Emissions Of Hazardous Air Pollutants Research Articles

Landfill reactions to society actions: The case of local and global air pollutants of Cerro Patacón in Panama

This paper studies landfill emissions and the related environmental and health risks in Panama City, with the aim to sensitize the population about the harmful effects of irresponsible resource consumption and non-deliberate solid waste generation that it is disposed of in an uncontrolled manner in landfills. Empirical data on Cerro Patacón, Panama City's landfill was obtained to describe the status of municipal waste disposal. Ten known methane generation models were used to estimate the yearly emission rate of methane from the landfill for a 100-year period starting from its inception in 1986. From the models used, the GasSIM model was chosen to estimate emission rates of six long-term hazardous air pollutants. The AERMOD source dispersion model was used to simulate their atmospheric downwind dispersion by levels of concentration over nearby affected communities; results were mapped in Google Earth. The relative contributions by population of the 32 towns making up Panama City to the forecasted waste generation in 2022 and related hazardous air pollutants emission rates from the landfill were assessed. It was found that Cerro Patacón will generate 45% of the countrywide methane generation by 2022; an average of 47 Gg. The solid waste generated by the 1.5 million inhabitants of Panama City impacts the health of ~73,600 inhabitants in nearby communities through the dispersion of hazardous atmospheric pollutants derived from the landfill. The highest emission rates were from hydrogen sulfide and dichloromethane, which can be largely attributed to the waste generated by the communities of Juan Diaz and Tocúmen. The concentration of hydrogen sulfide and benzene was over the reference concentration (uncertainty factor spanning three orders of magnitude) for all communities and years simulated. The concentration of vinyl chloride was over the RfC for all communities and years simulated, except in 2018 for 12 communities.

Atmospheric change as a driver of change in the Canadian boreal zone1

Global anthropogenic emissions of greenhouse gases and hazardous air pollutants have produced broad yet regionally disparate changes in climatic conditions and pollutant deposition in the Canadian boreal zone (the boreal). Adapting boreal resource management to atmospheric change requires a holistic understanding and awareness of the ongoing and future responses of terrestrial and freshwater ecosystems in this vast, heterogeneous landscape. To integrate existing knowledge of and generate new insights from the broad-scale impacts of atmospheric change, we first describe historical and present trends (∼1980–2015) in temperature, precipitation, deposition of hazardous air pollutants, and atmospheric-mediated natural disturbance regimes in this region. We then examine their associations with ecosystem condition and productivity, biological diversity, soil and water, and the carbon budget. These associations vary considerably among ecozones and likely undergo further changes under the emerging risks of atmospheric change. We highlight the urgent need to establish long-term, boreal-wide monitoring for many key components of freshwater ecosystems to better understand and project the influences of atmospheric change on boreal water resources. We also formulate three divergent future scenarios of boreal ecosystems in 2050. Our scenario analysis reveals multiple undesirable changes in boreal ecosystem structure and functioning with more variable atmospheric conditions and frequent land disturbances, while continuing business-as-usual management of natural resources. It is possible, though challenging, to reduce unwanted consequences to ecosystems through management regimes focussed on socio-ecological sustainability and developing resilient infrastructure and adaptive resource-management strategies. We emphasize the need for proactive actions and improved foresight for all sectors of society to collaborate, innovate, and invest in anticipation of impending global atmospheric change, without which the boreal zone will face a dim future.

Airborne Air Toxics Characteristics and Inhalation Health Risk Assessment of a Metropolitan Industrial Complex

