Energy Harvesting Research Articles

Progress on Si‐based photoelectrodes for industrial production of green hydrogen by solar‐driven water splitting

AbstractSolar power has been regarded as the ultimate green‐energy source because of its inexhaustibility and eco‐friendliness. The solar‐driven water‐splitting technology for green hydrogen production is considered to be one of effective ways for solar energy harvesting and storage, which may provide solutions for the energy crisis and environmental issues. In the past decades, great progress has been achieved in this area. Photoelectrochemical (PEC) water splitting is especially promising for the production of solar fuels because of expected large‐scale industrial application. Silicon (Si), as an ideal candidate for the photoelectrode, is the most suitable material for the PEC device in industrial photocatalytic water splitting because of its abundance, mature fabrication technology, and suitable band gap. Here, we give a systematic review on the recent progress for Si‐based photoelectrodes for water splitting with a focus on the industrial application. Particularly, the strategies, such as band‐alignment control, morphology design, and surface engineering, are summarized to enhance the PEC performance and durability for practical application. Furthermore, the perspective for the design of commercial Si‐based PEC devices with high PEC performance, long‐term stability, large‐size, and low cost are given at the end, which shall guide the development of PEC water splitting for industrial application.

Templatesec-Built Structural Designs for Piezoelectrochemical Pressure Sensors.

Self-powered sensors, capable of detecting static and dynamic pressure without an external power source, are pivotal for advancements in human-computer interaction, health monitoring, and artificial intelligence. Current sensing technologies, however, often fall short of meeting the growing needs for precise and timely pressure monitoring. This article introduces a novel self-powered pressure sensor utilizing electrochemical reactions. The sensor's ion conduction path and internal resistance adjust in response to external stress across a broad range. Its three-dimensional structure, crafted by using a simple template on the electrolyte, enables the efficient and cost-effective detection of various mechanical stimuli. This device not only achieves an optimized power density of approximately 2.34 mW cm-2─surpassing most existing technologies─but also features excellent flexibility, quick response, and recovery times (0.15 and 0.19 s respectively); high durability (2000 cycles); and a broad sensing range (0.23-20 kPa). Moreover, it serves as an ionic touchpad, enhancing data collection and recognition, and integrates seamlessly with a mouthpiece for accurate, real-time monitoring of respiratory activities. This innovative sensor offers minimal cost and simple process requirements while providing multifunctional capabilities for energy harvesting and pressure sensing, marking a significant step forward in the design of next-generation sensors.

From Lab to Life: Self-Powered Sweat Sensors and Their Future in Personal Health Monitoring.

The rapid development of wearable sweat sensors has demonstrated their potential for continuous, non-invasive disease diagnosis and health monitoring. Emerging energy harvesters capable of converting various environmental energy sources-biomechanical, thermal, biochemical, and solar-into electrical energy are revolutionizing power solutions for wearable devices. Based on self-powered technology, the integration of the energy harvesters with wearable sweat sensors can drive the device for biosensing, signal processing, and data transmission. As a result, self-powered sweat sensors are able to operate continuously without external power or charging, greatly facilitating the development of wearable electronics and personalized healthcare. This review focuses on the recent advances in self-powered sweat sensors for personalized healthcare, covering sweat sensors, energy harvesters, energy management, and applications. The review begins with the foundations of wearable sweat sensors, providing an overview of their detection methods, materials, and wearable devices. Then, the working mechanism, structure, and a characteristic of different types of energy harvesters are discussed. The features and challenges of different energy harvesters in energy supply and energy management of sweat sensors are emphasized. The review concludes with a look at the future prospects of self-powered sweat sensors, outlining the trajectory of the field and its potential to flourish.

