmission characteristics of coaxial gun discharge plasma. The results show that the snowplow effect continues to play a role in the plasma transport process, and the plasma accumulation is induced by the combination of shock wave compression. The current-driven magneto hydrodynamics instability occurs during the transport process, and the luminous signal of the plasma current sheet oscillates periodically. In addition, the plasma impact effect is obvious and the gas retarding effect is enhanced with the increase in the gas pressure. These results give us a more comprehensive view of the coaxial gun discharge process and plasma transport and provide a certain reference for optimizing the parameters selection and physical design of coaxial gun discharge plasma characteristics.

Magnetic diffusion in solar atmosphere produces measurable electric fields

The efficient release of magnetic energy in astrophysical plasmas, such as during solar flares, can in principle be achieved through magnetic diffusion, at a rate determined by the associated electric field. However, attempts at measuring electric fields in the solar atmosphere are scarce, and none exist for sites where the magnetic energy is presumably released. Here, we present observations of an energetic event using the National Science Foundation’s Daniel K. Inouye Solar Telescope, where we detect the polarization signature of electric fields associated with magnetic diffusion. We measure the linear and circular polarization across the hydrogen Hε Balmer line at 397 nm at the site of a brightening event in the solar chromosphere. Our spectro-polarimetric modeling demonstrates that the observed polarization signals can only be explained by the presence of electric fields, providing conclusive evidence of magnetic diffusion, and opening a new window for the quantitative study of this mechanism in space plasmas.

Effect of the indirect sonication on the plasma formation and energy parameters in the cathodic regime of the plasma-driven solution electrolysis

Effect of the indirect sonication on the plasma formation and energy parameters in the cathodic regime of the plasma-driven solution electrolysis

Pulsed laser deposition of MoS2 thin films at different mean kinetic plasma energies

In recent years, molybdenum disulfide has become a material of great interest for research for electronic and optoelectronic applications due to its 2-dimensional graphene-like structure and its bandgap within the visible spectrum. In this work, thin films of MoS2 were grown using pulsed laser deposition on glass substrates at room temperature and at deposition pressure of 2 × 10−5 Torr. We ablated a MoS2 target obtained by compressing high-purity powders, with a Nd-YAG pulsed laser with a wavelength of 1064 nm, 6 ns pulse width, and 10 Hz repetition rate. Laser produced plasmas were diagnosed by means of the time-of-flight technique using a Langmuir planar probe, from which mean kinetic energy and density of ions were estimated. Experimental control is more reliable using plasma parameters rather than fluence. The crystalline properties of the deposits were characterized using Raman spectroscopy and X-Ray diffraction; their chemical analysis was carried out by X-ray photoelectron spectroscopy; their thickness and morphology were characterized using atomic force microscopy and scanning electron microscopy, respectively. Results are discussed as a function of mean kinetic energy variations. It was observed that as the mean kinetic energy of the plasma decreased, the crystallinity improved and the crystal size increased.

Electron Dissipation and Electromagnetic Work

AbstractWith the increase in technical capabilities of computer simulation in recent years, it has become feasible to quantify the degradation of fluid scale plasma and electromagnetic energies in favor of increases of internal energies. While it is understood that electromagnetic energy can be exchanged with fluid scale velocities, it is the pressure strain interaction that exchanges energy between fluid motions and internal energy. Here using simulations of both turbulence and reconnection we show that for electrons, the pressure strain and electromagnetic work are closely related and are frequently comparable when appropriate time and spatial averaging is applied. Otherwise, the instantaneous spatial averaged pressure strain and electromagnetic work are nearly equal for slowly evolving systems, like the reconnection case, while they differ significantly in rapidly evolving systems, like the turbulence case. This clarifies the relationship between these two quantities, which are each frequently used as measures of dissipation.

