Energetic Perspective Research Articles

Scientific exploration and hypotheses concerning the meridian system in traditional Chinese medicine

The meridian theory is an important component of traditional Chinese medicine, playing a crucial role in disease diagnosis, treatment, and health preservation. Serving as the media for the effects of acupuncture, moxibustion, herbal medicine, and acupressure massage, meridians exert undeniable impact on the human body. However, the essence of meridians remains a topic of debate. Recent research has primarily focused on their anatomical structures, leading to numerous hypotheses. Simultaneously, other researchers have approached this subject from an energetic perspective, discovering information interactions within the meridian system. These findings suggest that meridians possess both physical and information dimensions, indicating that a singular approach to their study is insufficient. To bridge this gap, a shift from purely structural research toward an exploration of the information aspects of meridians is necessary. By integrating this information approach with traditional meridian theory, it may be possible to develop a new, modernized meridian theory that is aligned with contemporary concepts, making it more accessible and applicable in clinical settings.

Infection-nutrition feedbacks: fat supports pathogen clearance but pathogens reduce fat in a wild mammal.

Though far less obvious than direct effects (clinical disease or mortality), the indirect influences of pathogens are difficult to estimate but may hold fitness consequences. Here, we disentangle the directional relationships between infection and energetic reserves, evaluating the hypotheses that energetic reserves influence infection status of the host and that infection elicits costs to energetic reserves. Using repeated measures of fat reserves and infection status in individual bighorn sheep (Ovis canadensis) in the Greater Yellowstone Ecosystem, we documented that fat influenced ability to clear pathogens (Mycoplasma ovipneumoniae) and infection with respiratory pathogens was costly to fat reserves. Costs of infection approached, and in some instances exceeded, costs of rearing offspring to independence in terms of reductions to fat reserves. Fat influenced probability of clearing pathogens, pregnancy and over-winter survival; from an energetic perspective, an animal could survive for up to 23 days on the amount of fat that was lost to high levels of infection. Cost of pathogens may amplify trade-offs between reproduction and survival. In the absence of an active outbreak, the influence of resident pathogens often is overlooked. Nevertheless, the energetic burden of pathogens likely has consequences for fitness and population dynamics, especially when food resources are insufficient.

A numerical study on tensile strength of low-density Kagome networks made of brittle fibers

In this paper, we present a numerical study on the tensile strength of low-density Kagome networks made of brittle fibers. First, an elastic beam model is employed to analytically predict the effective elastic properties and tensile strength, as well as the critical condition for buckling of the fibers in Kagome networks. A series of finite element analyses are then conducted to simulate the elastic deformation and failure of Kagome networks under tension. The numerical results based on unit-cell models reveal four possible failure modes of the Kagome networks subject to uniaxial tension, summarized in a phase diagram in terms of the relative density and the fiber strength. The pre-buckling failure mode is restricted to cases with relatively high density and low fiber strength. A low-density Kagome network is likely to fail by one of the post-buckling modes, with an effective tensile strength much lower than the prediction by the elastic beam model. For Kagome networks consisting of a large number of unit cells, the effect of boundary conditions on the tensile strength is examined. Under periodic boundary conditions, the effective tensile strength is nearly identical to that predicted by the unit-cell model, independent of the model size. Under a roller boundary condition, with damage initiation near the free edges followed by a diffusive damage progression, the effective tensile strength is lower than that under periodic boundary conditions for the cases of relatively low fiber strengths. Under a clamped boundary condition, the effective tensile strength is higher than that under periodic boundary conditions for the cases of relatively high fiber strengths, where fiber buckling is largely suppressed by the clamped boundaries. Finally, the effect of a crack-like defect on the effective tensile strength is studied for Kagome networks under the clamped boundary condition. With a small defect, the effective strength is nearly independent of the defect size. In contrast, with a relatively long defect, the effective strength decreases almost linearly with the length of the crack-like defect. The effective toughness for damage initiation and steady-state damage progression in the Kagome networks is discussed from an energetic perspective.