ABSTRACT Air toxics, also well-known as hazardous air pollutants (HAPs), have significant health effects on human health and are of great concern. This paper studied a number of hazardous air pollutants in an industrial and metropolitan complex area in order to determine their ambient abundance and potential health impacts. The target pollutants in this study are benzene, formaldehyde, 1,3-butadiene, arsenic, 2,3,7,8-TCDD, and diesel particulate matter (DPM). A cancer risk assessment was conducted to determine the health effects of exposure to the six HAPs by using the AERMOD model. Results indicated that the emission of benzene, formaldehyde, 1,3-butadiene, arsenic and DPM was 184.5; 227.3; 68.0; 238, and 316 ton year–1, respectively, and the emission of 2,3,7,8-TCDD was 4,994 mg-TEQ year–1. Benzene (86%), formaldehyde (69%), and 1,3-butadiene (77%) were mainly emitted from on-road mobile sources. Arsenic (70%) and 2,3,7,8-TCDD (about 100%) were mainly emitted from stationary sources and DPM was emitted from diesel engines, port operations and ocean-going vessels. Spatial air toxic distribution indicated that the highest concentration of DMP, benzene, formaldehyde, and 1.3-butadiene occurred on the highway and in the downtown district due to their high traffic volume. DPM occupied more than 80% of total cancer risk in the region, followed by 1,3-butadiene, benzene, formaldehyde, arsenic, and 2,3,7,8-TCDD. In the industrial and residential complex area, about 99% of the cancer risk stemmed from on-road vehicles and port operations due to hazardous air pollutant emissions, especially DPM. The control scenario was made huge efforts to reduce the emission, however the results indicated only reduced the overall cancer risk assessment by 10%–15%. Policy makers have to think carefully about whether implementing the kind of emissions regulations simulated in this control scenario will need to be enhanced with additional measures to further reduce the risk of air pollution for human health.

Retrospective Evaluation of the Costs of Complying with Light-Duty Vehicle Surface Coating Requirements.

This paper compares the U.S. Environmental Protection Agency's (EPA) ex-ante compliance cost estimates for the 2004 Automobile and Light-Duty Truck Surface Coating National Emission Standards for Hazardous Air Pollutants to ex-post evidence on the actual costs of compliance based on ex-post cost data gathered from a subset of the industry via pilot survey and follow-up interviews. Unlike many prior retrospective studies on the cost of regulatory compliance, we use this newly-gathered information to identify the key drivers of any differences between the ex-ante and ex-post estimates. We find that the U.S. EPA overestimated the cost of compliance for the plants in our sample and that overestimation was driven primarily by differences in the method of compliance rather than differences in the perunit cost associated with a given compliance approach. In particular, the U.S. EPA expected facilities to install pollution abatement control technologies in their paint shops to reduce emissions of hazardous air pollutants, but instead these plants complied by reformulating coatings.

A preliminary effort to reduce carcinogenic polycyclic aromatic hydrocarbons from diesel exhaust by using different blends of diesel and synthesized Biodiesel

In the present investigation, an attempt for the reduction of six hazardous air Pollutants (HAPs) from diesel exhaust by different blends of diesel and biodiesel has been made. The synthesis of biodiesel has been done from Jetrofa, Linseed Castor and Karanja oils which are commonly used in the Indian market. Blending of diesel with biodiesel was done in different ratios (20 to 40 %) for the estimation of carcinogenic HAPs from the exhaust of a Honda engine (EBK 2010AC Model). The order of HAPs emission from engine exhaust by using diverse blends were Diesel>Jatropha-diesel>Linseed-diesel>Castor-diesel> Karanja-diesel. The maximum reduction of HAPs was established in the following ratio 40% (Biodiesel):60% (Diesel). B(a)P and Chrysene were the two individual aromatic hydrocarbons (AHCs) found in higher concentration in almost all blending fuels, ranging between 50 ng/µl to 101.1 ng/µl. The emission of almost all AHCs reduces by Blending of Diesel with Biodiesel. This was the first comprehensive information which showed the reduction of carcinogenic pollutants from diesel exhaust.

Concurrent improvements in crosslinking degree and interfacial adhesion of hemp fibers reinforced acrylated epoxidized soybean oil composites

Biocomposites with high performance and biobased contents were prepared from renewable feedstocks, i.e., hemp fibers (HFs) and acrylated epoxidized soybean oil (AESO). Two bifunctional isocyanates, i.e., isocyanatoethyl methacrylate (IEM) and 3-isopropenyldimethylbenzyl isocyanate (TMI), were used as reactive diluents for AESO, respectively. The incorporated IEM or TMI carrying both CC bonds and isocyanate groups not only crosslinked with the CC bonds of AESO by a free-radical polymerization, but also reacted with the –OH groups of both AESO and HFs to concurrently improve the unsaturation level of AESO monomers and the interfacial adhesion between HFs and AESO matrix, which was verified by FTIR and DSC analyses. Both IEM-AESO and TMI-AESO resins exhibited favorable viscosities and curing temperatures for the production of HFs-reinforced composites while without the emission of hazardous air pollutants. The composite with 15 wt% IEM modified AESO (based on the total weight of IEM-AESO blend) had comparable tensile and flexural strengths with the composite from 30 wt% styrene; while the 15 wt% TMI resulting composite obtained higher tensile strength and modulus as well as flexural strength and modulus than the composites from 15 wt% IEM or 30 wt% styrene. This indicated that TMI has a higher reinforcing efficiency on the composites than IEM. Significant improvements in storage modulus, glass transition temperature, and water resistance were obtained for the composites from IEM or TMI relative to the composite from pure AESO resin, which is attributed to the simultaneously improved crosslinking density and interfacial adhesion of the composites as confirmed by SEM analysis.