Applicability of Bernoulli's theorem to upstream and downstream of the bow shock

In this research, the validity of Bernoulli's theorem for the solar wind crossing the Earth's bow shock has been investigated based on space explorations. Using solar wind plasma and interplanetary magnetic field data from the OMNI database, along with magnetosheath plasma and magnetic field data measured by the magnetospheric multiscale satellite in 2016 and 2018, 95 events were selected to study the Bernoulli invariant from the upstream to the downstream of Earth's bow shock (from the unshocked solar wind region to the shocked magnetosheath region). Statistical investigations show that the differences in the characteristic energy of plasmas between the solar wind region and the magnetosheath region are less than 5%, regardless of the upstream solar wind speed and the satellite's location in the magnetosheath. These results quantitatively support the generalization of Bernoulli's equation to the solar wind flowing through the bow shock, including the contribution of magnetic field energy.

Morphology and Wettability of Polystyrene film on QCM Sensor Caused by Oxygen Plasma with DC Bias

Surface wettability and morphology are important aspects of developing QCM sensors for chemical sensors and biosensors. The functionality and morphology of the sensitive coating on the sensor surface affect the sensor sensitivity and selectivity. Various materials and methods to improve the functionality and morphology of the sensor surface have been developed, one of which is plasma. Species and parameters of the generated plasma play an important role in the treatment. One parameter is the DC-bias voltage of RF plasma, which plays an important role in plasma generation and bombardment on the surface being modified. This work shows the effect of the DC bias of the 2 MHz RF plasma with oxygen species. Surface functionality and morphology modification of the polystyrene film on the QCM sensor was done by surface modification using oxygen plasma. Partial etching of the polystyrene film occurred when treated with oxygen plasma generated using 2 MHz with negative DC-bias. CII, CO+, and CO were detected during the exposure of oxygen plasma on polystyrene film, indicating a chemical reaction between the plasma species, oxygen plasma, and the polystyrene. Observation by optical microscope and SEM showed the occurrence of partial etching on the polystyrene film. As there is no masking, the partial etching occurred randomly. The average size of the etched film increased with the DC bias voltage, but the percentage of the etched area was not. The oxygen plasma converts the polystyrene film from hydrophobic to hydrophilic, but hydrophobicity increases with the DC bias voltage. HIGHLIGHTS Polystyrene surface treatment using oxygen plasma can be used to alter the surface hydrophobicity. The DC bias plays important role in the surface modification. High DCV bias gives stronger plasma energy which may etched the polystyrene film. Observation using SEM shows part of the polystyrene film was etched as the DC bias voltage increase. The amount of the etched surface can be measured using optical microscope and processed using ImageJ. Increasing the DC bias result in a wider etched film. GRAPHICAL ABSTRACT

Using Schottky Arc-plasma for Modelling the Cathode Temperatures of Various Materials at High Pressure

Theoretical investigation for cathodes of different metals, including hafnium (Hf), niobium (Nb), tungsten (W), and molybdenum (Mo) were used. It was noticed that the plasma energy at the cathode (Hf) has a higher value than that at the cathode metal because the energy losses of electrons for (Hf) are less due to inelastic collisions. As for the energy of electrons, their value for the metal (Hf) is also higher than of the other metals, and the reason is that the energy is proportional to the temperature according to the equation: (E = 3/2 KT). It was also noted that the energy of ions for all metals is almost equal at temperature (Tw≅4000K) due to energy losses due to elastic and inelastic collisions, this leads to a state of saturation. There is a large decrease in the voltage barrier accompanied by an increase in the current density, differences occur in the values of the voltage barrier due to the difference in the work function which varies according to the metal.

Impact of repetitive ELM transients on ITER divertor tungsten monoblock top surfaces

Abstract Owing to the high stored energy of ITER plasmas, the heat pulses due to uncontrolled Type I edge localized modes (ELMs) can be sufficient to melt the top surface of several poloidal rows of tungsten monoblocks in the divertor strike point regions. Coupled with the melt motion associated with tungsten in the strong tokamak magnetic fields, the resulting surface damage after even a comparatively small number of such repetitive transients may have a significant impact on long-term stationary power handling capability. The permissible numbers set important boundaries on operation and on the performance required from the plasma control system. Modelling is carried out with the recently updated MEMENTO melt dynamics code, which is tailored to tackle melt motion problems characterized by a vast spatio-temporal scale separation. The crucial role of coupling between surface deformation and shallow angle heat loading in aggravating melt damage is highlighted. As a consequence, the allowable operational space in terms of ELM-induced transient heat loads is history-dependent and once deformation has occurred, weaker heat loads, incapable of melting a pristine surface, can further extend the damage.

