VOC Emissions Research Articles

Residential combustion of coal: Effect of the fuel and combustion stage on emissions

Worldwide coal is still used for household heating purposes not only because it is available and cheap but also due to behavioural issues. Regional variability in fuels and combustion appliances make accurate emission estimates from this source hard to achieve. In the present study, gaseous (CO, VOCs, SO2 and NOX) and particulate matter (TSP) emission factors (EFs) were determined for Spanish household coal combustion covering three commercial coals and distinct combustion stages and mimicking usage patterns in real households. TSP samples were analysed to determine water-soluble inorganic ions, metal(loid)s, and organic and elemental carbon (OC and EC). Additionally, the morphology of the emitted particles was also characterised.CO (3.43–169 g kg−1), NOX (1.29–6.00 g kg−1) and SO2 (8.96–22.3 g kg−1) EFs showed no trend regarding the combustion stage or coal type tested. On the other hand, VOC, TSP and EC EFs were higher for the ignition/devolatilisation combustion stage, regardless of the fuel tested. TSP EFs (0.085–1.08 g kg−1) increased with increasing coal volatile matter while the opposite trend was recorded for VOC emissions (0.045–3.39 gC kg−1).TSP carbonaceous matter was dominated by EC while OC represented a small fraction of the particulate mass emitted (less than 8 %wt.). Inorganic compounds composed an important fraction of the TSP samples. Sulphate particulate mass fractions (8.66–22.9 %wt.) appeared to increase with coal S-content. Coal combustion released particles with diverse morphologies, including silicate-rich particles, ferro- and glassy-spheres. This study provides novel emission factors to update emission inventories of residential coal combustion. Additionally, detailed chemical profiles were obtained for source apportionment.

An integrated monitoring system (IMS) for air quality: Observations of a unique ozone-exceedance event in Maryland

Ozone (O3) exceedance events in the mid-Atlantic states of the U.S. are typically observed during the summer months. They frequently result from local diurnal emissions of NO2 and VOCs where photochemical production of O3 is most prevalent. Occasionally, summertime O3-exceedances in the region are driven by long-range transport of pollutants or regional nocturnal dynamics. Discussed herein is the use of multiple observation platforms as an integrated monitoring system (IMS) to characterize the spatiotemporal confluence of long-range transport and nocturnal low-level jet induced O3-exceedances impacting air quality in the mid-Atlantic region. The IMS discussed is comprised of enhanced monitoring of vertically resolved observations of O3, atmospheric backscatter, winds, and state variables (e.g., temperature and relative humidity). This is in combination with surface-O3 observations, satellite-retrieved aerosol optical depth (by the moderate resolution imaging spectroradiometer (MODIS)), and simulations of air mass transport by NOAA's hybrid single-particle Lagrangian trajectory (HYSPLIT) model. Here we discuss an exceedance event that impacted the Mid-Atlantic region on May 20, 2021, where seven air monitoring sites in Maryland were driven by the combination of nocturnal low-level jet downmixing of pollutants and long-range transport of biomass-burning pollutants/O3-precursors. The most notable features of this case are this event's deviation from decadal O3-exceedance seasonality trends, the large spatial context of high surface-O3 impacting traditionally non-exceedance sites (sites that have not exceeded in years), the arrival of a well-mixed polluted air mass into the region, and nocturnal increases in surface-O3 induced by NLLJ.

Photochemistry in the urban agglomeration along the coastline of southeastern China: Pollution mechanism and control implication

The concentrations of ground-level ozone (O3) in China have undergone a rapid increase in recent years, resulting in adverse impacts on the air quality and climate change. However, limited research has been conducted on the coastal urban agglomerations with increasingly serious O3 pollution. Therefore, in order to better understand in situ photochemistry, comprehensive field observations of O3 and its precursors, coupled with the model simulation, were conducted in autumn of 2019 at six sites in an urban agglomeration along the coastline of southeastern China. Results indicated that O3 pollution in the southern part of the urban agglomeration was more severe than that in the northern part, due to higher levels of O3 precursors and stronger atmospheric oxidation capacity (AOC) in the southern regions. Oxygenated volatile organic compounds (OVOCs), NO2, and CO dominated the total OH reactivity, and the site-average daytime Ox (O3 + NO2) increments correlated well (R2 = 0.94) with the total OH reactivity of CO and VOCs at these sites except for Quanzhou, where industrial emissions (35.1 %) and solvent usages (33.7 %) dominated the VOC sources. However, vehicle exhausts (31.1 %) were the most predominant contributors to the VOC sources at other sites. The results of model simulations showed that net O3 formation rates were larger at the southern sites. Furthermore, O3 production was mainly controlled by VOCs at most sites, but co-limited by VOCs and NOx at Quanzhou. The most significant VOC groups contributing to O3 formation were aromatics and alkenes, with m/p-xylene, toluene, propene, and ethene being the main contributors at these sites. This study offers a more comprehensive understanding of the characteristics and formation of photochemical pollutions on the scale of the urban areas, indicating the critical need to reduce VOC emissions as a means of mitigating their photochemical effects.