Hazardous air pollutants and primary liver cancer in Texas.

The incidence of hepatocellular carcinoma (HCC), the most common primary liver cancer, is increasing in the US and tripled during the past two decades. The reasons for such phenomenon remain poorly understood. Texas is among continental states with the highest incidence of liver cancer with an annual increment of 5.7%. Established risk factors for HCC include Hepatitis B and C (HBV, HCV) viral infection, alcohol, tobacco and suspected risk factors include obesity and diabetes. While distribution of these risk factors in the state of Texas is similar to the national data and homogeneous, the incidence of HCC in this state is exceptionally higher than the national average and appears to be dishomogeneous in various areas of the state suggesting that other non-recognized risk factors might play a role. No population-based studies are currently available investigating the effect of exposure to Hazardous Air Pollutants (HAPs) as a contributing risk factor for liver cancer. Incidence rate of liver cancer in Texas by counties for the time period between 2002 and 2012 was obtained from the Texas Cancer Registry (TCR). Through Principal Component Analysis (PCA) a subgroup of pollutants, explaining almost all the dataset variability, were identified and used to cluster Texas counties. The analysis generated 4 clusters showing liver cancer rate either higher or lower than national average in association with either high or low levels of HAPs emission in the environment. The study shows that the selected relevant HAPs, 10 among 253 analyzed, produce a significant correlation (P = 0.01–0.05) and some of these have been previously identified as carcinogens. An association between the increased production and consequent exposure to these HAPs and a higher presence of liver cancer in certain counties is suggested. This study provides a new insight on this complex multifactorial disease suggesting that environmental substances might play a role in the etiology of this cancer.

The impact of various ethanol-gasoline blends on particulates and unregulated gaseous emissions characteristics from a spark ignition direct injection (SIDI) passenger vehicle

This study investigated the effects of various ethanol-gasoline blends on the hazardous air pollutants (HAPs) emissions from a wall-guided direct injection passenger vehicle. The fuel economy (FE) as well as regulated and unregulated gaseous emissions was evaluated on a chassis dynamometer using the federal test procedure (FTP-75) mode. Five fuels with varying ethanol contents of E0, E10, E30, E50, and E85 were prepared by blending ethanol into commercial gasoline on a volumetric basis and were analyzed each fuel specification. The engine control schemes of fuel injection quantity for various ethanol blends were adjusted to optimize the engine starting capability, vehicle drivability and emissions performance. The FE of the E85 fueled vehicle decreased by 29% relative to gasoline fuel due to the low energy content of ethanol. Blending ethanol into gasoline produced a dramatic decrease of particulate emission, because pure ethanol has no aromatic compounds and carbon content lower than that of gasoline. As a result, nano-particles were rarely emitted in the vehicle tests of fuels with more than 30% ethanol. Carbonyl compounds emissions, which originate from partial oxidization or incomplete combustion of ethanol, also rose sharply as the ethanol content increased, while volatile organic compound (VOC) emissions were reduced considerably with medium- and high-ethanol formulations due to the lower proportion of aromatic components in these fuels.

