Energy Conversion System Research Articles

A maximum power point tracking control strategy of tidal energy conversion system based on fixed-time observer technology

To achieve maximum tidal current energy capture in complex and harsh marine environments, this paper proposes a nonlinear control based on fixed-time observer (NCFTO) for tidal energy conversion system (TECS). The TECS operating in the ocean not only needs to face time-varying ocean current speed, but also needs to consider the adverse effects brought by parameter uncertainties and unknown disturbances in actual operation. Considering the high nonlinearity of TECS, conventional linear control systems may not necessarily provide satisfactory performance. Therefore, the NCFTO takes into account the TECS parameter uncertainties and unknown disturbances in its design. This mainly involves using a designed fixed-time observer to accurately estimate a concentrated disturbance term containing TECS nonlinearities, parameter uncertainties, disturbances in real time, and offsetting the adverse effects of actual disturbances on the control system. Meanwhile, a linear controller is designed based on the linearization of TECS to ensure satisfactory performance of NCFTO under time-varying ocean current speed, thus laying a solid foundation for achieving maximum tidal current energy capture. In addition, to verify the feasibility and effectiveness of NCFTO, three simulation testing scenarios have been set up, namely time-varying ocean current speed, rotor inertia uncertainty, and unknown disturbance torque.

Synergistic Innovations: Organometallic Frameworks on Graphene Oxide for Sustainable Eco-Energy Solutions

Combining organometallic frameworks with graphene oxide presents a fresh strategy to enhance the electrochemical capabilities of supercapacitors, contributing to the advancement of sustainable energy solutions. Continued refinement of materials and device design holds promise for broader applications across energy storage and conversion systems. This featured application underscores the inventive utilization of organometallic frameworks on graphene oxide, shedding light on the creation of superior energy storage devices for eco-friendly solutions. This review article delves into the synergistic advancements resulting from the fusion of organometallic frameworks with graphene oxide, offering a thorough exploration of their utility in sustainable eco-energy solutions. This review encompasses various facets, including synthesis methodologies, amplified catalytic performances, and structural elucidations. Through collaborative efforts, notable progressions in photocatalysis, photovoltaics, and energy storage are showcased, illustrating the transformative potential of these hybrids in reshaping solar energy conversion and storage technologies. Moreover, the environmentally conscious features of organometallic–graphene oxide hybrids are underscored through their contributions to environmental remediation, addressing challenges in pollutant elimination, water purification, and air quality enhancement. The intricate structural characteristics of these hybrids are expounded upon to highlight their role in tailoring material properties for specific eco-energy applications. Despite promising advancements, challenges such as scalability and stability are candidly addressed, offering a pragmatic view of the current research landscape. The manuscript concludes by providing insights into prospective research avenues, guiding the scientific community towards surmounting hurdles and fully leveraging the potential of organometallic–graphene oxide hybrids for a sustainable and energy-efficient future.

High-performance osmotic energy harvesting enabled by the synergism of space and surface charge in two-dimensional nanofluidic membranes

As promising prospects for renewable power harvesting, two-dimensional (2D) nanochannels for osmotic energy capture in a reverse electrodialysis arrangement have garnered significant attention. However, existing 2D nanochannel membranes have shown limited power generation capabilities due to challenges in balancing ion flux and selectivity. Here, we construct montmorillonite (MMT)/TEMPO-mediated oxidation cellulose nanofibers (TOCNFs) nanocomposite membranes for enhanced ion transmembrane transport. The intercalation of TOCNFs not only enlarges the interlayer distance, but also provides abundant space charge inside the nanochannels. Benefiting from the strong ion selectivity and high ion flux, the composite membrane achieves a remarkable power output of ∼16.57 W/m2 in the gradient of artificial seawater and river water, exceeding that of the state-of-the-art heterogeneous membrane-based osmotic energy conversion systems. Both experimental and theoretical findings confirm that the synergism of space and surface charge plays a crucial role in promoting osmotic energy conversion. This research contributes valuable insights into the optimization of 2D membranes for efficient clean energy harvesting purposes.

