Abstract Nanofluidic energy absorption materials (NEAs) represent smart and efficient energy absorption composite materials in the ever-growing application of advanced protective structures. In this paper, an integrated experimental and molecular dynamics simulation study is conducted on the NEAs (ZSM-5/water) to investigate the tunable strategy of mechanical performance and energy absorption by considering the microstructural, mechanical, and thermal factors. The results demonstrate that the NEAs is an efficient and tunable liquid spring-like volume memory material. The typical NEAs show superior energy absorption capacity, achieving a specific energy absorption of 5.17 J/cm³ and an energy absorption ratio of 1.14 J/cm³ per cycle. Compared with insensitivity of the loading rate, the solid-fluid mass ratio is confirmed to significantly affect energy absorption performance, with an optimal ratio of approximate 1. Temperature is validated as an effective in-situ tunable parameter for NEAs in terms of both infiltration and energy absorption properties, with only slight effect on exfiltration. The critical infiltration pressure and specific energy absorption decrease by 23% and 40% as temperature increase from 25°C to 80°C. The gas-fluid interaction based energy absorption mechanism under high temperatures is proposed according to the comparison between experimental results and molecular dynamics simulations. The findings in this work will provide novel materials solutions for the intelligent energy absorption protective structures.
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