Ultrafine Particle Emissions Research Articles

Determination of ultrafine particle number emission factors from building materials in standardized conditions.

When comparing the particle emissivity for different materials and/or mechanical activities, a serious methodological issue emerges due to the dynamic nature of solid aerosols. Particle size distribution and concentration depend on initial particle emission that constantly evolves due to aerodynamic collisions. In this context, we propose a methodological approach and an experimental setup that enables to assess the release of fine/ultra-fine particles maintaining a steady-state inhalable mass concentration, here chosen at the Swiss occupational exposure level value for biopersistent granular particles (OEL: 10mg/m3) in a controlled ventilation chamber. As a case study, this methodological protocol was tested in the occupational exposure scenario in which a series of insulating materials based on silica aerogel and conventional mortar and concrete were subjected to handling or sawing. Once the OEL was reached, the particle size distribution and morphology of the aerosols were characterized using direct reading instruments (scanning mobility sizer, aerosol photometer) and electron microscopy (SEM and TEM) analyses. As a main result, the presence of silica aerogel in the mortar did not modify the emission profile for submicronic particles during sawing in comparison to the bulk mortar. Emission factors for ultra-fine particles were found to be 88×106 and 81×106 particles/µg of inhalable dust for the aerogel mortar and bulk mortar, respectively. For concrete sawing, the number concentration of submicronic particles at the OEL is one order of magnitude greater. The aerogel-glass-wool handling generated similar particle number concentration at the OEL with ultra-fine particle emission factors of 647×106 particles/µg of inhalable dust, in comparison to 758×106 particles/µg of inhalable dust during dry concrete sawing. In conclusion, the methodology introduced in this work provides standardized particle emission factors for comparing materials and activities, while establishing a link between particle number emissions and occupational exposure limits.

Exploring ultrafine particle emission characteristics from in-use light-duty diesel trucks in China using a portable measurement system

Diesel vehicle exhaust is one of the major contributors to ultrafine particles (UFPs) in urban areas in China. However, there is still a lack of knowledge about UFPs emission characteristics from current in-use diesel vehicles. This study has carried out an on-road test of 10 in-use Light-duty Diesel Trucks (LDDTs) with different emission control standards in China using a self-established portable measurement system based on the Electronic Low-pressure Impactor (ELPI) and characterized the ultrafine particle number (PN) concentration, particle size distribution and metal element contents. The results revealed a significant reduction of 93.37% in the average PN0.1 emission factor of LDDTs from China IV to China VI. Notably, LDDTs compliant with the China VI vehicle emission control standard exhibited the lowest PN0.1 and PM0.1 emission factors, measuring 4.991×1014 #/km and 0.627 g/km, respectively. By taking into account emissions under real driving conditions, we found that the PN emission rates grow with the increase of the Vehicle Specific Power (VSP). The cold-start phase had higher PN emissions than the hot-start phase, with 8590, 1890, 477, and 22 times higher than those of the ambient air (1.18×105 #/cm3), respectively. The installation of Diesel Particulate Filter (DPF) can decrease UFPs by more than 99.8%, while the PN emission factor during the DPF regeneration stage (1.85×1016 #/km) increased by 5 orders of magnitude that of the DPF normal works (7.51×1011 #/km). Metal element contents analysis shows that Fe, Ca, Al and Mg are the dominant elements in UFPs of LDDT exhaust gas, but the element of Ni is slightly increasing in a China VI, possibly due to the new automotive engine exhaust manifolds being made of Ni instead of cast iron for the purpose of having more high-temperature resistance. Our study demonstrates the importance of monitoring and routine maintenance of exhaust after-treatment systems.

Humic substances and inorganic ions synergistically precipitate at the gas–liquid interface in a simulation experiment of direct-contact heat and mass transfer processes

Direct-contact heat and mass transfer processes are widely employed in saline wastewater treatment. However, these processes are accompanied by serious ultrafine particle emission, a phenomenon associated with the solute’s transition across the gas–liquid interface. A thorough comprehension of the solute’s behavior at this gas–liquid interface is vital for clarifying the crossing process and guiding particle control strategies. Here, solutions containing saturated inorganic ions and humic substances were evaporated to analyze their behaviors at the gas–liquid interface in an experimental simulation of direct-contact heat and mass transfer processes. It was found that these substances co-precipitated at this interface. Humic substances can bind with inorganic ions via chemical bonds, monovalent ions through cation-π interactions, and divalent ions through electrostatic and chelation interactions. Moreover, humic substances can act as nucleation sites for precipitating inorganic crystals. These distinctive binding mechanisms caused a synergistic relationship between humic substances and inorganic ions during precipitation. Amidst precipitation, humic substances with high humification degrees and large molecular weights were predominantly enriched. Inorganic ions, comprising over 93% of the total precipitate mass, constituted the principal constituents. Among these, Na+, with an enrichment factor of 2.10, precipitated more readily at the gas–liquid interface compared to divalent ions. These conclusions concerning the binding mechanisms of humic substances and inorganic ions, along with their precipitation characteristics, were validated in the submerged combustion evaporation process of membrane-concentrated leachate.