Performance evaluation and economic analysis of integrated solid oxide electrolyzer cell and proton exchange membrane fuel cell for power generation

In order to generate clean electricity from thermal energy, a hybrid electrochemical system is conceptually developed by coupling the proton exchange membrane fuel cell (PEMFC) and solid oxide electrolyzer cell (SOEC). For evaluating the proposed hybrid system, firstly, the two subsystems are modeled numerically and then they are merged into an integrated SOEC-PEMFC system. Moreover, the SOEC-PEMFC is analytically modeled for further evaluation. The effects of important operational parameters are examined. The outcomes show that when the SOEC operating temperature increases from 823 to 1273 K, the efficiency increases from 18.7 % to 38 % and the net output power improves about 36 % while cost per unit of power of hybrid system decreases about 80 %. Furthermore, by increasing the PEMFC operating temperature from 323 to 348 K, the system net output power and efficiency increase about 16.7 % and 10 %, respectively, whilst the cost per unit of electricity decreases about 19 %. In addition by increasing operating pressure of system, the net output power and efficiency are also improved. The proposed system has maximum output power density of 3.9 kW.m−2 and maximum efficiency of 38 %. In addition, the SOEC-PEMFC system is compared with the previously studied proton exchange membrane electrolyzer cell-proton exchange membrane fuel cell (PEMEC-PEMFC) system. In comparison with the previous PEMEC-PEMFC system, the present system's cost per unit of power and efficiency are about 16 % and 17 % higher, respectively; while the output power density is about double that of the PEMEC-PEMFC system. Generally, because hydrogen-powered systems offer reliable operation from an economic and energetic perspective, the SOEC-PEMFC system represents a promising technological solution to the clean energy demands.

Comparison of Metabolic Power and Energy Cost of Submaximal and Sprint Running Efforts Using Different Methods in Elite Youth Soccer Players: A Novel Energetic Approach.

Sprinting is a decisive action in soccer that is considerably taxing from a neuromuscular and energetic perspective. This study compared different calculation methods for the metabolic power (MP) and energy cost (EC) of sprinting using global positioning system (GPS) metrics and electromyography (EMG), with the aim of identifying potential differences in performance markers. Sixteen elite U17 male soccer players (age: 16.4 ± 0.5 years; body mass: 64.6 ± 4.4 kg; and height: 177.4 ± 4.3 cm) participated in the study and completed four different submaximal constant running efforts followed by sprinting actions while using portable GPS-IMU units and surface EMG. GPS-derived MP was determined based on GPS velocity, and the EMG-MP and EC were calculated based on individual profiles plotting the MP of the GPS and all EMG signals acquired. The goodness of fit of the linear regressions was assessed by the coefficient of determination (R2), and a repeated measures ANOVA was used to detect changes. A linear trend was found in EMG activity during submaximal speed runs (R2 = 1), but when the sprint effort was considered, the trend became exponential (R2 = 0.89). The EMG/force ratio displayed two different trends: linear up to a 30 m sprint (R2 = 0.99) and polynomial up to a 50 m sprint (R2 = 0.96). Statistically significant differences between the GPS and EMG were observed for MP splits at 0-5 m, 5-10 m, 25-30 m, 30-35 m, and 35-40 m and for EC splits at 5-10 m, 25-30 m, 30-35 m, and 35-40 m (p ≤ 0.05). Therefore, the determination of the MP and EC based on GPS technology underestimated the neuromuscular and metabolic engagement during the sprinting efforts. Thus, the EMG-derived method seems to be more accurate for calculating the MP and EC in this type of action.

Searching for the Achilles' Heel of Urethane Linkage-An Energetic Perspective.