LDHs and their Derivatives for Electrochemical Energy Storage and Conversion Systems: Design, Insights and Applications

AbstractElectrochemical energy storage and conversion systems (EESCSs), including batteries, supercapacitors, fuel cells, and water electrolysis technologies, enabling the direct conversion between chemical and electrical energies. They are key to the flexible storage and utilization of renewable energy and play an important role in future energy technologies. The physical and chemical properties of electrode materials significantly influence the performance of EESCSs, necessitating the development of materials with both high cost‐effectiveness and superior electrochemical storage and catalytic capabilities. Layered double hydroxides (LDHs), due to their unique properties as high surface area, evenly distributed active sites, and tunable compositions, makes themselves and the derivatives have become focal points in the EESCSs. This review summarizes recent advances of LDH and their derivates for diverse EESCSs applications, aims to elucidate the modification strategies of LDH materials and provide valuable insights for exploring LDH‐derived materials in various electrochemical devices, offering interdisciplinary perspectives for the rational design of LDH‐based materials.

Non‐Ti (M2X and M3X2) MXenes for Energy Storage/Conversion

AbstractMXenes, with a particular emphasis on Ti3C2 (M3X2) have been extensively studied and established as the foundational material for 2D MXenes. However, the exploration of other transitional metals as 2D MXenes holds great promise, offering applications beyond the existing knowledge. Non‐Ti (M2X and M3X2) MXenes have garnered attention due to their distinctive properties. This review article focuses on explaining the potential and challenges of non‐Ti (M2X and M3X2) MXenes in energy storage and conversion systems, specifically in the domains of supercapacitors, batteries (Li‐ion and Li‐S), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and oxygen reduction reaction (ORR). By providing a comprehensive overview of the current progress and addressing the associated challenges, this review offers valuable insights into the future prospects of not only non‐Ti (M2X and M3X2) MXenes but also other MXenes for energy storage and conversion. The findings presented herein pave the way for further research and multifaceted applications of these MXenes across various fields.

Model-free control for variable-speed wind energy conversion systems based on power tracking

Model-free control for variable-speed wind energy conversion systems based on power tracking

Nano-etching of carbon nanofiber surface and subsequent Fe–N–C thin film coating for enhancement of oxygen evolution reaction

The oxygen evolution reaction (OER) is involved in many electrical–chemical energy conversion systems; however, the slow reaction rate of the OER leads to a high overpotential (η) and low energy efficiency. Recently, an extremely low-η OER phenomenon was observed at a carbonaceous Fe–N-doped thin film with enriched step edges on highly oriented pyrolytic graphite and the carbon fiber surface in an alkaline electrolyte, although the activity was limited. In this study, multi-walled carbon nanotubes (MWCNTs) were used as substrates to utilize their high specific surface areas to develop an active OER catalyst. Nanoscale etching of the MWCNT surface was performed by Fe3O4 nanoparticle loading and subsequent heat treatment in an inert atmosphere, followed by acid washing. Afterwards, a carbonaceous thin film containing Fe and N was coated on the surface via sublimation, deposition, and pyrolysis of Fe phthalocyanine (Pc). A roughened surface was observed for the FePc-derived thin film coated on the nano-etched MWCNT, in contrast to the smooth surface observed for the film coated on the MWCNT without nano-etching. The combination of the nano-etching and the thin-film coating enhanced the OER, which was analyzed by parallel Tafel processes.

Vibration Analysis of the Double Row Planetary Gear System for an Electromechanical Energy Conversion System

Electromechanical energy conversion systems (EECSs) are widely used in vehicles to combine the double-row planetary gear system (DRPGS) with high transmission efficiency and high-performance motors. The integrated structure of the ring gear and motor rotor have put forward higher demands for the vibration performance of the DRPGS. This paper establishes a multibody dynamic model of the DRPGS for an EECS. Based on the kinetic relationship between the gear pairs and bearing components, the dynamic equations of the DRPGS are derived. The DRPGS model is simulated under different operating conditions. The results are compared to reveal the relationships between the system vibration and the operating speed and load torque. The typical conditions are selected to study the effectiveness of the structural parameters in reducing the DRPGS vibrations. The structural parameters, including the bearing clearance, the ball numbers, the gear tooth modification amount, and length, are comprehensively discussed. Several suggestions for the low-vibration design of the DRPGS for the EECS are provided.