Modeling of secondary organic aerosols (SOA) based on two commonly used air quality models in China: Consistent S/IVOCs contribution but large differences in SOA aging

Secondary organic aerosol (SOA) is an important component of atmospheric fine particulate matter (PM2.5), with contributions from anthropogenic and biogenic volatile organic compounds (AVOC and BVOC) and semi- (SVOC) and intermediate volatility organic compounds (IVOC). Policymakers need to know which SOA precursors are important but accurate simulation of SOA magnitude and contributions remain uncertain. Findings from existing SOA modeling studies have many inconsistencies due to differing emission inventory methodologies/assumptions, air quality model (AQM) algorithms, and other aspects of study methodologies. To address some of the inconsistencies, we investigated the role of different AQM SOA algorithms by applying two commonly used models, CAMx and CMAQ, with consistent emission inventories to simulate SOA concentrations and contributions for July and November 2018 in China. Both models have a volatility basis set (VBS) SOA algorithm but with different parameters and treatments of SOA photochemical aging. SOA generated from BVOC (i.e., BSOA) is found to be more important in southern China. In contrast, SOA generated from anthropogenic precursors is more prevalent in the North China Plain (NCP), Yangtze River Delta (YRD), Sichuan Basin and Central China. Both models indicate negligible SOA formation from SVOC emissions compared to other precursors. In July, when BVOC emissions are abundant, SOA is predominantly contributed by BSOA (except for NCP), followed by IVOC-SOA (i.e., SOA produced from IVOC) and ASOA (i.e., SOA produced from anthropogenic VOC). In contrast, in November, IVOC became the leading SOA contributor for all selected regions except PRD, illustrating the important contribution of IVOC emissions to SOA formation.While both models generally agree in terms of the spatial distributions and seasonal variations of different SOA components, CMAQ tends to predict higher BSOA, while CAMx generates higher ASOA concentrations. As a result, CMAQ results suggest that BSOA concentration is always higher than ASOA in November, while CAMx emphasizes the importance of ASOA. Utilizing a conceptual model, we found that different treatment of SOA aging between the two models is a major cause of differences in simulated ASOA concentrations. The step-wise SOA aging scheme implemented in the CAMx VBS (based on gas-phase reactions with OH radical and similar to other models) exhibits a strong enhancement effect on simulated ASOA concentrations, and this effect increases with the ambient organic aerosol (OA) concentrations. The CMAQ aerosol module implements a different SOA aging scheme that represents particle-phase oligomerization and has smaller impacts on total OA. Different structures and/or parameters of the SOA aging schemes are being used in current models, which could greatly affect model simulations of OA in ways that are difficult to anticipate. Our results indicate that future control policies should aim at reducing IVOC emissions as well as traditional VOC emissions. In addition, aging schemes are the major driver in CMAQ vs. CAMx treatments of ASOA and their resulting predicted mass. More sophisticated measurement data (e.g., with resolved OA components) and/or chamber experiments (e.g., investigating how aging influences SOA yields) are needed to better characterize SOA aging and constrain model parameterizations.

Changes in Ozone Pollution Trend Characteristics and Sensitivity in Jinan from 2015 to 2020