A sudden increase in polyurethane (PU) production necessitates viable recycling methods for the waste generated. PU is one of the most important plastic materials with a wide range of applications; however, the stability of the urethane linkage is a major issue in chemical recycling. In this work, termination reactions of a model urethane molecule, namely methyl N-phenyl carbamate (MPCate), are investigated using G3MP2B3 composite quantum chemical method. Our main goal was to gain insights into the energetic profile of urethane bond termination and find an applicable chemical recycling method. Hydrogenation, hydrolysis, methanolysis, peroxidation, glycolysis, ammonolysis, reduction with methylamine and termination by dimethyl phosphite were explored in both gas and condensed phases. Out of these chemicals, degradation by H2, H2O2 and CH3NH2 revealed promising results with lower activation barriers and exergonic pathways, especially in water solvation. Implementing these effective PU recycling methods can also have significant economic benefits since the obtained products from the reactions are industrially relevant substances. For example, aniline and dimethyl carbonate could be reusable in polymer technologies serving as potential methods for circular economy. As further potential transformations, several ionizations of MPCate were also examined including electron capture and detachment, protonation/deprotonation and reaction with OH-. Alkaline digestion against the model urethane MPCate was found to be promising due to the relatively low activation energy. In an ideal case, the transformation of the urethane bond could be an enzymatic process; therefore, potential enzymes, such as lipoxygenase, were also considered for the catalysis of peroxidation, and lipases for methanolysis.

What Metals Should Be Used to Mediate Electrosynthesis of Ammonia from Nitrogen and Hydrogen from a Thermodynamic Standpoint?

Recently, metal-mediated electrochemical conversion of nitrogen and hydrogen to ammonia (M-eNRRs) has been attracting intense research attention as a potential route for ammonia synthesis under ambient conditions. However, which metals should be used to mediate M-eNRRs remains unanswered. This work provides an extensive comparison of the energy consumption in the classical Haber Bosch (H-B) process and the M-eNRRs. The results indicate that when employing lithium and calcium, metals popularly used to mediate the M-eNRRs, the energy consumption is more than 10 times greater than that of the H-B process even assuming a 100% Faradaic efficiency and zero overpotentials. Only electrosynthesis with a cell voltage not exceeding 0.38 V might have the potential to rival the H-B process from an energetic perspective. A further analysis of other metals in the periodic table reveals that only some heavy metals, including In, Tl, Co, Ni, Ga, Mo, Sn, Pb, Fe, W, Ge, Re, Bi, Cu, Po, Tc, Ru, Rh, Ag, Hg, Pd, Ir, Pt, and Au, can potentially consume less energy than that of the H-B process purely from a thermodynamic standpoint, but whether they can activate N2 under ambient conditions is yet to be explored. This work shows the importance of performing thermodynamic analysis for the development of an innovative strategy to synthesize ammonia with the ultimate goal of replacing the H-B process on a large scale.

Factors Contributing to Historical and Future Trends in Arctic Precipitation

AbstractThe Arctic is notable as a region where the greatest rate of increase in precipitation associated with global warming is anticipated. The Arctic precipitation simulated by the Coupled Model Intercomparison Project Phase 6 models showed a strong increasing trend since the 1980s. We found that the forcing factor of the trend is a combination of the continued strengthening of greenhouse gas forcing and the leveling off of aerosol forcing dominated in earlier periods. From an energetic perspective, we found that the increased atmospheric radiative cooling and reduced sensible heat transport from lower latitudes contributed equally to the recent increase in Arctic precipitation. The combination of these two energetic factors suggests a doubling of the Arctic amplification factor for precipitation relative to that for temperature. Future Arctic precipitation will change in proportion to the temperature change, and the fractional contributions of the energetic factors will remain stable across various scenarios.

Effect of microwave pretreatment on truffle solar drying from an energetic perspective

AbstractDrying, an age‐old method of food preservation, involves the concurrent exchange of heat and mass, resulting in reduced moisture content. The current study is based on experimental approach to evaluate the impact of combined microwave and solar drying on the drying kinetics and the energy efficiency of truffle drying. This study explores the impact of a 4‐min microwave pretreatment on the solar drying of truffle slices. The findings demonstrate that microwave treatment significantly reduces the time required for solar drying. When compared to solar drying without pretreatment, microwave treatment leads to a reduction in drying time ranging from 23.07% to 70.37% at temperatures between 50 and 80°C. The Midilli–Kucuk model is employed to elucidate the experimental results, revealing strong fits with high correlation coefficients and low standard error values. Microwave pretreatment enhances the drying rate of truffle slices, resulting in a higher effective moisture diffusivity compared to untreated slices. The activation energy for drying also decreases from 76.37 to 25.25 kJ/mol after microwave pretreatment. An energy analysis of the drying process underscores that elevating the drying air temperature reduces energy consumption. Furthermore, the proposed microwave pretreatment influences the energy efficiency of the drying process.