Prediction of urban ultrafine particle emission fluxes using generalized additive models

Ultrafine particles (UFP) are abundant in urban atmospheres. To assess the strength and temporal variation of urban UFP emission sources, information on the surface-atmosphere exchange, i.e. the turbulent vertical flux of particles, is vital. A three-year time series of UFP emission fluxes (FUFP) observed at an urban site in Berlin, Germany, using the eddy covariance technique was utilized to develop and evaluate generalized additive models (GAM) for FUFP. GAM allow to account for non-linear relationships between response and predictor variables. Two separate models for summer and winter were developed. The predictors that most strongly influenced modelled FUFP in the summer model were traffic activity, friction velocity, land use, air temperature and PM10 concentration, whereas the winter model additionally incorporated relative humidity. The GAM were evaluated by ten-fold cross-validation for the first two study years, and by predicting the third year based on the model trained with observational data of the first two years. The coefficients of determination of the two validation methods were R2 = 0.52 (uncertainty of −47 to 88% for FUFP) and R2 = 0.48 (−45 to 82% for FUFP) for the winter model, whereas the summer model yielded R2 = 0.48 and 0.44 (uncertainty of −51 to 102%). GAM were shown to successfully capture the non-linear relationships between predictor variables and FUFP for the three-year data set at this urban site.

Brake Wear and Airborne Particle Mass Emissions from Passenger Car Brakes in Dynamometer Experiments Based on the Worldwide Harmonized Light-Duty Vehicle Test Procedure Brake Cycle

Brake wear particles, as the major component of non-exhaust particulate matter, are known to have different emissions, depending on the type of brake assembly and the specifications of the vehicle. In this study, brake wear and wear particle mass emissions were measured under realistic vehicle driving and full friction braking conditions using current commercial genuine brake assemblies. Although there were no significant differences in either PM10 or PM2.5 emissions between the different cooling air flow rates, brake wear decreased and ultrafine particle (PM0.12) emissions increased with the increase in the cooling air flow rate. Particle mass measurements were collected on filter media, allowing chemical composition analysis to identify the source of brake wear particle mass emissions. The iron concentration in the brake wear particles indicated that the main contribution was derived from disc wear. Using a systematic approach that measured brake wear and wear particle emissions, this study was able to characterize correlations with elemental compositions in brake friction materials, adding to our understanding of the mechanical phenomena of brake wear and wear particle emissions.

The relative contributions of traffic and non-traffic sources in ultrafine particle formations in Tehran mega city

Emissions of ultrafine particles (UFPs; diameter < 100 nm) are strongly associated with traffic-related emissions and are a growing global concern in urban environments. The aim of this study was to investigate the variations of particle number concentration (PNC) with a diameter > 10 nm at nine stations and understand the major sources of UFPs (primary vs. secondary) in Tehran megacity. The study was carried out in Tehran in 2020. NOx and PNC were reported from a total of nine urban site locations in Tehran and BC concentrations were examined at two monitoring stations. Data from all stations showed diurnal changes with peak morning and evening rush hours. The hourly PNC was correlated with NOx. PNCs in Tehran were higher compared to those of many cities reported in the literature. The highest concentrations were at District 19 station (traffic) and the lowest was at Punak station (residential) such that the average PNC varied from 8.4 × 103 to 5.7 × 104 cm−3. In Ray and Sharif stations, the average contributions of primary and secondary sources of PNC were 67 and 33%, respectively. Overall, we conclude that a decrease in primary emission leads to a decrease in the total concentration of aerosols, despite an increase in the formation of new particles by photo nucleation.

Indoor Emissions Contributed the Majority of Ultrafine Particles in Chinese Urban Residences.