The surface ozone (O3) spatiotemporal distribution, variations, and its causes in Ji'nan from 2015 to 2020 were revealed based on the air quality monitoring network data and satellite retrievals from the Ozone Monitoring Instrument (OMI). The results showed that the ozone concentration in Ji'nan gradually increased from 2015 to 2020. The annual 90th percentile of the daily maximum 8-h average (MDA8) O3(namely the annual evaluation value) and the MDA8 O3(April-September) increased by 4.8 μg·(m3·a)-1 and 3.8 μg·(m3·a)-1, respectively. The trend of the ozone levels in the high-concentration range increased faster than that in the low-concentration range. The MDA8 in June increased by 7.4 μg·(m3·a)-1, and the rate range of increases was 2.6-3.9 μg·(m3·a)-1 in the cool seasons (December-February); thus, the O3 control in winter cannot be ignored. It is apparent from the diurnal variations in ozone from 2015 to 2020 in April-September that the average ozone levels have risen in recent years. The growth rate in the daytime was higher than that at night. The capacity of photochemical production has been increasing, especially in recent years. Additionally, it is noteworthy that the peak time for ozone levels occurred approximately 1-2 h earlier. The disparity of ozone concentrations among different stations gradually decreased in recent years. Compared with that in 2015, the range of areas with high O3 concentrations in 2019-2020 was further expanded. The significant positive trends in MDA8-90th and MDA8 (April-September) were observed in 16.1% and 22.6% of the monitoring sites in Ji'nan (P<0.05), most of which were located in urban areas and the suburbs close to urban areas. The temporal and spatial changes in ozone in Jinan had been affected by the changes in VOCs and NOx emissions since 2015. Satellite remote sensing data from 2015 to 2020 revealed that the NO2 tropospheric columns (April-September) showed reductions of 20.6%, with a decreasing rate of 0.3×1015 mole·(cm2·a)-1, especially in the urban areas and suburbs. The detected variation trends of tropospheric HCHO were weak and insignificant, which suggested that the decrease in NOx emissions was much greater than the decrease in VOCs emissions, and the gap had become more obvious in the urban areas. With responses to precursor emissions, the chemical sensitivity of O3 formation had been changing. The VOCs-limited regimes continuously decreased, and the mixed NOx/VOCs-sensitive regimes and NOx-limited regimes increased. In general, such an extremely inappropriate control ratio of ozone precursor NOx/VOCs led to an overall trend of slow increasing fluctuations of O3 in Ji'nan. The findings clearly indicate that the reduction of VOCs in Ji'nan was far from sufficient, and strengthening the current control of VOCs emissions is an effective measure to control the growth trend of O3 pollution in Ji'nan in the near future, especially in urban and surrounding suburban areas.

Response of PM2.5 and O3 to Emission Reductions in Nanjing Based on Random Forest Algorithm

High levels of fine particulate matter (PM2.5) and ozone (O3) in ambient air affect climate change and also endanger human health and ecosystems. Air pollution in Nanjing has been improving since the implementation of the "Air Pollution Prevention and Control Action Plan" in 2013. However, Nanjing still faces PM2.5 and O3 pollution. Evaluating the response of pollutant concentrations to the reductions in precursor emissions is helpful to obtain effective strategies of emission reduction to improve pollution levels. The sensitive simulations of emission perturbation in atmospheric chemistry models directly demonstrate the response of pollution to the reductions in emissions. Nevertheless, these sensitive simulations are limited in computing time and resources. The random forest algorithm was trained by using the simulation results of the atmospheric chemical transport model (GEOS-Chem) in 2015. The changes in daily PM2.5 and daily maximum eight-hour O3 (MDA8 O3) concentrations in Nanjing in 2019 were efficiently predicted under different reduction scenarios of anthropogenic emissions. The simulations showed that the seasonal average of ρ(PM2.5) in Nanjing would decrease by 2-4 μg·m-3 with the reduction in anthropogenic emissions of 10% in 2019 in China. In the case of controlling only local emissions in Nanjing, the concentrations of PM2.5 in Nanjing decreased significantly without local anthropogenic emissions. Additionally, the simulations showed that the annual average of ρ(PM2.5) in Nanjing could be lower than the national secondary limit (35 μg·m-3) when the anthropogenic emission reduction in China was higher than 20% in 2019. For ozone, the equal proportional emission reductions in nitrogen oxides (NOx) and volatile organic pollutants (VOCs) of O3 precursors in China likely led to the increase in seasonal average concentrations of O3 in Nanjing. For the proportional reduction of anthropogenic emissions by 10%-50% in China, the seasonal average of ρ(MDA8 O3) in Nanjing in 2019 would increase by 1-3 μg·m-3 in spring, 1-4 μg·m-3 in autumn, and 3-11 μg·m-3 in winter, respectively, compared with that in the base simulation. With the reduction in anthropogenic NOx emission by 10% and VOCs by 20%, the seasonal average of ρ(MDA8 O3) in Nanjing would decrease by 3-6 μg·m-3. On this basis, further increasing the proportion (30%) of VOCs emission reduction could reduce the annual average of ρ(MDA8 O3) in Nanjing by 7 μg·m-3. However, the annual average of ρ(MDA8 O3) of Nanjing in 2019 increased by 1 μg·m-3, with the local emission reduction of NOx by 10% and VOCs by 30%. Therefore, this showed that the key to alleviate ozone pollution in Nanjing is a reasonable control ratio of ozone precursor emissions and the implementation of regional joint prevention and control. In order to effectively reduce the O3 pollution in Nanjing, the emission reduction ratio of NOx and VOCs in China should be less than 1:2. The response of pollutant concentrations to reductions in precursor emissions were efficiently obtained by the random forest algorithm and GEOS-Chem model. The simulations would provide the scientific basis for the emission control strategy to alleviate air pollution.