How nuclear receptors transition between active and inactive forms: An energetic perspective.

Nuclear receptors regulate transcriptional programs in response to the binding of natural and synthetic ligands. These ligands modulate the receptor by inducing dynamic changes in the ligand binding domain that shift the C-terminal helix (H12) between active and inactive conformations. Despite decades of study, many questions persist regarding the nature of the inactive state and how ligands shift receptors between different states. Here, we use molecular dynamics (MD) simulations to investigate the timescale and energetic landscape of the conformational transition between inactive and active forms of progesterone receptor (PR) bound to a partial agonist. We observe that the microsecond timescale is insufficient to observe any transitions; only at millisecond timescales achieved via accelerated MD simulations do we find the inactive PR switches to the active state. Energetic analysis reveals that both active and inactive PR states represent energy minima separated by a barrier that can be traversed. In contrast, little or no transition is observed between active and inactive states when an agonist or antagonist is bound, confirming that ligand identity plays a key role in defining the energy landscape of nuclear receptor conformations.

Simulation methodology and numerical comparison of boxer and opposed free piston linear generator configuration in 0D/1D environment

Free Piston Linear Generators (FPLGs) are thermal machines suitable for both stationary power generation unit (PU) and vehicle propulsion. They convert chemical energy from the fuel into electric energy to charge a battery using a linear electric generator. Due to the reduction of friction losses and the ability to work with different compression ratios, FPLGs are potentially characterized by high overall global efficiency with respect to a conventional alternative internal combustion engine. Like conventional internal combustion engines, FPLGs have several configurations: single piston, dual piston, opposed piston and boxer are the configurations considered in this work. Two configurations are compared in this paper from a functional and energetic perspective: opposed piston (Opposed) and Boxer. This is done with the aim to highlights pro and cons of these configurations. They are modelled using the 0D/1D modelling coupling GT-Power® and Simulink®. The comparison between the two configurations was done modelling the architecture with the same size and in two-strokes operating mode. The comparison of the two configurations highlights differences between them in terms of scavenging process, thermodynamic efficiency and global energy efficiency, putting in evidence what aspects need to be improved for each configuration and what are their advantageous features. Boxer configuration can provide less power due to lower volumetric efficiency compared to the Opposed configuration. Boxer configuration can provide 102.2 kW while Opposed can provide 110.0 kW at full load with a frequency of 20 Hz (equivalent to 1200 rpm). The Opposed configuration results in lower heat loss but higher energy lost at the exhaust. The final balance shows that Boxer configuration has a slightly higher brake efficiency (equal to 28.9 %) compared to the value found for Opposed (27.6 %).

Energy analysis and environmental impact assessment for self-sufficient non-interconnected islands: The case of Nisyros island