Ultrafine particle (UFP) pollution should be controlled to reduce its effects on health. The design of control measures is limited owing to the uncertainty of source contributions in Chinese residences, where indoor UFP pollution is more severe than in Western residences. Herein, a source-specific, time-dependent UFP concentration model was developed by applying an infiltration factor model incorporating coagulation effects. A Monte Carlo framework with the UFP concentration model was employed to estimate the probabilistic distribution of source contributions in Chinese residences. The input parameter distributions were determined based on our survey and previous studies. The annually averaged indoor UFP concentration was estimated at (2.75 ± 1.71) × 104 #/cm3, ranging from 2.35 × 103 to 1.27 × 105 #/cm3 outside the kitchen, and at (5.48 ± 3.08) × 104 #/cm3, ranging from 2.90 × 103 to 1.94 × 105 #/cm3 in the kitchen. Indoor sources contributed more to indoor UFPs, accounting for 61% in the nonkitchen and 80% in the kitchen, surpassing their contribution to indoor PM2.5 in Chinese residences. Meanwhile, the indoor UFP emission contributions were higher than those in the United States, Canada, and Germany, owing to higher emissions from cooking and cigarette smoking. These results will aid in elucidating human exposure to UFPs and in designing more targeted control measures.

A traffic-induced shift of ultrafine particle sources under COVID-19 soft lockdown in a subtropical urban area

During the unprecedented COVID-19 city lockdown, a unique opportunity arose to dissect the intricate dynamics of urban air quality, focusing on ultrafine particles (UFPs) and volatile organic compounds (VOCs). This study delves into the nuanced interplay between traffic patterns and UFP emissions in a subtropical urban setting during the spring-summer transition of 2021. Leveraging meticulous roadside measurements near a traffic nexus, our investigation unravels the intricate relationship between particle number size distribution (PNSD), VOCs mixing ratios, and detailed vehicle activity metrics. The soft lockdown era, marked by a 20–27% dip in overall traffic yet a surprising surge in early morning motorcycle activity, presented a natural experiment. We observed a consequential shift in the urban aerosol regime: the decrease in primary emissions from traffic substantially amplified the role of aged particles and secondary aerosols. This shift was particularly pronounced under stagnant atmospheric conditions, where reduced dilution exacerbated the influence of alternative emission sources, notably solvent evaporation, and was further accentuated with the resumption of normal traffic flows. A distinct seasonal trend emerged as warmer months approached, with aromatic VOCs such as toluene, ethylbenzene, and xylene not only increasing but also significantly contributing to more frequent particle growth events. These findings spotlight the criticality of targeted strategies at traffic hotspots, especially during periods susceptible to weak atmospheric dilution, to curb UFP and precursor emissions effectively. As we stand at the cusp of widespread vehicle electrification, this study underscores the imperative of a holistic approach to urban air quality management, embracing the complexities of primary emission reductions and the resultant shifts in atmospheric chemistry.

An analytical model-based assessment of Wet Electrostatic Scrubbing for mitigating fine and ultrafine particles emissions in domestic biomass boilers

This paper proposes the general design of a Wet Electrostatic Scrubber aimed at mitigating fine and ultrafine particles emissions from domestic heating boilers. The design is based on particle capture modelling supported by specific experiments and technical literature information. Results indicate up to 96.6% removal efficiency, consuming 1.2 kg/h of water and 0.3 W per 1 m3/h of gas treated. Comparative analysis highlights the balanced performance of Wet Electrostatic Scrubber in particle capture, energy and water usage, pressure drop, and space occupancy, with the additional benefit of more efficient absorption of gas pollutants.

Comprehensive framework for overcoming scientific challenges related to assessing radioactive ultra-fine (nano/micro) particles transfer at the atmosphere-leaf interface

Food products are prone into contamination after a nuclear emission of radionuclides. While the mechanisms of emission and deposition of ultrafine radioactive particles are well documented, the transfer of these species from the atmosphere into plants is poorly assessed. This is evident in the lack of quantification of particles distributed within plants, especially regarding particles physical-chemical criteria to plant of different properties. Such knowledge gaps raise the concern about the representativeness of risk assessment tools designed for the transfer evaluation of ionic/soluble species to be qualified for simulating insoluble species exposure and proposes a possible underestimation. This highlights the possible need for special particle codes development to be implemented in models for future emissions. In addition, the later tools utilize transfer factors aggregating relevant sub-processes, suggesting another weak point in their overall reliability. As researchers specialized in the nuclear safety and protection, we intend in this perspective, to develop a compressive analysis of the interaction of ultrafine particles with plants of different specificities at different level processes starting from particles retention and gradual translocation to sink organs. This analysis is leveraged in providing insights for possible improvements in the current modeling tools for better real-life scenarios representation.