Numerical investigation of the impact of urban trees on O3–NOx–VOCs chemistry and pollutant dispersion in a typical street canyon

Urban greening is one of major factors that influences flow, turbulence and air quality in street canyons. This paper aims to investigate the impact of urban trees on O3–NOx–VOCs (ozone -nitrogen oxides - volatile organic compounds) chemistry and pollutant dispersion in street canyons by Computational Fluid Dynamics (CFD). The Atmospheric Photolysis calculation framework (i.e., APFoam), which includes complex O3–NOx–VOCs chemistry into CFD, is employed to carry out the numerical simulations. The validation of the APFoam modelling results has been completed prior to further modelling works, including turbulent airflow, pollutant dispersion, and photochemical reactions. The influence of aerodynamic effects, biogenic VOC (BVOCs) emission and dry deposition of urban trees on air quality in a typical two-dimensional (2D) street canyon with aspect ratio H/W = 1 (where H is the building height and W the street width) are thoroughly examined. Moreover, the source contribution on ozone (O3) creation and the human health risk are also analyzed. Results show that, inside the street canyon, aerodynamic effects of trees have a greater impact on photochemical pollutant concentrations than BVOCs emission and dry deposition, the latter showing the smallest impact. In particular, the aerodynamic effects cause a wind reduction by 35%–45% at pedestrian level and subsequently an increase of nitrogen monoxide (NO) and nitrogen dioxide (NO2) concentrations by 95% and 66% near the ground, respectively, and an O3 concentration decrease by 35%. Further, the BVOCs emitted from trees, the vehicle VOCs and the background VOCs contribute 15%, 67%, and 9% to O3 production, respectively. These findings further suggest that the APFoam is an effective and promising tool which allows us to investigate the influencing mechanisms of trees on photochemical pollutant dispersion and urban air quality for the purpose of developing sustainable urban policy.

Silane coupling agent 3‐aminopropyltriethoxysilane modified silica/epoxidized solution‐polymerized styrene butadiene rubber nanocomposites

AbstractIn this paper, epoxidized solution‐polymerized styrene butadiene rubber (ESSBR) as the matrix and silica as filler, a small quantity of 3‐aminopropyltriethoxysilane (APTES) is used to adjust the cross‐linking network of ESSBR/silica. The effect of two APTES addition methods (ESSBR/APTES/silica and ESSBR/silica/APTES) on the nanocomposite properties is investigated. The epoxy groups of ESSBR and the ethoxy groups of APTES can react with the hydroxyl groups on silica to improve dispersion. At the same time, the amino groups at another end of APTES can react with the epoxy groups of ESSBR to increase the cross‐linking density. Compared with bis(3‐triethoxysilylpropyl) disulfide (TESPD) modified SSBR/silica (SSBR/TESPD/silica), ESSBR/APTES/silica shows 133% improvement in wet‐skid resistance, 14% reduction in rolling resistance with less silane coupling agent and volatile organic compounds emissions. ESSBR/APTES/silica has excellent overall performance and offers a good prospect for the preparation of green tire tread.Highlights APTES modified silica/ESSBR nanocomposites are prepared. Epoxy groups and APTES react with silica to improve dispersion. APTES can increase the cross‐linking density. The nanocomposite has excellent comprehensive performance as green tire tread. The nanocomposite has less silane coupling agent and VOCs emission.

Study on VOC Emission Accounting Method from Sewage Pool in Oilfield Based on COMSOL and Response Surface Methodology

Study on VOC Emission Accounting Method from Sewage Pool in Oilfield Based on COMSOL and Response Surface Methodology

Region-wise and state-wise synthesis of vehicular emissions in India and their mitigation due to vehicular emissions standards