The European continent is surrounded by islands, which even though geographically and socially diverse, share common energy burdens regarding heavy fossil fuels reliance. More specifically, the non-interconnected islands (NII) encounter unique challenges in the decarbonization processes, rendering them particularly vulnerable to the impacts of such transitions. Numerous studies have been conducted to address such emerging issues. However, a research gap exists, as most of the proposed RES-related grid interventions neglect actual historical data in favor of a more theoretical, but possibly misleading, approach. In addition, potential grid stability concerns arising from high levels of RES penetration remain unaddressed. To this end, the objective of the present study focuses on addressing mainly electrical grid stability and resiliency considerations (e.g. imbalances, frequency fluctuations, voltage unbalance rate, for the case of energy islands, as in the case of the NII Greek island of Nisyros). Two sustainable scenarios including novel technologies (e.g. flywheel instead of conventional BESS, a hybrid transformer, vehicle-to-grid chargers) are examined from an energetic and environmental perspective, for short- (2030) and mid-term (2050) implementation horizons, reaching electrical and energy self-sufficiency targets up to 50% and 95%, respectively. For the energy analysis, capacity-investment optimization problems, power flow simulations and specialized transient simulations were conducted, while for the environmental impact assessment a novel in-house developed tool was utilized. As a result, the proposed interventions can result in significant fossil fuel cost savings of about 88%, reduced CO2 emissions up to 38% and overall remarkable financial and environmental benefits. In conclusion, this study demonstrates that a NII can realistically abolish thermal energy to a bare minimum and enhance its self-sufficiency by harnessing local renewable energy potential, while at the same time ensuring grid stability.

Atomic-scale characterization of V-shaped interface structure of η1 precipitates in Al–Zn–Mg alloy

Al–Zn–Mg alloys have attracted significant interest in the automotive industry owing to their high strength and light weight. Precipitation hardening is the primary mechanism by which these alloys are strengthened, meaning the analysis of the shape, size, and fraction of the precipitates is crucial. In this study, the interfacial structure of precipitates, which influences the mechanical properties of alloys, was investigated. Aberration-corrected scanning transmission electron microscopy studies revealed the atomic structure of the unique V-shaped interface structure of the η1 precipitates, which are the most prevalent among the η precipitates produced in this alloy. The structure was investigated from an energetic perspective using first-principles calculations, which revealed that the formation of the V-shaped interface structure increased the stability through strain relaxation in both the aluminum matrix and η1. The results provide valuable insights into the formation and growth mechanisms of precipitates, paving the way for further advancements in this field.

Systems theory, thermodynamics and life: Integrated thinking across ecology, organization and biological evolution.

In this paper we explore the relevance and integration of system theory and thermodynamics in terms of the Earth system. It is proposed that together, these fields explain the evolution, organization, functionality and directionality of life on Earth. We begin by summarizing historical and current thinking on the definition of life itself. We then investigate the evidence for a single unit of life. Given that any definition of life and its levels of organization are intertwined, we explore how the Earth system is structured and functions from an energetic perspective, by outlining relevant thermodynamic theory relating to molecular, metabolic, cellular, individual, population, species, ecosystem and biome organization. We next investigate the fundamental relationships between systems theory and thermodynamics in terms of the Earth system, examining the key characteristics of self-assembly, self-organization (including autonomy), emergence, non-linearity, feedback and sub-optimality. Finally, we examine the relevance of systems theory and thermodynamics with reference to two specific aspects: the tempo and directionality of evolution and the directional and predictable process of ecological succession. We discuss the importance of the entropic drive in understanding altruism, multicellularity, mutualistic and antagonistic relationships and how maximum entropy production theory may explain patterns thought to evidence the intermediate disturbance hypothesis.

Energetic perspective on emergent inductance exhibited by magnetic textures in the pinned regime

Spatially varying magnetic textures can exhibit electric-current-induced dynamics as a result of the spin-transfer torque effect. When such a magnetic system is electrically driven, an electric field is generated, which is called the emergent electric field. In particular, when magnetic-texture dynamics are induced under the application of an AC electric current, the emergent electric field also appears in an AC manner, notably, with an out-of-phase time profile, thus exhibiting inductor behavior, often called an emergent inductor. Here we show that the emergent inductance exhibited by magnetic textures in the pinned regime can be explained in terms of the current-induced energy stored in the magnetic system. We numerically find that the inductance values defined from the emergent electric field and the current-induced magnetization-distortion energy, respectively, are in quantitative agreement in the so-called adiabatic limit. Our findings indicate that emergent inductors retain the basic concept of conventional inductors; that is, the energy is stored under the application of electric current.

