In industrial wireless sensor networks (IWSNs), a lot of energy is wasted in the form of electromagnetic radiations. It can be effectively utilized with energy harvesting (EH), which absorbs part of the energy in the transmission signal but reduces the throughput and reliability of IWSNs. In this article, we study the throughput optimization of IWSNs with EH from the interference radio-frequency (RF) signal considering the reliability constraint of the industrial information transmission. Under the premise of limited energy supply of EH relays, the throughput maximization of IWSNs is formulated as a nonconvex optimization problem. In order to transform the nonconvex problem to a convex optimization problem, the successive convex approximation (SCA) approach is adopted. Furthermore, a power allocation algorithm is designed to maximize the total transmission rate of the network. Simulation results demonstrate that the proposed algorithm can maximize the throughput under the primise of SINR reliability.