The implementation of different stages of Bharat Stage Emission standards (BSES) in India for reducing the vehicular emissions has been in different parts of the country at various points of time. A quantitative assessment of the emission standards in mitigating vehicular emissions at different Indian states will provide an estimate of achievable emissions standards for future norms. In this regard, the present work reports an assessment of the BS standards – BS-III, BS-IV and BS-VI in reducing the exhaust emissions in each of the Indian states. The assessment is performed through the survival fraction of the vehicles registered with different norms in the two age groups 2013–2017 and 2018–2022 and the corresponding emissions of NOx, CO, VOC, PM2.5 and BC. Over the years 2013–2022, the NOx emissions are the major contributors of vehicular emissions in all the states studied. Surprisingly, the BS-IV vehicles contributed significantly to vehicular emissions in particular states when compared to the BS-III vehicles. This urged to analyse the impact of meteorological and topographical factors on the vehicular emissions. The results revealed that the vehicular emissions are largely dependent on the temperature and altitude and with an increase in temperature and at high altitudes, the CO and VOC emissions are predominant, even in regions with low vehicle population. This finding therefore indicates that the emission limits are not the same for all over the country and meteorology dependent emission limit should be included in framing the vehicle emission norms.

Air quality and related health impact in the UNECE region: source attribution and scenario analysis

Abstract. The TM5-FAst Scenario Screening Tool (TM5-FASST) was used to study the influence of abatement policies within and outside the United Nations Economic Commission for Europe (UNECE) region on the exposure to O3 and PM2.5 and associated mortality in the UNECE countries. To that end, the impacts of pollutants derived from different geographic areas and activity sectors were evaluated using ECLIPSE V6b scenarios of air pollutant and greenhouse gas (GHG) emission reduction. The mortalities were attributed to O3 and PM2.5 following the Global Burden of Disease (GBD) approach and allocated to geographic areas (UNECE and non-UNECE) and activity sectors, including natural sources. In addition, a combination of runs designed for the purpose led to allocating exposure to O3 and related mortality to two families of precursors: NOx–VOC and CH4. In this study, the baseline scenario (current legislation scenario, CLE), which assumes that all air quality and greenhouse gas abatement measures adopted by 2018 are fully implemented, is compared with more ambitious scenarios (maximum feasible reduction, MFR). The findings from this comparison indicate that O3 exposure within the UNECE area is more sensitive to measures outside the UNECE region than PM2.5 exposure, even though the latter leads to higher mortality than the former. In the CLE, the mortality associated with O3 exposure in the UNECE region grows steadily from 2020 to 2050. The upward trend is mainly associated with the growing impact of CH4 emissions from areas outside UNECE. Also, the mortality related to NOx–VOC emissions outside UNECE increases in the same period. By comparison, a measurable decrease (13 %) is observed in the mortality attributable to NOx–VOC emissions within UNECE. In the same time window, the mortality associated with PM2.5 exposure in the UNECE region decreases between 2020 and 2040 and then rises until 2050. The PM2.5-related mortality in UNECE is mainly due to anthropogenic emissions within this region followed by natural sources (sea salt and dust) mainly located outside the UNECE region. Between 2020 and 2050, the impact of some UNECE anthropogenic sources on PM2.5-related mortality decreases progressively, in particular road transport, energy production and domestic combustion, while others, namely agriculture and industry, show an upward trend. Finally, the analysis of MFR scenarios confirms that abatement measures in line with UN Sustainable Development Goals (SDGs) and the Paris Agreement can lead to significant co-benefits between air quality and climate policies.

Enhanced compressive strength of preheated limonite pellets with biomass-derived binders

Sodium lignosulfonate (SL) is a powder-like by-product of the pulp and paper industry derived from lignocellulosic biomass. SL can potentially be a low-cost and highly efficient binder for the pelletization of iron ore powder in the ironmaking industry because it is a natural polymer compound containing multiple functional groups, such as hydroxyl, carboxyl, and sulfonic acid. In this paper, the strong organic binder, namely SL, was used to enhance the compressive strength of the limonite pellet, which is required to reduce VOC emission during the iron-making process. The limonite pellets' pellet size variation and compressive strength prepared with SL-based binders were studied at a temperature range from 900 °C −1100 °C. Experimental results showed that the compressive strength of the preheated pellets was the highest at a preheating temperature of 1100 °C, reaching 342.55 N/P which is qualified for the subsequent iron-making process. These experimental results provide essential references for optimizing the preparation of limonite pellets with SL-based binders. Furthermore, this study employed artificial neural networks to process experimental data and generate predicted values for corresponding experimental conditions. The predicted results closely matched the observed values, further assisting enterprises in accelerating their digitization and automation processes.

