AbstractThe utilization of solar energy in heating, ventilation, and air conditioning (HVAC) systems has gained significant attention as a sustainable and environmentally friendly solution to meet the increasing energy demands. Therefore, this research work introduces a novel engineering study that explores solar‐HVAC systems. However, the study utilized hybrid nanofluids (HNFs) consisting of silicon dioxide and copper nanoparticles, with propylene glycol serving as the base fluid. Furthermore, this exploration features a magnetohydrodynamics (MHD) driven rotating flow with activation energy to enhance the heat transfer performance of solar‐HVAC systems. To increase the model novelty, 3D mathematical models were developed to characterize boundary conditions, which include the speed slippery and Smoluchowski temperature slippage. The partial differential equations in the model are transformed into ordinary differential equations (ODEs) through the use of similarity transformations. The Wavelets and Gegenbauer wavelets method in Mathematica was utilized to solve ODEs and investigate physical attributes such as plate friction, Nusselt number, Sherwood number, and mass flux. The findings show that the solar thermal radiation and magnetic field improve the thermal transfer efficiency of solar‐HVAC. Therefore, the findings of the research have practical applications in solar energy for HVAC systems and can contribute to technological improvements in the manufacturing industry.