Interactive roles of temperature and food availability in predicting habitat suitability for marine invertebrates

Natural variability in habitat characteristics, including their interactions, can affect marine invertebrate development. Controlled laboratory experiments seek to assess responses to such variability. For marine invertebrates, responses to temperature are typically assessed but a continuous gradient of all temperatures that a species may encounter is not frequently used. For planktonic larvae of marine invertebrates, biotic factors such as food availability receive less attention due to difficulty in simulating planktonic biotic interactions in a controlled laboratory setting. Here, a laboratory experiment was used to quantify larval development (growth, pelagic larval duration and survival) of the Atlantic surfclam, Spisula solidissima, in response to a continuous range of temperatures and food (phytoplankton) concentrations, allowing quantification of thermal and food availability niches. A second experiment was conducted to quantify the thermal and food availability niches for recruit (post-settlement) surfclams. These experiments were uniquely designed to inform future climate change-based forecasting and habitat suitability modeling. Larval growth and survival increased with increased food availability, while pelagic larval duration decreased with increased food availability. Larval survival decreased with increased temperature, growth peaked near 22 °C and pelagic larval duration was lowest near 22 °C. For recruits, survival and growth increased with both temperature and food availability, but growth decreased at temperatures >22 °C. Broadly, results suggest potential food limitation for continental shelf bivalve larvae and demonstrate that natural variation in food availability may affect thermal tolerances. Results also suggest that throughout the range of the surfclam, high food and moderate temperature areas such as New York Bight and Georges Bank are ideal for larvae and early recruits, whereas low food and high temperature areas, including continental shelf waters in the southern Middle Atlantic Bight, are suboptimal for early life stages of surfclams. This framework may be used for habitat suitability modeling, from an energetic perspective, for other marine invertebrate taxa.

The effects of structural variations in neutral phosphorus extractants on UO22+ extraction behavior and radiation stability: Experimental and theoretical insights

In the present work, the effects of four neutral phosphorus extractants (TBP, TAP, THP, TEHP) with different molecular structures on the extraction behaviors towards U(Ⅵ) and radiation stability were systematically studied. The results of the batch extraction and the γ-radiolysis experiments manifested that the extraction performance and radiation stability of the four extractants followed the order of TEHP > THP > TAP > TBP. Moreover, DFT calculations and Multiwfn software were utilized to analyze the properties of the extractants. The electrostatic potentials (ESP) and frontier molecular orbital of extractants indicated that the nucleophilic ability was ranked as TEHP > THP > TAP > TBP. The analyses of quantum theory of atoms in molecules (QTAIM) and Wiberg indices (WBIs) revealed that the UO22+ ions exhibited stronger complexation ability with O atoms in TEHP compared to the other three extractants. The bonds between UO22+ ions and extractants were primarily ionic in nature. From the energetic perspective, the thermodynamic energy demonstrated that the Gibbs free energy of TEHP in aqueous solution was the most negative, implying that it should be easier to combine with UO22+. This work elucidates that the increase of alkyl chain length and the presence of branched chains can enhance the extraction performance and radiation stability of neutral phosphorus extractants. It not only lays the theoretical foundation for designing novel organic phosphorous extractants with superior extraction performance and high radiation stability, but also provides scientific basis for the extraction process of uranium in spent nuclear fuel reprocessing.

Mechanical and metabolic power in accelerated running-Part II: team sports.

This manuscript is devoted to discuss the interplay between velocity and acceleration in setting metabolic and mechanical power in team sports. To this aim, an essential step is to assess the individual Acceleration-Speed Profile (ASP) by appropriately analysing training sessions or matches. This allows one to estimate maximal mechanical and metabolic power, including that for running at constant speed, and hence to determine individual thresholds thereof. Several approaches are described and the results, as obtained from 38 official matches of one team (Italian Serie B, season 2020-2021), are reported and discussed. The number of events in which the external mechanical power exceeded 80% of that estimated from the subject's ASP ([Formula: see text]) was 1.61 times larger than the number of accelerations above 2.5 ms-2 ([Formula: see text]). The difference was largest for midfielders and smallest for attackers (2.30 and 1.36 times, respectively) due to (i) a higher starting velocity for midfielders and (ii) a higher external peak power for attackers in performing [Formula: see text]. From the energetic perspective, the duration and the corresponding metabolic power of high-demanding phases ([Formula: see text]) were essentially constant (6 s and 22 W kg-1, respectively) from the beginning to the end of the match, even if their number decreased from 28 in the first to 21 in the last 15-min period, as a consequence of the increased recovery time between [Formula: see text] from 26 s in the first to 37 s in the last 15-min period. These data underline the flaws of acceleration counting above fixed thresholds.