Ultrafine particle emissions from dry clutches: number concentration, size distribution and chemical composition

Clutches in automobiles are shown to produce ultrafine particles, consisting of several metallic elements, which become airborne.

Size-resolved emission rates of episodic indoor sources and ultrafine particle dynamics

Indoor airborne ultrafine particles (UFPs) are mainly originated from occupant activities, such as candle burning and cooking. Elevated exposure to UFPs has been found to increase oxidative stress and cause DNA damage. UFPs originating from indoor sources undergo dynamic aerosol transformation mechanisms. This study investigates the dynamics of UFPs following episodic indoor releases of the six distinct emission sources: 1) candle, 2) gas stove, 3) clothes dryer, 4) tea & toast, 5) broiled fish, and 6) incense. Based on the analytical model of aerosol dynamic processes, this study reports size-resolved source emission rates along with relative contributions of coagulation, deposition, and ventilation to the particle size distribution dynamics. The study findings indicate a significant variation in the geometric mean diameter (GMD) and size-resolved number concentration over time for the sources that emit a substantial amount of UFPs smaller than 10 nm. As the emission progresses, the UFP number concentrations increase in a log-normal distribution, while the GMD shows a tendency to increase over time. The observed result suggests that coagulation can have a considerable impact on UFP number concentration and size, even during the indoor UFP emission. The estimated emission rates of the six indoor sources appear to follow a log-normal distribution while the emission rate ranges from 107 min−1 to 1012 min−1. The indoor UFP concentration and size distribution dynamics are substantially affected by the interplay of the three aerosol loss mechanisms that compete with each other, and this impact varies according to the source type and the indoor environmental conditions. Ultimately, using the aerosol transformation mechanisms examined in this study, researchers can refine exposure assessment for epidemiological studies on indoor ultrafine particles.

Emissions of ultrafine particles from civil aircraft: dependence upon aircraft type and passenger load

Very high concentrations of ultrafine particles (UFP) were measured at Heathrow Airport London. Exposure to UFP is strongly linked to adverse health effects and guidance for exposure limits has recently been provided by the World Health Organization (WHO). Using 1 s resolution UFP measurements and aircraft GPS data, measurements were assigned to individual aircraft and their operating mode, and this information was used to model UFP emission rates. In all cases, the highest emission rates were associated with departing aircraft, with rates for larger aircraft higher than smaller aircraft. Emission rates per passenger is influenced by the number of passengers carried, especially for arriving aircraft. Calculated emission rates are significantly higher than stated literature values, due to the inclusion of condensable particles in the measurements. These condensable particles are specifically not included in the regulated emission rates. Measured UFP concentrations within the airport boundary (and therefore not accessible to the general public) exceed the WHO guidance, indicating that UFP concentrations outside of the airport boundary could also be of concern. Assessing population exposure close to airports will be of increasing importance in future.

Chemical characterization of particulates and volatile organic compounds emitted during fused deposition modeling

Additive manufacturing (AM) is largely regarded as an environmentally friendly alternative to traditional manufacturing techniques. However, some studies have pointed out that AM may carry its own environmental implications. It has been reported that high concentrations of ultrafine particle emissions as well as volatile and semi volatile organic compound emissions from the fused deposition modeling (FDM) 3D printing process. The health consequences of exposure to these ultrafine particles and organic compounds are unknown. Determining the chemical composition of the ultrafine particles and the volatile organic compounds is the first step toward understanding potential health risks of FDM process. In this study, we collect air emissions from FDM printing using ABS plastic filament for chemical characterization. Using solid phase microextraction (SPME), compounds in samples are adsorbed or absorbed on a fiber coating and analyzed with gas chromatography mass spectrometry (GC–MS). Several compounds are successfully identified in printer emissions and compared with samples collected from filament wash prior to extrusion. The most predominant compound was styrene, followed by various benzene aromatics, nitrogenated aromatics, and siloxanes. Measurements identifies substantial cross over between compounds found from printer emission and filament wash tests, suggesting that some emissions could possibly be reduced, or in some cases, even eliminated by washing 3D printer filament prior to use.