Impacts of aerosol direct effects on PM2.5 and O3 respond to the reductions of different primary emissions in Beijing-Tianjin-Hebei and surrounding area

In recent years, the rapid pollution emission reductions significantly decreased the PM2.5, which weakened the aerosol radiation feedback effect and in turn influenced the changes of PM2.5 and O3. To promote our understanding of this effect, we used an online-coupled meteorology-chemistry model (WRF-Chem) to investigate the influence of aerosol direct effects (ADE) on PM2.5 and O3 responding to different pollutant emissions reduction for a summer PM2.5-O3 compound pollution month in Beijing-Tian-Hebei region (BTH) and surrounding area. We performed scenario simulations with turning on/off both aerosol influences on the meteorology (ADE_MET) and photolysis (ADE_PHO), and turning on only ADE_PHO with different reduction ratios for primary PM2.5 (100%), SO2 (80%) and NOx (40%) emissions. Our results showed that total reduction of primary PM2.5, SO2 and NOx emissions led to overall declines of surface PM2.5 in BTH and surrounding area. The SO2 and NOx emission reductions both furtherly decreased PM2.5 via the changed ADE, while the primary PM2.5 emission reduction increased the PM2.5 by its induced ADE. Different from PM2.5, O3 significantly increased in BTH after cutting the three types of emissions. The primary PM2.5 emission reduction led to O3 increase over the whole region mostly by the induced ADE, while the NOx emission reduction directly enhanced O3 in the plain areas mainly due to incompatible reduction of NOx and VOCs emissions. The O3 enhanced by emission-reduction-induced ADE accounted for 56.1% of the total increase. The ADE_PHO caused by PM2.5 primary emissions reduction was the dominant contribution to the total ADE induced increases of PM2.5 and O3, which enhanced the photolysis of gases and led to overall increase of oxidants that strengthened secondary aerosol formation, and also promoted the production of O3 via photochemical processes. The results implicate that with the continuously strengthened abatement of PM2.5 primary emissions, it may offset part of the reduction effect on PM2.5 decrease by the changed ADE, and also increase O3 over the whole region. The results also suggested that while controlling both PM2.5 and O3 in BTH in summer, not only the cooperative emission reduction of NOx and VOCs is essential, the induced ADE effect by PM2.5 primary emissions reduction should also be considered.

Analysis of O3 Sources in Yulin City in Summer Based on WRF-CMAQ/ISAM Model

In order to have a clearer understanding of the sources of ozone pollution in Yulin City in summer and put forward scientific governance suggestions, the WRF-CMAQ model was used to simulate the O3 concentration in Yulin City and surrounding areas (including Taiyuan City, Xi'an City, Yinchuan City, Hohhot City, and other provincial capital cities) in July 2019. Using the ISAM module, the sources of O3 and its precursors NOx and VOCs in a heavy pollution process in Yulin City were quantified. The results showed that on heavy pollution days, the O3 in Yulin City mainly came from the long-distance transmission outside the simulation area (55.5%), followed by the photochemical reaction of precursors in the simulation area (20.6%, 10.0%, 5.0%, 2.3%, and 2.1%, respectively, in Yulin City, Shanxi Province, Inner Mongolia Autonomous Region, and Shaanxi Province, 1.2% in Gansu Province, Ningxia Hui Autonomous Region, and Henan Province in total), and initial conditions (0.3%); the remaining sources (23.6%) could not be successfully labeled. Yulin City is in the VOCs control area, and its VOCs were composed of paraffin (76.5%), ketones (9.2%), and other types of VOCs (14.3%). The VOCs came from the emission of pollution sources in the simulation area (45.6%, 22.0%, 11.4%, 6.3%, and 5.1%, respectively, in Yulin City, Shanxi Province, Inner Mongolia Autonomous Region, and Shaanxi Province, 0.8% in Gansu Province, Ningxia Hui Autonomous Region, and Henan Province in total) and the long-distance transmission outside the simulation area (27.9%); the remaining 26.5% were not successfully marked. This research showed that to control the O3 pollution in Yulin, not only should the local VOCs emissions be controlled, but the overall planning of VOCs emissions in the peripheral areas should also be done well.