Health risk assessment of volatile organic compounds in urban areas

ABSTRACTThe atmosphere is the first medium containing hazardous compounds entering the living environment. Metropolitan areas contain many industrial complex areas with high emissions of volatile organic compounds (VOCs), and consequently also large-scale exposure groups. As respiration is the most important part of the human exposure pathway, the atmosphere should be treated with greater importance than other media. It is therefore very important to monitor the emission of hazardous air pollutants (HAPs) and measure the concentration of VOCs in the atmosphere of such areas. It is essential to establish basic measures in order to protect public health as part of overall national safety management. This study utilized the national air pollution monitoring network data from Seoul, Incheon, and Gyeonggi, and investigated the differences in risk levels for humans considering various factors of the receptors, including gender and age. A total of 13 VOCs were categorized into carcinogens and noncarcinogens for risk assessment. The carcinogens 1,3-butadiene and benzene demonstrated a high level of cancer risk, ranging between 10−4 and 10−6, respectively. Noncarcinogens did not exceed Hazard Quotient (HQ) 1 in any area. The results will serve as important references for managing urban air environments and setting air quality standards.

Historical and future emission of hazardous air pollutants (HAPs) from gas-fired combustion in Beijing, China.

The consumption of natural gas in Beijing has increased in the past decade due to energy structure adjustments and air pollution abatement. In this study, an integrated emission inventory of hazardous air pollutants (HAPs) emitted from gas-fired combustion in Beijing was developed for the period from 2000 to 2014 using a technology-based approach. Future emission trends were projected through 2030 based on current energy-related and emission control policies. We found that emissions of primary HAPs exhibited an increasing trend with the rapid increase in natural gas consumption. Our estimates indicated that the total emissions of NO X , particulate matter (PM)10, PM2.5, CO, VOCs, SO2, black carbon, Pb, Cd, Hg, As, Cr, Cu, Ni, Zn, polychlorinated dibenzo-p-dioxins and dibenzofurans, and benzo[a]pyrene from gas-fired combustion in Beijing were approximately 22,422t, 1042t, 781t, 19,097t, 653t, 82t, 19t, 0.6kg, 0.1kg, 43kg, 52kg, 0.3kg, 0.03kg, 4.3kg, 0.6kg, 216μg, and 242g, respectively, in 2014. To mitigate the associated air pollution and health risks caused by gas-fired combustion, stricter emission standards must be established. Additionally, combustion optimization and flue gas purification system could be used for lowering NO X emissions from gas-fired combustion, and gas-fired facilities should be continuously monitored based on emission limits. Graphical abstract Spatial distribution and typical live photos of gas-fired boiler in Beijing.

Effects of Clean Air Act on Patenting Activities in Chemical Industry: Learning from Past Experiences

The chemical industry provides essential goods we use in our daily lives and key ingredients for many diverse industries. On the other hand, their production and use require serious attention while they may be seriously harmful to local air quality. The Clean Air Act (CAA) and its subsequent amendments regulate the emissions of hazardous air pollutants to protect public health and welfare in the U.S.A. since 1970. This study aimed to assess the impact of CAA on the rate of patenting in the chemical industry. With this in mind, basic chemical utility patents were analyzed to detect the effects of CAA on the patenting activities. Subsequent to the fitting of the ARIMA (Autoregressive Integrated Moving Average) model (producing the least square of errors), a significant outlier was detected with the Dixon’s r22 Ratio Test. This outlier was the number of patents granted in 1972. Contextual queries in the text of those patent documents have shown that there was a considerable increase in the patents of chemistry which takes the sustainability relevant terms (air, emission, pollution, etc.) into consideration. It was concluded that companies in the chemistry industry adapted themselves very rapidly to the changes and CAA was an important incentive to create novel technologies.

Enhanced propellant performance via environmentally friendly curable surface coating

Abstract Surface coating of granular propellants is widely used in a multiplicity of propellants for small, medium and large caliber ammunition. All small caliber ball propellants exhibit burning progressivity due to application of effective deterrent coatings. Large perforated propellant grains have also begun utilizing plasticizing and impregnated deterrent coatings with the purpose of increasing charge weights for greater energy and velocity for the projectile. The deterrent coating and impregnation process utilizes volatile organic compounds (VOCs) and hazardous air pollutants (HAPs) which results in propellants that need to be forced air dried which impacts air quality. Propellants undergo temperature fluctuations during their life. Diffusion coefficients vary exponentially with variations in temperature. A small temperature increase can induce a faster migration, even over a short period of time, which can lead to large deviations in the concentration. This large concentration change in the ammunition becomes a safety or performance liability. The presence of both polymeric deterrents and nitroglycerin(NG) in the nitrocellulose matrix and organic solvents leads to higher diffusion rates. This results in continued emissions of VOCs and HAPs. Conventional polymers tend to partition within the propellant matrix. In other words, localized mixing can occur between the polymer and underlying propellant. This is due to solvent induced softening of the polymer vehicle over the propellant grain. In effect this creates a path where migration can occur. Since nitrate esters, like NG, are relatively small, it can exude to the surface and create a highly unstable and dangerous situation for the warfighter. Curable polymers do not suffer from this partitioning due to “melting” because no VOC solvents are present. They remain surface coated. The small scale characterization testing, such as closed bomb testing, small scale sensitivity, thermal stability, and chemical compatibility, will be presented. The 30 mm gun demonstration firing data at hot, cold, and ambient temperatures will also be presented.