Evaluating the Efficacy of Lead-Free Piezoelectric Materials in Microcantilever Based Vibration Energy Harvesters

Abstract The piezoelectric materials have been extensively utilized in various applications, such as sensors, actuators, and energy harvesters. This study evaluates the performance of six lead-free piezoelectric materials- aluminium nitride (AlN), barium titanate (BaTiO3), lithium niobate (LiNbO3), lithium tantalate (LiTaO3), polyvinylidene fluoride (PVDF), and zinc oxide (ZnO) in MEMS-based piezoelectric vibration energy harvesters (PVEHs) using cantilever configurations. Finite element analysis via COMSOL Multiphysics was employed to assess the deflection, voltage, and power outputs of these materials at their resonance frequencies, both with and without proof masses. The results indicate that BaTiO3 and PVDF cantilevers exhibited the highest voltage outputs, reaching 207.14 mV and 202.07 mV, respectively, with AlN also showing comparable performance at 184.72 mV. ZnO-based cantilevers demonstrated the highest power output of 1.35 nW without proof masses and 190.5 nW with proof masses, indicating its potential for high-power applications. The addition of proof masses generally reduced resonant frequencies but enhanced power outputs, like for ZnO. This comprehensive analysis underscores the critical impact of material selection and structural modifications on the efficiency of PVEHs, with BaTiO3, PVDF, and ZnO emerging as the most promising candidates for optimizing energy harvesting devices. This research lays a foundation for further advancements in piezoelectric MEMS technology, aiming for more efficient energy harvesting solutions.

Research on triboelectric-piezoelectric energy harvesting technology driven by wind

Abstract In this paper, the triboelectric-piezoelectric energy harvesting technology is systematically studied. Piezoelectric materials and friction materials are combined to form integrated piezoelectric plates. A wind energy harvester based on integrated piezoelectric plates is designed and its performance is evaluated. Experimental results reveal that the maximum peak voltage for piezoelectricity and triboelectricity are 38.91 V and 12.4 V, respectively. Notably, the output voltage of the integrated piezoelectric plate is observed to increase by 31.87% compared to the original piezoelectric plate. The maximum piezoelectric peak voltage of the overall wind energy harvester is 145.23 V, and the maximum triboelectric peak voltage is 43.25 V, which can provide continuous power for small components. The integrated piezoelectric plates demonstrates a substantial enhancement in the original piezoelectric output voltage, indicating significant application potential.

Vibration Suppression and Energy Harvesting of Nonlinear Energy Sink-Based Piezoelectric System with Combined Damping and Bistability Properties for Nonlinear Oscillator

Nonlinear energy sink (NES) as a new type of dynamic absorber has received widespread attention due to its broadband vibration suppression capability, but it has a certain requirement of energy triggering threshold. In this work, a bistable NES-based piezoelectric system with combined damping (BCPNES) and low threshold requirement is proposed. Electromechanical-coupled equations for the nonlinear oscillator coupled with BCPNES (NO-BCPNES) are established. The vibration suppression and vibration energy harvesting performance for the coupled system are investigated numerically and analytically. The frequency–energy plots of the conservative system are investigated using the complex-variable averaging method and the electromechanical decoupling method. The influence of circuit parameters on the target energy transfer threshold and harvested energy is discussed through the equivalent stiffness and damping of the circuit. The vibration suppression performance and the target energy transfer characteristics are analyzed in terms of the time–history response, the time–frequency response and the slowly varying dynamic flow, respectively. The results show that the electromechanical coupling coefficient affects the skeleton curve of frequency–energy plots in the form of equivalent stiffness. The NO-BCPNES system exhibits higher energy dissipation performance and better targeted energy transfer form under various excitations. From the phase perspective, NES-based piezoelectric system achieves vibration suppression of the main structure through the phase locking phenomenon. The mechanism of the influence of piezoelectric device parameters on the energy harvesting performance of the systems is clarified.