Characteristics of VOCs and Assessment of Emission Reduction Effect During the Epidemic Lockdown Period in Shenzhen Urban Area

To prevent disease spreading during the COVID-19 epidemic, Shenzhen adopted lockdown measures in March of 2022. This provided an opportunity to study the response of changes in anthropogenic volatile organic compounds (AVOCs) in Shenzhen to emission reduction and to evaluate the effectiveness of current emission reduction measures. This study analyzed the variety of AVOCs before, during, and after the epidemic lockdown based on the online observation data of pollutants at Lianhua Station in Shenzhen from March 7, 2022 to March 27, 2022. Additionally, the sensitivity of ozone formation and the assessment of the reduction effect of precursors was conducted by an observation based model(OBM). The results showed that:affected by regional influences and the interference of meteorological conditions, the average value of AVOCs in Shenzhen urban areas did not drop significantly during the lockdown period compared to that before the lockdown. However, the peak of AVOCs at the morning peak time under the influence of "sea and land wind" during the epidemic lockdown period dropped by 46% on average compared with that during the non-lockdown period, and the aromatic hydrocarbon component dropped the most by 59%. Additionally, under the influence of continuous easterly wind, or during the accumulation and increase of AVOCs affected by regional transmission, aromatic components also decreased by an average of 25% and 21%, respectively. During the lockdown period of the epidemic in Shenzhen, the O3 formation in urban areas was still AVOCs-limited. Increasing the emission reduction ratio of AVOCs was the most effective measure to reduce O3 in the short term. In order to ensure the effectiveness of emission reduction, it was recommended that the coordinated emission reduction ratio of AVOCs and NOx should be greater than 1:2. It was only possible to enter the downward channel of O3 if the deep emission reduction was more than 60%. This study revealed that the emission reduction of AVOCs during the morning traffic peak during the epidemic lockdown period was conducive to inhibiting the formation of O3, whereas the control of NOx would promote it. Strengthening the control of local aromatic hydrocarbon components during the regional impact process could also significantly reduce O3 production. At this stage, Shenzhen should strengthen the management and control of industrial solvents, especially to reduce the aromatic hydrocarbon components in the solvent source that have a greater impact on the generation of O3. Further, Shenzhen should continue to promote the reform of the energy structure of motor vehicles to reduce the emission of VOCs in fuel combustion.

Towards understanding of inhalation exposure of pilots in the control cabin environment

Transport characteristics of TVOC in cockpits of commercial airliners have not been carefully studied relative to passenger cabins, and VOC emissions are currently not well regulated by the standards (e.g. ASHRAE, FAA, etc.). This study numerically performed a comprehensive assessment of cockpit environment using the developed all-in-one model, for the first time, integrating a full-scale A320 cockpit model and detailed manikins with 3D-rebuilt nasal cavity models. A generalised total volatile organic compound (TVOC) was selected as one representative gaseous contaminant and two representative emission scenarios in the cabin environment (aged and new aircraft) were analysed. Potential risky regions of the nasal system after inhaling the given contaminants were further evaluated. The outcomes demonstrated that windshield inlets were the key determinant of yielding the strong local vortex in the pilot’s near field, which could potentially promote the contaminant lock-up. For aged aircraft, the average contaminant concentration in the pilots’ breathing zone was nearly half of that in a brand-new aircraft, while TVOC concentrations were significantly higher in the human upper respiratory system than those detected in the breathing zones for both cases, particularly for vestibule, olfactory, sinus and nasopharynx regions. Olfactory regions were the most affected region in two cases, with an approximately 20% increase in the case of brand-new aircraft compared to an aged one. This study enlightened a novel pathway to assess indoor environment, from tracing the pollutants from the release source to ultimately quantifying the contaminant distribution characteristics in human upper respiratory system.

Effect of the Addition of Extractives on The Reduction Of Vocs Emissions from Lacquers in the liquid state

Effect of the Addition of Extractives on The Reduction Of Vocs Emissions from Lacquers in the liquid state

Interpretation of odor complaint records with BTEX pollutants and meteorological factors: Çorlu case study

