The understanding of empathy is complex. Research suggests that there is a tripartite classification of empathy, which comprises cognitive empathy, emotional (or affective) empathy, and compassionate empathy (or empathic concern). This paper will delve into the concepts, explain the brain functions for empathy, and present emotion contagion, simulation theories and mirror neurons as central to the neuro-analysis of empathy. Notably, there has been a stark increase in studies that focus on the link between empathy and other emotional competences, like emotional literacy and holistic and academic achievement. The paper will present this collection of studies and will discuss the concept of positive schooling, positive classroom setting and positive pedagogy, where students experience empathy and emotional health, and where they can flourish more in life and at their school. Finally, it will present possibilities for practice where empathy can be enhanced in the classroom setting.