Fine and ultrafine particle emission factors and new diagnostic ratios of PAHs for peat swamp forest fires

Peatland fires are one of the major global sources of atmospheric particles. Emission factors for fine (PM1 and PM2.5) and ultrafine (PM0.1) particles and particle-bound polycyclic aromatic hydrocarbons (PAHs) from plants in the peat swamp forest (PSF), including Melaleuca cajuputi leaves, M. cajuputi branches, M. cajuputi bark, Lepironia articulata (Retz.) Domin, forest leaf litter and peat were measured in a laboratory combustion chamber. From these measurements, new PAH diagnostic ratios for fine and ultrafine particles were proposed for identifying the forest burning source. The new emission factors for PM were PM0.1: 0.03–0.33, PM1: 0.69–2.11 and PM2.5: 1.12–4.18 g/kg; for PM-bound PAHs, the factors were PM0.1: 5.7–166.0, PM1: 31.5–1338.9 and PM2.5: 36.3–3641.1 μg/kg. The predominant PAHs for PSF burning were Pyr, BbF, DBA (in PM0.1), Flu, DBA, BghiPe (in PM1), and BbF, DBA and BghiPe (in PM2.5). We also presented new diagnostic ratios for PSF burning, including BaP/(BaP + Chr): 0.39–0.75, BaP/(BaP + BbF): 0.21–0.47 and BaA/(BaA + Chr): 0.36–0.53. Moreover, the physical and chemical characteristics of ambient fine and ultrafine particles in the Kuan Kreng forest during the 2019 forest fire (FF) and 2021 non-forest fire (NFF) periods were investigated. The mean PM0.1, PM1 and PM2.5 concentrations during the FF period were approximately 3.5–4.4 times as high as those during the 2021 NFF period. New PAH diagnostic ratios of BaP/(BaP + BbF) versus BaP/(BaP + Chr) were able to identify PAH burning sources in PM1 and PM2.5 but were less clear for PM0.1, which was dominated by a single source – M. cajuputi. Chemical mass balance studies identified peat forest burning emissions as the main source of fine and ultrafine particles during the FF period. This study suggests that the new PAH diagnostic ratios can be used to identify the burning source for more precise source apportionment.

Harmful algal bloom aerosols and human health.

Harmful algal blooms (HABs) are increasing across many locations globally. Toxins from HABs can be incorporated into aerosols and transported inland, where subsequent exposure and inhalation can induce adverse health effects. However, the relationship between HAB aerosols and health outcomes remains unclear despite the potential for population-level exposures. In this review, we synthesized the current state of knowledge and identified evidence gaps in the relationship between HAB aerosols and human health. Aerosols from Karenia brevis, Ostreopsis sp., and cyanobacteria were linked with respiratory outcomes. However, most works did not directly measure aerosol or toxin concentrations and instead relied on proxy metrics of exposure, such as cell concentrations in nearby waterbodies. Furthermore, the number of studies with epidemiological designs was limited. Significant uncertainties remain regarding the health effects of other HAB species; threshold dose and the dose-response relationship; effects of concurrent exposures to mixtures of toxins and other aerosol sources, such as microplastics and metals; the impact of long-term exposures; and disparities in exposures and associated health effects across potentially vulnerable subpopulations. Additional studies employing multifaceted exposure assessment methods and leveraging large health databases could address such gaps and improve our understanding of the public health burden of HABs.

Study of sugarcane bagasse/straw combustion and its atmospheric emissions using a pilot-burner.

This work conducted experimental combustion on a closed chamber using two different materials: mixture (1:1) sugarcane bagasse/straw and pre-treated biomass. The sampling method was an Andersen cascade impactor with eight stages. Tests were carried out on untreated biomass varying the velocities observed in the sampling duct (4.18; 5.20, 6.85, and 8.21m.s-1). Pre-treated biomass tests were performed at 4.19m.s-1 because in this condition there is a higher speed stability inside the duct. During the combustion tests, the concentration of emitted particles was higher for the lower speed range, with an order of 4.19 > 5.40 > 6.85 > 8.21m.s-1. The higher speeds observed inside the duct behaved as a dragging agent for particulate material. For the tests at the speed of 8.21m.s-1 where the flow inside the duct was 0.088m3s-1, this behavior is more evident. Considering the fine diameter particles (< 2.5µm), they were emitted in a higher concentration, due to the biomass combustion process, which results in higher emission of ultrafine particles. The emission factors (EFs) obtained for PM10 for untreated biomass were in the range of 0.414 and 0.840. On the other hand, considering the pre-treated biomass, these factors were 0.70 and 1.51. The EFs of PM from the burning of the pre-treated biomass were higher when compared to untreated biomass, which is mainly due to the higher temperature of the process due to the higher HHV (higher heating value) of this material, caused by the removal of hemicellulose (4.71 times) and a proportional increase in lignin (1.52 times). Biomass combustion has the potential to partially replace fossil fuels in heat and energy generation. Nevertheless, more stringent and comprehensive legislation should be established to ensure that air quality is maintained. Furthermore, the emission factors obtained in this study might be useful as input data for air quality modeling in the context of sugarcane's burning biomass, thus, contributing to the generation of inventories that include emissions of this nature.