Evaluation of Different Methodologies for Wave Energy Conversion Systems Integration into the Power Grid Using Power Hardware-in-Loop Emulation

The ocean energy resources hold the promise of a sustainable solution within global efforts to diversify energy sources and mitigate climate change. Wave energy conversion (WEC) systems, as emerging technologies, offer adaptability and the potential to harness predictable wave energy. However, integration of WEC systems into a power grid brings challenges for system operators due to their nature of operation. Addressing these demands is a multilayered process that involves highly efficient power electronic devices, control systems, and efficient energy storage solutions. This paper specifically focuses on the methodologies of the grid integration of a specific wave energy conversion system—a point absorber developed by the company Sigma Energy. Proposed methodologies are experimentally tested using power hardware-in-loop (PHIL) emulation of a fully monitored and controlled small-scale microgrid equipped with a battery energy storage system (BESS), different emulators of loads, and distributed generators (DG).

Artificial Intelligence with Metaheuristic Algorithm Based Optimization for a Hybrid Energy Storage System

This paper presents an optimization framework for a hybrid energy storage system (HESS) integrating photovoltaic (PV) and wind energy conversion systems (WECS). The PV system voltage is stepped up using a Cuk converter, controlled by a Particle Swarm Optimization (PSO) tuned Artificial Neural Network (ANN) controller to enhance dynamic performance and ensure maximum power point tracking (MPPT). The Doubly Fed Induction Generator (DFIG) based WECS is interfaced through a Pulse Width Modulation (PWM) rectifier regulated by a Proportional Integral (PI) controller, maintaining stable and efficient power conversion. Both converter outputs converge at a common DC link, whose voltage is subsequently applied to a single phase Voltage Source Inverter (VSI). This VSI is connected to the grid through an LC filter, ensuring smooth power delivery with minimal harmonics. The proposed system combines AI and metaheuristic algorithms for optimized control, enhancing overall efficiency, reliability and stability of the renewable energy integration into the grid. Simulation results demonstrate the effectiveness of the PSO ANN and PI control strategies in managing the dynamic interactions and power quality of the hybrid system. The proposed hybrid controller shows 92.47% tracking efficiency and the proposed converter shows 89.6% efficiency.

Samarium-doped vanadium pentoxide nanorods anchored reduced graphene oxide nanocomposite as a bi-functional electrode material for supercapacitor and direct methanol oxidation fuel cell applications

In this work, we demonstrate a novel, facile synthesis of reduced graphene oxide nanosheets decorated samarium-doped vanadium pentoxide (RGO/Sm:V2O5) nanocomposite material and explore its application toward supercapacitor and direct methanol oxidation process. As-fabricated material and electrode were well-characterized to evaluate its surface morphology and functionalities. Results indicate a maximum capacitance value of 544 F/g for RGO/Sm:V2O5 modified electrode than the 2% Sm:V2O5 (346 F/g) and V2O5 (133 F/g) modified electrodes. In addition, an excellent Rct value (3.2 Ω) was achieved for the RGO-loaded Sm:V2O5 electrode than the 2% Sm:V2O5 electrode (4.7Ω). The RGO/Sm:V2O5 electrode also shows higher cyclic efficiency (98 %) at the 1000th cycle than the non-RGO loaded Sm:V2O5 electrodes. Furthermore, the fabricated electrodes were also examined for the direct methanol oxidation performances, and the results indicate a higher current density value of 181 mA/cm2 for RGO/Sm:V2O5 electrode than 2% Sm:V2O5 electrode (139 mA/cm2). The excellent electrochemical performance of the RGO/Sm: V2O5 electrode is mainly due to the presence of RGO nanosheet in the synthesized nanocomposite material. Therefore, as-prepared material can be applied as an excellent alternative electrode material for energy storage and conversion systems.

Overall Design of a Gradient‐Ordered Membrane Electrode Assembly for Direct Liquid Fuel Cells

AbstractThe direct liquid fuel cell (DLFC) constitutes a promising energy conversion system that directly conveys the chemical energy of liquid fuels into electrical energy. In certain DLFCs, gas is produced as a product of electrochemical reactions during operation. However, the accumulation of gas inside the porous electrode can significantly hinder the transport of reactants, leading to the failure of active sites and severe concentration loss. To address this issue, a gradient‐ordered membrane electrode assembly (MEA) is designed and fabricated, consisting of a dual‐gradient diffusion layer that comprises a pore‐size gradient and a wettability gradient as well as a catalyst layer constructed by nanoneedle catalyst. This MEA promptly removes the produced gas and delivers the fresh solution, thereby enhancing the cell power output and stability. The fuel cell with the gradient‐ordered MEA achieves a remarkable peak power density of 177 mW cm−2 and a discharging time of 19 h, which are more than four times and 30 times, respectively, higher than those of the conventional MEA.