Modeling and Analyzing of CMOS Cross-Coupled Differential-Drive Rectifier for Ultra-Low-Power Ambient RF Energy Harvesting

This paper models and analyzes the Complementary Metal Oxide Semiconductor (CMOS) cross-coupled differential-drive (CCDD) rectifier for Ultra-Low-Power ambient radio-frequency energy harvesters (RFEHs) working in the subthreshold region. In this paper, two closed-form equations of CCDD rectifier output voltage and input resistance in the subthreshold region were derived based on BSIM4 models of NMOS and PMOS. The model give insight to specify circuit parameters according to different inputs, transistor sizes, threshold voltages, numbers of stages, load conditions and compensation voltages, which can be used to optimize the rectifier circuit. There is a good agreement between the simulation results and these models, and these models have a maximum deviation of 10% in comparison with the simulation results in the subthreshold region. The measurement results of a single-stage CCDD rectifier reported in a previous paper were adopted to verify the model. The output voltage and input resistance predicted by these models provide excellent consistency with corresponding measurement results. The model can be employed to optimize the CCDD rectifier without expensive calculation in the design stage.

Full-duplex cooperative relaying systems for simultaneous wireless information and power transfer with non-orthogonal multiple access

In this research, we propose a system model based on cooperative non-orthogonal multiple access (NOMA) for simultaneous wireless information and power transfer (SWIPT) within a full-duplex (FD) communication framework. We investigate two protocols - time switching protocol (TSR) and power splitting protocol (PSR) - designed to accommodate delay-tolerant-transmission (DTT) as well as delay-limited-transmission (DLT), thereby improving data processing and energy harvesting (EH). We present explicit formulas for pivotal performance measures such as energy efficiency, ergodic rate, throughput, and outage probability. These performance measures are thoroughly evaluated in numerous specifications, encompassing inter-user separation, required spectral efficiency, EH efficiency, time and power splitting ratios in moderate-to-high signal-to-noise ratio scenarios. The results expose improved EH efficiency, hence meliorated transmission reliability. Importantly, NOMA in the proposed system model is proved to be considerably better than traditional orthogonal multiple access.

Energy conversion and transport in molecular-scale junctions

Molecular-scale junctions (MSJs) have been considered the ideal testbed for probing physical and chemical processes at the molecular scale. Due to nanometric confinement, charge and energy transport in MSJs are governed by quantum mechanically dictated energy profiles, which can be tuned chemically or physically with atomic precision, offering rich possibilities beyond conventional semiconductor devices. While charge transport in MSJs has been extensively studied over the past two decades, understanding energy conversion and transport in MSJs has only become experimentally attainable in recent years. As demonstrated recently, by tuning the quantum interplay between the electrodes, the molecular core, and the contact interfaces, energy processes can be manipulated to achieve desired functionalities, opening new avenues for molecular electronics, energy harvesting, and sensing applications. This Review provides a comprehensive overview and critical analysis of various forms of energy conversion and transport processes in MSJs and their associated applications. We elaborate on energy-related processes mediated by the interaction between the core molecular structure in MSJs and different external stimuli, such as light, heat, electric field, magnetic field, force, and other environmental cues. Key topics covered include photovoltaics, electroluminescence, thermoelectricity, heat conduction, catalysis, spin-mediated phenomena, and vibrational effects. The review concludes with a discussion of existing challenges and future opportunities, aiming to facilitate in-depth future investigation of promising experimental platforms, molecular design principles, control strategies, and new application scenarios.

Spider Webs‐Inspired Aluminum Coordination Hydrogel Piezoionic Sensors for Tactile Nerve Systems