Dynamical generation of macroscale magnetic fields and fast flows in a four-component astrophysical plasma

We explore the possibility of the generation or amplification of macroscale magnetic fields and flows in a four-component astrophysical dusty plasma composed of mobile massless electrons and positrons, inertial positive ions and negatively charged static dust particles. The investigation demonstrates that when microscopic turbulent ambient plasma energy is predominantly kinetic, a straight dynamo (DY) mechanism is feasible. Conversely, a unified reverse-dynamo/dynamo (RDY/DY) mechanism is possible when the microscopic turbulent ambient plasma energy is primarily magnetic. Additionally, the evolution of Alfvén Mach numbers at the macro- and microscale are significantly affected by plasma species densities and invariant helicities. The potential implications of the present study for astrophysical settings are also highlighted.

1D modeling of plasma streamers at ammonia-air flame conditions

Abstract This work is a self-consistent 1D modeling of streamers in ammonia-oxygen-nitrogen-water mixtures. A fluid model that includes species transport, electrostatic potential, and detailed chemistry was developed and verified. This model is then used to simulate the avalanche, streamer formation and propagation phases, driven by a nanosecond voltage pulse, at different thermochemical conditions derived from a 1D laminar premixed ammonia-air flame. The applicability of the Meek’s criterion in predicting the streamer inception location was successfully confirmed. Streamer formation and propagation duration were found to vary significantly with different thermochemical conditions, due to the difference in ionization rates. The thermochemical state also affected the breakdown characteristics which was tested by maintaining the background reduced electric field constant. Detailed kinetic analyses revealed the importance of O(1D) in the production of key radicals, such as O, OH, and NH2. Furthermore, the contributions of the dissociative electronic excitation of NH3 towards the production of H and NH2 radicals have also been reported. Spatial and temporal evolution of the electron energy loss fractions for various inelastic collision processes at different thermochemical states uncovered the input plasma energy spent of fuel dissociation and the large variability in the dominant processes during the avalanche and streamer propagation phases. The methodology and analyses reported in this work are key towards developing effective strategies for controlled nanosecond-pulsed non-equilibrium plasma sources used for ammonia ignition and flame stabilization.

Improved-Performance Amorphous Ga2O3 Photodetectors Fabricated by Capacitive Coupled Plasma-Assistant Magnetron Sputtering

Ga2O3 has received increasing interest for its potential in various applications relating to solar-blind photodetectors. However, attaining a balanced performance with Ga2O3-based photodetectors presents a challenge due to the intrinsic conductive mechanism of Ga2O3 films. In this work, we fabricated amorphous Ga2O3 (a-Ga2O3) metal–semiconductor–metal photodetectors through capacitive coupled plasma assisted magnetron sputtering at room temperature. Substantial enhancement in the responsivity is attained by regulating the capacitance-coupled plasma power during the deposition of a-Ga2O3. The proposed plasma energy generated by capacitive coupled plasma (CCP) effectively improved the disorder of amorphous Ga2O3 films. The results of X-ray photoelectron spectroscopy (XPS) and current-voltage tests demonstrate that the additional plasma introduced during the sputtering effectively adjust the concentration of oxygen vacancy effectively, exhibiting a trade-off effect on the performance of a-Ga2O3 photodetectors. The best overall performance of a-Ga2O3 photodetectors exhibits a high responsivity of 30.59 A/W, a low dark current of 4.18 × 10−11, and a decay time of 0.12 s. Our results demonstrate that the introduction of capacitive coupled plasma during deposition could be a potential approach for modifying the performance of photodetectors.