Soot, organics, and ultrafine ash from air- and oxy-fired coal combustion

Pulverized bituminous coal was burned in a 10W externally heated entrained flow furnace under air-combustion and three oxy-combustion inlet oxygen conditions (28, 32, and 36%). Experiments were designed to produce flames with practically relevant stoichiometric ratios (SR=1.2–1.4) and constant residence times (2.3s). Size-classified fly ash samples were collected, and measurements focused on the soot, elemental carbon (EC), and organic carbon (OC) composition of the total and ultrafine (<0.6µm) fly ash. Results indicate that although the total fly ash carbon, as measured by loss on ignition, was always acceptably low (<2%) with all three oxy-combustion conditions lower than air-combustion, the ultrafine fly ash for both air-fired and oxy-fired combustion conditions consists primarily of carbonaceous material (50–95%). Carbonaceous components on particles <0.6µm measured by a thermal optical method showed that large fractions (52–93%) consisted of OC rather than EC, as expected. This observation was supported by thermogravimetric analysis indicating that for the air, 28% oxy, and 32% oxy conditions, 14–71% of this material may be OC volatilizing between 100°C and 550°C with the remaining 29–86% being EC/soot. However, for the 36% oxy condition, OC may comprise over 90% of the ultrafine carbon with a much smaller EC/soot contribution. These data were interpreted by considering the effects of oxy-combustion on flame attachment, ignition delay, and soot oxidation of a bituminous coal, and the effects of these processes on OC and EC emissions. Flame aerodynamics and inlet oxidant composition may influence emissions of organic hazardous air pollutants (HAPs) from a bituminous coal. During oxy-coal combustion, judicious control of inlet oxygen concentration and placement may be used to minimize organic HAP and soot emissions.

Trends of multiple air pollutants emissions from residential coal combustion in Beijing and its implication on improving air quality for control measures

Residential coal combustion is considered to be an important source of air pollution in Beijing. However, knowledge regarding the emission characteristics of residential coal combustion and the related impacts on the air quality is very limited. In this study, we have developed an emission inventory for multiple hazardous air pollutants (HAPs) associated with residential coal combustion in Beijing for the period of 2000–2012. Furthermore, a widely used regional air quality model, the Community Multi-Scale Air Quality model (CMAQ), is applied to analyze the impact of residential coal combustion on the air quality in Beijing in 2012. The results show that the emissions of primary air pollutants from residential coal combustion have basically remained the same levels during the past decade, however, along with the strict emission control imposed on major industrial sources, the contribution of residential coal combustion emissions to the overall emissions from anthropogenic sources have increased obviously. In particular, the contributions of residential coal combustion to the total air pollutants concentrations of PM10, SO2, NOX, and CO represent approximately 11.6%, 27.5%, 2.8% and 7.3%, respectively, during the winter heating season. In terms of impact on the spatial variation patterns, the distributions of the pollutants concentrations are similar to the distribution of the associated primary HAPs emissions, which are highly concentrated in the rural-urban fringe zones and rural suburb areas. In addition, emissions of primary pollutants from residential coal combustion are forecasted by using a scenario analysis. Generally, comprehensive measures must be taken to control residential coal combustion in Beijing. The best way to reduce the associated emissions from residential coal combustion is to use economic incentive means to promote the conversion to clean energy sources for residential heating and cooking. In areas with reliable energy supplies, the coal used for residential heating can be replaced with gas-burning wall-heaters, ground-source heat pumps, solar energy and electricity. In areas with inadequate clean energy sources, low-sulfur coal should be used instead of the traditional raw coal with high sulfur and ash content, thereby slightly reducing the emissions of PM, SO2, CO and other toxic pollutants.