AbstractPiezoionics, a new frontier that employs mobile ions as energy and charge carriers, plays an important role in new energy and intelligent electronics. However, a significant challenge consists in balancing the structural design of metal ions coordination hydrogel (HG‐MI) piezoionics for current conduction, voltage generation, and especially mechanical adaptability. Herein, inspired by the spider webs' unique structure, a strategy by realizing the full potential of metal‐ligand ions ([(OH)Cl2]3−) to facilitate the keggin‐type structure AlOHAlOH generation together with activate functional carboxyls is introduced. Impressively, the whole property of the product HG‐AlPAC, especially the mechanical performance is improved. For example, the toughness of HG‐AlPAC is 2.75 MJ m−3, more than twofold that of traditional HG‐AlAS/AC/AN samples. Due to the stable fixation of ─Al─OH─ thus promoting Cl− separation upon external force, HG‐AlPAC achieves a piezoionic coefficient of 0.89 mV KPa−1 and energy conversion efficiency of 1.29%, promising for mechanical‐electrical conversion and sensing. Combined with the good mechanical performance with the excellent piezoionic properties, underscores its potential as a tactile nerve system of analgesia patients to prevent them from being injured. This work intends to provide a stride toward mechanically robust self‐powered piezoionic sensors and offer insights into ionotropic materials for energy harvesting, human‐machine interaction, and biointerface.

A compliant mechanism actuated bistable hybrid mode triboelectric nanogenerator

Abstract Triboelectric nanogenerators (TENGs) working in sliding mode offer higher power generation capability compared with those working in contact-separation mode (CS-TENGs). However, unlike CS-TENGs, sliding action can limit TENG lifespan due to wear and tear. A TENG combining both modes with intermittent sliding actions can overcome this limitation. In this study, we propose a bistable hybrid mode TENG (BHM-TENG) that can leverage the functionalities of the traditional sliding TENG and CS-TENG and achieve both durability and satisfactory performance, enabled by a compliant mechanism design. A self-rotating base introduces sufficient sliding during intermittent contact, leading to significant improvement in charge transfer (44%) and voltage output (58%) compared with the conventional TENGs while minimising wear and tear. The prototyped device, excited using compliant beams, can be effectively actuated even at extremely low input frequencies (<0.1 Hz), as explained by a mathematical model. The real-world energy harvesting applications enabled by BHM-TENG is proposed based on the output of BHM-TENG.

High-efficiency quad-band RF energy harvesting system with improved cross-coupled differential-drive rectifier

Abstract RF energy harvesting technology has garnered significant attention from researchers in recent years. This paper presents a high-efficiency quad-band RF energy harvesting (RFEH) system. It introduces an improved cross-coupled differential-drive rectifier designed for ambient wireless powering, capable of harnessing power from four distinct ambient RF sources: FM-100, DTV-600, GSM-1800, and WiFi-2400 frequency bands. The proposed RFEH system demonstrates notable advancements, achieving a high RF to DC conversion efficiency of over 80 % within an input power range of −5 dB m to +13 dB m, with a 5 kΩ resistance load. This power output is deemed sufficient for energizing low-power micro-devices autonomously, without reliance on external power sources. Notably, the DC output voltage of the proposed RFEH system exhibits a high level of stability against variations in input power, a characteristic not adequately addressed in existing systems.

Hybrid Triboelectric‐Electromagnetic‐Electric Field Energy Harvester for Simultaneous Wind and Electric Field Energy Capture in High‐Voltage Transmission System

AbstractWith the development of smart grids, efficient condition monitoring of high voltage transmission system has become crucial, necessitating reliable power supplies for distributed sensors. Traditional energy harvesters often focus on either internal or external sources, limiting overall efficiency. This study introduces a triboelectric‐electromagnetic‐electric field hybrid energy harvester (TEE‐HEH) that synergistically integrates triboelectric nanogenerators (TENGs), electromagnetic generators (EMGs), and electric field energy harvesters (EEHs) to simultaneously capture electric field and wind energy. Electric field energy is harvested via displacement currents between transmission lines and the ground, while TENGs and EMGs efficiently capture low‐ and high‐speed wind energy, respectively, enabling broadband harvesting (2.3–10 m s−1). The synergistic combination of TENG, EMG, and EEH within the TEE‐HEH leads to significantly enhanced energy capture efficiency from multiple sources. At a wind speed of 5 m s−1, a transmission line voltage of 25 kV, and a distance of 1.5 m, the TEE‐HEH achieved peak power outputs of 18.5 mW (TENG), 262 mW (EMG), and 1.85 mW (EEH), demonstrating enhanced energy collection efficiency. An environmental monitoring system has been powered, demonstrating the TEE‐HEH's practicality for dual‐source energy harvesting in smart grid applications.

