Objectives This study classified potential profiles according to the level of achievement goal orientation targeting Korean learners in their teens and 20s, and investigated explicit and implicit should-thought, gender, subject, fear of failure, academic difficulty (comprehension and amount), and positive and negative emotional reaction to to study, explicit and implicit emotional exhaustion about schoolwork, and academic procrastination to predict potential group classification. Methods The study participants were 629 teenagers and 864 students in their 20s who participated online. Latent profile analysis was conducted through the results of the achievement goal orientation scale, and multinomial logistic regression analysis was performed to confirm the influence of predictor variables on the latent profile. Results As a result, teen learners were divided into 3 potential groups and learners in their 20s into 5 potential groups, and the three groups of High All Goals, High-intermediate All Goals, and Average All Goals were identified in both age groups. Low All Goals and Mastery Goals were identified in 20s only. It was confirmed that fear of failure, academic efficacy, and should-thinking, and positive emotions to studying were related to High All Goals, and academic efficacy, should-thought, and positive emotions to studying were found to be related to High-intermediate All Goals. In addition, factors that act differentially according to the age of the potential group were also found. Conclusions These results suggest the need to consider the learner's developmental level in understanding the latent group profile and predictive factors, and help the learner's academic adjustment by exploring the relevance of the profile by dealing with relevant variables that affect academic adjustment. It is meaningful in that it provided implications for the intervention necessary for this purpose.