Air pollution in urban areas increases as a result of emitted air from different sources within the mixing layer of troposphere. Odor pollution is amongst the primary reasons behind environmental nuisance and occurrence of citizen complaints. Frequent exposure to odorous compounds and/or odor nuisance are increasingly associated with air pollution problems. Besides, there is no universally accepted environmental odor management method reported so far. Level of air pollutants emission, distance of emission sources to residential areas, to-pography, geographical and meteorological conditions have influence on imposed level of air pollution and odor pollution in cities.&#x0D; &#x0D; This study is built on the citizen odor complaint data (based on frequency, intensity, duration, odor tone and location (namely the FIDOL factors) collected in Çorlu/Tekirdağ through the GIS integrated public participated platform, namely the Çorlu KODER mobile application. The annual odor complaint data was briefly introduced and given an evaluation with the mo-bile app users demographic information. The obtained data between August 28-November 2 of 2021, was subjected to interpretative evaluation and statistical analysis with BTEX (benzene, toluene, ethylene benzene and xylen) concentrations, inorganic air pollution concentrations and meteorological factors. In light of the obtained results, temperature, wind speed, relative humidity and toluene concentration were found to play a significant role on the number of citizen odor complaints. The EU reported limit value, lower rating threshold and upper rating threshold for BTEX pollutants have been exceeded several times.&#x0D; &#x0D; The average Toluene/benzene ratios obtained during the study show that; non-traffic sources contribute significantly to VOC emissions. Air pollutants transportation mechanism from neighbouring OIZ settlements become a prominent justification and support the hypothesis that residential areas of Corlu are under the effect of industrial air pollution and odor pollution con-stituents. There is low level of negative correlation between the benzene measured in Çorlu and WS (r=-0.63). Below 2.4 m/s, the average number of odor complaints (ANOC) tend to increase, while above this level odor complaints are diminished). The ANOC remained around 4 for[C] &lt; 4 ug/m3 and reached to 18 for [C]BTEXtotal &gt; 8 ug/m3. Above [C]Toluen=3 ug/m3 conditions, Daily ANOC increase from 7 to 19. Over [C]Toluen= 4 ug/m3 conditions, it reached up to 23. Increses in the number of daily ANOC by temperature is distinct over 21 C0 and reaches to 35. &#x0D; &#x0D; The GIS integrated citizen complaint collection platforms are critical for real-time data collection of environmental complaints with high spatiotemporal accuracy. Citizen odor complaint surveys are useful monitoring tools and obtained data sets can be used to identify sensitive areas where and when specific actions should be taken and air pollutants measuement studies be performed.

Effects of long-distance transport on O3 and secondary inorganic aerosols formation in Qingdao, China

This work presents a three-year continuous observation of ozone (O3) and fine particle (PM2.5), as well as their precursors in Qingdao, China, from September 2018 to August 2021. The annual concentrations of O3 and PM2.5 were measured as 35.9–44.5 ppbv and 31.6–34.2 μg m−3, respectively. Analysis of the interannual variations of O3 and PM2.5 concentration indicated the effective control measures for PM2.5 and O3 pollution in Qingdao in recent years. Nevertheless, we still observed 85 O3 episodes and 80 PM2.5 episodes during the whole observation. And it was found that the fraction of secondary inorganic aerosols (SIA) in PM2.5 mass significantly increased during PM2.5 episodes. By employing the Lagrangian photochemical trajectory model (LPTM), we investigated the roles of local production and regional transport (i.e., short-distance transport and long-distance transport) that play in the O3 and SIA formation in these episodes. The contribution of local production, short-distance transport, and long-distance transport to O3 concentration was calculated as 36%, 25%, and 39%, respectively. Long-distance transport seemed to play a more significant role in the SIA formation, accounting for 56% of SIA concentration. Moreover, the calculation results of the relative incremental reactivity (RIR) showed that both O3 and SIA formation were mainly affected by NOx and VOCs emissions during the process of long-distance transport. The observed unexpectedly high contribution of long-distance transport to O3 and SIA formation suggests that more extensive regional joint prevention and control policies on NOx and VOCs emissions are warranted to mitigate secondary air pollution.

Multiple sources emission inventory closely integrated with atmospheric environment management: A case study of Guangdong, China

The framework design and compilation methods of air emission inventory cannot connect multiple sets of environmental management statistics. The environmental statistics with different emission results increase the difficulty of policy making by the administrative departments. Based on the existing statistical system of environmental management in Guangdong Province, this study combines traditional compilation method of atmospheric pollution source emission inventory to optimize the classification system of air emission inventory and the integration based on multi-source data of environmental management. The study proposes a four-level classified pollution source system of national economy with Guangdong characteristics as well as a calculation method of multi-source data fusion supporting annually updating. Taking 2020 emission inventory formation as an example, results show that the emissions of SO2, NOx, VOCs, NH3, PM2.5, PM10 and CO in Guangdong Province are about 180, 985, 1,989, 390, 270, 750 and 2844 thousand tons respectively. In this case, SO2 and CO mainly come from industrial sources, NOx and PM2.5 mainly come from mobile sources, VOCs mainly come from natural sources, NH3 mainly comes from agricultural sources, and PM10 mainly comes from dust sources. The study raises a method of uncertainty grading evaluation and conducts a simulation verification of emission inventory accuracy. Results suggest that the emission inventory can reflect the emission status in 2020, but the quality of environmental management data of residential sources, dust sources and eastern Guangdong region still needs to be improved, and the pollution source control strategy of such sources or the region needs to be strengthened.