Cantilever configurations in vibration-based piezoelectric energy harvesting: A comprehensive review on beam shapes and multi-beam formations.

Abstract Vibration-based energy harvesting technology is a well-established research area that has attracted tremendous interest over the last decade. This interest is primarily owing to its extension into a wide range of engineering domains, particularly in Microelectromechanical Systems (MEMS). The cantilever beam is the most common and widely used model for vibration-based energy harvester, driven by two key factors: a) simplicity in design, and b) high output power density. Numerous studies over the years have focused on optimizing the cantilever beam design to increase output power capacity and/or widen the frequency bandwidth of the harvester. While researchers have proposed a plethora of cantilever beam configurations for specific purposes (e.g., low-frequency harvesting, multi-directional frequency harvesting, etc.), there is a notable lack of detailed literature on the types and configurations of cantilever beams. This gap hinders researchers from gaining a comprehensive understanding of the cantilever beams already introduced. Following the need, in this article a comprehensive review is made to list the types of cantilever beams proposed by the researchers over the years. This review covers the working principles of piezoelectric energy harvesting, analyses existing solutions geared towards increasing power output and widening working frequency, and discusses diverse configurations including single and multiple beam setups. The listed beams are categorized based on their structural shape and organization such that it can be helpful for a reader to anticipate which cantilever beam design can be suitable for a specific need. Power output capacity and operating frequency for every beam design are also presented in a tabular form, under each beam category. This would enable the researchers to tailor their designs for specific applications, enhance material efficiency, drive innovation, and open new application possibilities.

Investigation of a Magnetic Levitation Architecture with a Ferrite Core for Energy Harvesting

This work presents the development of a magnetic levitation system with a ferrite core, designed for electromagnetic energy harvesting from mechanical vibrations. The system consists of a fixed enamel-coated copper coil and five neodymium-iron-boron permanent magnets housed within a PVC spool. To enhance magnetic flux concentration, a manganese-zinc ferrite (Mn-Zn) ring was employed within the spool. Experimental tests were conducted at frequencies up to 20 Hz, demonstrating the device’s potential for harvesting energy from small vibrations, such as those generated by human biomechanical movements, achieving operating voltages up to 3 V. Additionally, the architecture is scalable for larger systems and allows for the integration of multiple transducers without magnetic field interference, independent of the frequency or excitation phase of each transducer.

Free‐Standing, Multifunctional Thermoelectric and Acoustic Absorbing Nanocomposite Foams

AbstractThermoelectric materials are potential energy harvesting technologies that enable direct, clean conversion between thermal and electrical energy. The efficacy of thermoelectric energy conversion is influenced by the electrical conductivity, thermal conductivity, and Seebeck coefficient. Flexibility, manufacturability, and cost‐effectiveness are also important factors. Polymeric nanocomposites offer advantages in these respects. However, the development of conductive‐polymer thermoelectric materials is limited to an in‐plane architecture, which does not resemble common real‐world scenarios. Moreover, existing works have low thermoelectric properties or rely on additives for performance improvement. In this work, a free‐standing thermoelectric nanocomposite foam is fabricated via the integration of thermally activated microspheres. Due to the microstructure, a thermal conductivity as low as 0.03 W m−1 K−1 is achieved, which is lower than reported for aerogels fabricated via freeze‐drying methods. Additionally, the nanocomposite foam can reach a maximum electrical conductivity of 1.13 S cm−1, power factor of 0.12 µW m−1 K−2, and thermoelectric figure of merit of 3.0 × 10−4. The study also evaluated the compressive stiffness and demonstrated the potential for sound absorption. With the unique combination of the thermoelectric, sound absorption, and mechanical behavior, these nanocomposite foams would offer versatile solutions to address the next generation energy harvesting and acoustic absorption applications.

