Neodymium is a technologically important metal in green energy due to its properties which are critical in wind turbines as permanent magnets and in rechargeable batteries for electric vehicles. However, its production and supply are concentrated in China and this, together with its high demand, has led to categorise it as a critical metal. Therefore, instead of relying exclusively on mining, neodymium recovery from end of life products is one of the most interesting ways to tackle the availability.Our research has been focused on electrolyte synthesis to attain Nd in the metallic and more expensive form via electrodeposition as an environmentally friendly approach.Electrochemical deposition of neodymium has also been attempted in several ionic liquids, but only been partially successful in phosphonium -based ILs, therefore that family of ionic liquids have been at the core of our research. The long alkyl chain trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)imide, [P66614][TFSI], have been selected due to its hydrophobic properties and electrochemical stability. The effect of concentration and water has been explored in our research concluding that, in fact, water promoted the Nd electrodeposition. A three-fold increase in current densities was observed in comparison with the analogous mixture with less water, which leads to more abundant deposits.[1] , [2] An in-depth study of the Nd3+ solvation in the bulk electrolyte indicated the presence of both bis(trifluoromethylsulfonyl)imide (TFSI) and water in the solvation sphere, as well as insight into the different mode of coordination of TFSI with Nd3+ (i.e. cis/ trans and mono/bidentate).More recently, we have reported a cleaner approach to recover Nd using a pyrrolidinium non-fluorinated ionic liquid (IL) (N-butyl-N-methylpyrrolidinium dicyanamide ([C4mpyr][DCA])) in the presence of neodymium nitrate. The main advantages of these electrolyte mixtures, is the elimination of higher risk of persistence, ecotoxicity when fluorine is decomposed. Additionally, relatively low manufacturing cost as opposed to fluorinated systems as contain only carbon and nitrogen. Our results presented eight times higher current density (-38 mA cm-2) at a lower temperature (halved to 50 °C) and less controlled environment (0.15 – 4.6 wt% H2O) compared to the literature.[3] This is translated into a more cost-effective recovery process. [1] Laura Sánchez-Cupido, Jennifer M. Pringle, Amal L. Siriwardana, Ainhoa Unzurrunzaga, Matthias Hilder, Maria Forsyth, Cristina Pozo-Gonzalo, “Water Facilitated Electrodeposition of Neodymium in a Phosphonium-based Ionic Liquid”, The Journal of Physical Chemistry Letters, 2019, 10, 2, 289-294 [2] Laura Sanchez Cupido, Jennifer M. Pringle, Amal Siriwardana, Matthias Hilder, Maria Forsyth, Cristina Pozo-Gonzalo,” Correlating electrochemical behaviour and speciation in neodymium ionic liquid electrolyte mixtures in the presence of water”, ACS Sustainable Chemistry & Engineering, 2020, 8, 14047-14057 [3] Kalani Periyapperuma, Jennifer M. Pringle, Laura Sanchez-Cupido, Maria Forsyth, and Cristina Pozo-Gonzalo,“Fluorine-Free Ionic Liquid Electrolytes for Sustainable Neodymium Recovery Using an Electrochemical Approach, Green chemistry”, 2021, DOI: 10.1039/D1GC00361E
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