Superior Performance of Hollow Plasmonic Cubic Structures for Solar Energy Harvesting, Conversion, and Storage Systems

Superior Performance of Hollow Plasmonic Cubic Structures for Solar Energy Harvesting, Conversion, and Storage Systems

An improved regression‐based perturb and observation global maximum power point tracker methods

AbstractSolar photovoltaic energy is a vital renewable resource because it is clean, endless, and pollution‐free. Due to the fast growth of the semiconductor and power electronics sectors, photovoltaic (PV) technologies are climbing significant attention in modern electrical power applications. Operating PV energy conversion systems at the maximum power point is essential for getting the maximum power output and raising efficiency. This paper proposes a regression‐based Perturb and Observe method to quickly find a global maximum power point, avoiding being stuck in local maxima, likewise analytical and metaheuristic methods. The improved control focuses on the narrowed search areas by linear and non‐linear regression analyses using the generated PV model on a flexible Python environment. Furthermore, the method's accuracy is validated in real time under variable temperatures, irradiations, and loads. This method was proven with a hardware implementation. The proposed method is more than 98% accurate and can withstand long‐term modelling. The suggested regression‐based perturbation and observation method provided a short learning time and easy implementation. Additionally, the dynamic recorded results can be visualized for researchers to utilize efficiently.

Recent progresses in transmission electron microscopy studies of two-dimensional ferroelectrics

The rich potential of two-dimensional materials endows them with superior properties suitable for a wide range of applications, thereby attracting substantial interest across various fields. The ongoing trend towards device miniaturization aligns with the development of materials at progressively smaller scales, aiming to achieve higher integration density in electronics. In the realm of nano-scaling ferroelectric phenomena, numerous new two-dimensional ferroelectric materials have been predicted theoretically and subsequently validated through experimental confirmation. However, the capabilities of conventional tools, such as electrical measurements, are limited in providing a comprehensive investigation into the intrinsic origins of ferroelectricity and its interactions with structural factors. These factors include stacking, doping, functionalization, and defects. Consequently, the progress of potential applications, such as high-density memory devices, energy conversion systems, sensing technologies, catalysis, and more, is impeded. In this paper, we present a review of recent research that employs advanced transmission electron microscopy (TEM) techniques for the direct visualization and analysis of ferroelectric domains, domain walls, and other crucial features at the atomic level within two-dimensional materials. We discuss the essential interplay between structural characteristics and ferroelectric properties on the nanoscale, which facilitates understanding of the complex relationships governing their behavior. By doing so, we aim to pave the way for future innovative applications in this field.

Development of stability charts for double salience reluctance machine modeled using hill’s equation

The paper presents a novel algorithm for the development of stability charts. The second-order differential homogeneous equation describing a double salient reluctance machine with a capacitance connected to its stator winding is transformed into hill’s equation. The circuit components are the stator coil time-varying inductance of a double salient reluctance machine, capacitance and resistance. All these are modeled by hill’s equation. The double salient reluctance machine acts as an energy conversion system. The maximum and minimum inductance of the energy conversion system is measured in laboratory by inductance, capacitance, and resistance (LCR) meter. These values help to determine the inductance modulation index. The inductance modulation indetx, the characteristic constant and the characteristic parameter obtained from modeling equations are used in the MATLAB/Simulink model. The MATLAB/Simulink simulations generate stable and unstable oscillations to form stability charts. The proposed stability charts are in good agreement with the Ince-Stritt stability chart, which is widely applied in physics, mechanics and in electrical engineering, especially where the state of stability of a system or an electric oscillatory circuit is to be determined.