Development of the virtual battery concept in the paper industry: Applying a dynamic life cycle assessment approach

Energy-intensive industries face the challenge of reducing carbon emissions while remaining competitive. Key measures include fossil fuel substitution, energy efficiency, and integration of renewable energy sources, but their fluctuating production profile makes them difficult to integrate and require industries to adapt their current consumption and production patterns to become more flexible.In this study, the virtual battery concept (VBC), exemplarily demonstrated for a specific site in the paper industry, is introduced and evaluated from an environmental, energetic, and techno-economic perspective. A mathematical optimization model of the class mixed integer linear programming (MILP) was applied to express the industrial site as VBC and derive the operational data basis for the subsequent life cycle assessment (LCA). A dynamic LCA approach is presented to allow the consideration and assessment of the temporal behavior of energy load profiles and their associated environmental implications.The results showed that compared to a static LCA, the dynamic approach leads up to 42 % lower greenhouse gas (GHG) emissions for 1 MJ of public electricity. The global warming potential (GWP) of the total energy supply chain was reduced by 40 % for electricity and 8 % for heat, respectively. By means of a scenario analysis, the GWP to produce one ton of paper was reduced up to 33 % compared to the business-as-usual (BAU) case to 672 kgCO2eq.r in the best case. However, the total primary energy demand (PED) increased by 34 %, but the fossil PED was reduced by 32 % and the renewable PED increased by 157 %. The renewable PED share covered up to 67 % of the total PED. The techno-economic analysis revealed total annual cost savings of up to 44 % to 64.6 € per ton of paper. Environmental costs were estimated to range from 79.6 to 88.9 € per ton of paper.The VBC is considered a promising approach to utilize regional renewable excess electricity effectively, reduce fossil-based energy generation, increase grid stability, and to avoid costly grid infrastructure investments in future. In principle, the VBC is site-independent and replicable to other industries but needs to be evaluated site specifically according to certain process characteristics and requirements.

Exploring pressure-dependent inelastic deformation and failure in bonded granular composites: An energetic materials perspective

In polymer-filled granular composites, damage may develop in mechanical loading prior to material failure. Damage mechanisms such as microcracking or plastic deformation in the binder phase can substantially alter the material’s mesostructure. For energetic materials, such as solid propellants and plastic bonded explosives, these mesostructural changes can have far reaching effects including degraded mechanical properties, potentially increased sensitivity to further insults, and changes in expected performance. Unfortunately, predicting damage is nontrivial due to the complex nature of these composites and the entangled interactions between inelastic mechanisms. In this work, we assess the current literature of experimental knowledge, focusing on the pressure-dependent shear response, and propose a simple simulation framework of bonded particles to study four limiting-case material formulations at both meso- and macro-scales. To construct the four cases, we systematically vary the relative interfacial strength between the polymer binder and granular filler phase and also vary the polymer’s glass transition temperature relative to operating temperature which determines how much the binder can plastically deform. These simulations identify key trends in global mechanical response, such as the emergence of strain hardening or softening regimes with increasing pressure which qualitatively resemble experimental results. By quantifying the activation of different inelastic mechanisms, such as bonds breaking and plastically straining, we identify when each mechanism becomes relevant and provide insight into potential origins for changes in mechanical responses. The locations of broken bonds are also used to define larger, mesoscopic cracks to test various metrics of damage. We primarily focus on triaxial compression, but also test the opposite case of triaxial extension to highlight the impact of Lode angle on mechanical behavior.