The importance of toxicity in determining the impact of hazardous air pollutants on the respiratory health of children in Tennessee

Respiratory diseases, exacerbated through point source pollution, are currently among the leading causes of hospitalization of children in the United States. This paper investigates the relationship between the proximity of hazardous air pollutants (HAPs) emitted from Toxic Release Inventory (TRI) facilities and the number of children diagnosed in hospitals with a respiratory disease in Tennessee. The importance of controlling for toxicity of those HAPs is of particular interest. Hospital discharge, socioeconomic, TRI emission, and HAP toxicity data are used to estimate, via Generalized Linear Methods, a logistic regression model describing the relationship between the percent of children living in a zip code area treated for respiratory illness and the average annual emissions over the previous 10 years of HAPs from TRI sites in that area. Controlling for area socioeconomic characteristics, we find that accounting for toxicity is important in uncovering the relationship between HAP emissions and respiratory health of children. A one standard deviation increase in toxicity-weighted emissions per 100 square miles is associated with an increase in the number of children diagnosed with asthma (chronic bronchitis) by about 1205 (260). The evidence suggests that, with a goal to improving children’s respiratory health, monitoring the toxicity of chemicals being emitted is at least as important as simply monitoring total emission levels. This suggests that the EPA should consider making efforts toward establishing toxicity adjusted emission guidelines.

A comprehensive emission inventory of multiple air pollutants from iron and steel industry in China: Temporal trends and spatial variation characteristics

China has become the largest producer of iron and steel throughout the world since 1996. However, as an energy-and-pollution intensive manufacturing sector, a detailed comprehensive emission inventory of air pollutants for iron and steel industry of China is still not available. To obtain and better understand the temporal trends and spatial variation characteristics of typical hazardous air pollutants (HAPs) emissions from iron and steel production in China, a comprehensive emission inventory of multiple air pollutants, including size segregated particulate matter (TSP/PM10/PM2.5), gaseous pollutants (SO2, NOx, CO), heavy metals (Pb, Cd, Hg, As, Cr, Ni etc.), as well as the more dangerous PCDD/Fs, is established with the unit-based annual activity, specific dynamic emission factors for the historical period of 1978–2011, and the future potential trends till to 2050 are forecasted by using scenario analysis. Our results show that emissions of gaseous pollutants and particulate matter have experienced a gradual increase tendency since 2000, while emissions of priority-controlled heavy metals (Hg, Pb, As, Cd, Cr, and Ni) have exhibited a short-term fluctuation during the period of 1990 to 2005. With regard to the spatial distribution of HAPs emissions in base year 2011, Bohai economic circle is identified as the top emission intensity region where iron and steel smelting plants are densely built; within iron and steel industry, blast furnaces contribute the majority of PM emissions, sinter plants account for most of gaseous pollutants and the majority of PCDD/Fs, whereas steel making processes are responsible for the majority of heavy metal emissions. Moreover, comparisons of future emission trends under three scenarios indicate that advanced technologies and integrated whole process management strategies are in great need to further diminish various hazardous air pollutants from iron and steel industry in the future.

Volatile and semivolatile organic compounds in laboratory peat fire emissions

In this study, volatile and semi-volatile organic compound (VOCs and SVOCs) mass emission factors were determined from laboratory peat fire experiments. The peat samples originated from two National Wildlife Refuges on the coastal plain of North Carolina, U.S.A. Gas- and particle-phase organic compounds were quantified by gas chromatography-mass spectrometry and by high pressure liquid chromatography. Hazardous air pollutants (HAPs) accounted for a large fraction (∼60%) of the speciated VOC emissions from peat burning, including large contributions of acetaldehyde, formaldehyde, benzene, toluene, and chloromethane. In the fine particle mass (PM2.5), the following organic compound classes were dominant: organic acids, levoglucosan, n-alkanes, and n-alkenes. Emission factors for the organic acids in PM2.5 including n-alkanoic acids, n-alkenoic acids, n-alkanedioic acids, and aromatic acids were reported for the first time for peat burning, representing the largest fraction of organic carbon (OC) mass (11–12%) of all speciated compound classes measured in this work. Levoglucosan contributed to 2–3% of the OC mass, while methoxyphenols represented 0.2–0.3% of the OC mass on a carbon mass basis. Retene was the most abundant particulate phase polycyclic aromatic hydrocarbon (PAH). Total HAP VOC and particulate PAH emissions from a 2008 peat wildfire in North Carolina were estimated, suggesting that peat fires can contribute a large fraction of state-wide HAP emissions.