Turbulent partially cracked ammonia/air premixed spherical flames

The combustion of ammonia requires, for most energy conversion systems, a combustion promoter such as hydrogen to guarantee the start-up, stability and combustion efficiency. Partially cracked ammonia (PCA) can provide sufficient hydrogen concentrations to enhance the burning velocity in comparison with pure ammonia. However, little work exists on the use of PCA blends operating under relevant turbulent conditions. To that end the outwardly propagating spherical flame configuration was employed to determine the laminar and turbulent flame propagation characteristics of PCA (NH3/(H2+N2)) and corresponding binary (NH3/H2) mixtures across various turbulent combustion regimes. First, PCA and ammonia-hydrogen blends exhibit similar flame propagation rates under various turbulent intensities, even for the laminar case. The highest turbulent burning velocity was observed at leanest conditions, as opposed to laminar flames which exhibited highest flame speed at conditions above stoichiometry. Under rich conditions, no substantial flame enhancement due to turbulence was measured irrespective of the hydrogen content. This lack of flame enhancement under turbulent conditions is attributed to the effect of preferential diffusion with good agreement observed with trends in measured Markstein numbers. The normalized turbulent flame speed is dominated by the enhanced molecular diffusivity afforded by the presence of hydrogen up to 15 % enrichment, prior to decreasing upon further hydrogen addition under lean and stoichiometric conditions. This ‘bending’ phenomenon may be the contribution of several factors including; the transitioning between combustion regimes associated with low Damköhler numbers (Da) and flame thickening; merging of flamelets due to the presence of ammonia enhancing wrinkling; and combined changes in laminar burning velocity and preferential diffusional behavior. Furthermore, good agreement for turbulent flame speed is observed with a correlation that includes the influence of turbulent stretch (Ka) and non-equidiffusion (Le), with the agreement reducing with decreasing chemical to turbulent time scale ratios (Da << 1).

Molecular Design of New High-Capacity Redox Active Organic Compounds for Energy Storage and Conversion Systems

Molecular Design of New High-Capacity Redox Active Organic Compounds for Energy Storage and Conversion Systems

Exploring electron transfer: Bioinspired, biomimetics, and bioelectrochemical systems for sustainable energy and Value-Added compound synthesis

Electron transfer (ET) is a fundamental process that underlies various phenomena in physics, chemistry, and biology. Understanding ET mechanisms is crucial for developing sustainable energy solutions and synthesizing value-added compounds efficiently. In this context, the present review provides the fundamental aspects of ET involving bioinspired, biomimetics, and biological entities and its significance for sustainable energy and green electrosynthesis fields. Among the theoretical and experimental cornerstones, Marcus Theory, electronic conductance, computational modeling, biomolecular thermodynamics, electrochemical and kinetic theories, protein film voltammetry, and the emergence of in situ and operando techniques are explored. Theoretical modeling is vital for understanding and predicting ET processes. Additionally, the significance of experimental techniques for investigating the ET process in biological entities and interfaces is discussed. Protein film voltammetry is a valuable and consolidated technique for studying ET processes at the protein-electrode interface, whereas in situ and operando techniques for interrogating ET processes in real time provide insights into the dynamics and mechanisms of ET. The concept of quantum conductance in biological structures is addressed, evidencing a trend and power of single-entity analysis. Aspects of extracellular and interfacial ET processes are presented and discussed in the electrochemical energy conversion systems. A deep understanding of these processes can improve the design of efficient bioinspired catalysts. Therefore, this multidisciplinary work aims to fill the gaps between different scientific fields related to ET involving bioentities to develop innovative energy and value-added compound synthesis solutions.

An innovative dry-lab test rig for mechanical-hydraulic power take-off of wave energy conversion system

A dry-lab test rig is a powerful means to reduce costs in the design process of a wave energy conversion system (WECs). A dry-lab test rig technique allows the use of real components inside a simulation of a mathematical model. This paper presents the development of an innovative dry-lab test rig for the mechanicalhydraulic power take-off (MHPTO) unit of WECs. The development of a drylab test rig of MHPTO involves several processes, such as three-dimension (3D) modelling, component purchasing, structure fabrication, component installation, and operational testing. The developed dry-lab test rig consists of two main parts, such as the simulated wave emulator plant and the real MHPTO unit plant. The simulated wave emulator plant was developed in this test rig to replicate the interaction motion between the ocean wave motion and the wave absorber device. The developed dry-lab test rig was tested using five different irregular wave input conditions to ensure it could perform under the five different wave input conditions. The overall results demonstrate that the developed dry-lab test rig was successfully performed in all sea states. From the results, the profile of electrical power produced by the real MHPTO unit can be clearly obtained in each sea state.