102 Insights from Workplace Exposure Campaigns During Metal 3D Printing Procedures with Portable Equipment to Monitor Ultrafine Particles Emissions

Abstract Metal 3D printing is an emergent technology gaining much interest in a wide range of sectors, namely in the automotive and aeronautics sectors. This technology enables rapid prototyping, offering development of products with a remarkable time and cost reduction, and allows the creation of almost any shape, overcoming the difficulties of the conventional techniques. However, innovation always brings new risks and uncertainties about human exposure and hazards of the new materials, products, or by-products of the innovative technologies. It has been reported that from metal 3D printing procedures, volatile and non-volatile particles might be emitted, turning the people directly involved in the process and the other present in the facilities, potentially exposed to those emissions. Therefore, especial efforts must be imputed on risk assessments to particles emitted on occupational or domestic settings, from 3D printing activities. Addressing the exposure to airborne ultrafine particles during several metal 3D printing procedures, namely plasma metal deposition, wire arc additive manufacturing, wire-laser additive manufacturing and atmospheric pressure plasma deposition, this study evaluated the use of real-time portable equipment to characterise the exposure (in terms of number and size of particles). Different operating conditions were investigated, with different machines and materials. The airborne ultrafine particles emissions were characterised, and the efficiency of the implemented control measures was evaluated. Some limitations were found, and therefore as outcome from the study, some recommendations are proposed concerning the exposure mitigation and insights from the monitoring campaigns are provided.

Snapshots of wintertime urban aerosol characteristics: Local sources emphasized in ultrafine particle number and lung deposited surface area

Urban air fine particles are a major health-relating problem. However, it is not well understood how the health-relevant features of fine particles should be monitored. Limitations of PM2.5 (mass concentration of sub 2.5 μm particles), which is commonly used in the health effect estimations, have been recognized and, e.g., World Health Organization (WHO) has released good practice statements for particle number (PN) and black carbon (BC) concentrations (2021). In this study, a characterization of urban wintertime aerosol was done in three environments: a detached housing area with residential wood combustion, traffic-influenced streets in a city centre and near an airport. The particle characteristics varied significantly between the locations, resulting different average particle sizes causing lung deposited surface area (LDSA). Near the airport, departing planes had a major contribution on PN, and most particles were smaller than 10 nm, similarly as in the city centre. The high hourly mean PN (>20 000 1/cm3) stated in the WHO's good practices was clearly exceeded near the airport and in the city centre, even though traffic rates were reduced due to a SARS-CoV-2-related partial lockdown. In the residential area, wood combustion increased both BC and PM2.5, but also PN of sub 10 and 23 nm particles. The high concentrations of sub 10 nm particles in all the locations show the importance of the chosen lower size limit of PN measurement, e.g., WHO states that the lower limit should be 10 nm or smaller. Furthermore, due to ultrafine particle emissions, LDSA per unit PM2.5 was 1.4 and 2.4 times higher near the airport than in the city centre and the residential area, respectively, indicating that health effects of PM2.5 depend on urban environment as well as conditions, and emphasizing the importance of PN monitoring in terms of health effects related to local pollution sources.

Accurate measurements of particle emissions from a three-dimensional printer using a chamber test with a mixer-installed sampling system

Recently, three-dimensional (3D) printing has attracted attention as a new manufacturing technology. However, there is lack of data and regulations regarding the emissions of ultrafine particles from 3D printers. Therefore, we investigated particle emissions from a 3D printer using a chamber system. The test system was improved by installing a developed mixer for accurate measurement. Without a mixer, the particle concentration was unstable depending on the sampling point; however, reliable data with good uniformity were obtained by installing a mixer. Using the test system with a mixer, we investigated particle emissions from a 3D printer during operation. Filaments made each of acrylonitrile butadiene styrene (ABS) and polylactic acid (PLA) were used as the printing material. The effects of nozzle temperature and printing time were investigated. Compared to the effect of the printing time, the nozzle temperature had greater impact on the particle emissions. The dominant particle size for the emissions from a 3D printer is less than 10 nm, and the particle concentration decreased with increasing particle size.