Catalytic Destruction of a Surrogate Organic Hazardous Air Pollutant as a Potential Co-benefit for Coal-Fired Selective Catalytic Reduction Systems

Catalytic destruction of benzene (C6H6), a surrogate for organic hazardous air pollutants (HAPs) produced from coal combustion, was investigated using a commercial selective catalytic reduction (SCR) catalyst for evaluating the potential co-benefit of the SCR technology for reducing organic HAP emissions. Bench-scale experiments were performed using simulated coal combustion flue gases under a broad range of SCR reaction conditions. C6H6 was added at 1 or 17 ppm into the flue gas mixtures with different concentrations of sulfur dioxide (SO2), nitrogen oxide (NO), hydrogen chloride (HCl), and ammonia (NH3) to simulate the combustion of bituminous and sub-bituminous coals. The destruction of the C6H6 across the catalyst was measured by a total hydrocarbon analyzer and a resonance-enhanced multiphoton ionization time-of-flight mass spectrometer (REMPI–TOFMS) for the experiments with high (17 ppm) and low (1 ppm) concentrations of C6H6, respectively. The operating parameters of the SCR process, including the ...

Atmospheric emission inventory of hazardous air pollutants from China's cement plants: Temporal trends, spatial variation characteristics and scenario projections

Abstracts A multiple-year comprehensive emission inventory of typical hazardous air pollutants (HAPs) from China's cement industry for the period 1980–2012, has been established by using technology-based dynamic emission factors and detailed annual plant-specific cement production from different types of kilns. Our results show that the total emissions of various HAPs (SO 2 , NO X , CO, PM, Hg, Cd, Cr, Pb, Zn, As, Ni and Cu) have rapidly increased by about 1–21 times at an annual average growth rate of 1–10% over the past three decades. Remarkably uneven spatial allocation features of these pollutants among provinces are observed. HAPs emissions are primarily concentrated in the eastern and coastal provinces due to the concentration of cement plants and their huge volume of coal consumption. We predict the future emission trends of HAPs through 2050 based on industry construction and policy guidance, and our scenario analysis indicates that HAPs emissions will drop substantially because of the combined effects of cement production yields reduction and the increasing application rate of various air pollution control devices. The study suggests that highlighted attention should be paid to this energy-intensive industry to ensure stricter emission standards are implemented for these HAPs emissions in the future.

Present and future emissions of HAPs from crematories in China

Abstract China is the most populous country in the world. The amount of death population has reached 9.65 million and 49.5% of human corpses are cremated by about 1700 crematories spread throughout the country in 2012, leading to considerable discharge of various hazardous air pollutants (HAPs) into the atmosphere and great concerns on regional air quality and health risks for surrounding residents. By using the practicable or best available emission factors, for the first time, a multiple-year emission inventory of typical hazardous air pollutants discharged from crematories in the Chinese mainland, has been established for the historical period of 1990–2012, and the future trends of HAPs emissions until 2030 are forecasted based on three scenarios analysis. Our results show that the total emissions have gradually increased to 906 t of NO X , 443 t of SO 2 , 2713 t of CO, 477.7 t of PM, 377 t of HCl, 36 t of H 2 S, 25 t of NH 3 , 62 t of NMVOCs, 592 kg of Hg, 48 kg of Pb, 14 kg of Cd, 53 kg of As, 40 kg of Cr, 37 kg of Cu, 51 kg of Ni, and 96 g of PCDD/Fs as TEQ (toxic equivalent quantity) by the year 2012. Under the business-as-usual (BAU) scenario, various HAPs emitted from cremators would continuously increase with an average growth rate of 3% till to 2030; whereas the emissions will peak at around 2015 and then decline gradually with varied speed under the two improved control scenarios. To mitigate the associated air pollution and health risks caused by crematories, it is of great necessary for implementing more strict emission standards, applying combustion optimization and requiring installation of best available flue gas purification system, as well as powerful supervision for sound operation of crematories.