Triboelectric nanogenerator based on silane-coupled LTA/PDMS for physiological monitoring and biomechanical energy harvesting

Energy harvesting from ambient sources present in the environment is essential to replace traditional energy sources. These strategies can diversify the energy sources, reduce maintenance, lower costs, and provide near-perpetual operation of the devices. In this work, a triboelectric nanogenerator (TENG) based on silane-coupled Linde type A/polydimethylsiloxane (LTA/PDMS) is developed for harsh environmental conditions. The silane-coupled LTA/PDMS-based TENG can produce a high output power density of 42.6 µW/cm2 at a load resistance of 10 MΩ and operates at an open-circuit voltage of 120 V and a short-circuit current of 15 µA under a damping frequency of 14 Hz. Furthermore, the device shows ultra-robust and stable cyclic repeatability for more than 30 k cycles. The fabricated TENG is used for the physiological monitoring and charging of commercial capacitors to drive low-power electronic devices. Hence, these results suggest that the silane-coupled LTA/PDMS approach can be used to fabricate ultra-robust TENGs for harsh environmental conditions and also provides an effective path toward wearable self-powered microelectronic devices.

Paper‐Based Electronics: Toward Sustainable Electronics

AbstractThe emergence of paper‐based electronic devices marks a significant leap forward in the design of flexible, lightweight, and eco‐friendly electronics. Paper‐based electronic sensors represent a transformative approach to creating flexible, lightweight, and environmentally friendly electronics. This review will discuss recent applications of paper‐based electronics, mainly in exploring emergent technologies employed in developing innovative sensors for chemical analysis. Furthermore, the role of paper‐based electronics in electrochemical, and physical sensing, specifically addressing relative humidity, temperature, pressure, and strain sensors will be commented. In addition, the integration of paper electronics in energy harvesting and storage is discussed, covering solar cells, tribogenerators, antennas, and supercapacitors. These advancements underscore the versatility and potential of paper‐based electronics in diverse applications, from wearable health monitors to sustainable energy solutions, paving the way for the future of recyclable and biodegradable electronic devices.

An integrated and intelligent milling temperature sensing tool holder with electromagnetic energy harvesting system

An integrated and intelligent milling temperature sensing tool holder with electromagnetic energy harvesting system

Sustainable Solution Processing Toward High‐Efficiency Organic Solar Cells: A Comprehensive Review of Materials, Strategies, and Applications

AbstractOrganic solar cells (OSCs) have emerged as promising candidates for renewable energy harvesting due to their lightweight, flexible, and low‐cost fabrication potential. The efficiency of OSCs is largely determined by the choice of solvents, which significantly affect the film morphology of the active layers, the intermixed donor‐acceptor domains, and overall device performance. Beginning with an introduction to the importance of solvent selection, the screening and classification of solvents, emphasizing their characteristics and classification based on sustainability, solubility, and other additional considerations are explored. Various non‐halogenated solvents, highlighting commonly used aromatic solvents, biomass‐derived solvents, and water/alcohol‐based solvents are explored. The state‐of‐the‐art donor and acceptor materials, focusing on efficient donor materials such as PM6 and D18, and high‐performing Y‐series acceptors are also presented. Strategies for developing high‐performance OSCs processed using non‐halogenated solvents are examined, including solvent engineering with additive and additive‐free approaches, ternary strategies, and layer‐by‐layer techniques. The fabrication of large‐area devices using non‐halogenated solvents is addressed, focusing on blade‐coating, slot‐coating, and other processing techniques. Finally, this review outlines future research directions in the non‐halogenated solvent processing of OSCs, emphasizing the need for continuous innovation to overcome existing limitations and propel OSC technology toward commercial viability.